CN111421907A - 石墨烯导电面料 - Google Patents

石墨烯导电面料 Download PDF

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CN111421907A
CN111421907A CN201910365508.4A CN201910365508A CN111421907A CN 111421907 A CN111421907 A CN 111421907A CN 201910365508 A CN201910365508 A CN 201910365508A CN 111421907 A CN111421907 A CN 111421907A
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parts
fabric
water
graphene conductive
conductive fabric
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CN111421907B (zh
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陈明贤
孙立新
董洪波
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Zhejiang Dongjin New Material Co ltd
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Abstract

本发明公开了一种石墨烯导电面料，包括石墨烯薄膜、粘结层、表层面料以及在表层面料表面施加的防水层；所述石墨烯导电面料的制备方法为：a、防水剂与水配成30份/L的防水剂水溶液；b、表层面料浸入防水剂水溶液，两浸两轧，轧液率70‑90％；c、90℃烘干、150℃焙烘，表层面料表面形成防水层；d、在表层面料下表面涂覆粘结胶；e、将石墨烯薄膜与表层面料涂覆有粘结胶的表面贴合；f、100℃烘干、160℃焙烘，形成所述的石墨烯导电面料。

Description

石墨烯导电面料
技术领域
本发明涉及一种石墨烯导电面料，属于功能纺织品面料领域。
背景技术
户外服装面料通常由功能薄膜与纺织品通过粘结组分复合而成。由于户外服装多数由化学纤维制成，静电问题较为突出。静电的危害一般表现为衣服易起毛起球，易沾染灰尘污垢，贴近皮肤时有电击感和粘滞感等。抗静电面料一般是在织物中织入金属丝，将摩擦产生的静电及时传导散逸到外界去，但是这种导电面料柔软性不好。另一种方法是利用聚丙烯酸酯等具有吸湿作用的抗静电剂，在织物表面涂一层可以吸附水分子的化学薄膜，使织物表面形成一层连续的导电水膜，将静电传导逸散。
石墨烯是目前发现的最薄的二维材料，由六边形晶格组成，构成一个二维空间无限延伸的基面，其C-C键键长大约为0.142nm。石墨烯中每个中心碳原子的σ键与周围的其他碳原子连接，石墨烯具有优良的结构刚性。每个碳原子都有一个未成键的π电子，π电子在与平面垂直方向上形成了π轨道，电子可以在晶格中自由移动，所以石墨烯具有良好的导电性。
将石墨烯分散后均匀加入聚酯组分中，形成具有导电性能的聚酯薄膜，再以该薄膜与面料复合，则可解决户外复合面料的静电问题。
户外服装面料因户外环境中紫外线的存在，其面料中的染料易褪色，即面料的耐日晒牢度差，因此需在面料后整理时施加抗紫外线剂，改善面料的耐晒性能。
发明内容
本发明目的是提供一种导电面料，具体提供一种含石墨烯薄膜与表层面料复合形成的导电面料。
为实现上述目的，本发明采用了如下技术方案。
一种石墨烯导电面料，包括石墨烯薄膜、粘结层、表层面料以及在表层面料表面施加的防水层；
所述石墨烯导电面料的制备方法为：
a、防水剂与水配成30份/L的防水剂水溶液；
b、表层面料浸入防水剂水溶液，两浸两轧，轧液率70-90％；
c、90℃烘干、150℃焙烘，表层面料表面形成防水层；
d、在表层面料下表面涂覆粘结胶；
e、将石墨烯薄膜与表层面料涂覆有粘结胶的表面贴合；
f、100℃烘干、160℃焙烘，形成所述的石墨烯导电面料；
所述的防水剂，制备方法为：
1)将50份纳米硅溶胶加入搅拌容器中，加入400mL体积比为1:1的无水乙醇和超纯水的均匀混合液，超声分散0.5h；60℃时于搅拌状态下缓慢滴入0.9份硅烷偶联剂KH570及1.2份二苯甲酮基硅氧烷(如式1所示)，再恒温搅拌24h，将产物注入离心管中高速离心分离，抽滤得到改性纳米硅溶胶；
2)将40份去离子水、1.8份十二烷基硫酸钠(SDS)和壬基酚聚氧乙烯醚(OP-10)(质量比为2∶1)加入到搅拌器中，溶解均匀后，在30min内匀速滴加12份有机硅聚合单体(如式2所示)、8份有机氟单体，滴加完毕后，用磁力搅拌器以1500rpm/min的速度搅拌30min，制得预乳化液；
3)在装有搅拌器、回流冷凝管、温度计的反应器中加入120份水、30份改性硅溶胶、3.2份十二烷基硫酸钠(SDS)和壬基酚聚氧乙烯醚(OP-10)(质量比为2∶1)，搅拌均匀后升温至75℃，然后在2h内同时滴加预乳化液和引发剂水溶液(0.3份引发剂与10份水)，滴完后保温30min，再升温至85℃、保温2h；冷却降温至40℃以下，用氨水将乳液的pH值调至7，得到所述防水剂乳液。
Figure BDA0002048006210000031
所述的二苯甲酮基硅氧烷，其制备方法为：a、在氮气保护下，按摩尔比1.02:1，将3-异氰酸酯基丙基三甲氧基硅烷、2-羟基-4-甲氧基二苯甲酮加入至反应器中，加入占3-异氰酸酯基丙基三甲氧基硅烷质量0.5％的辛酸亚锡，在70℃下搅拌反应5h，得二苯甲酮基硅氧烷(如式1所示)。
所述的有机硅聚合单体，由2-(三甲基硅氧基)乙醇胺与甲基丙烯酸异氰酸酯乙酯反应制成，其方法如下：
在装有搅拌器、温度计、冷凝管的反应器中，加入经脱水处理的2-(三甲基硅氧基)乙醇胺、甲基丙烯酸异氰酸酯乙酯、二月桂酸二丁基锡，100℃搅拌反应5h，得含C＝C键的功能性有机硅聚合单体(如式2所示)；2-(三甲基硅氧基)乙醇胺、甲基丙烯酸异氰酸酯乙酯的摩尔比1:1，二月桂酸二丁基锡的质量占反应单体总质量的0.4％。
所述的石墨烯薄膜，厚度为0.02mm。
所述的表层面料为涤纶双层面料，含90％涤纶、10％氨纶，面料规格为75D+40D*75D+40D/150D+40D，克重260g/m2。
所述的粘结胶由增稠剂、粘合剂、交联剂组成，各组分质量比为1:100:0.5。
所述的增稠剂为聚丙烯酸。
所述的粘合剂为丙烯酸酯乳液。
所述的交联剂为封闭型异氰酸酯交联剂。
所述的有机氟单体为甲基丙烯酸三氟乙酯、丙烯酸三氟乙酯、甲基丙烯酸六氟丁酯中的一种。
本发明石墨烯导电面料由表层面料和石墨烯薄膜复合而成，表层面料设有疏水层，赋予本发明所述面料良好的疏水及导电性能。
将紫外吸收单体引入有机硅聚合物中，使防水剂兼具防水、抗紫外线功能，可提高表层面料的耐日晒牢度。
防水剂采用有机—无机复合材料来制作低表面能材料，即通过有机材料来降低表面能，无机材料来构造微小凹凸结构，利用两者共同作用来生产效果更好的超疏水效果。
对面料做防水、抗紫外线功能整理时，因防水剂与抗紫外线剂表面性能的差异，往往对这两种整理分别进行。本发明防水剂结合了抗紫外单体，实现了一剂复合多种功能，一次整理即可实现多种功能，缩短了加工工艺流程。
具体实施方式
本发明中所述物质的单位“份”指的是“质量份”。
本发明公开了一种石墨烯导电面料，包括石墨烯薄膜、粘结层、表层面料以及在表层面料表面施加的防水层；
制备该石墨烯导电面料时，先在表层面料表面施加防水层，再将表层面料与石墨烯薄膜经粘结剂复合；其具体制备方法为：
a、防水剂与水配成30份/L的防水剂水溶液；
b、表层面料浸入防水剂水溶液，两浸两轧，轧液率70-90％；
c、90℃烘干、150℃焙烘，表层面料表面形成防水层；
d、在表层面料下表面涂覆粘结胶；
e、将石墨烯薄膜与表层面料涂覆有粘结胶的表面贴合；
f、100℃烘干、160℃焙烘，形成所述的石墨烯导电面料；粘结胶固化成粘结层。
所述的粘结胶由增稠剂、粘合剂、交联剂组成，各组分质量比为1:100:0.5；配制时，将增稠剂缓慢加入至粘合剂乳液中，搅拌，使乳液增稠，粘度30000CPS左右，在对面料涂覆粘结剂前，加入交联剂。粘结剂的涂覆量250-280g/m2。
所述的增稠剂为聚丙烯酸，如广东南辉新材料有限公司的丙烯酸增稠剂CO-0177。
所述的粘合剂为丙烯酸酯乳液，如苏州联胜化学有限公司的特软印花粘合剂HB0200。
所述的交联剂为封闭型异氰酸酯交联剂，如上海尤恩化工有限公司的封闭型异氰酸酯交联剂UN-7038。
本发明所述石墨烯导电面料，表层面料具有防水性能，即面料阻止透过一定压力或动能的液态水的性能。此外，石墨烯薄膜含有微孔，其直径控制在比水蒸气分子大而比水滴小的范围内，当两侧存在水蒸气压力差时，水蒸气和空气可自由通过相互贯通、曲折的微孔，而水滴不能通过，从而达到防水透湿的目的。
所述的防水剂，由改性纳米硅溶胶、有机硅聚合单体、有机氟单体、乳化剂、水在引发剂作用下经聚合而成，按质量份计，各组分为改性纳米硅溶胶30份、有机硅聚合单体12份、有机氟单体8份、乳化剂5份、水170份、引发剂0.3份；
1)将40份去离子水、1.8份十二烷基硫酸钠(SDS)和壬基酚聚氧乙烯醚(OP-10)(质量比为2∶1)加入到搅拌器中，溶解均匀后，在30min内匀速滴加12份有机硅聚合单体(如前述式2所示)、8份有机氟单体，滴加完毕后，用磁力搅拌器以1500rpm/min的速度搅拌30min，制得预乳化液；
2)在装有搅拌器、回流冷凝管、温度计的反应器中加入120份水、30份改性硅溶胶、3.2份十二烷基硫酸钠(SDS)和壬基酚聚氧乙烯醚(OP-10)(质量比为2∶1)，搅拌均匀后升温至75℃，然后在2h内同时滴加预乳化液和引发剂水溶液(0.3份引发剂与10份水)，滴完后保温30min，再升温至85℃、保温2h；冷却降温至40℃以下，用氨水将乳液的pH值调至7，得到所述防水剂乳液。
其中，改性纳米硅溶胶制备方法为：
将50份纳米硅溶胶加入搅拌容器中，加入400mL体积比为1:1的无水乙醇和超纯水的均匀混合液，超声分散0.5h；60℃时于搅拌状态下缓慢滴入0.9份硅烷偶联剂KH570及1.2份二苯甲酮基硅氧烷(如前述式1所示)，再恒温搅拌24h，将产物注入离心管中高速离心分离，抽滤得到改性纳米硅溶胶。
所述的有机氟单体为甲基丙烯酸三氟乙酯、丙烯酸三氟乙酯、甲基丙烯酸六氟丁酯中的一种。
所述的有机硅聚合单体，由2-(三甲基硅氧基)乙醇胺与甲基丙烯酸异氰酸酯乙酯反应制成，其方法如下：
在装有搅拌器、温度计、冷凝管的反应器中，加入经脱水处理的2-(三甲基硅氧基)乙醇胺、甲基丙烯酸异氰酸酯乙酯、二月桂酸二丁基锡，100℃搅拌反应5h，得含C＝C键的功能性有机硅聚合单体；2-(三甲基硅氧基)乙醇胺、甲基丙烯酸异氰酸酯乙酯的摩尔比1:1，二月桂酸二丁基锡的质量占反应单体总质量的0.4％。所涉反应过程如(1)所示。
Figure BDA0002048006210000071
其中，2-(三甲基硅氧基)乙醇胺的制备方法为：在带有机械搅拌、温度计的反应器中，投入乙醇胺，搅拌滴加六甲基二硅氮烷，于5～50℃反应0.5～2h，反应完毕，经减压抽滤得2-(三甲基硅氧基)乙醇胺。乙醇胺与六甲基二硅氮烷的摩尔比为2:1。
纳米硅溶胶改性时使用的所述二苯甲酮基硅氧烷，由2-羟基-4-甲氧基二苯甲酮与3-异氰酸酯基丙基三甲氧基硅烷制成，方法如下：在氮气保护下，按摩尔比1.02:1，将3-异氰酸酯基丙基三甲氧基硅烷、2-羟基-4-甲氧基二苯甲酮加入至反应器中，加入占3-异氰酸酯基丙基三甲氧基硅烷质量0.5％的辛酸亚锡，在70℃下搅拌反应5h，得二苯甲酮基硅氧烷。所涉反应过程如(2)所示。
Figure BDA0002048006210000072
乙烯基硅氧烷偶联剂，由于含有可水解基团Si-O-C，在乳液聚合过程中，即使采取延迟滴加、添加水解抑制剂等措施，仍会发生一定程度的水解、缩合、聚合物分子间过度交联而导致聚合反应失稳。本发明防水剂采用了-Si(CH3)3基团的有机硅聚合单体，由于其空间位阻大、不水解，大大提高了乳液聚合的稳定性，使有机硅在聚合物分子链中的分布更均衡，有效增强聚合物的拒水性能。
有机氟化合物的C-F键长短，键能高，氟原子半径较小，从而使其分子内部结构非常紧密，紧密缠绕着C-C主链，对其主链具有屏蔽保护作用，使氟具有相对较低表面能，与具有较低表面张力的硅氧烷共聚，可赋予织物低表面张力、较为突出的疏水性和耐久性，还可让处理后的织物保持本身的柔软性和透气性。
所述的石墨烯薄膜，厚度为0.02mm。
所述的表层面料为涤纶双层面料，含90％涤纶、10％氨纶，面料规格为75D+40D*75D+40D/150D+40D，克重260g/m2。
实施例1：
一种防水剂，由改性纳米硅溶胶、有机硅聚合单体、有机氟单体、乳化剂、水在引发剂作用下经聚合而成，按质量份计，各组分为改性纳米硅溶胶30份、有机硅聚合单体12份、有机氟单体8份、乳化剂5份、水170份、引发剂0.3份；
1)将40份去离子水、1.8份十二烷基硫酸钠(SDS)和壬基酚聚氧乙烯醚(OP-10)(质量比为2∶1)加入到搅拌器中，溶解均匀后，在30min内匀速滴加12份有机硅聚合单体(如前述式2所示)、8份有机氟单体，滴加完毕后，用磁力搅拌器以1500rpm/min的速度搅拌30min，制得预乳化液；
2)在装有搅拌器、回流冷凝管、温度计的反应器中加入120份水、30份改性硅溶胶、3.2份十二烷基硫酸钠(SDS)和壬基酚聚氧乙烯醚(OP-10)(质量比为2∶1)，搅拌均匀后升温至75℃，然后在2h内同时滴加预乳化液和引发剂水溶液(0.3份引发剂过硫酸钠与10份水)，滴完后保温30min，再升温至85℃、保温2h；冷却降温至40℃以下，用氨水将乳液的pH值调至7，得到所述防水剂乳液。
其中，改性纳米硅溶胶制备方法为：
将50份纳米硅溶胶加入搅拌容器中，加入400mL体积比为1:1的无水乙醇和超纯水的均匀混合液，超声分散0.5h；60℃时于搅拌状态下缓慢滴入0.9份硅烷偶联剂KH570及1.2份二苯甲酮基硅氧烷(如前述式1所示)，再恒温搅拌24h，将产物注入离心管中高速离心分离，抽滤得到改性纳米硅溶胶。
所述的有机氟单体为甲基丙烯酸三氟乙酯、丙烯酸三氟乙酯、甲基丙烯酸六氟丁酯中的一种。
所述的有机硅聚合单体，由2-(三甲基硅氧基)乙醇胺与甲基丙烯酸异氰酸酯乙酯反应制成，其方法如下：在装有搅拌器、温度计、冷凝管的反应器中，加入经脱水处理的2-(三甲基硅氧基)乙醇胺、甲基丙烯酸异氰酸酯乙酯、二月桂酸二丁基锡，100℃搅拌反应5h，得含C＝C键的功能性有机硅聚合单体；2-(三甲基硅氧基)乙醇胺、甲基丙烯酸异氰酸酯乙酯的摩尔比1:1，二月桂酸二丁基锡的质量占反应单体总质量的0.4％。其中，2-(三甲基硅氧基)乙醇胺的制备方法为：在带有机械搅拌、温度计的反应器中，投入乙醇胺，搅拌滴加六甲基二硅氮烷，于5～50℃反应0.5～2h，反应完毕，经减压抽滤得2-(三甲基硅氧基)乙醇胺。乙醇胺与六甲基二硅氮烷的摩尔比为2:1。
所述的二苯甲酮基硅氧烷，由2-羟基-4-甲氧基二苯甲酮与3-异氰酸酯基丙基三甲氧基硅烷制成，方法如下：在氮气保护下，按摩尔比1.02:1，将3-异氰酸酯基丙基三甲氧基硅烷、2-羟基-4-甲氧基二苯甲酮加入至反应器中，加入占3-异氰酸酯基丙基三甲氧基硅烷质量0.5％的辛酸亚锡，在70℃下搅拌反应5h，得二苯甲酮基硅氧烷。
防水剂应用方法：
处方：
防水剂 30份/L，余量为水
整理液pH 6-8
工艺流程：
将涤纶织物浸渍在防水剂整理液中(二浸二轧，轧余率70-90％)→预烘(90℃，4min)→焙烘(150℃，1-3min)。
涤纶织物为涤纶双层面料，含90％涤纶、10％氨纶，面料规格为75D+40D*75D+40D/150D+40D，克重260g/m2。
表1防水剂处理后面料各项性能测试结果
Figure BDA0002048006210000101
涤纶织物经实施例1防水剂整理后，防水性能、抗紫外线性能明显提升。
实施例2：
一种石墨烯导电面料，包括石墨烯薄膜、粘结层、表层面料以及在表层面料表面施加的防水层；石墨烯导电面料的制备方法为：
a、防水剂与水配成30份/L的防水剂水溶液；
b、表层面料浸入防水剂水溶液，两浸两轧，轧液率70-90％；
c、预烘(90℃，4min)→焙烘(150℃，1-3min)，表层面料表面形成防水层；
d、在表层面料下表面涂覆粘结胶；粘结胶由增稠剂、粘合剂、交联剂组成，质量比为1:100:0.5，将丙烯酸增稠剂CO-0177(广东南辉新材料有限公司)缓慢加入至特软印花粘合剂HB0200(苏州联胜化学有限公司)中，搅拌，使乳液增稠，粘度30000CPS左右，在向面料涂覆前，加入封闭型异氰酸酯交联剂UN-7038(上海尤恩化工有限公司)，粘结剂的涂覆量250-280g/m2；
e、将石墨烯薄膜与表层面料涂覆有粘结胶的表面贴合，石墨烯薄膜厚度为0.02mm，基材为PU；
f、烘干(100℃，3min)、焙烘(160℃，1-3min)，制得所述的石墨烯导电面料；粘结剂经固化后形成粘结层。
所述的防水剂，制备方法为：
1)将50份纳米硅溶胶加入搅拌容器中，加入400mL体积比为1:1的无水乙醇和超纯水的均匀混合液，超声分散0.5h；60℃时于搅拌状态下缓慢滴入0.9份硅烷偶联剂KH570及1.2份二苯甲酮基硅氧烷(如前述式1所示)，再恒温搅拌24h，将产物注入离心管中高速离心分离，抽滤得到改性纳米硅溶胶；
2)将40份去离子水、1.8份十二烷基硫酸钠(SDS)和壬基酚聚氧乙烯醚(OP-10)(质量比为2∶1)加入到搅拌器中，溶解均匀后，在30min内匀速滴加12份有机硅聚合单体(如前述式2所示)、8份有机氟单体甲基丙烯酸三氟乙酯，滴加完毕后，用磁力搅拌器以1500rpm/min的速度搅拌30min，制得预乳化液；
3)在装有搅拌器、回流冷凝管、温度计的反应器中加入120份水、30份改性硅溶胶、3.2份十二烷基硫酸钠(SDS)和壬基酚聚氧乙烯醚(OP-10)(质量比为2∶1)，搅拌均匀后升温至75℃，然后在2h内同时滴加预乳化液和引发剂水溶液(0.3份引发剂过硫酸钠与10份水)，滴完后保温30min，再升温至85℃、保温2h；冷却降温至40℃以下，用氨水将乳液的pH值调至7，得到所述防水剂乳液。
防水剂中，所述的二苯甲酮基硅氧烷，其制备方法为：a、在氮气保护下，按摩尔比1.02:1，将3-异氰酸酯基丙基三甲氧基硅烷、2-羟基-4-甲氧基二苯甲酮加入至反应器中，加入占3-异氰酸酯基丙基三甲氧基硅烷质量0.5％的辛酸亚锡，在70℃下搅拌反应5h，得二苯甲酮基硅氧烷。
防水剂中，所述的有机硅聚合单体，由2-(三甲基硅氧基)乙醇胺与甲基丙烯酸异氰酸酯乙酯反应制成，其方法如下：在装有搅拌器、温度计、冷凝管的反应器中，加入经脱水处理的2-(三甲基硅氧基)乙醇胺、甲基丙烯酸异氰酸酯乙酯、二月桂酸二丁基锡，100℃搅拌反应5h，得含C＝C键的功能性有机硅聚合单体；2-(三甲基硅氧基)乙醇胺、甲基丙烯酸异氰酸酯乙酯的摩尔比1:1，二月桂酸二丁基锡的质量占反应单体总质量的0.4％。
所述的表层面料为涤纶双层面料，含90％涤纶、10％氨纶，面料规格为75D+40D*75D+40D/150D+40D，克重260g/m2。
表2石墨烯导电面料各项性能测试结果
Figure BDA0002048006210000121
透湿性能：参照GB/T 12704-2009《织物透湿量测定方法-透湿杯法》方法测试。
防水性能：参照GB/T 4745-2012《纺织品防水性能的检测和评价沾水法》测定。
抗紫外线性能：参照GB/T 18830-2009《纺织品防紫外线性能的评定》测试。
石墨烯导电面料表面电阻率的采用LFY-406织物表面比电阻测试仪按GB/T1410-2006《固体绝缘材料体积电阻率和表面电阻率试验方法》测定。

Claims (8)

1.一种石墨烯导电面料，包括石墨烯薄膜、粘结层、表层面料以及在表层面料表面施加的防水层；
所述石墨烯导电面料的制备方法为：
a、防水剂与水配成30份/L的防水剂水溶液；
b、表层面料浸入防水剂水溶液，两浸两轧，轧液率70-90％；
c、90℃烘干、150℃焙烘，表层面料表面形成防水层；
d、在表层面料下表面涂覆粘结胶；
e、将石墨烯薄膜与表层面料涂覆有粘结胶的表面贴合；
f、100℃烘干、160℃焙烘，形成所述的石墨烯导电面料；
所述的防水剂，制备方法为：
1)将50份纳米硅溶胶加入搅拌容器中，加入400mL体积比为1:1的无水乙醇和超纯水的均匀混合液，超声分散0.5h；60℃时于搅拌状态下缓慢滴入0.9份硅烷偶联剂KH570及1.2份二苯甲酮基硅氧烷(如式1所示)，再恒温搅拌24h，将产物注入离心管中高速离心分离，抽滤得到改性纳米硅溶胶；
2)将40份去离子水、1.8份质量比为2∶1的十二烷基硫酸钠和壬基酚聚氧乙烯醚加入到搅拌器中，溶解均匀后，在30min内匀速滴加12份有机硅聚合单体(如式2所示)、8份有机氟单体，滴加完毕后，用磁力搅拌器以1500rpm/min的速度搅拌30min，制得预乳化液；
3)在装有搅拌器、回流冷凝管、温度计的反应器中加入120份水、30份改性硅溶胶、3.2份质量比为2∶1的十二烷基硫酸钠和壬基酚聚氧乙烯醚，搅拌均匀后升温至75℃，然后在2h内同时滴加预乳化液和0.3份引发剂与10份水的溶液，滴完后保温30min，再升温至85℃、保温2h；冷却降温至40℃以下，用氨水将乳液的pH值调至7，得到所述防水剂乳液。
Figure FDA0002048006200000021
2.根据权利要求1所述的一种石墨烯导电面料，其特征在于：所述的石墨烯薄膜，厚度为0.02mm。
3.根据权利要求1所述的一种石墨烯导电面料，其特征在于：所述的表层面料为涤纶双层面料，含90％涤纶、10％氨纶，面料规格为75D+40D*75D+40D/150D+40D，克重260g/m2。
4.根据权利要求1所述的一种石墨烯导电面料，其特征在于：所述的粘结胶由增稠剂、粘合剂、交联剂组成，各组分质量比为1:100:0.5。
5.根据权利要求4所述的一种石墨烯导电面料，其特征在于：所述的增稠剂为聚丙烯酸。
6.根据权利要求4所述的一种石墨烯导电面料，其特征在于：所述的粘合剂为丙烯酸酯乳液。
7.根据权利要求4所述的一种石墨烯导电面料，其特征在于：所述的交联剂为封闭型异氰酸酯交联剂。
8.根据权利要求1所述的一种石墨烯导电面料，其特征在于：所述的有机氟单体为甲基丙烯酸三氟乙酯、丙烯酸三氟乙酯、甲基丙烯酸六氟丁酯中的一种。
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