CN104404499A - Spot-bronze coloring liquid and application thereof - Google Patents
Spot-bronze coloring liquid and application thereof Download PDFInfo
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- CN104404499A CN104404499A CN201410614963.0A CN201410614963A CN104404499A CN 104404499 A CN104404499 A CN 104404499A CN 201410614963 A CN201410614963 A CN 201410614963A CN 104404499 A CN104404499 A CN 104404499A
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- Prior art keywords
- spot
- coloring liquid
- copper
- foundry goods
- weight part
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- 238000004040 coloring Methods 0.000 title claims abstract description 61
- 239000007788 liquid Substances 0.000 title claims abstract description 61
- 229910000906 Bronze Inorganic materials 0.000 title abstract 8
- 239000010974 bronze Substances 0.000 title abstract 8
- 238000002360 preparation method Methods 0.000 claims abstract description 19
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims abstract description 13
- 239000002994 raw material Substances 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910052956 cinnabar Inorganic materials 0.000 claims abstract description 7
- 229910000365 copper sulfate Inorganic materials 0.000 claims abstract description 7
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims abstract description 7
- 239000012153 distilled water Substances 0.000 claims abstract description 7
- WUUHFRRPHJEEKV-UHFFFAOYSA-N tripotassium borate Chemical compound [K+].[K+].[K+].[O-]B([O-])[O-] WUUHFRRPHJEEKV-UHFFFAOYSA-N 0.000 claims abstract description 7
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 46
- 229910052802 copper Inorganic materials 0.000 claims description 46
- 239000010949 copper Substances 0.000 claims description 46
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 20
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 12
- 238000005266 casting Methods 0.000 claims description 8
- 238000004140 cleaning Methods 0.000 claims description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 6
- 229910001297 Zn alloy Inorganic materials 0.000 claims description 6
- 238000009835 boiling Methods 0.000 claims description 6
- TVZPLCNGKSPOJA-UHFFFAOYSA-N copper zinc Chemical compound [Cu].[Zn] TVZPLCNGKSPOJA-UHFFFAOYSA-N 0.000 claims description 6
- 229910052742 iron Inorganic materials 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 4
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 3
- DPDMMXDBJGCCQC-UHFFFAOYSA-N [Na].[Cl] Chemical compound [Na].[Cl] DPDMMXDBJGCCQC-UHFFFAOYSA-N 0.000 claims description 3
- 229910017604 nitric acid Inorganic materials 0.000 claims description 3
- 238000000034 method Methods 0.000 abstract description 8
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 239000007769 metal material Substances 0.000 abstract description 2
- 238000004381 surface treatment Methods 0.000 abstract description 2
- 238000005562 fading Methods 0.000 abstract 1
- 235000011164 potassium chloride Nutrition 0.000 abstract 1
- 239000001103 potassium chloride Substances 0.000 abstract 1
- 244000137852 Petrea volubilis Species 0.000 description 4
- 238000007654 immersion Methods 0.000 description 4
- FFRBMBIXVSCUFS-UHFFFAOYSA-N 2,4-dinitro-1-naphthol Chemical compound C1=CC=C2C(O)=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 FFRBMBIXVSCUFS-UHFFFAOYSA-N 0.000 description 1
- 229910001369 Brass Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910052948 bornite Inorganic materials 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000002223 garnet Substances 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000004018 waxing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/68—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous solutions with pH between 6 and 8
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Mold Materials And Core Materials (AREA)
Abstract
The invention discloses a spot-bronze coloring liquid and an application thereof, and belongs to the field of metal material surface treatment and handicraft making. The coloring liquid is prepared by using the following raw materials, by weight, 10-20 parts of copper sulfate, 6-15 parts of potassium chloride, 1-4 parts of potassium borate, 4-12 parts of cinnabar and 150-300 parts of distilled water. The coloring liquid is used in spot-bronze production to obtain dark red spot-bronze, and spot-bronze obtained in the invention has unsophisticated and beautiful appearance; the color of the spot-bronze can be controlled according to the time length and personal preference, and can be dark or brilliant, and the preparation process is flexible and controllable; the obtained spot-bronze has the characteristics of stability, and no color change or fading; and a making method of the spot-bronze has the advantages of simple operation, low production cost, non-restriction by the shape of a product, and beautiful color of the product.
Description
Technical field
The present invention relates to a kind of coloring liquid and application of spot copper, belong to surface treatment and the ornameutal handiwork field of metallic substance.
Background technology
Spot copper is as the peculiar brass in Yunnan, and it adopts high-grade copper-based alloy material, and through shape-designing, casting, Seiko is polished and the subsequent technique process making of other complexity obtains, and obtains the speckle being mingled with shape, varying in color.Spot copper has been valued for spot, speckle dimly visible in Copper base material make bornite handicraft have red in the marvellous color of thoroughly spot, golden yellow friendship brightness, be the exclusive a kind of special warfare of China.The surface of its maroon, the speckle presented, has simple and honest, simple and unsophisticated, elegant impression, can be rated as the hat of smithcraft.Its surface shows the staggered color of various irregular magnificent decorative pattern and golden red, is the distinctive folk traditional craft product in Yunnan Province, is also the traditional handicraft product that China shows unique characteristics, has very high artistic value.Current spot copper main " ripe spot ", because " ripe spot " is synthetic, and raw material sources is sufficient, so in moulding, the artwork variation that " ripe spot " makes, and not by the restriction of volume size, dissimilar circular engravure, high relief and bas-relief all can make." give birth to spot " because its starting material are rare, processed complex, cost is higher, and industrial scale is less, can only be used for manufacturing simple, that the scale of construction is small and exquisite ancient cooking vessel, stove, bottle etc.
The object of the invention is to propose a kind of new spot copper production method, adopt the spot coppery Ze Huali that present method is produced, and it is low to have cost, and simple to operate, color controllable is good, and the advantage such as can be mass-produced.Alleviate the short supply state of " raw spot " raw material to a certain extent, and provide technical guarantee for the casting of spot copper and retrofit.
Summary of the invention
The object of the present invention is to provide a kind of coloring liquid of spot copper, described coloring liquid is obtained by following preparation of raw material, copper sulfate 10 ~ 20 weight part, Repone K 6 ~ 15 weight part, potassium borate 4 ~ 12 weight part, cinnabar 1 ~ 4 weight part, distilled water 150 ~ 300 weight part.
Another object of the present invention is to provide the coloring liquid of described spot copper for the preparation of the method for spot copper, specifically comprise the following steps:
(1) put into diluted acid after foundry goods being polished and soak 3 ~ 5min, then foundry goods is cleaned up;
(2) foundry goods after cleaning in step (2) is put in aobvious spot solution reacts 5 ~ 10 minutes, the foundry goods after aobvious spot is cleaned;
(3) described coloring liquid is placed at normal temperatures and is obtained coloring liquid A in 6 ~ 8 days, and directly configuration obtains coloring liquid B;
(4) coloring liquid A is boiled directly water (consumption of coloring liquid A at least can drench whole foundry goods) on foundry goods afterwards, then foundry goods is put into the coloring liquid B after boiling and boil 25 ~ 40min, 8 ~ 14h is soaked after cool to room temperature, the height of coloring liquid exceedes foundry goods 6 ~ 10cm, rinses well and obtains dark red color spot copper casting.
The copper zinc alloy foundry goods of foundry goods of the present invention to be copper content be 93 ~ 97wt%.
Diluted acid of the present invention is hydrochloric acid, sulfuric acid or nitric acid, and its concentration is 10 ~ 12mol/L.
The composition of aobvious spot solution of the present invention is iron(ic) chloride 7 ~ 9wt%, hydrochloric acid 8 ~ 10wt%, Repone K or sodium-chlor 0.5 ~ 1wt%.
Cleaning process in described the present invention all adopts clear water to rinse.
The present invention compared with prior art has following advantages and effect:
(1) the spot copper color that coloring liquid of the present invention prepares is garnet or redness, can be used to prepare various artwork color and luster simple and unsophisticated magnificent, because the preparation process reaction times is longer, therefore the spot copper color controllable for preparing of described method is fine, the color of gained spot copper can be controlled according to the length of time and individual hobby, color is more thick and heavy can be grown some the time, and the more bright-colored time can be a little less, and preparation process is controlled flexibly;
(2) gained spot copper stability is fine, exposes not easy to change in atmosphere, facilitates waxing and processing further in subsequent process; Spot copper abundant raw materials of the present invention, production cost is low, simple to operate, and preparation process is not by the restriction of shape of product.
Embodiment
Below in conjunction with embodiment, the present invention is described further, but the invention is not restricted to the following stated scope.
Embodiment 1
Described in the present embodiment, the coloring liquid of spot copper is obtained by following preparation of raw material, copper sulfate 10 weight part, Repone K 6 weight part, potassium borate 4 weight part, cinnabar 1 weight part, distilled water 150 weight part.
Coloring liquid described in the present embodiment, for the preparation of spot copper, specifically comprises the following steps:
(1) polish to the copper zinc alloy foundry goods that copper content is 93wt% with sand paper, guarantee cast(ing) surface is level and smooth without hole, puts into the hydrochloric acid immersion removal surface oxide layer that concentration is 10mol/L, then foundry goods is cleaned up;
(2) foundry goods after cleaning being put into composition is iron(ic) chloride 8.1wt%, corrode 5 minutes in the aobvious spot solution of hydrochloric acid 9.6wt%, Repone K 0.8wt%, foundry goods just there will be the spot differed in size, then the foundry goods after aobvious spot is cleaned, ensure the not aobvious spot solution of cast(ing) surface;
(3) described coloring liquid is placed at normal temperatures and is obtained coloring liquid A in 6 days, and directly configuration obtains coloring liquid B;
(4) coloring liquid A is boiled rear directly watering on foundry goods, then foundry goods is put into the coloring liquid B after boiling and boil 25min, soak 14h after cool to room temperature, the height of coloring liquid exceedes foundry goods 6cm, rinses well and obtains dark red color spot copper casting.
Embodiment 2
Described in the present embodiment, the coloring liquid of spot copper is obtained by following preparation of raw material, copper sulfate 13 weight part, Repone K 9 weight part, potassium borate 8 weight part, cinnabar 2 weight part, distilled water 180 weight part.
Coloring liquid described in the present embodiment, for the preparation of spot copper, specifically comprises the following steps:
(1) polish to the copper zinc alloy foundry goods that copper content is 95wt% with sand paper, guarantee cast(ing) surface is level and smooth without hole, puts into the sulfuric acid immersion removal surface oxide layer that concentration is 11mol/L, then foundry goods is cleaned up;
(2) foundry goods after cleaning being put into composition is iron(ic) chloride 7wt%, corrode 8 minutes in the aobvious spot solution of hydrochloric acid 10wt%, Repone K 0.5wt%, foundry goods just there will be the spot differed in size, then the foundry goods after aobvious spot is cleaned, ensure the not aobvious spot solution of cast(ing) surface;
(3) described coloring liquid is placed at normal temperatures and is obtained coloring liquid A in 7 days, and directly configuration obtains coloring liquid B;
(4) coloring liquid A is boiled rear directly watering on foundry goods, then foundry goods is put into the coloring liquid B after boiling and boil 30min, soak 8h after cool to room temperature, the height of coloring liquid exceedes foundry goods 7cm, rinses well and obtains dark red color spot copper casting.
Embodiment 3
Described in the present embodiment, the coloring liquid of spot copper is obtained by following preparation of raw material, copper sulfate 16 weight part, Repone K 13 weight part, potassium borate 10 weight part, cinnabar 3 weight part, distilled water 300 weight part.
Coloring liquid described in the present embodiment, for the preparation of spot copper, specifically comprises the following steps:
(1) polish to the copper zinc alloy foundry goods that copper content is 97wt% with sand paper, guarantee cast(ing) surface is level and smooth without hole, puts into the hydrochloric acid immersion removal surface oxide layer that concentration is 12mol/L, then foundry goods is cleaned up;
(2) foundry goods after cleaning being put into composition is iron(ic) chloride 9wt%, corrode 10 minutes in the aobvious spot solution of hydrochloric acid 8wt%, sodium-chlor 1wt%, foundry goods just there will be the spot differed in size, then the foundry goods after aobvious spot is cleaned, ensure the not aobvious spot solution of cast(ing) surface;
(3) described coloring liquid is placed at normal temperatures and is obtained coloring liquid A in 7.5 days, and directly configuration obtains coloring liquid B;
(4) coloring liquid A is boiled rear directly watering on foundry goods, then foundry goods is put into the coloring liquid B after boiling and boil 35min, soak 10h after cool to room temperature, the height of coloring liquid exceedes foundry goods 8cm, rinses well and obtains dark red color spot copper casting.
Embodiment 4
Described in the present embodiment, the coloring liquid of spot copper is obtained by following preparation of raw material, copper sulfate 20 weight part, Repone K 15 weight part, potassium borate 12 weight part, cinnabar 4 weight part, distilled water 200 weight part.
Coloring liquid described in the present embodiment, for the preparation of spot copper, specifically comprises the following steps:
(1) polish to the copper zinc alloy foundry goods that copper content is 95wt% with sand paper, guarantee cast(ing) surface is level and smooth without hole, puts into the nitric acid immersion removal surface oxide layer that concentration is 12mol/L, then foundry goods is cleaned up;
(2) foundry goods after cleaning being put into composition is iron(ic) chloride 9wt%, corrode 10 minutes in the aobvious spot solution of hydrochloric acid 8wt%, Repone K 0.8wt%, foundry goods just there will be the spot differed in size, then the foundry goods after aobvious spot is cleaned, ensure the not aobvious spot solution of cast(ing) surface;
(3) described coloring liquid is placed at normal temperatures and is obtained coloring liquid A in 8 days, and directly configuration obtains coloring liquid B;
(4) coloring liquid A is boiled rear directly watering on foundry goods, then foundry goods is put into the coloring liquid B after boiling and boil 40min, soak 12h after cool to room temperature, the height of coloring liquid exceedes foundry goods 10cm, rinses well and obtains dark red color spot copper casting.
Claims (5)
1. a coloring liquid for spot copper, is characterized in that: described coloring liquid is obtained by following preparation of raw material, copper sulfate 10 ~ 20 weight part, Repone K 6 ~ 15 weight part, potassium borate 4 ~ 12 weight part, cinnabar 1 ~ 4 weight part, distilled water 150 ~ 300 weight part.
2. the coloring liquid of spot copper described in claim 1 is for the preparation of spot copper, it is characterized in that specifically comprising the following steps:
(1) put into diluted acid after foundry goods being polished and soak 3 ~ 5min, then foundry goods is cleaned up;
(2) foundry goods after cleaning in step (2) is put in aobvious spot solution reacts 5 ~ 10 minutes, the foundry goods after aobvious spot is cleaned;
(3) described coloring liquid is placed at normal temperatures and is obtained coloring liquid A in 6 ~ 8 days, and directly configuration obtains coloring liquid B;
(4) coloring liquid A is boiled rear directly watering on foundry goods, then foundry goods is put into the coloring liquid B after boiling and boil 25 ~ 40min, soak 8 ~ 14h after cool to room temperature, the height of coloring liquid exceedes foundry goods 6 ~ 10cm, rinses well and obtains dark red color spot copper casting.
3. the coloring liquid of spot copper, for the preparation of spot copper, is characterized in that according to claim 2: the copper zinc alloy foundry goods of described foundry goods to be copper content be 93 ~ 97wt%.
4. the coloring liquid of spot copper, for the preparation of spot copper, is characterized in that according to claim 2: described diluted acid is hydrochloric acid, sulfuric acid or nitric acid, and its concentration is 10 ~ 12mol/L.
5. the coloring liquid of spot copper, for the preparation of spot copper, is characterized in that according to claim 2: the composition of described aobvious spot solution is iron(ic) chloride 7 ~ 9wt%, hydrochloric acid 8 ~ 10wt%, Repone K or sodium-chlor 0.5 ~ 1wt%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410614963.0A CN104404499B (en) | 2014-11-05 | 2014-11-05 | The coloring liquid of a kind of speckle copper and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410614963.0A CN104404499B (en) | 2014-11-05 | 2014-11-05 | The coloring liquid of a kind of speckle copper and application |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104404499A true CN104404499A (en) | 2015-03-11 |
| CN104404499B CN104404499B (en) | 2016-09-14 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410614963.0A Expired - Fee Related CN104404499B (en) | 2014-11-05 | 2014-11-05 | The coloring liquid of a kind of speckle copper and application |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104404499B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106756973A (en) * | 2016-11-29 | 2017-05-31 | 云南兴达工艺美术有限公司 | A kind of color method of spot bronze, brass or copper ware tool |
| CN107672376A (en) * | 2017-09-30 | 2018-02-09 | 铜仁市万山区天下红实业发展有限责任公司 | A kind of processing method of cinnabar relief painting |
| CN108866532A (en) * | 2017-05-16 | 2018-11-23 | 王淑琴 | A kind of surface treatment method for making bronze, brass or copper ware that there is packet slurry effect |
| CN112144045A (en) * | 2020-09-21 | 2020-12-29 | 河北师范大学 | Method for changing color of copper foil at room temperature |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2012173399A (en) * | 2011-02-18 | 2012-09-10 | Jsr Corp | Coloring composition, color filter and display element |
| CN102691060A (en) * | 2012-06-14 | 2012-09-26 | 昆明理工大学 | Coloring process for spot copper |
| CN102899647A (en) * | 2012-09-07 | 2013-01-30 | 昆明理工大学 | Coloring method for red spot copper |
-
2014
- 2014-11-05 CN CN201410614963.0A patent/CN104404499B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2012173399A (en) * | 2011-02-18 | 2012-09-10 | Jsr Corp | Coloring composition, color filter and display element |
| CN102691060A (en) * | 2012-06-14 | 2012-09-26 | 昆明理工大学 | Coloring process for spot copper |
| CN102899647A (en) * | 2012-09-07 | 2013-01-30 | 昆明理工大学 | Coloring method for red spot copper |
Non-Patent Citations (1)
| Title |
|---|
| 王少龙 等: "云南斑铜的显斑着色工艺研究", 《表面技术》 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106756973A (en) * | 2016-11-29 | 2017-05-31 | 云南兴达工艺美术有限公司 | A kind of color method of spot bronze, brass or copper ware tool |
| CN108866532A (en) * | 2017-05-16 | 2018-11-23 | 王淑琴 | A kind of surface treatment method for making bronze, brass or copper ware that there is packet slurry effect |
| CN107672376A (en) * | 2017-09-30 | 2018-02-09 | 铜仁市万山区天下红实业发展有限责任公司 | A kind of processing method of cinnabar relief painting |
| CN107672376B (en) * | 2017-09-30 | 2019-12-31 | 铜仁市万山区天下红实业发展有限责任公司 | Processing and manufacturing method of cinnabar relief painting |
| CN112144045A (en) * | 2020-09-21 | 2020-12-29 | 河北师范大学 | Method for changing color of copper foil at room temperature |
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| Publication number | Publication date |
|---|---|
| CN104404499B (en) | 2016-09-14 |
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Granted publication date: 20160914 Termination date: 20211105 |