CN102350915B - Manufacturing method of filigreeing silver tire fusion-welding cloisonne product - Google Patents
Manufacturing method of filigreeing silver tire fusion-welding cloisonne product Download PDFInfo
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- CN102350915B CN102350915B CN2011103149550A CN201110314955A CN102350915B CN 102350915 B CN102350915 B CN 102350915B CN 2011103149550 A CN2011103149550 A CN 2011103149550A CN 201110314955 A CN201110314955 A CN 201110314955A CN 102350915 B CN102350915 B CN 102350915B
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- silver
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- soldering
- cloisonne
- silk
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- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 title claims abstract description 139
- 229910052709 silver Inorganic materials 0.000 title claims abstract description 139
- 239000004332 silver Substances 0.000 title claims abstract description 139
- 238000003466 welding Methods 0.000 title claims abstract description 16
- 238000004519 manufacturing process Methods 0.000 title abstract description 4
- 239000000843 powder Substances 0.000 claims abstract description 45
- 238000005476 soldering Methods 0.000 claims abstract description 40
- 238000005554 pickling Methods 0.000 claims abstract description 23
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 238000000227 grinding Methods 0.000 claims abstract description 9
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 9
- 239000011701 zinc Substances 0.000 claims abstract description 9
- HJTAZXHBEBIQQX-UHFFFAOYSA-N 1,5-bis(chloromethyl)naphthalene Chemical compound C1=CC=C2C(CCl)=CC=CC2=C1CCl HJTAZXHBEBIQQX-UHFFFAOYSA-N 0.000 claims abstract description 8
- GOLCXWYRSKYTSP-UHFFFAOYSA-N arsenic trioxide Inorganic materials O1[As]2O[As]1O2 GOLCXWYRSKYTSP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000000034 method Methods 0.000 claims abstract description 7
- 238000005498 polishing Methods 0.000 claims abstract description 6
- 210000003298 dental enamel Anatomy 0.000 claims description 35
- 238000005245 sintering Methods 0.000 claims description 18
- 239000000047 product Substances 0.000 claims description 17
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 12
- 229910021538 borax Inorganic materials 0.000 claims description 12
- 239000004328 sodium tetraborate Substances 0.000 claims description 12
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 12
- 238000002360 preparation method Methods 0.000 claims description 11
- 238000010304 firing Methods 0.000 claims description 8
- 229910052751 metal Inorganic materials 0.000 claims description 8
- 239000002184 metal Substances 0.000 claims description 8
- 239000011265 semifinished product Substances 0.000 claims description 8
- 238000002844 melting Methods 0.000 claims description 7
- 230000008018 melting Effects 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 241001313857 Bletilla striata Species 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 6
- 238000007710 freezing Methods 0.000 claims description 6
- 230000008014 freezing Effects 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 238000004080 punching Methods 0.000 claims description 6
- 239000004576 sand Substances 0.000 claims description 6
- 239000002002 slurry Substances 0.000 claims description 6
- 239000007921 spray Substances 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 238000009987 spinning Methods 0.000 claims description 5
- 244000137852 Petrea volubilis Species 0.000 claims description 4
- 238000000748 compression moulding Methods 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 2
- 239000004575 stone Substances 0.000 claims description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract description 7
- 229910052802 copper Inorganic materials 0.000 abstract description 6
- 239000010949 copper Substances 0.000 abstract description 6
- 241001122767 Theaceae Species 0.000 abstract 1
- 230000004907 flux Effects 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 238000007747 plating Methods 0.000 abstract 1
- 238000005516 engineering process Methods 0.000 description 5
- 239000007787 solid Substances 0.000 description 4
- DJHGAFSJWGLOIV-UHFFFAOYSA-N Arsenic acid Chemical compound O[As](O)(O)=O DJHGAFSJWGLOIV-UHFFFAOYSA-N 0.000 description 2
- 229940000488 arsenic acid Drugs 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 244000247747 Coptis groenlandica Species 0.000 description 1
- 235000002991 Coptis groenlandica Nutrition 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000035622 drinking Effects 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Landscapes
- Tyre Moulding (AREA)
- Tires In General (AREA)
Abstract
The invention relates to a manufacturing method of a filigreeing silver tire fusion-welding cloisonne product, comprising the steps of tire making, filigreeing, wire feeding, burn-in, pickling, blue spotting, blue grinding, polishing, gold-plating and the like; and finally finished products are obtained through the steps. Silver soldering medical powders are adopted when burn-in, and the ingredients of the silver soldering medical powders in proportion by weight comprise: 65-70% of silver, 30-35% of red copper, 25-30% of arsenic trioxide and 5-10% of zinc; and the silver soldering medical powders are melt, and then the silver wires are welded on the silver tire. The invention adopts the silver wires to prepare decorative patterns of the cloisonne product, and replaces a traditional copper tire cloisonne filigreeing process, wherein the process of the invention adopts the special silver soldering medical powders and a soldering flux to implement the burn-in; and the cloisonne obtained by the process can be firmly filigreed and located, can never be faded, and has a wear-resisting property, high rigidity and a good effect. The silver tire cloisonne disclosed by the invention can be used for manufacturing various high-grade handicrafts such as various wine sets, tea sets, flower vases, bracelets and the like; and thereby the filigreeing silver tire fusion-welding cloisonne product is beautiful and practical, has a high collection value, and satisfies the requirements of high-grade users.
Description
Technical field
The present invention relates to a kind of preparation method of cloisonne ' products, particularly relate to a kind of preparation method of the silver-colored tire melting welding cloisonne ' products that wires inlay.
Background technology
Cloisonne enamel has another name called " copper tire thread weaving enamel ", is unique handicraft that a kind of porcelain copper combines, and makes base with red copper, processes various moulding, pinches into various flowers with gold thread or copper wire again, wherein fills enamel glaze, and fired, polishing, operation such as gold-plated are processed.The cloisonne enamel moulding is special, makes fineness, and pattern is serious, and color is gorgeous, and is splendid, has distinct national characters, is the traditional outlet handicraft of China.
Along with the continuous development and the market demand of cloisonne handicraft, people need more high-grade cloisonne enamel, require that the cloisonne enamel surface is will never fade, wear-resisting, sound construction, hardness be high, needs to explore better process to obtain better handicraft.
Summary of the invention
The technical problem that the present invention will solve: overcome shortcoming of the prior art, the preparation method of colour-fast, the wear-resisting silver-colored tire melting welding cloisonne ' products that wires inlay in a kind of surface is provided.
Technical scheme of the present invention:
A kind of preparation method of the silver-colored tire melting welding cloisonne ' products that wires inlay may further comprise the steps:
(1) make base: silver strip is cut into the cloisonne ' products size, carries out spinning, welding obtains complete silver tire;
(2) wire inlay: as lines, use punching block compression moulding with thin flat silver silk;
(3) go up silk: the silver silk that will wire inlay is put into stove fire and is fired, treat the deliquescing of silver silk after, clamp the silver silk with tweezers and dip in bletilla striata slurry, according to pattern the silver silk is bonded on the silver tire;
(4) freeze: on the silver tire, evenly spray water, evenly sprinkle one deck (about 0.1-0.5mm is thick) silver soldering medicinal powder and borax then, the weight ratio of silver soldering medicinal powder and borax is 3:1; The silver tire is heated to 780-900 ℃, makes the fusing of silver soldering medicinal powder, the silver wire bond is connected on the silver tire;
Wherein silver soldering medicinal powder composition is: weight ratio is the silver of 65-70%, the red metal of 30-35%, the inferior arsenic acid of the 25-30% of silver soldering medicinal powder weight, the zinc of 5-10%.
(5) pickling: the silver tire after will freezing carried out pickling 10-16 hour;
(6) fill enamel: the color according to indicating is filled in the enamel glaze of getting ready in the silver reel frame on the silver tire, carries out sintering, and sintering temperature is 720-780 ℃, and heating back enamel glaze is molten into liquid, becomes the color glaze layer that anchors on the carcass after cooling; If the color glaze layer is lower than silver reel frame height, then fill enamel glaze, sintering once more once more, 3-4 time so repeatedly, equal with silver reel frame until the color glaze layer;
(7) mill is blue: the semi-finished product that obtain are placed on the blue machine of mill polish with 50 orders, 150 purpose rough sand stone mills, carry out fine grinding respectively with 400 orders, 800 orders, 1500 purpose sand paper respectively then;
(8) polishing, gold-plated: the semi-finished product after the fine grinding are polished, electroplate, obtain finished product at last.
Temperature is 300-600 ℃ when firing in said step (3) stove fire, and the firing time is 30-60 second.
Said silver soldering medicinal powder composition is: the silver of weight ratio 66%, and 34% red metal, other adds the arsenic trioxide of silver soldering medicinal powder weight 25%, 5% zinc.
Said pickling temperature is 40 ℃, and used acid is 20% sulfuric acid.
Positive beneficial effect of the present invention:
(1) the silver-colored tire cloisonne enamel that the wires inlay of the present invention technology of wiring inlay constitutes the decorative pattern of cloisonne ' products with the silver silk, substitutes traditional copper tire cloisonne enamel technology of wiring inlay; Adopt punching block compression moulding in the technology, adopt special silver soldering medicinal powder and scaling powder to freeze, be easy to welding; Firm welding; The cloisonne enamel that obtains wires inlay the location accurately, wear-resisting, hardness is high, will never fade, effective.
(2) the silver-colored tire cloisonne enamel of the present invention technology of wiring inlay adopts spinning process when making base, when wiring inlay the silver silk is used punching block compression moulding, compares with traditional handicraft and has shortened technical process greatly, has improved production efficiency.
(3) silver-colored tire cloisonne enamel of the present invention can be made various high-grade handicrafts such as various drinking utensils, tea set, vase, bracelet, and is both artistic and practical, and reserve value is high, can satisfy high-level customer requirements.
The specific embodiment
Instance one:A kind of preparation method of the silver-colored tire melting welding cloisonne ' products that wires inlay may further comprise the steps:
(1) make base: silver strip is cut into the cloisonne ' products size, carries out spinning, welding obtains complete silver tire;
(2) wire inlay: as lines, be pressed with punching block with thin flat silver silk;
(3) go up silk: will wire inlay and put into stove fire and fire, treat the deliquescing of silver silk after, clamp the silver silk with tweezers and dip in bletilla striata slurry, the silver silk that will pinch according to pattern is bonded on the silver tire; Temperature was 300-600 ℃ when stove fire was fired, and the firing time is 30-60 second;
(4) freeze: on the silver tire of first-class silk, evenly spray water; Evenly sprinkle one deck (about 0.1-0.5mm is thick) silver soldering medicinal powder and borax then; The weight ratio of silver soldering medicinal powder and borax is 3:1, is heated to 780-900 ℃ and makes the fusing of silver soldering medicinal powder, and the silver wire bond is connected on the silver tire;
Wherein silver soldering medicinal powder composition (percentage by weight) is: silver 66%, red metal 34%, and other adds the zinc of inferior arsenic acid (being arsenic trioxide), 5-10% of silver soldering medicinal powder weight 25-30% as scaling powder;
(5) pickling: the silver tire after will freezing carries out pickling, and pickling temperature is 40 ℃, and the pickling time is 16 hours, and used acid is the sulfuric acid of mass content 20%;
(6) fill enamel: the enamel glaze of getting ready is filled in the silver reel frame on the silver tire carries out sintering; Sintering temperature is 720-780 ℃, and enamel glaze is molten into liquid by the sand shape solid, becomes the color glaze layer that anchors on the carcass after cooling; If the color glaze layer is lower than silver reel frame height; Then fill enamel glaze, sintering once more once more, 3-4 time so repeatedly, equal with silver reel frame until the color glaze layer;
(7) mill is blue: the semi-finished product that obtain are placed on mill Lan Jishang, polish with 50 orders, 150 purpose sandstone mill, carry out fine grinding with 400 orders, 800 orders, 1500 purpose sand paper respectively then;
(8) polishing, silver-plated: the semi-finished product after the fine grinding are polished, electroplate, obtain finished product.
Instance two:The wire inlay preparation method of silver-colored tire melting welding cloisonne ' products may further comprise the steps:
(1) make base: silver strip is cut into the cloisonne ' products size, carries out spinning, welding obtains complete silver tire;
(2) wire inlay: as lines, be pressed with punching block with thin flat silver silk;
(3) go up silk: will wire inlay and put into stove fire and fire, treat the deliquescing of silver silk after, clamp the silver silk with tweezers and dip in bletilla striata slurry, the silver silk that will pinch according to pattern is bonded on the silver tire; Temperature was 300-500 ℃ when stove fire was fired, and the firing time is 40-60 second;
(4) freeze: on the silver tire of first-class silk, evenly spray water, evenly sprinkle one deck silver soldering medicinal powder and borax then, the weight ratio of silver soldering medicinal powder and borax is 3:1, is heated to 780-900 ℃ and makes the fusing of silver soldering medicinal powder, and the silver wire bond is connected on the silver tire; Wherein silver soldering medicinal powder composition is: silver 66%, red metal 34%; Other adds the arsenic trioxide, 10% zinc of silver soldering medicinal powder weight 30% as scaling powder;
(5) pickling: the silver tire after will freezing carries out pickling, and pickling temperature is 40 ℃, and the pickling time is 16 hours, and used acid is the sulfuric acid of mass content 20%;
(6) fill enamel: the enamel glaze of getting ready is filled in the silver reel frame on the silver tire carries out sintering; Sintering temperature is 720-780 ℃, and enamel glaze is molten into liquid by the sand shape solid, becomes the color glaze layer that anchors on the carcass after cooling; If the color glaze layer is lower than silver reel frame height; Then fill enamel glaze, sintering once more once more, 3-4 time so repeatedly, equal with silver reel frame until the color glaze layer;
(7) mill is blue: the semi-finished product that obtain are placed on mill Lan Jishang, polish with 50 orders, 150 purpose sandstone mill, carry out fine grinding with 400 orders, 800 orders, 1500 purpose sand paper respectively then;
(8) polishing, silver-plated: the semi-finished product after the fine grinding are polished, electroplate, obtain finished product.
Instance three:Basic identical with example one, something in common is no longer narrated, and difference is:
(3) go up silk: will wire inlay and put into stove fire and fire, treat the deliquescing of silver silk after, clamp the silver silk with tweezers and dip in bletilla striata slurry, the silver silk that will pinch according to pattern is bonded on the silver tire; Temperature was 500 ℃ when stove fire was fired, and the firing time is 50 seconds; Right
(4) freeze: on the silver tire of first-class silk, evenly spray water, evenly sprinkle one deck silver soldering medicinal powder and borax then, the weight ratio of silver soldering medicinal powder and borax is 3:1, is heated to 780-900 ℃ and makes the fusing of silver soldering medicinal powder, and the silver wire bond is connected on the silver tire;
Wherein silver soldering medicinal powder composition is: silver 65%, red metal 35%, and other adds the arsenic trioxide, 8% zinc of silver soldering medicinal powder weight 25% as scaling powder;
(5) pickling: the silver tire after will freezing carries out pickling, and pickling temperature is 40 ℃, and the pickling time is 12 hours, and used acid is the sulfuric acid of mass content 20%;
(6) fill enamel: the enamel glaze of getting ready is filled in the silver reel frame on the silver tire carries out sintering; Sintering temperature is 780 ℃, and enamel glaze is molten into liquid by the sand shape solid, becomes the color glaze layer that anchors on the carcass after cooling; If the color glaze layer is lower than silver reel frame height; Then fill enamel glaze, sintering once more once more, 3 times so repeatedly, equal with silver reel frame until the color glaze layer.
Instance four:Basic identical with example one, something in common is no longer narrated, and difference is:
(3) go up silk: will wire inlay and put into stove fire and fire, treat the deliquescing of silver silk after, clamp the silver silk with tweezers and dip in bletilla striata slurry, the silver silk that will pinch according to pattern is bonded on the silver tire; Temperature was 600 ℃ when stove fire was fired, and the firing time is 30 seconds;
(4) freeze: on the silver tire of first-class silk, evenly spray water, evenly sprinkle one deck silver soldering medicinal powder and borax then, the weight ratio of silver soldering medicinal powder and borax is 3:1, is heated to 780-900 ℃ and makes the fusing of silver soldering medicinal powder, and the silver wire bond is connected on the silver tire;
Wherein silver soldering medicinal powder composition is: silver 66%, red metal 34%, and other adds the arsenic trioxide, 5% zinc of silver soldering medicinal powder weight 28% as scaling powder;
(5) pickling: the silver tire after will freezing carries out pickling, and pickling temperature is 40 ℃, and the pickling time is 10-16 hour, and used acid is the sulfuric acid of mass content 20%;
(6) fill enamel: the enamel glaze of getting ready is filled in the silver reel frame on the silver tire carries out sintering; Sintering temperature is 720 ℃, and enamel glaze is molten into liquid by the sand shape solid, becomes the color glaze layer that anchors on the carcass after cooling; If the color glaze layer is lower than silver reel frame height; Then fill enamel glaze, sintering once more once more, 3-4 time so repeatedly, equal with silver reel frame until the color glaze layer.
Claims (4)
1. preparation method of silver-colored tire melting welding cloisonne ' products of wiring inlay is characterized in that this method may further comprise the steps:
(1) make base: silver strip is cut into the cloisonne ' products size, carries out spinning, welding obtains complete silver tire;
(2) wire inlay: as lines, use punching block compression moulding with thin flat silver silk;
(3) go up silk: the silver silk that will wire inlay is put into stove fire and is fired, treat the deliquescing of silver silk after, clamp the silver silk with tweezers and dip in bletilla striata slurry, according to pattern the silver silk is bonded on the silver tire;
(4) freeze: on the silver tire, evenly spray water, evenly sprinkle one deck silver soldering medicinal powder and borax then, the weight ratio of silver soldering medicinal powder and borax is 3:1; The silver tire is heated to 780-900 ℃, makes the fusing of silver soldering medicinal powder, the silver wire bond is connected on the silver tire;
Wherein silver soldering medicinal powder is that the silver of 65-70%, the red metal of 30-35% are formed by percentage by weight, and other adds the zinc of arsenic trioxide, 5-10% of the 25-30% of silver soldering medicinal powder weight as scaling powder;
(5) pickling: the silver tire after will freezing carried out pickling 10-16 hour;
(6) fill enamel: the color according to indicating is filled in the enamel glaze of getting ready in the silver reel frame on the silver tire, carries out sintering, and sintering temperature is 720-780 ℃, and heating back enamel glaze is molten into liquid, becomes the color glaze layer that anchors on the carcass after cooling; If the color glaze layer is lower than silver reel frame height, then fill enamel glaze, sintering once more once more, 3-4 time so repeatedly, equal with silver reel frame until the color glaze layer;
(7) mill is blue: the semi-finished product that obtain are placed on the blue machine of mill polish with 50 orders, 150 purpose rough sand stone mills respectively, carry out fine grinding respectively with 400 orders, 800 orders, 1500 purpose sand paper respectively then;
(8) polishing, gold-plated: the semi-finished product after the fine grinding are polished, electroplate, obtain finished product at last.
2. preparation method according to claim 1 is characterized in that, temperature is 300-600 ℃ when firing in said step (3) stove fire, and the firing time is 30-60 second.
3. preparation method according to claim 1 is characterized in that, said silver soldering medicinal powder composition is: the silver of weight ratio 66%, 34% red metal, other adds the arsenic trioxide of silver soldering medicinal powder weight 25%, 5% zinc.
4. preparation method according to claim 1 is characterized in that, said pickling temperature is 40 ℃, and used acid is 20% sulfuric acid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011103149550A CN102350915B (en) | 2011-10-18 | 2011-10-18 | Manufacturing method of filigreeing silver tire fusion-welding cloisonne product |
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| Application Number | Priority Date | Filing Date | Title |
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| CN2011103149550A CN102350915B (en) | 2011-10-18 | 2011-10-18 | Manufacturing method of filigreeing silver tire fusion-welding cloisonne product |
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| CN102350915A CN102350915A (en) | 2012-02-15 |
| CN102350915B true CN102350915B (en) | 2012-10-31 |
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Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103624863B (en) * | 2013-12-05 | 2016-09-21 | 赵爱民 | Welding agent in the gold tire melting welding cloisonne ' products that wires inlay and the manufacture method of cloisonne ' products |
| CN103738099B (en) * | 2013-12-26 | 2016-04-06 | 乌鲁木齐哈玛铜制工艺品有限公司 | A kind of making method of copper artwork |
| CN105082861A (en) * | 2014-05-22 | 2015-11-25 | 过鹏儒 | Novel silver blank enamel manufacturing process |
| CN104473392B (en) * | 2014-11-19 | 2015-11-18 | 河南梦祥纯银制品有限公司 | A kind of manufacturing process of silver-colored painted enamel |
| CN104527294B (en) * | 2014-12-29 | 2018-05-08 | 北京汉艺煌景泰蓝工艺品有限公司 | Exempt from gold-plated cloisonne enamel technique |
| CN104894565B (en) * | 2015-05-08 | 2017-10-10 | 河南梦祥纯银制品有限公司 | A kind of method for boiling silver product |
| CN104894578B (en) * | 2015-05-08 | 2019-01-18 | 河南梦祥纯银制品有限公司 | A kind of production method of primary colors silver |
| CN104889827B (en) * | 2015-05-08 | 2017-05-24 | 河南梦祥纯银制品有限公司 | Method for polishing silver product |
| CN104908503B (en) * | 2015-06-30 | 2017-10-31 | 丹寨县国春银饰有限责任公司 | A kind of method for normalizing of fine silver silk establishment peacock |
| CN107933178A (en) * | 2017-11-01 | 2018-04-20 | 丽江木氏贡银商贸有限公司 | A kind of production method of enamel silver vase |
| CN108081850B (en) * | 2017-12-28 | 2020-05-19 | 卓见 | Copper carving enamel glass ware and manufacturing method |
| CN109017105B (en) * | 2018-08-29 | 2021-01-05 | 河南梦祥纯银制品有限公司 | Method for manufacturing surface applique of noble metal jewelry |
| CN109530965B (en) * | 2018-12-28 | 2020-11-10 | 云南乌铜走银文化产业有限公司 | Soldering lug for manufacturing black copper by silver and preparation method thereof |
| CN111732454A (en) * | 2020-06-11 | 2020-10-02 | 刘永腾 | Method for manufacturing cloisonne enamel on ceramic body and purple sand body |
| CN112659802B (en) * | 2020-12-18 | 2022-08-02 | 昆明德源文化传播有限公司 | Method for manufacturing cloisonne enamel color painting made of tin material |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57200563A (en) * | 1981-06-04 | 1982-12-08 | Ise Kogyo Kk | Cloisonne |
| CN1644402A (en) * | 2005-01-31 | 2005-07-27 | 苗新田 | Cloisonne enamel production |
| CN101362416A (en) * | 2008-09-23 | 2009-02-11 | 上海康宇杰森水晶艺术品有限公司 | Cloisonne products through cupronickel fusion welding and production technology thereof |
| CN102173271B (en) * | 2011-01-27 | 2012-12-12 | 山西银满楼景泰蓝银器制品有限公司 | Process of manufacturing cloisonne silverware |
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- 2011-10-18 CN CN2011103149550A patent/CN102350915B/en active Active
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| CN102350915A (en) | 2012-02-15 |
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