CN101595891B - Chlorine dioxide composition with selective antioxidation - Google Patents
Chlorine dioxide composition with selective antioxidation Download PDFInfo
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- CN101595891B CN101595891B CN200810111220A CN200810111220A CN101595891B CN 101595891 B CN101595891 B CN 101595891B CN 200810111220 A CN200810111220 A CN 200810111220A CN 200810111220 A CN200810111220 A CN 200810111220A CN 101595891 B CN101595891 B CN 101595891B
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Abstract
The invention discloses a chlorine dioxide composition with selective antioxidation, which has complete spontaneity without any assistance of machines and uses the Brownian motion molecular driving theory on physics to reach the effect of sterilizing space within very short time even though people are on site without withdrawing. When activated, the composition cannot be influenced by the concentration of acid and alkali so as to achieve strong resolving capacity to kill harmful substances such as bacteria, virus, chemical toxins, residual agricultural chemical, and the like, thereby reaching the effect of sterilizing and purifying air; in addition, the invention can be widely used for medicine, industry, agriculture, people's livelihood, and the like.
Description
Technical field
The present invention relates to a kind of chlorine dioxide combination of tool selective antioxidation; It is that main material is processed with sodium chlorite and disodium ethylene diamine tetraacetate; Have sterilization simultaneously, decompose toxic chemical substance and, and can be widely used in each industry such as doctor, worker, farming, the people's livelihood the corrosion protection effect of metal objects.
Background technology
Generally surpassed last a century as the history that disinfection uses with chlorine-containing agent, and factor such as it is cheap, and easy to use and bactericidal effect is definite, so type disinfection drug still accounts for the great majority in market.But general chlorine-containing agent (like bleaching water) has its unsurmountable shortcoming: 1. its smell is pungent makes us being difficult to stand; 2. chlorine (Cl
2) when mixing with water, organic substance in the water and chlorine atomic reaction can generate materials such as chloroform, chlorinated phenol, and carcinogenic, hepatotoxicity and nephrotoxic causing harm are arranged; 3. during as if generation chloroacetonitrile or chloro ketone, then have the effect that modificator gene is poisoned.Therefore, more and more many at present people pay attention to this problem.
So some American-European economically developed countries were to replace aforesaid chlorine-containing agent with the dualistic formula chlorine dioxide, chlorine dioxide (ClO mostly when doing water treatment in recent years
2) be to participate in reaction with organic matter reaction by " oxygen "; When reacting completely; Chlorine dioxide becomes chloride ion (Cl-); As promptly containing this type material in sea salt and the seasoning salt, so chlorine dioxide is to see through oxidation reaction and can not produce poisonous accessory substance, this is the aforementioned general chlorine-containing agent emphasis that is beyond one's reach; Only need a spot of chlorine dioxide to get final product kill bacteria, microorganism and free from environmental pollution again, " environmental protection shape disinfectant " is otherwise known as.Yet chlorine dioxide is trivial operations in use, join existing usefulness at present, the consumption that will calculate " activator " during allotment with calculate soak time, and then calculate a series of formalities such as diluted concentration, so use very inconvenience, be difficult to popularization; In addition; Because of it is an oxide; So what can produce the situation of oxidation and rusting to some metal materials; And be an impediment to Medical Instruments or Medical Instruments and other disinfection applications aspects that needs long-term sterilization that be used in, and cause the raw material use of prior art being done sterilization merely with chlorine dioxide, necessity of research and development improvement is again arranged in fact.
Summary of the invention
The inventor is because above-mentioned prior art is done the disappearance that disinfectant uses with the chlorine dioxide preparation of scene modulation; And study intensively; And long-pending individual is engaged in research and development of this cause and the many years of experience of producing and selling, and develops a kind of chlorine dioxide combination of brand-new tool selective antioxidation eventually again.
Main purpose of the present invention aims to provide a kind of chlorine dioxide combination of tool selective antioxidation, and it does not need on-the-spot modulation for a kind of, and convenient lozenge, the powder product of preserving with function of use of tool.
A time purpose of the present invention aims to provide a kind of chlorine dioxide combination of tool selective antioxidation, and it is a kind of lozenge, powder product that metal material is had the corrosion protection function.
For reaching above-mentioned purpose; The chlorine dioxide combination of a kind of tool selective antioxidation of the present invention; It is a main material with 23～70% sodium chlorite and 5～15% disodium ethylene diamine tetraacetate (EDTA disodium); A kind of tool metal rust preventing defencive function and the convenient disinfection agent of chlorine dioxide that uses cooperate acidic materials 5～15%, disintegrant 5～15% and alkaline matter 5～15% to mix the form of forming ingot shape or powdery again, can effectively be provided; Wherein,
Percentage is percetage by weight described in this paper;
Sodium chlorite is for producing the main material of chlorine dioxide;
Disodium ethylene diamine tetraacetate can play the corrosion protection effect to metallics;
Acidic materials, for example be citric acid, tartaric acid one of them, or compound of other acidity or mixture, and it can discharge the titanium dioxide carbon compound; Be to be used for disengaging chlorine dioxide with the sodium chlorite reaction;
Disintegrant is selected from sodium bicarbonate, CMC (Nacmc), and it can help the abundant disintegration activation of lozenge;
Alkaline matter, be selected from niter cake, Sodium Benzoate, lauryl sodium sulfate one of them, or compound of other alkalescence or mixture use as filler, can reach the effect of abundant sterilization and make the lozenge bonding and smooth in appearance, glossy effect.When above-mentioned composition uses, can have deodorizing, control air clump count and volatile compound (as: formaldehyde, nicotine) simultaneously, and aerosol capable of using sterilization and can be widely used in each industry such as medical treatment, industry, the agriculture and people's livelihood.
Its characteristic is: 1. soluble in water, and be difficult for again being hydrolyzed and in water, exist with molecular conformation; Not with water in organic matter combine to generate the chloroform carcinogen; 3. have strong oxidability,, reach the effect of sterilization, chemical decomposition toxin and removal stink with ammonia, sulphide, phenol, aldehyde, the effect of cyanide organic matter of various material surfaces.
Its advantage is: 1. avirulence, can not cause secondary pollution, and do not develop immunity to drugs, meet the examination criteria of food additives; 2. strong sterilizing power, consumption is few, and drug effect is quick; 3. drug effect does not receive the influence of pH value; 4. can increase the dissolved oxygen in water amount; 5. the sterilizing rate to bacterium, microorganism, virus reaches the ability more than 99.9999%; 6. have wide range of applications.
Embodiment
The chlorine dioxide combination of a kind of tool selective antioxidation of the present invention; It comprises sodium chlorite 23～70%, disodium ethylene diamine tetraacetate 5～15%, acidic materials 5～15%, disintegrant 5～15%, reaches alkaline matter 5～15%, protects and make things convenient for the disinfection by chlorine dioxide lozenge of function of use so that a kind of tool metal rust preventing effectively to be provided; Wherein,
Sodium chlorite is for producing the main material of chlorine dioxide;
Disodium ethylene diamine tetraacetate is playing optionally anti-oxidant corrosion protection effect to metallics;
Acidic materials mainly are to be used for disengaging harmless chlorine dioxide with the sodium chlorite reaction;
Disintegrant is CMC (Nacmc), the abundant disintegration of its lozenge that can help this composition to process;
Alkaline matter has lozenge bonding that this composition processes and smooth in appearance, the glossy effect of making;
According to above-mentioned composition combination, the chlorine dioxide that the present invention is discharged in the time of contacting with water or air with said composition and the composition of disodium ethylene diamine tetraacetate are to reach disinfection and metallic article is produced corrosion protection work simultaneously; Again, composition of the present invention, the effective addition scope when its mixed water uses all has good bactericidal effect in 0.5～600mg/L.
Step when making: 1. respectively with all material oven dry (temperature is no more than 60 ℃) like above-mentioned composition; 2. with 50 purpose screen cloth separation screenings; 3. according to proper proportion batching (in the aforementioned ratio scope); 4. fully mix (about 30 minutes); 5. compressing tablet is processed lozenge or is not needed compressing tablet to process the kenel of pulvis.During use; Can directly drop into and make its natural disintegration in the water and soluble in water,, maybe place air initiatively to inhale this lozenge and gather airborne moisture to reach the purification of water quality effect; Reach activation by this; It can volatilize naturally and reach the effect that purifies air, so the present invention is very convenient in the use, and can extensively apply to each industry such as medical treatment, industry, agricultural and the people's livelihood.
Above-mentioned for another example composition is said, acidic materials wherein can be selected from citric acid, tartaric acid one of them, or compound of other acidity or mixture, and it can discharge the titanium dioxide carbon compound;
Disintegrant wherein can be selected from sodium bicarbonate, CMC one of them, sodium bicarbonate and acidic materials reaction can make lozenge disintegration rapidly in water; And,
Alkaline matter wherein optional from niter cake, Sodium Benzoate, lauryl sodium sulfate one of them, or compound of other alkalescence or mixture, this basic species mass-energy makes the outward appearance of processing lozenge more smooth, glossy; Again, wherein Sodium Benzoate also can play stable and anticorrosion and protective effect to the lozenge that the present invention processes, and lauryl sodium sulfate is that surfactant can help chlorine dioxide to reach the effect of abundant sterilization.
Percentage like each composition of above disclosed example composition; Can in the described percentage range of this case, freely modulate with user demand; Or the colorant or the spices that add other uses, so claim of the present invention is not limited thereto all not departing under the condition that the present invention conceives; Acidic materials wherein, disintegrant and alkaline matter ... wait additive, understand similar of affiliated person skilled or etc. congruent the replacement.
In sum; The present invention's " chlorine dioxide combination of a kind of tool non preference oxidation " can reach the effect with strong disinfecting, chemical decomposition material really; And can produce corrosion protection effect simultaneously, and then increase the practicality and the economic worth of this product metallic article.
More than explanation is just illustrative for the purpose of the present invention; And nonrestrictive, those of ordinary skills understand, under the situation of spirit that does not break away from claim and limited and scope; Can make many modifications, variation or equivalence, but all will fall within protection scope of the present invention.
Claims (4)
1. the chlorine dioxide combination of a tool selective antioxidation; It is characterized in that: in its gross weight; Comprise sodium chlorite 23～70%, disodium ethylene diamine tetraacetate 5～15%, acidic materials 5～15%, disintegrant 5～15%, reach alkaline matter 5～15%, so that a kind of tool metal rust preventing defencive function and the convenient chlorine dioxide antiseptic lozenge that uses effectively to be provided;
Sodium chlorite is for producing the main material of chlorine dioxide;
Disodium ethylene diamine tetraacetate is playing the corrosion protection effect to metallics;
Acidic materials mainly are to be used for reacting to disengage chlorine dioxide with sodium chlorite;
Disintegrant is that methylcellulose is received, and can help the abundant disintegration of lozenge, and said disintegrant is a sodium carboxymethylcellulose;
Alkaline matter has the lozenge of making bonding and smooth in appearance, glossy effect.
2. according to the chlorine dioxide combination of the tool selective oxidation of claim 1, it is characterized in that: acidic materials be selected from citric acid, tartaric acid one of them, or compound of other acidity or mixture.
3. according to the chlorine dioxide combination of the tool non preference oxidation of claim 1, it is characterized in that: alkaline matter be selected from niter cake, Sodium Benzoate, lauryl sodium sulfate one of them, or compound of other alkalescence or mixture.
4. the application of the chlorine dioxide combination of the tool non preference oxidation of claim 1 is characterized in that: it should be reached the corrosion protection to metal objects in sterilization.
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| CN200810111220A CN101595891B (en) | 2008-06-05 | 2008-06-05 | Chlorine dioxide composition with selective antioxidation |
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| CN200810111220A CN101595891B (en) | 2008-06-05 | 2008-06-05 | Chlorine dioxide composition with selective antioxidation |
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| CN101595891B true CN101595891B (en) | 2012-09-05 |
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| CN101898078B (en) * | 2010-07-19 | 2013-03-27 | 陈学成 | Slow-release indoor disinfecting and decoration odor removing agent and production method and use method thereof |
| TWI785627B (en) * | 2021-05-31 | 2022-12-01 | 威爾斯生醫股份有限公司 | Disinfecting tablet and preparation method and uses thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1122189A (en) * | 1995-06-29 | 1996-05-15 | 叶中良 | Bactericidal disinfectant |
| CN1969633A (en) * | 2006-12-06 | 2007-05-30 | 刘桂发 | Monophyletic solid disinfectant of chlorine dioxide and preparation method thereof |
| CN101142916A (en) * | 2007-10-18 | 2008-03-19 | 薛林余 | One system chlorine dioxide sterilizing tablet and its producing method |
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2008
- 2008-06-05 CN CN200810111220A patent/CN101595891B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1122189A (en) * | 1995-06-29 | 1996-05-15 | 叶中良 | Bactericidal disinfectant |
| CN1969633A (en) * | 2006-12-06 | 2007-05-30 | 刘桂发 | Monophyletic solid disinfectant of chlorine dioxide and preparation method thereof |
| CN101142916A (en) * | 2007-10-18 | 2008-03-19 | 薛林余 | One system chlorine dioxide sterilizing tablet and its producing method |
Non-Patent Citations (3)
| Title |
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| 孙梅君等.高效低腐蚀消毒剂的研制.《食品与发酵工业》.1997,第23卷(第5期), * |
| 沈晓东等.二氧化氯有机稳定化的探讨.《工业水处理》.2007,第27卷(第4期), * |
| 贺启环 潘慧云 刘绍刚.有机稳定性二氧化氯初步研究.《水处理标准与质量》.2005, * |
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Effective date of registration: 20170106 Address after: Hangzhou City, Zhejiang Province, Jianggan District Qianjiang No. 188 Fuchun road Civic Center, block B room 0242 Patentee after: Hangzhou Shuang Sheng Biotechnology Co., Ltd. Address before: Taipei City, Taiwan, China Patentee before: Liao Weikai |
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Address after: Room b1502, 15 / F, building B, 369 IOT street, Xixing street, Binjiang District, Hangzhou, Zhejiang 310000 Patentee after: Hangzhou Shuangchun Environmental Technology Co., Ltd Address before: Room 0242, block B, civic center, 188 Fuchun Road, Qianjiang New Town, Jianggan District, Hangzhou, Zhejiang 310000 Patentee before: Hangzhou Shuangchun Environmental Technology Co., Ltd |