CN111296418A - Flax seed coating agent and preparation method and application thereof - Google Patents

Flax seed coating agent and preparation method and application thereof Download PDF

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Publication number
CN111296418A
CN111296418A CN202010257463.1A CN202010257463A CN111296418A CN 111296418 A CN111296418 A CN 111296418A CN 202010257463 A CN202010257463 A CN 202010257463A CN 111296418 A CN111296418 A CN 111296418A
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flax
agent
coating agent
seed coating
flax seed
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Inventor
杨崇庆
颉瑞霞
张新学
穆兰海
牛永岐
张久盘
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Ningxia Academy Of Agriculture And Forestry Sciences Guyuan Branch
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Ningxia Academy Of Agriculture And Forestry Sciences Guyuan Branch
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • A01N25/04Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01CPLANTING; SOWING; FERTILISING
    • A01C1/00Apparatus, or methods of use thereof, for testing or treating seed, roots, or the like, prior to sowing or planting
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01CPLANTING; SOWING; FERTILISING
    • A01C1/00Apparatus, or methods of use thereof, for testing or treating seed, roots, or the like, prior to sowing or planting
    • A01C1/06Coating or dressing seed
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01GHORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G22/00Cultivation of specific crops or plants not otherwise provided for
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/06Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
    • A01N43/12Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings condensed with a carbocyclic ring
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647Triazoles; Hydrogenated triazoles
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N45/00Biocides, pest repellants or attractants, or plant growth regulators, containing compounds having three or more carbocyclic rings condensed among themselves, at least one ring not being a six-membered ring
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N61/00Biocides, pest repellants or attractants, or plant growth regulators containing substances of unknown or undetermined composition, e.g. substances characterised only by the mode of action

Abstract

The invention discloses a flax seed coating agent and a preparation method and application thereof. Adding polyglutamic acid, a growth regulator, a dispersing agent, an anticaking agent, a film forming agent, a filler, a preservative, a coloring agent and water in an emulsifying and dispersing machine according to a ratio, and stirring and mixing; homogenizing and dispersing the mixed solution under vacuum and airtight conditions, uniformly adding into a sand mill at a constant speed, grinding, adding a suspending agent into an aqueous solution prepared according to a ratio to adjust the viscosity, and uniformly mixing and stirring to obtain a flax seed coating agent; the coating agent comprises, by mass, 0.5-1 part of polyglutamic acid, 0.05-0.1 part of a growth regulator, 2-7 parts of a dispersing agent, 1-4 parts of an anticaking agent, 1-6 parts of a suspending agent, 0.1-3 parts of a film forming agent, 1-10 parts of a filler, 1-3 parts of a preservative, 0.5-5 parts of a colorant and 60.95-83.85 parts of water. The flax seed coating agent can obviously improve the lodging resistance of flax after the flax seeds are coated and sown.

Description

Flax seed coating agent and preparation method and application thereof
Technical Field
The invention belongs to the technical field of agricultural production, and particularly relates to a flax seed coating agent, a preparation method thereof and application thereof in improving the lodging resistance of flax.
Background
The sesame is one of five major oil crops in China, and is mainly distributed in Gansu, inner Mongolia, Shanxi, Ningxia, Hebei, Xinjiang and the like, the sesame has rich nutrient components, the sesame seeds are called as functional food of the 21 st century, the oil content of the seeds reaches 38-45%, the alpha-linolenic acid content is 40-60%, the linoleic acid content is 16.7%, the sesame seed further contains 18 amino acids, three vitamins, 8 trace elements and rich lignans, proteins and the like which are necessary for human bodies, is α -oil crops with the highest linolenic acid content, is also an important green food resource for improving the living and health level of people, the food therapy and health care effects of the sesame seed are known by more and more people, and the sesame oil can play roles of reducing blood pressure, blood fat and cholesterol after being frequently eaten, and has an inhibiting effect on anaphylactic reaction and tumors.
The lodging problem of the flax is increasingly prominent in production in addition to the restriction of drought, rain, diseases, pests and weeds in the development of the flax industry in China, and the flax is a densely planted crop, has long branches and multiple branches, loose plant shapes, dispersed leaves, flowers and fruits in a larger space and range, easily deviated center of gravity, difficult to recover after deviation, closed canopy and easy to be influenced by external forces such as wind, rain and the like, so that the lodging degree is aggravated, and the lodging of the flax is more common and serious than that of other crops such as wheat and the like under the same conditions. After the flax is laid down, the flax is greedy and late-maturing, the synthesis and running of dry matters are blocked, metabolic dysfunction occurs, partial nutritive organs reappear, the accumulation of the dry matters is influenced, and the serious yield reduction and the quality reduction are caused. In recent years, investigation of flax production data shows that in an ecological region with the annual rainfall of 350-450 mm, rainwater is abundant in autumn, flax is in the period from blooming to fruiting, and the flax is more seriously lodging in rainy and windy days, and the yield reduction caused by the flax lodging is up to 29-64% by measurement.
Under the current production conditions, besides the breeding of the variety with lodging resistance, the enhancement of the lodging resistance of the flax by the cultivation technology has important application value for ensuring the stable yield and the mechanized harvest of the flax. In production, the flax lodging is of two types, namely stem lodging and root lodging, the flax is likely to lodging in different degrees due to weather between a rapid growth period and a mature period, the lodging from a flowering period to a mature period is common, a large amount of rainwater can be attached to the flax plant crowns in the weather of heavy wind and rainfall, the stem lodging can occur due to the fact that the bearing capacity of the stems is exceeded, the flax stem flexibility is good, the lodging can not damage the stem transportation and conduction tissue of the flax generally, the flax plant crowns can recover after rainwater is evaporated in fine weather, but sometimes the flax plant crowns which are fallen from stems are wound with each other and can not recover due to wind direction instability, the lower layer lodging flax cannot be photosynthetic due to the shielding of the upper layer flax, and the yield loss of the flax is serious. The root lodging is caused by the injury of the conduction tissues such as vascular bundles at the root of the flax, and the injury is the most serious to the yield loss of the flax because the flax cannot be recovered. In the final flowering period of the flax, the fresh weight of the overground part of the flax is at a high peak value, the crown-stem ratio is the largest, the gravity center height of the flax is the highest, root lodging is most likely to occur when the flax stems are lodged, and at the moment, the lodging resistance of the root of the flax is the worst, so that in the flax cultivation measures, the root promotion, the seedling strengthening and the root lodging resistance of the flax are necessary cultivation measures. The existing research shows that the main root length, the main root volume and the surface area, the root number, the total length of fibrous roots and the total surface area of fibrous roots are main factors forming the lodging resistance index of the flax, in order to further clarify the main characters influencing the lodging resistance index, the lodging resistance index and the constituent factors are subjected to correlation analysis and path analysis, and the result shows that the main root volume which contributes most to the lodging resistance of the fibrous roots is the main root volume, and the fibrous roots are the secondary root number. The lodging-resistant contribution is sequentially the main root volume, the hair root number, the main root length, the hair root surface area and the total hair root length, and the main root volume has very obvious effect and the maximum positive direct effect from the perspective of the correlation degree and the relative effect, and then the hair root number and the main root length.
The reason for lodging of the flax is extremely complex, depends on the genetic characteristics of the flax, is related to environmental conditions and cultivation measures, and is very difficult to integrate various excellent characters in the same variety, and the breeding period is obviously prolonged because the quantitative characters cannot be stabilized in a short period. The operability in the production link of the flax is poor through hilling and nitrogen fertilizer increasing, and the method is difficult to popularize and apply in production. Because the sensitivity of the flax to the mepiquat chloride is poor, the application amount of the mepiquat chloride in the production is increased, not only is the residual risk increased and the environmental pollution is increased, but also the production cost is correspondingly increased.
Disclosure of Invention
The invention aims to provide a flax seed coating agent, a preparation method thereof and application thereof in improving the lodging resistance of flax, aiming at solving the defects of the prior art in the background technology.
The invention is realized in such a way that the flax seed coating agent comprises the following components in parts by mass:
Figure BDA0002437929780000031
preferably, the polyglutamic acid is agricultural-grade polyglutamic acid with the mass content of 10%;
preferably, the growth regulator is one or more of gibberellin, ABT5 rooting powder and humic acid.
Preferably, the dispersant is one or more of polyoxyethylene octylphenol ether, polyoxyethylene phenethyl phenol ether and polyoxyethylene alkylphenol ether.
Preferably, the anticaking agent is one or more of sodium aluminosilicate, tricalcium phosphate and silicon dioxide.
Preferably, the film forming agent is one or more of polyvinyl alcohol, polyester vinyl ester and modified starch.
Preferably, the suspending agent is one or more of xanthan gum, polyvinyl alcohol and polyvinyl pyrrolidone;
the filler is one or more of kaolin, bentonite, attapulgite clay, diatomite and talcum powder;
the preservative is one or more of industrial formaldehyde, sodium benzoate and potassium sorbate;
the colorant is acid scarlet or acid red B.
The invention further discloses a preparation method of the flax seed coating agent, which comprises the following steps:
(1) adding polyglutamic acid, growth regulator, dispersant, anticaking agent, film-forming agent, filler, preservative, colorant and water in an emulsifying and dispersing machine according to the proportion, and stirring and mixing;
(2) and (3) homogenizing and dispersing the mixed solution under a vacuum closed condition, uniformly and uniformly adding the mixed solution into a sand mill for grinding, adding a suspending agent according to a ratio to prepare an aqueous solution, regulating the viscosity, and uniformly mixing and stirring to obtain the flax seed coating agent.
The invention further discloses application of the flax seed coating agent in improving the lodging resistance of flax.
Preferably, the application comprises the steps of:
(1) before seeding flax, soaking selected seeds in 70-75 wt% alcohol for 1.5-2.5 h, and then airing in the sun for 6-8 h;
(2) uniformly spraying surface dispersant organosilicon (1:8000) on the surface of flax seed, and stirring;
(3) mixing the flax seed coating agent and flax seeds according to the medicine seed ratio of 1: and (4) uniformly mixing the mixture and naturally drying and sowing the mixture.
Preferably, in step (1), the selected seeds have a germination rate of > 98%.
The invention overcomes the defects of the prior art and provides a flax seed coating agent, a preparation method thereof and application thereof in improving the lodging resistance of flax. In the research and development process, firstly, the lodging resistance of the flax can be obviously improved by utilizing root promoting and seedling strengthening, the influence factor of the flax root lodging is analyzed, and correlation analysis is carried out, wherein the factor which has the greatest contribution to the flax root lodging resistance is the main root volume, and secondly, the number of fibrous roots; on the basis, the invention finds out the optimal formula of the flax root lodging resistant seed coating agent finally through the prior technology accumulation by the technology with good popularization prospect on the production of flax seed coating through a large number of cultivation test comparative analysis; finally, the invention overcomes the difficult problem of poor coating effect of the flax seeds due to a small amount of grease attached to the surfaces of the flax seeds in the coating method, and the medicament can be well attached to the surfaces of the seeds after the coating agent is used through the pretreatment of alcohol and a surface dispersing agent.
Compared with the defects and shortcomings of the prior art, the invention has the following beneficial effects:
(1) the length, the surface area and the total volume of the main root of the flax subjected to seed coating treatment by the coating agent are respectively and remarkably greater than those of the flax variety not subjected to seed coating treatment, the length, the surface area and the total volume of the main root are respectively improved by 29.6 percent, 35.4 percent and 40.6 percent, and the difference reaches a remarkable level;
(2) the total number, length, surface area and total volume of the fibrous roots of the flax subjected to seed coating treatment by the coating agent are respectively remarkably greater than those of non-lodging-resistant flax varieties, the length, surface area and total volume of the fibrous roots are respectively increased by 44.3%, 34.3% and 22.54%, and the difference reaches a remarkable level.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the present invention is further described in detail with reference to the following embodiments. It should be understood that the specific embodiments described herein are merely illustrative of the invention and are not intended to limit the invention.
Examples 1 to 4
(1) Adding 1 part of agricultural-grade polyglutamic acid with the mass content of 10%, 0.05 part of growth regulator, 7 parts of dispersing agent, 4 parts of anticaking agent, 3 parts of film forming agent, 10 parts of filler, 3 parts of preservative, 5 parts of colorant and 83.85 parts of water in an emulsifying and dispersing machine according to the mixture ratio, and stirring and mixing;
(2) and (3) homogenizing and dispersing the mixed solution under a vacuum closed condition, uniformly and uniformly adding the mixed solution into a sand mill for grinding, adding an aqueous solution prepared from 6 parts of a suspending agent according to a ratio to adjust the viscosity, and uniformly mixing and stirring to obtain the flax seed coating agent.
In the method, the specific components and the amounts thereof involved in each flax seed coating agent prepared in each example are shown in table 1 below:
TABLE 1 Components and amounts
Figure BDA0002437929780000061
Example 5
The embodiment of the present invention is basically the same as the embodiment 1 described above, with the difference that:
(1) adding 0.5 part of agricultural polyglutamic acid with the mass content of 10%, 0.05 part of growth regulator, 2 parts of dispersant, 1 part of anticaking agent, 0.1 part of film-forming agent, 10 parts of filler, 1 part of preservative, 0.5 part of colorant and 60.95 parts of water in an emulsifying and dispersing machine according to the proportion, and stirring and mixing;
(2) and (2) homogenizing and dispersing the mixed solution under a vacuum closed condition, uniformly and uniformly adding the mixed solution into a sand mill for grinding, adding 1 part of suspending agent according to the proportion to prepare an aqueous solution for regulating the viscosity, and uniformly mixing and stirring to obtain the flax seed coating agent.
Example 7
The embodiment of the present invention is basically the same as the above embodiment 3, and the difference is:
(1) adding 0.8 part of agricultural polyglutamic acid with the mass content of 10%, 0.08 part of growth regulator, 5 parts of dispersant, 3 parts of anticaking agent, 1 part of film-forming agent, 5 parts of filler, 2 parts of preservative, 0.5 part of colorant and 70 parts of water in an emulsifying and dispersing machine according to the mixture ratio, and stirring and mixing;
(2) and (3) homogenizing and dispersing the mixed solution under a vacuum closed condition, uniformly and uniformly adding the mixed solution into a sand mill for grinding, adding 4 parts of suspending agent according to the proportion to prepare an aqueous solution for regulating the viscosity, and uniformly mixing and stirring to obtain the flax seed coating agent.
Example 8
(1) Before seeding the flax, selecting flax seeds, ensuring that the germination rate of the flax seeds is more than 98%, soaking the selected flax seeds in 70-75% alcohol for 2h, and then airing in the sun for 6-8 h;
(2) uniformly spraying surface dispersant organosilicon (1:8000) on the surface of flax seed, and stirring;
(3) mixing the flax seed coating agent prepared in the example 7 with flax seeds according to the mass ratio of the seeds to the coating agent of 1: and (5) after coating is finished by uniformly mixing 40-60 parts, naturally drying for later use.
Effects of the embodiment
The coated flax seeds obtained in example 8 were sown, and in contrast to uncoated flax seeds, representative 100 individuals were each harvested at the seedling stage of flax, and the soil on the root surface was carefully washed clean with tap water, and the entire root system was separated from the plants. And respectively measuring the length of each main root and the number of roots, the length of the total root, the volume of the total root and the dry weight of the total root of each plant, and calculating the length, the volume and the dry weight of the root of each plant. Measuring the root volume by a drainage method, deactivating enzyme at 105 ℃ for 30min, drying at 80 ℃ to constant weight, and weighing the dry weight of the root system. Another representative 3 individuals were cleaned and separated from the roots, packed into sealed bags and taken back to the laboratory for testing. Putting the complete root system sample into a special colorless transparent root disc filled with deionized water, adjusting the position of the root by using tweezers to avoid cross overlapping as much as possible, scanning the root system image by using a scanner (the model is EPSON10000XL), classifying the image according to different varieties and plant numbers and storing the image in a computer. Analysis was performed using WinRhizo Pro 2004a (Reagent Instruments, Canada) software. The results show that the length, the surface area and the total volume of the main root of the flax subjected to seed coating treatment by the coating agent are respectively and remarkably greater than those of the flax variety not subjected to seed coating treatment, the length, the surface area and the total volume of the main root are respectively increased by 29.6 percent, 35.4 percent and 40.6 percent, and the difference reaches a remarkable level; (2) the total number, length, surface area and total volume of the fibrous roots of the flax subjected to seed coating treatment by the coating agent are respectively remarkably greater than those of non-lodging-resistant flax varieties, the length, surface area and total volume of the fibrous roots are respectively increased by 44.3%, 34.3% and 22.54%, and the difference reaches a remarkable level.
The demonstration of the lodging-resistant flax coating technology is carried out in the ancient city of Pengyang county, namely hanging Magou village, and the demonstration area is 100 mu. The yield is measured, the yield per mu of the benne is 104.32kg by taking the conventional planting technology as a comparison, and the yield is increased by 11.58 percent by comparison.
The above description is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the invention, and any modifications, equivalents and improvements made within the spirit and principle of the present invention are intended to be included within the scope of the present invention.

Claims (10)

1. The flax seed coating agent is characterized by comprising the following components in parts by mass:
Figure FDA0002437929770000011
2. the flax seed coating agent of claim 1 wherein the polyglutamic acid is an agricultural grade polyglutamic acid having a mass content of 10%;
the growth regulator is one or more of gibberellin, ABT5 rooting powder and humic acid.
3. The flax seed coating of claim 1 wherein the dispersant is one or more of octylphenol polyoxyethylene ether, phenethylphenol polyoxyethylene ether, and alkylphenol polyoxyethylene ether.
4. The flax seed coating agent of claim 1 wherein said anti-caking agent is one or more of sodium aluminosilicate, tricalcium phosphate, and silicon dioxide.
5. The flax seed coating of claim 1 wherein said film former is one or more of polyvinyl alcohol, vinyl polyesterate, and modified starch.
6. The flaxseed coating agent of claim 1, wherein the suspending agent is one or more of xanthan gum, polyvinyl alcohol, polyvinyl pyrrolidone;
the filler is one or more of kaolin, bentonite, attapulgite clay, diatomite and talcum powder;
the preservative is one or more of industrial formaldehyde, sodium benzoate and potassium sorbate;
the colorant is acid scarlet or acid red B.
7. A method for preparing a flax seed coating agent according to any one of claims 1 to 6, comprising the steps of:
(1) adding polyglutamic acid, growth regulator, dispersant, anticaking agent, film-forming agent, filler, preservative, colorant and water in an emulsifying and dispersing machine according to the proportion, and stirring and mixing;
(2) and (3) homogenizing and dispersing the mixed solution under a vacuum closed condition, uniformly and uniformly adding the mixed solution into a sand mill for grinding, adding a suspending agent according to a ratio to prepare an aqueous solution, regulating the viscosity, and uniformly mixing and stirring to obtain the flax seed coating agent.
8. Use of a flaxseed coating agent according to any one of claims 1 to 6 for improving the lodging resistance of flaxseed.
9. The application of claim 8, wherein the application comprises the steps of:
(1) before seeding flax, soaking selected seeds in 70-75 wt% alcohol for 1.5-2.5 h, and then airing in the sun for 6-8 h;
(2) uniformly spraying surface dispersant organosilicon (1:8000) on the surface of flax seed, and stirring;
(3) mixing the flax seed coating agent and flax seeds according to the medicine seed ratio of 1: and (4) uniformly mixing the mixture and naturally drying and sowing the mixture.
10. The use of claim 9, wherein in step (1), the selected seeds have a germination rate of > 98%.
CN202010257463.1A 2020-04-03 2020-04-03 Flax seed coating agent and preparation method and application thereof Pending CN111296418A (en)

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CN108244105A (en) * 2018-01-17 2018-07-06 安徽省华禾种业有限公司 A kind of vegetable seeds coating agent and preparation method thereof
CN108112299A (en) * 2018-01-22 2018-06-05 马鞍山市全润农业科技有限公司 A kind of efficient Pregermination and seedling breeding method of celery seed
CN108976849A (en) * 2018-06-27 2018-12-11 来安县出尘茶业有限公司 A kind of coating agent for seed and preparation method thereof promoting broccoli growth
CN108684744A (en) * 2018-07-11 2018-10-23 合肥雪立歆农业科技有限公司 A kind of peanut seed coating agent and its coating method
CN108850025A (en) * 2018-07-31 2018-11-23 合肥浦邦农业科技有限公司 A kind of vegetable seeds coating agent and preparation method thereof

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