CN111332058A - Processing technology of cloisonne water jet mosaic - Google Patents

Processing technology of cloisonne water jet mosaic Download PDF

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Publication number
CN111332058A
CN111332058A CN202010354046.9A CN202010354046A CN111332058A CN 111332058 A CN111332058 A CN 111332058A CN 202010354046 A CN202010354046 A CN 202010354046A CN 111332058 A CN111332058 A CN 111332058A
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China
Prior art keywords
cloisonne
glaze
water jet
mosaic
red copper
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CN202010354046.9A
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Chinese (zh)
Inventor
黄永建
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CHENGDU ZAIJIAN DECORATING MAT
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CHENGDU ZAIJIAN DECORATING MAT
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Priority to CN202010354046.9A priority Critical patent/CN111332058A/en
Publication of CN111332058A publication Critical patent/CN111332058A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C3/00Processes, not specifically provided for elsewhere, for producing ornamental structures
    • B44C3/12Uniting ornamental elements to structures, e.g. mosaic plates
    • B44C3/126Devices for making mosaic constructs automatically
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21FWORKING OR PROCESSING OF METAL WIRE
    • B21F5/00Upsetting wire or pressing operations affecting the wire cross-section
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24CABRASIVE OR RELATED BLASTING WITH PARTICULATE MATERIAL
    • B24C1/00Methods for use of abrasive blasting for producing particular effects; Use of auxiliary equipment in connection with such methods
    • B24C1/04Methods for use of abrasive blasting for producing particular effects; Use of auxiliary equipment in connection with such methods for treating only selected parts of a surface, e.g. for carving stone or glass
    • B24C1/045Methods for use of abrasive blasting for producing particular effects; Use of auxiliary equipment in connection with such methods for treating only selected parts of a surface, e.g. for carving stone or glass for cutting
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B11/00Apparatus or processes for treating or working the shaped or preshaped articles
    • B28B11/04Apparatus or processes for treating or working the shaped or preshaped articles for coating or applying engobing layers
    • B28B11/044Apparatus or processes for treating or working the shaped or preshaped articles for coating or applying engobing layers with glaze or engobe or enamel or varnish
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/06Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
    • C23C8/08Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases only one element being applied
    • C23C8/10Oxidising
    • C23C8/12Oxidising using elemental oxygen or ozone

Abstract

The invention relates to a processing technology of cloisonne water jet mosaic, and the mosaic is composed of 2D water jet parts, 3D water jet parts and cloisonne. The processing technology comprises the steps of forming a blank, performing anti-oxidation pretreatment, wire inlaying, bluing and glazing, firing glaze, coating anti-oxidation, pasting a bottom plate, combining and paving, and inspecting quality and warehousing. The cloisonne water jet mosaic prepared by the processing technology disclosed by the invention is combined with 2D and 3D water jet parts, and cloisonne is fused in; not only forms a three-dimensional structure with 3D visual effect and dynamic effect, but also endows the mosaic with traditional artistic effect. In addition, the processing technology adds an anti-oxidation pretreatment procedure before wire inlay, so that the oxidation resistance of the copper tire bottom and the copper wire is enhanced; after glaze firing, metal with the activity of metal being less than that of copper or metal element with the activity of metal being more than that of copper but capable of forming a compact oxide layer is plated on the surface, so that the problems of easy oxidation and poor durability of cloisonne parts are solved, and the service life of cloisonne water jet mosaic as a decorative material is prolonged.

Description

Processing technology of cloisonne water jet mosaic
Technical Field
The invention relates to a mosaic product, in particular to a processing technology of cloisonne water jet mosaic.
Background
Cloisonne (Cloisonne), one of the famous special metal artworks in China, although originally a ship, quickly blends the traditional style of Chinese on the profound artistic soil of Chinese, until the manufacture of the technology reaches the peak in the bright Cloisonne year, becomes a bright pearl in the history of Chinese art. It is an indication of the identity of the royal at that time, as it is only allowed to circulate under palace supervision for a long time. In 2006, it was listed as the first national non-material cultural heritage due to its special historical meaning and technology. The mosaic art pattern formed by combining the copper-body cloisonne enamel and the materials such as stone, metal, glass, shells and the like is more in a modern design by integrating the cloisonne process into the mosaic manufacturing process.
Chinese patent 201310135891.7 discloses a method for preparing a landscape porcelain product, which utilizes a groove on a ceramic fitting substrate to fix a ceramic fitting on cloisonne enamel in an embedding manner, so that the obtained landscape porcelain product has more traditional artistic feeling, fine pattern and unique shape. Chinese patent 201020648683.9 discloses a wire inlay color sand artistic ceramic, which uses ceramic as a carrier and is inlaid with a color three-dimensional pattern on the surface. Firstly, drawing a pattern picture draft on the surface of ceramic, carving the line outline of the pattern by using a porcelain carving process, embedding the pattern outline formed by enclosing flat metal wires into the carved line, filling corresponding colored mortar bodies into different parts inside, spraying a layer of waterproof polymer on the surface, and plastically packaging the pattern on the surface of the ceramic. However, the cloisonne enamel product combining cloisonne and mosaic has the problems of poor oxidation resistance and durability because the cloisonne matrix type manufacturing and wire inlay are made of red copper materials, and the cloisonne is very obvious in phenomenon of darkening after being placed in the air for a long time, namely, a copper device is rusted after being placed in the air for a long time. The essence of the copper oxide is that copper can be oxidized into black copper oxide in humid air, and the copper oxide on the surface of copper continuously reacts with carbon dioxide in the air to generate a layer of green basic copper carbonate CuCO3Cu (OH); meanwhile, copper also reacts with hydrogen sulfide in the air to generate black copper sulfide. More important, along with the continuous promotion of decoration environment demand, combine mosaic product and cloisonne enamel simply, can not form the spatial configuration who has 3D visual effect and dynamic effect, the application can receive very big restriction.
Disclosure of Invention
The invention aims to provide a processing technology of cloisonne water jet mosaic to solve the problems in the background technology.
In order to achieve the purpose, the technical scheme adopted by the invention comprises the following steps:
(1) manufacturing a tire shape: firstly, cutting a red copper sheet into a specified shape according to a design drawing by using a water knife to form a red copper tire bottom.
(2) Anti-oxidation pretreatment: carrying out anti-oxidation pretreatment on the red copper tire bottom and the thin red copper wire obtained in the step (1), and specifically comprising the following steps: and (3) after the kiln is heated to 500 ℃, placing the red copper tire bottom and the thin red copper wires on a high-temperature net, oxidizing in the kiln for 5-10 min, and then cleaning and polishing.
(3) Wire inlaying: flattening the fine red copper wire obtained in the step (2) by using tweezers, pinching and breaking the fine red copper wire into exquisite patterns according to a design drawing, and adhering the fine red copper wire to the bottom of the red copper tire by using bletilla striata; and (3) spraying the welding flux, roasting at 900-1100 ℃ for 2 min, and fixing the thin red copper wire at the bottom of the red copper tire, and then performing steel brush rust removal treatment.
(4) Bluing and glazing and glaze firing: preparing enamel colored glaze according to a standard formula according to the required color of the design, putting the enamel colored glaze into a container, adding a proper amount of deionized water, stirring, and washing off ultrafine powder; then, adding deionized water into the cleaned enamel colored glaze again, wherein the dosage of the deionized water is based on the metric standard of submerging the enamel colored glaze; and finally, filling enamel glaze materials into the fixed copper wire pattern frame one by using a blue gun. And after the bluing and glazing are finished, roasting for 2 min at the temperature of 800-850 ℃. After the glaze burns once, the glaze sinks, highly is less than the copper and pinches a wire frame, and the colour does not reach the designing requirement, needs to turn blue glazing and glaze again, repeats 3~5 back, and the line parallel and level are pinched with copper to the glaze colour demonstrates full rich gloss sense until the glaze height.
(5) And (3) oxidation resistant plating: polishing and grinding the cloisonne wires, polishing, flattening and brightening the glaze-burned color-changing copper wires without damaging the cloisonne glaze surface, and then carrying out plating processing on the parts.
(6) Pasting a bottom plate: and (3) using SK-1692 epoxy resin glue to coat the cloisonne component with the oxidation resistance, and processing the cloisonne component on a marble bottom plate which has the same shape with the cloisonne component according to the size of a design drawing in advance, so that the thickness of the cloisonne mosaic component reaches the thickness required by the design.
(7) And (3) combined paving and pasting: and combining and paving the processed cloisonne mosaic parts with the 2D water jet cutter parts and the 3D water jet cutter parts according to the requirements of the design drawing to form a complete cloisonne water jet cutter mosaic.
(8) And (4) quality inspection and warehousing: after paving, a paving workshop firstly self-checks whether the product reaches the standard or not; after the quality inspection department is qualified, opening a product inspection qualified bill, opening a warehouse entry bill by a paving workshop, and delivering the product together with the product to a warehouse for checking and warehousing.
Further, the oxidation-resistant plating layer in the step (6) is one of silver, platinum or gold, which has metal activity smaller than that of copper, or one of tin or aluminum, which has metal activity larger than that of copper and can form a compact oxide layer.
Further, the 3D water jet cutting part in the step (7) is made of two or more of marble, metal, LAVA, glass, shell and the like through water jet cutting and 3D manufacturing.
Compared with the prior art, the invention has the beneficial effects that:
the cloisonne water jet mosaic prepared by the processing technology of the invention combines 2D and 3D water jet parts, and the cloisonne is fused in; not only forms a three-dimensional structure with 3D visual effect and dynamic effect, but also endows the mosaic with traditional artistic effect, greatly widens the application field of the product, and can meet the requirements of more decoration environments. In addition, the processing technology firstly adds an anti-oxidation pretreatment procedure after wire inlay is finished, so that the oxidation resistance of the copper tire bottom is enhanced; after glaze firing, metal with the activity of metal being less than that of copper is plated on the surface or metal elements with the activity of metal being more than that of copper but capable of forming a compact oxide layer are plated on the surface, so that the problems of easy oxidation and poor durability of cloisonne parts are solved, the service life of cloisonne water jet scalpel mosaic as a decorative material is prolonged, and the product quality is improved.
Detailed Description
The present invention will be described in further detail with reference to examples, but the present invention is not limited thereto.
Example one
The processing technology of the cloisonne water jet mosaic comprises the following steps:
(1) manufacturing a tire shape: firstly, cutting a red copper sheet into a specified shape according to a design drawing by using a water knife to form a red copper tire bottom.
(2) Anti-oxidation pretreatment: carrying out anti-oxidation pretreatment on the red copper tire bottom and the thin red copper wire obtained in the step (1), and specifically comprising the following steps: heating the kiln to 500 deg.C, placing red copper base and fine red copper wire on a high temperature net, oxidizing in the kiln for 5 min, cleaning, and polishing.
(3) Wire inlaying: flattening the fine red copper wire obtained in the step (2) by using tweezers, pinching and breaking the fine red copper wire into exquisite patterns according to a design drawing, and adhering the fine red copper wire to the bottom of the red copper tire by using bletilla striata; and (3) spraying the welding flux, roasting at 1100 ℃ for 2 min, and fixing the thin red copper wires at the bottom of the red copper tire to perform steel brush rust removal treatment.
(4) Bluing and glazing and glaze firing: preparing enamel colored glaze according to a standard formula according to the required color of the design, putting the enamel colored glaze into a container, adding a proper amount of deionized water, stirring, and washing off ultrafine powder; then, adding deionized water into the cleaned enamel colored glaze again, wherein the dosage of the deionized water is based on the metric standard of submerging the enamel colored glaze; and finally, filling enamel glaze materials into the fixed copper wire pattern frame one by using a blue gun. After the bluing and glazing are finished, roasting for 2 min at 800 ℃. After the glaze of once burns, the glaze sinks, highly is less than copper inlay a silk frame, and the colour does not reach the designing requirement, needs to turn blue glazing and glaze again, repeats 5 times after, until the glaze highly with copper inlay a silk line parallel and level to the glaze colour demonstrates full rich gloss and feels.
(5) And (3) oxidation resistant plating: polishing and grinding the cloisonne wires, polishing, flattening and brightening the glaze-burned color-changing copper wires without damaging the cloisonne glaze surface, and then processing the plating layer of the part, wherein the anti-oxidation plating layer is metal platinum with metal activity smaller than that of copper.
(6) Pasting a bottom plate: and (3) using SK-1692 epoxy resin glue to coat the cloisonne component with the oxidation resistance, and processing the cloisonne component on a marble bottom plate which has the same shape with the cloisonne component according to the size of a design drawing in advance, so that the thickness of the cloisonne mosaic component reaches the thickness required by the design.
(7) And (3) combined paving and pasting: and combining and paving the processed cloisonne mosaic parts with the 2D water jet cutter parts and the 3D water jet cutter LAVA/glass combined parts according to the design drawing requirements to form a complete cloisonne water jet cutter mosaic.
(8) And (4) quality inspection and warehousing: after paving, a paving workshop firstly self-checks whether the product reaches the standard or not; after the quality inspection department is qualified, opening a product inspection qualified bill, opening a warehouse entry bill by a paving workshop, and delivering the product together with the product to a warehouse for checking and warehousing.
Example two
The processing technology of the cloisonne water jet mosaic comprises the following steps:
(1) manufacturing a tire shape: firstly, cutting a red copper sheet into a specified shape according to a design drawing by using a water knife to form a red copper tire bottom.
(2) Anti-oxidation pretreatment: carrying out anti-oxidation pretreatment on the red copper tire bottom and the thin red copper wire obtained in the step (1), and specifically comprising the following steps: heating the kiln to 500 deg.C, placing red copper base and fine red copper wire on a high temperature net, oxidizing in the kiln for 10 min, cleaning, and polishing.
(3) Wire inlaying: flattening the fine red copper wire obtained in the step (2) by using tweezers, pinching and breaking the fine red copper wire into exquisite patterns according to a design drawing, and adhering the fine red copper wire to the bottom of the red copper tire by using bletilla striata; spraying the welding flux, roasting at 900 deg.C for 2 min, fixing the fine red copper wire on the bottom of the red copper tire, and removing rust with steel brush.
(4) Bluing and glazing and glaze firing: preparing enamel colored glaze according to a standard formula according to the required color of the design, putting the enamel colored glaze into a container, adding a proper amount of deionized water, stirring, and washing off ultrafine powder; then, adding deionized water into the cleaned enamel colored glaze again, wherein the dosage of the deionized water is based on the metric standard of submerging the enamel colored glaze; and finally, filling enamel glaze materials into the fixed copper wire pattern frame one by using a blue gun. After the bluing and glazing are finished, the mixture is roasted for 2 min at the temperature of 850 ℃. After the glaze of once burns, the glaze sinks, highly is less than copper inlay a silk frame, and the colour does not reach the designing requirement, needs to turn blue glazing and glaze again, repeats 3 times after, until the glaze highly with copper inlay a silk line parallel and level to the glaze colour demonstrates full rich gloss and feels.
(5) And (3) oxidation resistant plating: polishing and grinding the cloisonne wires, polishing, flattening and brightening the glaze-fired color-changing copper wires without damaging the cloisonne glaze surface, and then processing the plating layer of the part, wherein the plating layer is metallic tin.
(6) Pasting a bottom plate: and (3) using SK-1692 epoxy resin glue to coat the cloisonne component with the oxidation resistance, and processing the cloisonne component on a marble bottom plate which has the same shape with the cloisonne component according to the size of a design drawing in advance, so that the thickness of the cloisonne mosaic component reaches the thickness required by the design.
(7) And (3) combined paving and pasting: and combining and paving the processed cloisonne mosaic parts with the 2D water jet scalpel parts and the 3D marble/metal parts according to the design drawing requirements to form a complete cloisonne water jet mosaic.
(8) And (4) quality inspection and warehousing: after paving, a paving workshop firstly self-checks whether the product reaches the standard or not; after the quality inspection department is qualified, opening a product inspection qualified bill, opening a warehouse entry bill by a paving workshop, and delivering the product together with the product to a warehouse for checking and warehousing.
EXAMPLE III
The processing technology of the cloisonne water jet mosaic comprises the following steps:
(1) manufacturing a tire shape: firstly, cutting a red copper sheet into a specified shape according to a design drawing by using a water knife to form a red copper tire bottom.
(2) Anti-oxidation pretreatment: carrying out anti-oxidation pretreatment on the red copper tire bottom and the thin red copper wire obtained in the step (1), and specifically comprising the following steps: heating the kiln to 500 deg.C, placing red copper base and fine red copper wire on a high temperature net, oxidizing in the kiln for 6 min, cleaning, and polishing.
(3) Wire inlaying: flattening the fine red copper wire obtained in the step (2) by using tweezers, pinching and breaking the fine red copper wire into exquisite patterns according to a design drawing, and adhering the fine red copper wire to the bottom of the red copper tire by using bletilla striata; and (3) spraying the welding flux, roasting at 1050 ℃ for 2 min, and fixing the thin red copper wires at the bottom of the red copper tire, and then performing steel brush rust removal treatment.
(4) Bluing and glazing and glaze firing: preparing enamel colored glaze according to a standard formula according to the required color of the design, putting the enamel colored glaze into a container, adding a proper amount of deionized water, stirring, and washing off ultrafine powder; then, adding deionized water into the cleaned enamel colored glaze again, wherein the dosage of the deionized water is based on the metric standard of submerging the enamel colored glaze; and finally, filling enamel glaze materials into the fixed copper wire pattern frame one by using a blue gun. After the bluing and glazing are finished, the mixture is roasted for 2 min at the temperature of 830 ℃. After the glaze of once burns, the glaze sinks, highly is less than copper inlay a silk frame, and the colour does not reach the designing requirement, needs to turn blue glazing and glaze again, repeats 4 times after, until the glaze highly with copper inlay a silk line parallel and level to the glaze colour demonstrates full rich gloss and feels.
(5) And (3) oxidation resistant plating: polishing and grinding the cloisonne wires, polishing, flattening and brightening the glaze-burned color-changing copper wires without damaging the cloisonne glaze surface, and then carrying out plating processing on the parts.
(6) Pasting a bottom plate: and (3) using SK-1692 epoxy resin glue to coat the cloisonne component with the oxidation resistance, and processing the cloisonne component on a marble bottom plate which has the same shape with the cloisonne component according to the size of a design drawing in advance, so that the thickness of the cloisonne mosaic component reaches the thickness required by the design.
(7) And (3) combined paving and pasting: and combining and paving the processed cloisonne mosaic parts with the 2D water jet scalpel parts and the 3D marble/LAVA/metal parts according to the design drawing requirements to form a complete cloisonne water jet mosaic.
(8) And (4) quality inspection and warehousing: after paving, a paving workshop firstly self-checks whether the product reaches the standard or not; after the quality inspection department is qualified, opening a product inspection qualified bill, opening a warehouse entry bill by a paving workshop, and delivering the product together with the product to a warehouse for checking and warehousing.
The present invention is capable of other embodiments, and various changes and modifications may be made by one skilled in the art without departing from the spirit and scope of the invention.

Claims (3)

1. A processing technology of cloisonne water knife mosaic comprises the following steps: (1) manufacturing a tire shape: firstly, cutting a red copper sheet into a specified shape according to a design drawing by using a water knife to form a red copper tire bottom; (2) anti-oxidation pretreatment: carrying out anti-oxidation pretreatment on the red copper tire bottom and the thin red copper wire obtained in the step (1), and specifically comprising the following steps: after the kiln is heated to 500 ℃, placing the red copper tire bottom and the thin red copper wires on a high-temperature net, oxidizing in the kiln for 5-10 min, and then cleaning and polishing; (3) wire inlaying: flattening the fine red copper wire obtained in the step (2) by using tweezers, pinching and breaking the fine red copper wire into exquisite patterns according to a design drawing, and adhering the fine red copper wire to the bottom of the red copper tire by using bletilla striata; spraying welding flux, roasting at 900-1100 ℃ for 2 min, fixing the thin red copper wire at the bottom of the red copper tire, and then performing steel brush rust removal treatment; (4) bluing and glazing and glaze firing: preparing enamel colored glaze according to a standard formula according to the required color of the design, putting the enamel colored glaze into a container, adding a proper amount of deionized water, stirring, and washing off ultrafine powder; then, adding deionized water into the cleaned enamel colored glaze again, wherein the dosage of the deionized water is based on the metric standard of submerging the enamel colored glaze; finally, filling enamel glaze materials into the fixed copper wire pattern frame one by using a blue gun; after the bluing and glazing are finished, roasting for 2 min at the temperature of 800-850 ℃; after the primary glaze firing, the glaze sinks, the height of the glaze is lower than that of the copper wire inlay frame, the color does not meet the design requirement, the blue-lighting glazing and the glaze firing are needed again, and the process is repeated for 3-5 times until the height of the glaze is level with the copper wire inlay lines, and the color of the glaze is full and rich in luster; (5) and (3) oxidation resistant plating: polishing and grinding the cloisonne wire inlay, polishing, flattening and brightening the glaze-burned color-changing copper wire without damaging the cloisonne glaze surface, and then carrying out plating processing on the part; (6) pasting a bottom plate: using SK-1692 epoxy resin glue on the cloisonne component with the anti-oxidation coating and a marble bottom plate which is processed according to the size of a design drawing and has the same shape with the cloisonne component in advance, so that the thickness of the cloisonne mosaic component reaches the thickness required by the design; (7) and (3) combined paving and pasting: combining and splicing the processed cloisonne mosaic parts with 2D water jet cutter parts or mosaic large pictures and 3D water jet cutter parts according to the requirements of a design drawing to form a complete cloisonne water jet cutter mosaic; (8) and (4) quality inspection and warehousing: after paving, a paving workshop firstly self-checks whether the product reaches the standard or not; after the quality inspection department is qualified, opening a product inspection qualified bill, opening a warehouse entry bill by a paving workshop, and delivering the product together with the product to a warehouse for checking and warehousing.
2. The process of claim 1, wherein: the anti-oxidation coating in the step (6) is one of silver, platinum or gold with metal activity smaller than that of copper, or one of tin or aluminum with metal activity larger than that of copper and capable of forming a compact oxide layer.
3. The process of claim 1, wherein: the 3D water jet cutting part in the step (7) is made of two or more of marble, metal, LAVA, glass, shells and the like through water jet cutting and 3D manufacturing.
CN202010354046.9A 2020-04-29 2020-04-29 Processing technology of cloisonne water jet mosaic Pending CN111332058A (en)

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CN102173265A (en) * 2010-12-24 2011-09-07 林戈 Process for manufacturing cloisonne jade-inlaid artware
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