CN105360162A - Compound potassium hydrogen persulfate powder sanitizer and preparation method thereof - Google Patents

Compound potassium hydrogen persulfate powder sanitizer and preparation method thereof Download PDF

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CN105360162A
CN105360162A CN 201410426347 CN201410426347A CN105360162A CN 105360162 A CN105360162 A CN 105360162A CN 201410426347 CN201410426347 CN 201410426347 CN 201410426347 A CN201410426347 A CN 201410426347A CN 105360162 A CN105360162 A CN 105360162A
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sodium chloride
disinfectant
wall material
oxone
coated
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CN 201410426347
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Chinese (zh)
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张许科
刘兴金
高富红
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洛阳惠中兽药有限公司
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Abstract

The invention provides a compound potassium hydrogen persulfate powder sanitizer and a preparation method thereof. The sanitizer contains a sodium chloride wrapping substance. The sodium chloride wrapping substance is composed of a wrapped core material and a wrapping wall material, wherein the wrapping wall material is any one of high polymer slow release carriers including starch, methylcellulose, hydroxymethyl cellulose, Arabic gum and polyacrylic resin. Compared with an ordinary compound potassium hydrogen persulfate powder sanitizer with unwrapped sodium chloride, the compound potassium hydrogen persulfate powder sanitizer is not prone to moisture absorption, capable of preventing sodium chloride from making contact with an react with other components and high in stability.

Description

复合过硫酸氢钾粉消毒剂及其制备方法 Potassium hydrogen compound powder disinfectant and preparation method

技术领域 FIELD

[0001] 本发明涉及一种禽畜用消毒剂及其制备方法,特别是一种复合过硫酸氢钾粉消毒剂及其制备方法。 [0001] The present invention relates to a poultry disinfectant preparation method thereof, particularly to a powder disinfectant potassium bisulfate and preparation method too.

背景技术 Background technique

[0002] 消毒是杀灭环境中的各种病原微生物、切断传播途径的一项重要措施。 [0002] disinfection is to kill a variety of pathogenic microorganisms in the environment, an important measure to cut off the route of transmission. 随着现代养殖业的迅速发展,人们越来越重视消毒剂在预防和控制动物疫病中的应用。 With the rapid development of modern aquaculture industry, there is growing emphasis disinfectant in the prevention and control of animal diseases.

[0003]目前常用的消毒剂大概有以下几类,即醇类、酸类、氯制剂类、碘类、过氧化物类、 醛类、酚类、季铵盐类等。 [0003] The most commonly used disinfectant about the following categories, i.e., alcohols, acids, chlorine-based agents, iodine, peroxides, aldehydes, phenols, quaternary ammonium salts. 市场上常见的有过氧乙酸、戊二醛、聚维酮碘、季铵盐等。 Common are peracetic acid, glutaraldehyde, povidone iodine, quaternary ammonium salts on the market. 上述消毒剂均含有各自的缺点,如稳定性差、腐蚀性大、刺激性强、抗菌谱窄等,有的甚至还有致癌的危险,所以在临床应用上存在一定的局限性。 Disinfectants contain the above-described respective disadvantages, such as poor stability, high corrosion resistance, strong irritant, narrow antimicrobial spectrum, and some even the risk of cancer, there are some limitations on the clinical applications. 因此,在动物疫病日益复杂,改善饲养环境的观念日益加强的今天,生产一种绿色环保、高效稳定的消毒剂,已成为大势所趋。 Therefore, in an increasingly complex animal diseases, improve the breeding environment increasingly strengthened the idea today, to produce a green, highly efficient and stable disinfectant, it has become a trend.

[0004] 专利CN1545883A公开了一种复合过硫酸氢钾粉消毒剂,作为一种绿色、高效的消毒剂,能杀灭各种细菌和病毒,对操作者刺激性和腐蚀性小。 [0004] Patent No. CN1545883A discloses a composite powder oxone disinfectant, as a green and efficient disinfectant, can kill a variety of bacteria and viruses, small irritating and corrosive to the operator. 此产品密封保存时,不与外界接触,其产品的稳定性较强。 This product is sealed when not in contact with the outside world, the stability of its strong products. 但是,在其放置、使用过程中,容易受潮,尤其是其成分氯化钠在潮解后,能与过硫酸氢钾反应,产生氯气,以及与有机酸反应,产生氢离子、氧自由基等, 均能导致有效成分下降。 However, in its place, during use, easy to damp, in particular sodium chloride, after which component deliquescence, to the reaction with oxone to produce chlorine gas, as well as organic acids, to generate hydrogen ions, oxygen radicals, the active ingredient can lead to decline. 因此,如何解决产品易吸潮的问题,提高复合过硫酸氢钾粉消毒剂的稳定性,一直是本领域长期面临的一个技术难题。 So, how to solve the problem the product easy to absorb moisture and improve the complex oxone powder disinfectant stability, it has been a long-term technical problems faced by the art.

发明内容 SUMMARY

[0005] 本发明的目的在于提供一种不易吸潮,组份稳定的复合过硫酸氢钾粉消毒剂以及其制造方法。 [0005] The object of the present invention is to provide an easy to absorb moisture, a stable complex components oxone disinfectant powder and a manufacturing method.

[0006] 上述复合过硫酸氢钾粉消毒剂之特征在于,其含有过硫酸氢钾和氯化钠包被物。 [0006] The compound had oxone characterized in that the disinfectant powder, containing oxone and sodium chloride was coated.

[0007] 上述氯化钠包被物由被包覆的芯材和用于包覆的壁材组成。 [0007] The sodium chloride was coated by the wall material and core material are coated in a coating composition. 所述被包覆的芯材为呈颗粒状、粒径100μm~1000μm的氯化钠;所述用于包覆的壁材为淀粉、甲基纤维素、羟甲基纤维素、阿拉伯胶、聚丙烯酸树脂中任何一种的高分子缓释载体。 The coated granular core material, particle diameter of 100 m - 1000 m NaCl; for the wall material is coated with starch, methyl cellulose, hydroxymethyl cellulose, gum arabic, poly any resin acrylic polymer slow release carrier.

[0008] 根据本发明所提出的复合过硫酸氢钾粉消毒剂,其各组分的质量配比为:过硫酸氢钾20 %~65 %,氯化钠包被物1. 5 %~32 %,其他成分,包括有机酸、阴离子表面活性剂、 助洗剂、稀释剂3%~78. 5%。 [0008] Oxone sterilant composite powder provided by the present invention, the components of which mass ratio of: oxone 20% to 65%, sodium chloride 1.5% was coated with 32 ~ %, other ingredients include organic acids, anionic surfactants, builders, diluents, 3% to 78.5%.

[0009] 本发明还提供了一种复合过硫酸氢钾粉消毒剂的制备方法,其特征在于采用流化床干燥法制备氯化钠包被物,将氯化钠包被物与过硫酸氢钾及其它成分混合,用于制备复合过硫酸氢钾粉消毒剂。 [0009] The present invention further provides a method for preparing potassium hydrogen sulfate composite powder had disinfectant, characterized in that a fluidized-bed coating sodium sulfate was prepared, and sodium chloride was coated hydrogenmonopersulfate potassium and other ingredients for preparing the composite powder oxone disinfectant.

[0010] 所述的流化床干燥法制备氯化钠包被物,具体包括以下步骤: [0010] Preparation of the fluidized bed of sodium chloride dried coating composition, includes the following steps:

[0011] 1.将所述的壁材与水按照0. 005:1~0. 20:1的比例混合,制成有粘合剂效果的糊化壁材; . [0011] 1. The wall material with water at a 0.005: 1 to 020: 1 ratio, wall materials made of pasting an adhesive effect;

[0012] 2.将所述糊化壁材与氯化钠按按照0. 3:1~0. 8:1的比例混合均匀,形成氯化钠与糊化载体的混合物; . [0012] 2. The wall material and sodium chloride gelatinized press according to 0.3: 1 to 08: 1 ratio of homogeneous mixing, to form a mixture of sodium chloride and gelatinized carrier;

[0013] 3.将干燥壁材与上述混合物按照0. 4:1~1:1的比例称取,加入制粒机中,再喷入上述混合物,混合均匀,进行制粒,制成氯化钠包被物。 [0013] 3. The dry wall material in accordance with the above mixture 0.4: 1 to 1: 1 was weighed, added to a granulator, and then injected into the above mixture, uniformly mixed, granulated, made chloride sodium coating composition.

具体实施方式 Detailed ways

[0014] 下面结合具体实施例来进一步描述本发明,本发明的优点和特点将会随着描述更为清楚。 [0014] The following specific examples further describe the present invention in conjunction with, advantages, and features of the invention will become more apparent as the description. 但这些实施例仅是范例性的,并不对本发明的范围构成任何限制。 However, these examples are merely exemplary, and does not constitute any limitation on the scope of the invention. 本领域技术人员应该理解的是,在不偏离本发明的精神和范围下可以对本发明技术方案的细节和形式进行修改或替换,但这些修改和替换均落入本发明的保护范围内。 Those skilled in the art will appreciate that modifications or substitutions can be made in the form and details of the technical solutions of the present invention without departing from the spirit and scope of the present invention, but such modifications and alterations fall within the scope of the present invention.

[0015] 根据本发明所提出的复合过硫酸氢钾粉消毒剂,其所用原料的具体信息为: [0015] Oxone The composite powder of the present invention proposed a disinfectant, they use specific information for the starting material:

[0016] 过硫酸氢钾,含量99. 0%,购于吴江市南风精细化工有限公司,批号20111001; [0016] oxone, content 99.0%, available from Wujiang southerly Fine Chemical Co., lot number 20111001;

[0017] 氯化钠,含量99. 5%,购于天津市风船化学试剂科技有限公司,批号20110318; [0017] The sodium chloride content 99.5%, was purchased from Tianjin Chemical Reagent Co., Ltd. sailboat, lot number 20110318;

[0018] 淀粉,购于曲阜市药用辅料有限公司,批号20110502; [0018] starch, commercially available in a pharmaceutically acceptable excipient Qufu Co., lot number 20110502;

[0019] 甲基纤维素,含量99. 0%,购于广州市淇盛化工有限公司,批号20110601; [0019] Methyl cellulose content of 99.0%, purchased from Guangzhou Qi Sheng Chemical Co., Ltd., batch number 20110601;

[0020] 羟甲基纤维素,含量99. 0%,购于润辉化工有限公司,批号20101203; [0020] hydroxymethylcellulose, content 99.0%, available from Run-Chemical Co., lot number 20101203;

[0021] 阿拉伯胶,含量99. 0%,购于武汉但兴生物科技有限公司,批号20101101 ; [0021] gum arabic, content 99.0%, but purchased from Wuhan Xing Biotechnology Co., Ltd., batch number 20101101;

[0022] 聚丙烯酸树脂,含量45.0%,购于山东云清新技术开发有限公司,批号20110703。 [0022] The polyacrylic acid resin, the content of 45.0%, available from Shandong cloud fresh Technology Development Co., lot number 20110703.

[0023] 根据本发明所提出的复合过硫酸氢钾粉消毒剂,其各组分的质量配比为:过硫酸氢钾20 %~65 %,氯化钠包被物1. 5 %~32 %,其他成分,包括有机酸、阴离子表面活性剂、 助洗剂、稀释剂3%~78. 5%。 [0023] Oxone sterilant composite powder provided by the present invention, the components of which mass ratio of: oxone 20% to 65%, sodium chloride 1.5% was coated with 32 ~ %, other ingredients include organic acids, anionic surfactants, builders, diluents, 3% to 78.5%.

[0024] 其中所述有机酸是指一组具有酸性的有机化合物,如氨基磺酸、柠檬酸、苹果酸、 酒石酸、草酸、枸橼酸、水杨酸。 [0024] wherein the organic acid is an organic compound having a group of acidity, such as amino acids, citric acid, malic acid, tartaric acid, oxalic acid, citric acid, salicylic acid.

[0025] 所述阴离子表面活性剂是指在水中电离后起表面活性作用的部分带负电荷的表面活性剂,包括但不限于烷基硫酸钠、十二烷基苯磺酸钠、烷基磺酸钠、脂肪醇硫酸脂拿、仲烷基硫酸钠、油酰氨基酸钠。 [0025] The anionic surfactant refers to a surfactant with a negatively charged portion of the surface activity of the newcomer ionized water, including but not limited to sodium lauryl sulfate, sodium dodecylbenzene sulfonate, alkyl sulfonate sodium, aliphatic fatty alcohol sulfates take, secondary alkyl sulfate, sodium amino acid oil.

[0026] 所述助洗剂是指本身没有明显的洗涤能力,但能增强表面活性剂的洗涤去污能力的一种物质,包括但不限于三聚磷酸钠、碳酸钠、硅酸钠、硫酸钠、柠檬酸钠、聚丙烯酸。 [0026] The builder itself refers to no significant cleaning ability, but can enhance the detergency of a substance detergent surfactants, including, but not limited to, sodium tripolyphosphate, sodium carbonate, sodium silicate, sulfuric acid , sodium citrate, polyacrylic acid.

[0027] 所述"稀释剂"是指为了便于混合所加入的进行稀释的惰性物质,如陶土、滑石粉。 [0027] The "diluent" refers to facilitate mixing of the dilution was added an inert substance such as clay, talc.

[0028] 实施例1 [0028] Example 1

[0029] -种复合过硫酸氢钾粉消毒剂,其各组分的质量配比为过硫酸氢钾20%,氯化钠包被物1. 5%,有机酸、阴离子表面活性剂、助洗剂、稀释剂78. 5%。 [0029] - Compound Species oxone disinfectant powder, the mass ratio of the components thereof oxone 20%, sodium chloride 1.5% was coated, an organic acid, an anionic surfactant, co lotion, thinner 78.5%.

[0030] 本实施例的氯化钠包被物由被包覆的芯材和用于包覆的壁材组成。 [0030] package of the present embodiment is sodium chloride was coated by a core material and a wall material for coating compositions. 所述被包覆的芯材为呈颗粒状、粒径100μm~1000μm的氯化钠;所述用于包覆的壁材为淀粉、甲基纤维素、羟甲基纤维素、阿拉伯胶、聚丙烯酸树脂中任何一种的高分子缓释载体。 The coated granular core material, particle diameter of 100 m - 1000 m NaCl; for the wall material is coated with starch, methyl cellulose, hydroxymethyl cellulose, gum arabic, poly any resin acrylic polymer slow release carrier.

[0031] 所述氯化钠包被物采用以下制法得到: [0031] The coated sodium chloride was employed to obtain the following method:

[0032] 1.将所述的壁材与水按照0. 005:1~0. 20:1的比例混合,制成有粘合剂效果的糊化壁材; [0032] 1. The wall material with water at a 0.005: 1 to 020: 1 ratio, wall materials made of pasting an adhesive effect;

[0033]2.将所述糊化壁材与氯化钠按按照0. 3:1~0. 8:1的比例混合均匀,形成氯化钠与糊化载体的混合物; [0033] 2 the wall material and sodium chloride according gelatinized 0.3 Press: 1 to 08: 1 ratio mixed to form a mixture of sodium chloride and gelatinized carrier;.

[0034] 3.将干燥壁材与上述混合物按照0. 4:1~1:1的比例称取,加入制粒机中,再喷入上述混合物,混合均匀,进行制粒,制成氯化钠包被物。 [0034] 3. The dry wall material in accordance with the above mixture 0.4: 1 to 1: 1 was weighed, added to a granulator, and then injected into the above mixture, uniformly mixed, granulated, made chloride sodium coating composition.

[0035] 将上述氯化钠包被物与过硫酸氢钾及其它成分混合,制备复合过硫酸氢钾粉消毒剂。 [0035] The above-described chloride was coated with oxone and other ingredients were mixed to prepare a composite powder oxone disinfectant.

[0036] 实施例2 [0036] Example 2

[0037] -种复合过硫酸氢钾粉消毒剂,其各组分的质量配比为过硫酸氢钾40%,氯化钠包被物5%,有机酸、阴离子表面活性剂、助洗剂、稀释剂55%。 [0037] - Compound Species oxone disinfectant powder, the mass ratio of the components thereof oxone 40%, was coated with 5% sodium chloride, an organic acid, an anionic surfactant, builder , 55% thinner.

[0038] 本实施例的氯化钠包被物由被包覆的芯材和用于包覆的壁材组成。 [0038] The present embodiment is sodium package composed by the coated core material and a wall material for coating. 所述被包覆的芯材为呈颗粒状、粒径100μm~1000μm的氯化钠;所述用于包覆的壁材为淀粉、甲基纤维素、羟甲基纤维素、阿拉伯胶、聚丙烯酸树脂中任何一种的高分子缓释载体。 The coated granular core material, particle diameter of 100 m - 1000 m NaCl; for the wall material is coated with starch, methyl cellulose, hydroxymethyl cellulose, gum arabic, poly any resin acrylic polymer slow release carrier.

[0039] 本实施例的氯化钠包被物的制备工艺步骤及工艺参数同实施例1,仅仅是包覆的壁材原料做相应替换即可。 [0039] The present preparation process steps and process parameters embodiment is sodium package was the same as in Example 1, the wall material is only coated material can be replaced accordingly.

[0040] 将上述氯化钠包被物与过硫酸氢钾及其它成分混合,制备复合过硫酸氢钾粉消毒剂。 [0040] The above-described chloride was coated with oxone and other ingredients were mixed to prepare a composite powder oxone disinfectant.

[0041] 实施例3 [0041] Example 3

[0042] 一种复合过硫酸氢钾粉消毒剂,其各组分的质量配比为过硫酸氢钾50%,氯化钠包被物15%,有机酸、阴离子表面活性剂、助洗剂、稀释剂35%。 [0042] A composite oxone disinfectant powder, the mass ratio of the components thereof oxone 50%, was coated with 15% sodium chloride, an organic acid, an anionic surfactant, builder , 35% thinner.

[0043] 本实施例的氯化钠包被物由被包覆的芯材和用于包覆的壁材组成。 [0043] The present embodiment is sodium package composed by the coated core material and a wall material for coating. 所述被包覆的芯材为呈颗粒状、粒径100μm~1000μm的氯化钠;所述用于包覆的壁材为淀粉、甲基纤维素、羟甲基纤维素、阿拉伯胶、聚丙烯酸树脂中任何一种的高分子缓释载体。 The coated granular core material, particle diameter of 100 m - 1000 m NaCl; for the wall material is coated with starch, methyl cellulose, hydroxymethyl cellulose, gum arabic, poly any resin acrylic polymer slow release carrier.

[0044] 本实施例的氯化钠包被物的制备工艺步骤及工艺参数同实施例1,仅仅是包覆的壁材原料做相应替换即可。 [0044] The present preparation process steps and process parameters embodiment is sodium package was the same as in Example 1, the wall material is only coated material can be replaced accordingly.

[0045] 将上述氯化钠包被物与过硫酸氢钾及其它成分混合,制备复合过硫酸氢钾粉消毒剂。 [0045] The above-described chloride was coated with oxone and other ingredients were mixed to prepare a composite powder oxone disinfectant.

[0046] 实施例4 [0046] Example 4

[0047] -种复合过硫酸氢钾粉消毒剂,其各组分的质量配比为过硫酸氢钾60%,氯化钠包被物20%,有机酸、阴离子表面活性剂、助洗剂、稀释剂20%。 [0047] - Compound Species oxone disinfectant powder, the mass ratio of the components thereof oxone 60%, was coated with a 20% sodium chloride, an organic acid, an anionic surfactant, builder , 20% thinner.

[0048] 本实施例的氯化钠包被物由被包覆的芯材和用于包覆的壁材组成。 [0048] The present embodiment is sodium package composed by the coated core material and a wall material for coating. 所述被包覆的芯材为呈颗粒状、粒径100μm~1000μm的氯化钠;所述用于包覆的壁材为淀粉、甲基纤维素、羟甲基纤维素、阿拉伯胶、聚丙烯酸树脂中任何一种的高分子缓释载体。 The coated granular core material, particle diameter of 100 m - 1000 m NaCl; for the wall material is coated with starch, methyl cellulose, hydroxymethyl cellulose, gum arabic, poly any resin acrylic polymer slow release carrier.

[0049] 本实施例的氯化钠包被物的制备工艺步骤及工艺参数同实施例1,仅仅是包覆的壁材原料做相应替换即可。 [0049] The present production process steps and process parameters embodiment is sodium package was the same as in Example 1, the wall material is only coated material can be replaced accordingly.

[0050] 将上述氯化钠包被物与过硫酸氢钾及其它成分混合,制备复合过硫酸氢钾粉消毒剂。 [0050] The above-described chloride was coated with oxone and other ingredients were mixed to prepare a composite powder oxone disinfectant.

[0051] 实施例5 [0051] Example 5

[0052] -种复合过硫酸氢钾粉消毒剂,其各组分的质量配比为过硫酸氢钾65%,氯化钠包被物32%,有机酸、阴离子表面活性剂、助洗剂、稀释剂3%。 [0052] - Compound Species oxone disinfectant powder, the mass ratio of the components thereof oxone 65%, was coated with 32% sodium chloride, an organic acid, an anionic surfactant, builder , thinner 3%.

[0053] 本实施例的氯化钠包被物由被包覆的芯材和用于包覆的壁材组成。 [0053] The present embodiment is sodium package composed by the coated core material and a wall material for coating. 所述被包覆的芯材为呈颗粒状、粒径100μm~1000μm的氯化钠;所述用于包覆的壁材为淀粉、甲基纤维素、羟甲基纤维素、阿拉伯胶、聚丙烯酸树脂中任何一种的高分子缓释载体。 The coated granular core material, particle diameter of 100 m - 1000 m NaCl; for the wall material is coated with starch, methyl cellulose, hydroxymethyl cellulose, gum arabic, poly any resin acrylic polymer slow release carrier.

[0054] 本实施例的氯化钠包被物的制备工艺步骤及工艺参数同实施例1,仅仅是包覆的壁材原料做相应替换即可。 [0054] The present preparation process steps and process parameters embodiment is sodium package was the same as in Example 1, the wall material is only coated material can be replaced accordingly.

[0055] 将上述氯化钠包被物与过硫酸氢钾及其它成分混合,制备复合过硫酸氢钾粉消毒剂。 [0055] The above-described chloride was coated with oxone and other ingredients were mixed to prepare a composite powder oxone disinfectant.

[0056] 实施例6 [0056] Example 6

[0057] 在不同保存时间下,通过与含不被包被的氯化钠的普通复合过硫酸氢钾粉消毒剂的对比试验,研究根据本发明所述的消毒剂的稳定性。 [0057] In the different storage time, oxone sterilant by an ordinary powder-containing compound and sodium chloride are not coated with the comparative tests, the study of the stability of the disinfectant according to the present invention.

[0058] 按照以下配比组分,配制加入氯化钠包被物的复合过硫酸氢钾粉消毒剂(编号为消毒剂1)和加入氯化钠(未进行包被)的复合过硫酸氢钾粉消毒剂(编号为消毒剂2)。 [0058] The following components ratio, added to the composite formulation chloride was coated powder disinfectant Oxone (numbered 1 disinfectant) and sodium chloride complex (no coating) hydrogen sulfate potassium powder disinfectant (disinfectant number 2).

[0059] 消毒剂1的质量配比为:过硫酸氢钾65%,氯化钠包被物32%,有机酸、阴离子表面活性剂、助洗剂、稀释剂3%。 Mass [0059] The ratio of sterilant 1: 65% of potassium persulfate, 32% was coated with sodium chloride, an organic acid, an anionic surfactant, builder, diluent, 3%.

[0060] 消毒剂2的质量配比为:过硫酸氢钾65%,氯化钠6%,有机酸、阴离子表面活性剂、助洗剂、稀释剂29%。 Mass [0060] The ratio of sterilant 2: potassium persulfate 65%, 6% sodium chloride, an organic acid, an anionic surfactant, builder, diluent, 29%.

[0061] 将消毒剂1和消毒剂2在40°C,相对湿度75%条件下,分别放置3个月、6个月、9 个月、12个月、18个月,比较其有效成分氯含量以及消毒剂浓度为0. 125%时的对大肠杆菌8099、金黄色葡萄球菌ATCC6538的杀菌效果。 [0061] The sterilant and disinfectant 1 2 at 40 ° C, 75% relative humidity conditions, were placed for 3 months, 6 months, 9 months, 12 months, 18 months, which is an active ingredient chloro Comparative when the content of 0.125% and a concentration of the sterilant 8099, S. aureus ATCC6538 a bactericidal effect on E. coli. 具体结果见表1~5。 Specific results are shown in Table 1-5.

[0062] 表1保存3个月后有效氯含量及杀菌效果检测 [0062] Table 1 and save the chlorine content detected bactericidal effect 3 months after

[0063] [0063]

Figure CN105360162AD00061

[0064] 表2保存6个月后有效氯含量及杀菌效果检测 [0064] Table 2 to save chlorine content and bactericidal effect detection after 6 months

[0065] [0065]

Figure CN105360162AD00071

[0067] 表3保存9个月后有效氯含量及杀菌效果检测 [0067] Table 3 and the sterilization effect to save chlorine content detected after 9 months

[0068] [0068]

Figure CN105360162AD00081

[0069] 表4保存12个月后检测有效氯含量及杀菌效果检测 [0069] Table 4 and save the chlorine content detected sterilizing effect detection after 12 months

Figure CN105360162AD00082

Figure CN105360162AD00091

[0072] 表5保存18个月后检测有效氯含量及杀菌效果检测 [0072] Table 5 and stored chlorine content detected bactericidal effect detection after 18 months

[0073] [0073]

Figure CN105360162AD00092

[0074] 对表1~5中结果的有效氯含量进行分析,随着保存时间的增长,含氯化钠包被物的消毒剂1所含的有效氯含量比含未被包被的氯化钠的消毒剂2较高。 [0074] The results in Table 1 to 5 chlorine content was analyzed, with increasing storage time, the chlorine content of sodium chloride disinfectant containing coated material containing not more than 1 contained in the coated chloride sodium 2 disinfectant higher. 在相同条件下分别放置3个月、6个月、9个月、12个月、18个月,消毒剂1中有效氯含量均高于消毒剂2,其中在放置3个月、6个月时,二者的有效氯含量差异不显著;但在放置9个月、12个月、18个月时,二者有效氯含量呈显著性差异,消毒剂1显著高于消毒剂2。 Were placed under the same conditions for 3 months, 6 months, 9 months, 12 months, 18 months, 1 disinfectant disinfectant chlorine content higher than 2, wherein the left for 3 months, 6 months , the chlorine content is no significant difference between the two; but in place 9 months, 12 months, 18 months, both the chlorine content was significantly different, an antiseptic disinfectant significantly higher than 2.

[0075] 对表1-5中结果的消毒效果进行分析,随着保存时间的增长,含氯化钠包被物的消毒剂1的杀菌率比含未被包被的氯化钠的消毒剂2较高。 [0075] The disinfection results in Table 1-5 were analyzed, with increasing storage time, was coated with sodium-containing disinfectant sterilization rate than a disinfectant containing the sodium chloride is not a packet 2 high. 两者在相同条件下分别放置3 个月、6个月、9个月、12个月、18个月。 Both were placed under the same conditions for 3 months, 6 months, 9 months, 12 months, 18 months. 在放置3个月和6个月时,二者的消毒效果差异不显著;但在放置9个月、12个月、18个月时,二者的杀菌率呈显著性差异,消毒剂1显著高于消毒剂2。 When left for 3 months and 6 months, disinfection difference between the two is not significant; however, in place 9 months, 12 months, 18 months, the sterilization rate both showed a significant difference, disinfectants a significant 2 higher than disinfectant.

[0076] 上述结果说明,本发明所述的复合过硫酸氢钾粉消毒剂中,将氯化钠经过包被后, 消毒剂中有效成分以及杀毒效果随时间降低的速度减缓,组方的稳定性增强。 [0076] From the above result, the compound of the present invention, Oxone disinfectant powder, through the coating of sodium chloride, disinfectant active ingredients and anti-virus effect of slowing the decrease with time, stable Recipe enhancements.

[0077] 以上所述,仅是本发明的较佳实施例而已,是说明性的而不是限定性的,可按照所限定范围列举出若干个实施例,因此在不脱离本发明总体构思下的变化和修改,应属本发明的保护范围之内。 [0077] The above, only the preferred embodiment of the present invention, but are illustrative rather than limiting, and may include a number of embodiments according to the defined range, without departing from the general concept of the present invention modifications and variations, should be within the scope of the present invention.

Claims (8)

  1. 1. 一种复合过硫酸氢钾粉消毒剂,其特征在于,所述消毒剂含有过硫酸氢钾和氯化钠包被物。 A composite powder oxone disinfectant, characterized in that said disinfectant containing oxone and sodium chloride was coated.
  2. 2. 根据权利要求1所述的消毒剂,其特征在于,所述氯化钠包被物由被包覆的芯材和用于包覆的壁材组成。 2. The disinfectant according to claim 1, wherein said sodium chloride containment wall material composed of a core material to be coated and a coating composition.
  3. 3. 根据权利要求2所述的消毒剂,其特征在于,所述被包覆的芯材为呈颗粒状、粒径100μm~1000μm的氯化钠盐。 3. The disinfectant according to claim 2, characterized in that the coated granular core material, particle diameter of 100μm ~ 1000μm sodium chloride salt.
  4. 4. 根据权利要求2所述的消毒剂,其特征在于,所述用于包覆的壁材为淀粉、甲基纤维素、羟甲基纤维素、阿拉伯胶、聚丙烯酸树脂中任何一种的高分子缓释载体。 4. The disinfectant according to claim 2, wherein said wall material for coating as starch, methyl cellulose, hydroxymethyl cellulose, gum arabic, polyacrylic acid resin of any one of slow release macromolecular carrier.
  5. 5. 根据权利要求1~4任意一项所述的消毒剂,其特征在于,所述过硫酸氢钾的质量百分比为20%~65% ;所述氯化钠包被物的质量百分比为1. 5%~32% ;还包括占总重量3%~78. 5%的其他成分,包括有机酸、阴离子表面活性剂、助洗剂、稀释剂。 The disinfectant according to any one of claims 1 to 4, wherein the mass percentage of oxone in 20% to 65%; the mass percentage of sodium chloride, was coated with 1 5 to 32%; further comprising 3% to total 785 wt% of the other ingredients include organic acids, anionic surfactants, builders, diluents.
  6. 6. -种复合过硫酸氢钾粉消毒剂的制备方法,其特征在于采用流化床干燥法制备氯化钠包被物,将氯化钠包被物与过硫酸氢钾及其它成分混合,制备复合过硫酸氢钾粉消毒剂。 6. - The method of preparation is too complex species oxone disinfectant powder, characterized in that a fluidized-bed coating sodium sulfate was prepared, sodium chloride was coated with oxone and other ingredients, preparing a composite powder oxone disinfectant.
  7. 7. 根据权利要求6所述的制备方法,其特征在于,所述流化床干燥法制备氯化钠包被物的具体步骤包括:将所述壁材与水按一定比例混合,配置成有粘合剂效果的糊化壁材; 将所述糊化壁材与氯化钠按一定比例混合均匀,形成氯化钠与糊化载体的混合物;按比例称取干燥壁材,加入制粒机中,再喷入上述混合物,混合均匀,制成氯化钠包被物。 7. The method of preparation according to claim 6, wherein said step of drying processes particularly fluidized bed coating composition comprises sodium chloride: the wall material are mixed with water by a certain percentage, there is arranged adhesive effect gelatinization wall material; pasting the wall material mixed with sodium chloride uniformly by a certain percentage, a mixture of sodium chloride and gelatinized carrier; proportion wall material was dried weighed, added granulator , and then injected into the above mixture, uniformly mixed to prepare a coating composition of sodium chloride.
  8. 8. 根据权利要求7所述的制备方法,其特征在于,所述壁材与水的混合比例为0. 005:1~0. 20:1 ;所述糊化壁材与氯化钠的混合比例为0. 3:1~0. 8:1 ;所述干燥壁材与混合物的混合比例为〇. 4:1~1: 1。 8. The production method according to claim 7, wherein the mixing ratio of the wall material with water of 0.005: 1 to 020: 1; gelatinization mixing the wall material and sodium chloride ratio of 0.3: 1 to 08: 1; ratio of mixing the wall material and the dried mixture was square 4: 1 to 1: 1.
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CN106942271A (en) * 2017-04-25 2017-07-14 清远海贝生物技术有限公司 Composite potassium hydrogen persulfate disinfectant and preparation method thereof
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