CN1556046A - Synergism type chlorine dioxide bactericide and its manufacturing method and use in aquatic culture - Google Patents
Synergism type chlorine dioxide bactericide and its manufacturing method and use in aquatic culture Download PDFInfo
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- CN1556046A CN1556046A CNA2003101041833A CN200310104183A CN1556046A CN 1556046 A CN1556046 A CN 1556046A CN A2003101041833 A CNA2003101041833 A CN A2003101041833A CN 200310104183 A CN200310104183 A CN 200310104183A CN 1556046 A CN1556046 A CN 1556046A
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/80—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in fisheries management
- Y02A40/81—Aquaculture, e.g. of fish
Abstract
A synergistic ClO2 disinfectant used for the culture of aquatic products is composed of components A and B. The component A is the oxidant chosen from sodium chlorite, potassium (or ammonium) bromide, sodium hydroxide, etc. The component B consists of the reducer chosen from oxalate, sodium hydrogen sulfate, citrate, etc and the synergist chosen from trichloroisocyanuric acid, sodium chloride, etc. It is applied through dissolving in water, mixing, reaction, and diluting.
Description
Affiliated field
The present invention relates to a kind of sterilant, particularly a kind of Synergistic type chlorine dioxide bactericide and preparation method thereof and purposes in aquaculture of killing virus in the aquaculture, bacterium, fungi, algae etc.
Background technology
The culture fishery development is very swift and violent, but the sterilization technology at aquaculture relatively lags behind, general aquaculture mainly uses dioxide peroxide as sterilant, dioxide peroxide is the good oxidisability disinfection sanitizer of a kind of sterilization, has the broad-spectrum sterilization function, its oxidation capacity is 2.6 times of chlorine, it is also high 3 times than chlorine to suppress virus capable, sterilization is lasting, its sterilization long-lasting is more than 10 times of chlorine, the reaction of organism such as humic acids in dioxide peroxide and the water and fulvic acid does not generate haloform carcinogenss such as (THMS), is classified as A by the World Health Organization
1The level security sterilizing agent, in recent years, dioxide peroxide uses in aquaculture in a large number, effect is very outstanding in hydrocoles diseases prevention and treatment such as fish, shrimp, but, along with the high-density breeding of water industry and the raising of intensive culture level, water quality environment pollutes very serious, especially produces a large amount of poisonous ammonia (NH
3H
2O), and dioxide peroxide and ammonia do not produce reaction, and in other words dioxide peroxide can not be removed the ammonia in the water, and this is an one.Its two, the dioxide peroxide life-time service, its germ-resistant effective concentration is constantly soaring.
Summary of the invention
Purpose of the present invention promptly is to overcome the shortcoming of prior art, a kind of sterilizing rate height is provided, can effectively eliminate poisonous ammonia, the while is all harmless Synergistic type chlorine dioxide bactericides such as fishery products, people and water quality to culturing again, and this sterilant also has significant preventive and therapeutic effect to germ.
Another object of the present invention provides the making method of above-mentioned Synergistic type chlorine dioxide bactericide.
A further object of the present invention provides above-mentioned Synergistic type chlorine dioxide bactericide and is used for sick purposes such as aquaculture control virus, bacterium, fungi, algae.
Purpose of the present invention is achieved through the following technical solutions: a kind of sterilant, form for two doses by A, B, the A agent is an oxygenant, comprise solids such as Textone, Sodium Bromide (potassium, ammonium), sodium hydroxide, yellow soda ash, sodium sulfate, sodium bicarbonate, sodium chlorate, their weight ratio is 1～10: 1～10: 0.1～10: 0.1～10: 1～10: 0.1～10: 1～10; The B agent is reductive agent and synergistic agent, reductive agent comprises the solid mixt of at least three kinds of compositions in oxalate, sodium pyrosulfate, sodium bisulfite, Citrate trianion, the Sulfothiorine etc., and the weight ratio of oxalate, sodium pyrosulfate, sodium bisulfite, Citrate trianion, Sulfothiorine is 1～10: 1～10: 1～10: 1～10: 1～10; Synergistic agent is trichloroisocyanuric acid, DICHLOROISOCYANURIC ACID (sodium), bromine chlorine isocyanic acid potassium (sodium), two chlordantoins, bromochlorohydantoin, sodium-chlor etc., and the weight ratio of trichloroisocyanuric acid, DICHLOROISOCYANURIC ACID, Surchlor GR 60, bromine symclosene potassium, two chlordantoins, bromochlorohydantoin, sodium-chlor is 0.1～5: 0.1～5: 0.1～5: 0.1～5: 0.1～5: 0.1～5: 0.1～5.
A kind of making method of sterilant, the raw material of A agent, the reductive agent raw material and the synergistic agent raw material of B agent are pressed above-mentioned weight ratio proportioning respectively, stir after mixing respectively, press A agent oxidant feed: B agent reductive agent raw material: B agent synergistic agent raw material weight is than 3～5: 4～6: 0.5～2 packing, earlier the A agent is dissolved in the water of 100～150 times of weight then, again the B agent is dissolved in the water of 100～150 times of weight, after treating that two doses of A, B dissolve respectively, remix one reacted 2～3 minutes, promptly got required sterilant.
The purposes of sterilant is as the used for aquiculture sterilant.
From top narration as can be seen, the present invention has the following advantages, scientific formulation is reasonable, and is efficient, nontoxic, pollution-free, can effectively eliminate poisonous ammonia, sterilizing power is strong, effect is remarkable, and more single dioxide peroxide preparation sterilizing sterilization effect obviously improves, 5～8 times of synergy, virus in the aquaculture, bacterium, fungi, algae etc. are had extremely strong killing action, and this sterilant has very strong stability simultaneously.
Embodiment
The invention will be further described below in conjunction with embodiment
Embodiment 1: sterilant is made up of for two doses A, B, A agent oxygenant, and wherein the weight ratio of Textone, Sodium Bromide, sodium hydroxide, sodium sulfate, sodium chlorate is 5: 5: 0.5: 4: 3; B agent reductive agent, potassium oxalate, sodium pyrosulfate, Citrate trianion, Sulfothiorine weight ratio are 3: 5: 4: 3; B agent synergistic agent, trichloroisocyanuric acid, Surchlor GR 60, bromochlorohydantoin, weight sodium chloride ratio are 1: 2: 3: 3, the raw material of A agent, the reductive agent raw material and the synergistic agent raw material of B agent are pressed above-mentioned weight ratio proportioning respectively, stir after mixing respectively, get 20g in the A agent, B agent reductive agent 25g, B agent synergistic agent 5g, the A agent is dissolved in the 2Kg water, reductive agent and synergistic agent with the B agent is dissolved in the 3Kg water again, after treating two doses of dissolvings of A, B, mix reaction 2～3 minutes, put in the plastics of sealing or the vierics standby.
Laboratory test results is tested according to sterilizing agent bactericidal assay code requirement, and sterilant 0.05ppm of the present invention reaches more than 99% the sterilizing rate of streptococcus aureus; Sterilizing rate to Aeromonas hydrophila reaches more than 96%; To the sterilizing rate of Vibrio anguillarum more than 98%; The sterilizing rate of column being had a liking for the fiber bacterium is more than 95%.Calculate according to different time, the sterilizing rate to above-mentioned five kinds of pathogenic bacterium reached more than 82% in 15 minutes; Sterilizing rate reached about 92% in 35 minutes; Sterilizing rate reached more than 95% in 55 minutes, and the highest reaches more than 99%.Sterilant is to the prevention effect of fish fulminant disease: dioxide peroxide 0.05ppm prevention effect is more than 52%, and 0.02ppm Synergistic type chlorine dioxide bactericide is more than 92% to the control protection ratio of the fulminant disease of crucian.
Embodiment 2: sterilant is made up of for two doses A, B, A agent oxygenant, and wherein the weight ratio of Textone, Sodium Bromide (potassium, ammonium), sodium hydroxide, yellow soda ash, sodium sulfate, sodium bicarbonate, sodium chlorate is 10: 1: 0.1: 10: 10: 0.1: 1; The B agent is reductive agent and synergistic agent, and reductive agent oxalic acid is received, sodium pyrosulfate, sodium bisulfite, Citrate trianion, Sulfothiorine, and the weight ratio of oxalate, sodium pyrosulfate, sodium bisulfite, Citrate trianion, Sulfothiorine is 8: 10: 6: 10: 5; Synergistic agent is trichloroisocyanuric acid, DICHLOROISOCYANURIC ACID (sodium), bromine symclosene potassium (sodium), two chlordantoins, bromochlorohydantoin, sodium-chlor etc., and the weight ratio of trichloroisocyanuric acid, DICHLOROISOCYANURIC ACID, Surchlor GR 60, bromine symclosene potassium, two chlordantoins, bromochlorohydantoin, sodium-chlor is 0.5: 0.3: 2: 5: 0.1: 3: 0.1.The raw material of A agent, the reductive agent raw material and the synergistic agent raw material of B agent are pressed above-mentioned weight ratio proportioning respectively, stir after mixing respectively, the A agent is distributed into the 100g/ bag, B agent reductive agent is distributed into the 125g/ bag, synergistic agent is distributed into the 25g/ bag, is contained in then in the outer bag, concrete using method is that the A bag is dissolved in the 10Kg water,, again the B bag is dissolved in the 15Kg water, treat that two kinds of medicines dissolve respectively after, remix one reacted 2～3 minutes, sterilant of the present invention.
Claims (3)
1, a kind of sterilant, it is characterized in that: this sterilant is made up of for two doses A, B, the A agent is an oxygenant, comprise solids such as Textone, Sodium Bromide (potassium, ammonium), sodium hydroxide, yellow soda ash, sodium sulfate, sodium bicarbonate, sodium chlorate, their weight ratio is 1～10: 1～10: 0.1～10: 0.1～10: 1～10: 0.1～10: 1～10; The B agent is reductive agent and synergistic agent, reductive agent comprises the solid mixt of composition more than at least three kinds or three kinds in oxalate, sodium pyrosulfate, sodium bisulfite, Citrate trianion, the Sulfothiorine etc., and the weight ratio of oxalate, sodium pyrosulfate, sodium bisulfite, Citrate trianion, Sulfothiorine is 1～10: 1～10: 1～10: 1～10: 1～10; Synergistic agent is trichloroisocyanuric acid, DICHLOROISOCYANURIC ACID (sodium), bromine symclosene potassium (sodium), two chlordantoins, bromochlorohydantoin, sodium-chlor etc., and the weight ratio of trichloroisocyanuric acid, DICHLOROISOCYANURIC ACID, Surchlor GR 60, bromine symclosene potassium, two chlordantoins, bromochlorohydantoin, sodium-chlor is 0.1～5: 0.1～5: 0.1～5: 0.1～5: 0.1～5: 0.1～5: 0.1～5.
2, a kind of making method of sterilant, it is characterized in that: the raw material of A agent, the reductive agent raw material and the synergistic agent raw material of B agent are pressed the described weight ratio proportioning of claim 1 respectively, stir after mixing respectively, by A agent raw material: B agent oxidant feed: B agent synergistic agent raw material weight ratio is 3～5: 4～6: 0.5～2 packing, earlier the A agent is dissolved in the water of 100～150 times of weight then, again the B agent is dissolved in the water of 100～150 times of weight, after treating that two doses of A, B dissolve respectively, remix one reacted 2～3 minutes, promptly got required sterilant.
3, a kind of purposes of sterilant is characterized in that: it is as the used for aquiculture sterilant.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2003101041833A CN1556046A (en) | 2003-12-30 | 2003-12-30 | Synergism type chlorine dioxide bactericide and its manufacturing method and use in aquatic culture |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2003101041833A CN1556046A (en) | 2003-12-30 | 2003-12-30 | Synergism type chlorine dioxide bactericide and its manufacturing method and use in aquatic culture |
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| CN1556046A true CN1556046A (en) | 2004-12-22 |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101857341A (en) * | 2010-06-01 | 2010-10-13 | 吴有林 | Method for performing superchlorination to water body of soft shelled turtle culture pond |
| CN101933938A (en) * | 2010-08-27 | 2011-01-05 | 王锡麟 | Sustained-release in-vivo pathogen killing agent and preparation and using methods thereof |
| CN102379309A (en) * | 2011-07-27 | 2012-03-21 | 中北大学 | Binary-packaged reactive chlorine dioxide tablet and preparation method thereof |
| CN102422841A (en) * | 2011-09-30 | 2012-04-25 | 晋日亚 | Reactive chlorine dioxide powder and its preparation method |
| CN103146500A (en) * | 2013-03-21 | 2013-06-12 | 东北师范大学 | Dish washing detergent |
| CN110934136A (en) * | 2019-12-06 | 2020-03-31 | 江苏农牧科技职业学院 | Pond-cleaning disinfectant suitable for crustacean culture pond |
| CN111480657A (en) * | 2020-05-20 | 2020-08-04 | 陈冠荣 | Stable composite chlorine dioxide solid lozenge and preparation method thereof |
| CN113003679A (en) * | 2021-03-29 | 2021-06-22 | 浙江省农业科学院 | Land-based slow-release water quality regulator application device and application method |
| CN113207903A (en) * | 2021-04-21 | 2021-08-06 | 清远海贝生物技术有限公司 | Chlorine dioxide effervescent tablet and preparation method and application thereof |
-
2003
- 2003-12-30 CN CNA2003101041833A patent/CN1556046A/en active Pending
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101857341A (en) * | 2010-06-01 | 2010-10-13 | 吴有林 | Method for performing superchlorination to water body of soft shelled turtle culture pond |
| CN101857341B (en) * | 2010-06-01 | 2012-09-05 | 吴有林 | Method for performing superchlorination to water body of soft shelled turtle culture pond |
| CN101933938A (en) * | 2010-08-27 | 2011-01-05 | 王锡麟 | Sustained-release in-vivo pathogen killing agent and preparation and using methods thereof |
| CN102379309A (en) * | 2011-07-27 | 2012-03-21 | 中北大学 | Binary-packaged reactive chlorine dioxide tablet and preparation method thereof |
| CN102379309B (en) * | 2011-07-27 | 2013-05-22 | 中北大学 | Binary-packaged reactive chlorine dioxide tablet and preparation method thereof |
| CN102422841A (en) * | 2011-09-30 | 2012-04-25 | 晋日亚 | Reactive chlorine dioxide powder and its preparation method |
| CN103146500A (en) * | 2013-03-21 | 2013-06-12 | 东北师范大学 | Dish washing detergent |
| CN110934136A (en) * | 2019-12-06 | 2020-03-31 | 江苏农牧科技职业学院 | Pond-cleaning disinfectant suitable for crustacean culture pond |
| CN110934136B (en) * | 2019-12-06 | 2021-07-16 | 江苏农牧科技职业学院 | Pond-cleaning disinfectant suitable for crustacean culture pond |
| CN111480657A (en) * | 2020-05-20 | 2020-08-04 | 陈冠荣 | Stable composite chlorine dioxide solid lozenge and preparation method thereof |
| CN113003679A (en) * | 2021-03-29 | 2021-06-22 | 浙江省农业科学院 | Land-based slow-release water quality regulator application device and application method |
| CN113207903A (en) * | 2021-04-21 | 2021-08-06 | 清远海贝生物技术有限公司 | Chlorine dioxide effervescent tablet and preparation method and application thereof |
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