CN111226955A - Insecticidal and acaricidal composition containing macrolide insect/acarid - Google Patents
Insecticidal and acaricidal composition containing macrolide insect/acarid Download PDFInfo
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- CN111226955A CN111226955A CN201811446264.4A CN201811446264A CN111226955A CN 111226955 A CN111226955 A CN 111226955A CN 201811446264 A CN201811446264 A CN 201811446264A CN 111226955 A CN111226955 A CN 111226955A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/08—Oxygen or sulfur directly attached to an aromatic ring system
- A01N31/14—Ethers
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/22—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom rings with more than six members
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
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- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention belongs to the field of insecticides and acaricides, and relates to an insecticidal and acaricidal composition containing macrolide insecticidal/acaricidal agents. The composition comprises A, B; two active components, wherein the weight part ratio of the component A to the component B is 1:99-99: 1; the active component A is selected from a compound I shown in the following structural formula, the active component B is selected from macrolide insecticide/acaricide, the structure of the active component A is shown in the following, and the composition has the advantages of obvious synergism, resistance delay and the like, and can be used for controlling various pests.
Description
Technical Field
The invention belongs to the field of insecticides and acaricides, and relates to an insecticidal and acaricidal composition containing macrolide insecticidal/acaricidal agents.
Background
The insecticidal and acaricidal agent has obvious effect on preventing and controlling agricultural and forestry pests or urban sanitary pests.
The Chinese patent CN105541682 discloses a biphenyl compound and application thereof in controlling insect pests and mite pests, wherein the compound 1 (hereinafter referred to as compound I) can be used for controlling various pests and mites, and particularly has an outstanding control effect on the pest mites.
The insecticide and acaricide containing single active component can be continuously used for preventing and controlling pests, and is easy to cause the pests to generate drug resistance. The insecticide and acaricide with two active components are mixed into a mixed component according to a certain proportion, so that the control effect can be improved, the using amount of active components is reduced, the cost is saved, and the generation of drug resistance of pests can be delayed.
Although the combination of compound I or its homologues with other insecticides and acaricides has been widely disclosed in the prior art to provide additional advantages and effects, the technical scheme of the binary insecticide and acaricide composition containing compound I has not been specifically disclosed.
Disclosure of Invention
The invention aims to develop a composition for killing insects and mites, which contains macrolide insects/mites, so as to meet the requirements of increasing the effect of the insecticides and acaricides and continuously updating varieties in the aspects of controlling pests in the fields of agriculture and forestry and urban sanitation.
In order to achieve the purpose, the invention adopts the technical scheme that: a composition containing macrolide insecticide/acaricide comprises A, B two active components, wherein the weight part ratio of the active component A to the active component B is 1:99-9: 1; the active component A is selected from a compound I, and the active component B is selected from macrolide insecticide/acaricide;
the active component A compound I has the following structure:
the active component B is selected from abamectin, emamectin benzoate, spinosad, spinetoram, miticide, ivermectin, lepimectin, emamectin, milbemectin, carverol, Doramectin, Eprinomectin, Milbemycinoxime, Moxidectin, Sanguinarine or Selamectin.
Preferably, the active component A in the composition is a compound I, and the active component B is selected from abamectin or emamectin benzoate; the weight part ratio of the two active components is 50:1-1: 50.
Further preferably, the active component A is a compound I, and the active component B is selected from abamectin or emamectin benzoate; the weight part ratio of the two active components is 5:1-15: 1.
Preferably, the active component A in the composition is a compound I, and the active component B is selected from spinosad or spinetoram; the weight part ratio of the two active components is 50:1-1: 50.
Further preferably, the active component A is a compound I, and the active component B is selected from spinosad or spinetoram; the weight part ratio of the two active components is 5:1-1: 5.
The composition, the carrier and any one of the auxiliary agents are mixed to prepare a preparation containing the composition. The cumulative content of active ingredients in the preparation is between 0.5% and 95%. Preferably, the cumulative amount of active ingredient in the formulation is between 1% and 85%.
The application of a composition for killing insects and mites containing macrolide insecticide/acaricide is used for preparing insecticide acaricide for controlling agricultural pests or urban sanitary pests.
The invention also comprises the application of the composition prepared into an insecticidal and acaricidal preparation for controlling agricultural and forestry pests or urban sanitary pests. The insecticidal composition is particularly suitable for controlling various important agricultural pests such as armyworms, asparagus caterpillars, cotton bollworms, cutworms, cabbage loopers, apple leaf rollers, rice leaf rollers, corn borers, striped rice borers, diamond back moths, cabbage caterpillars, fall moths, tenebrio molitors, gypsy moths, east Asian locusts, underground pests, leaf miners, aphids, tetranychus cinnabarinus, hawthorn leaf mites, panonychus citri, citrus rust mites, apple leaf mites, tetranychus urticae, gall mites, pink mites and the like, and urban pests such as termites, cockroaches, ants, flies, mosquitoes and the like. It can be used for fruit trees such as apple, pear, citrus, and litchi, cereals such as wheat and rice, beans such as soybean and kidney bean, cotton, and vegetables such as cabbage, cauliflower, Chinese cabbage, rape, tomato, pepper, and flowers. When the insecticidal composition is used for preventing and controlling urban pests, the insecticidal composition can be used for families, various public places and office places, trees and dams and the like which are damaged by termites.
Further, the composition of the present invention is applied to the pest or the medium for growth thereof to be controlled by the prepared insecticide-acaricide in an effective dosage. Preferably, an effective dose of 10 g to 500 g per hectare is generally selected, preferably an effective dose of 15 g to 100 g per hectare.
The invention has the following advantages:
1. the composition of the invention shows obvious synergistic effect in a certain proportion range, and improves the control effect of the compound on pests.
2. The composition of the invention reduces the dosage of the compound in application, thereby reducing the use cost and reducing the environmental pollution.
3. The active ingredients in the composition have different action mechanisms, so that the problem of cross resistance does not exist, the pest resistance can be delayed by using the composition to control pests, and the control effect on resistant populations is improved.
Detailed Description
The following specific examples are intended to illustrate the invention in further detail, but the invention is by no means limited to these examples. In the examples, the proportions of the components are by weight.
Indoor biological activity assay
Example 1 determination of the synergistic Effect of a composition containing Compound I on Tetranychus cinnabarinus
Test subjects: tetranychus cinnabarinus (Tetranychus cinnabarinus Boisdival), adult mites, and indoor-reared sensitive strains.
And (3) testing conditions are as follows: temperature: 24-26 ℃, relative humidity: 60%, illumination: l: D ═ 14:10
Preparing a liquid medicine: according to different test requirements, accurately weighing the test samples by using an electronic analytical balance, wherein the original drug is dissolved by acetone and diluted into liquid medicine with a certain concentration by using 0.1% Tween 80 water according to the test design dosage.
The test method comprises the following steps: the activity of tetranychus cinnabarinus on adult tetranychus cinnabarinus is determined by a potted seedling spraying method. Firstly, 40-60 adult tetranychus cinnabarinus with consistent size are grafted to kidney bean seedlings (one true leaf is reserved) in a first true leaf development period, and the base number is counted after the adult tetranychus cinnabarinus is stabilized; then, the test specimens were treated with the liquid medicine by the Airbrush method, 1.5mL per specimen, and a blank control was set.
And after natural drying in the shade, placing the treated test material in an observation chamber, adjusting the temperature, humidity and illumination of the observation chamber as required, investigating the number of live mites after 72 hours, and calculating the mortality. Evaluation was carried out by the Bliss method, which is one of the classical methods for evaluating the effect of mixtures. Bliss, based on its proposed concept of independent combined action, believes that the theoretical mortality rate P of a combination of insecticides and acaricides can be calculated by the following formula:
P＝Pm+Pn(1-Pm)
Pmis the mortality (%) of the target at a concentration m of the first active ingredient; pnThe mortality (%) of the target at a concentration of n is used for the second active component.
If the actual mortality rate of the target after the two active components are mixed at a certain concentration is greater than the theoretical mortality rate P, the two active components are judged to have synergistic effect when being mixed at a set concentration, otherwise, the two active components are antagonistic.
The results are shown in Table 1.
TABLE 1 synergistic effect of compound I and 4 kinds of agents such as abamectin on tetranychus cinnabarinus mite formation
Example 2 indoor Activity assay of compositions containing Compound I against Tetranychus cinnabarinus
The effect data measured by the synergistic effect show that the composition formed by mixing the compound I and 4 medicaments such as abamectin has an obvious synergistic effect on the tetranychus cinnabarinus adult mites, and the compound I and the abamectin are further used for preparing a composition formed by testing 5:1-15: 1; the indoor activity of the composition consisting of the compound I and spinosad in the test 5:1-1:5 was measured by the Sun cloud Peel (Sun y-p) method.
Test targets: tetranychus cinnabarinus (Boisdivaval) becomes a sensitive strain which is bred indoors.
Preparing a liquid medicine: according to different test requirements, accurately weighing the test samples by using an electronic analytical balance, wherein the original drug is dissolved by acetone and diluted into a series of liquid medicines with a certain concentration gradient by using 0.1% Tween 80 water according to the test design dosage.
The test method comprises the following steps: the activity of tetranychus cinnabarinus on adult tetranychus cinnabarinus is determined by a potted seedling spraying method. Firstly, inoculating tetranychus cinnabarinus with consistent size to kidney bean seedlings (one true leaf is reserved) in a first true leaf flattening period, and counting the base number after the tetranychus cinnabarinus is stabilized; then uniformly spraying the liquid medicine by an Airbrush method according to the sequence of test design from low dose to high dose, wherein each plant is 1.5mL, and the treatment is repeated for 4 times, and a blank control is additionally arranged.
And (3) placing the treated test material in an observation chamber, wherein the temperature, the humidity and the illumination of the observation chamber can be adjusted as required. The number of dead and live mites was investigated after 72 hours. Calculating corrected mortality by abbott formula, performing statistical analysis by DPS data processing software, and calculating toxicity regression equation and LC for each single agent and different mixture ratio50The value and the 95% confidence limit, and the cotoxicity coefficient of each proportion is calculated by a Sun Yun Pei (Sun y-p) method, and the blending effect is evaluated.
The co-toxicity coefficient (CTC value) of the mixture was calculated according to the following formula:
in the formula: actually measuring a toxicity index of the ATI-mixed agent; LC of S-Standard drug50(ii) a LC of M-mixtures50。
TTI＝TIA×PA+TIB×PB
In the formula: TTI-mixture theory virulence index; TIA-A agent virulence index; the percentage content of the PA-A medicament in the mixture; TIB-B agent virulence index; the percentage content of the PB-B medicament in the mixture.
In the formula: CTC-co-toxicity coefficient; actually measuring a toxicity index of the ATI-mixed agent; TTI-mixture theory virulence index.
Co-toxicity coefficient (CTC) of the combination: CTC is more than or equal to 120 and shows synergistic effect; CTC is less than or equal to 80 and shows antagonism; 80< CTC <120 shows additive effects.
And, LC of the composition50LC with a value less than one or two of the single doses50By value, it is meant that the composition is administered in a dose less than one or both of the single doses, while achieving the same effect (mortality rate of 50%).
The test results are shown in tables 2 and 3.
Table 2: indoor combined toxicity determination result of compound I-abamectin on tetranychus cinnabarinus
Table 3: indoor combined toxicity determination result of compound I-pleocidin on tetranychus cinnabarinus
The compound I and pleocidin in the table are matched with 1 pair of tetranychus cinnabarinus LC50A value of 0.41mg/L, and a single dose of 0.45mg/L and 1.14mg/L, respectively, means that the dosage of the composition (0.41mg/L) is less than the dosage of one or both of the single doses (0.45mg/L and 1.14mg/L) at the same effect (mortality of 50%); in addition, the control effect of the composition is higher than the theoretical effect of two single agents to different degrees from the definition of co-toxicity coefficient; due to field dosage and indoor LC50The values are positively correlated, so the field dosage of the composition is correspondingly reduced, thereby reducing the use cost and reducing the environmental pollution.
Claims (10)
1. An insecticidal and acaricidal composition containing macrolide insecticidal/acaricidal agent, which is characterized in that: the composition contains A, B two active components, wherein the weight part ratio of the active component A to the active component B is 1:99-9: 1; the active component A is selected from a compound I, and the active component B is selected from macrolide insecticide/acaricide; the active component A compound I has the following structure:
2. the composition of claim 1, wherein: the active component B is selected from abamectin, emamectin benzoate, spinosad, spinetoram, miticide, ivermectin, lepimectin, emamectin, milbemectin, carverol, Doramectin, Eprinomectin, Milbemycinoxime, Moxidectin, Sanguinarine or Selamectin.
3. A composition according to claim 1 or 2, characterized in that: the active component A in the composition is a compound I, and the active component B is selected from abamectin or emamectin benzoate; the weight part ratio of the two active components is 50:1-1: 50.
4. A composition according to claim 3, characterized in that: the active component A is a compound I, and the active component B is selected from abamectin or emamectin benzoate; the weight part ratio of the two active components is 5:1-15: 1.
5. A composition according to claim 1 or 2, characterized in that: the active component A in the composition is a compound I, and the active component B is selected from spinosad or spinetoram; the weight part ratio of the two active components is 50:1-1: 50.
6. The composition of claim 5, wherein: the active component A is a compound I, and the active component B is selected from spinosad or spinetoram; the weight part ratio of the two active components is 5:1-1: 5.
7. The composition of claim 1, wherein: the composition, the carrier and any one of the auxiliary agents are mixed to prepare a preparation containing the composition.
8. The composition of claim 7, wherein: the cumulative content of active ingredients in the preparation is between 0.5% and 95%.
9. An insecticidal and acaricidal composition comprising a macrocyclic lactone as claimed in claim 1, wherein: the use of said composition for the preparation of an insecticidal and acaricidal agent for controlling agricultural or urban sanitary pests.
10. The insecticidal and acaricidal composition comprising a macrocyclic lactone as claimed in claim 9, wherein: the prepared insecticide and acaricide is applied to the pests to be controlled or the medium for the growth of the pests by using an effective dose meter.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2022012483A1 (en) * | 2020-07-17 | 2022-01-20 | 沈阳中化农药化工研发有限公司 | Substituted phenyl sulfide compound and application thereof |
| CN114642203A (en) * | 2020-12-17 | 2022-06-21 | 沈阳中化农药化工研发有限公司 | Insecticidal and acaricidal composition |
| WO2022166737A1 (en) * | 2021-02-05 | 2022-08-11 | 沈阳化工大学 | Biphenyl compound containing sulfide (sulfoxide) substitution and use thereof |
| CN115530170A (en) * | 2021-06-29 | 2022-12-30 | 沈阳中化农药化工研发有限公司 | Insecticidal and acaricidal composition |
| CN116158429A (en) * | 2021-11-25 | 2023-05-26 | 沈阳中化农药化工研发有限公司 | Stable liquid preparation containing biphenyl compounds |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009023910A (en) * | 2007-07-17 | 2009-02-05 | Kumiai Chem Ind Co Ltd | Biphenyl sulfide compound and insecticidal or acaricidal agent |
| CN101669496A (en) * | 2009-10-16 | 2010-03-17 | 深圳诺普信农化股份有限公司 | Bifenazate and milbemectin miticide composition and application thereof |
| CN101708005A (en) * | 2009-10-29 | 2010-05-19 | 青岛海利尔药业有限公司 | Acaricidal composition containing bifenazate and application thereof |
| CN104663679A (en) * | 2013-11-26 | 2015-06-03 | 中国中化股份有限公司 | Pest-killing and mite-killing composition containing macrolide insecticide |
| CN105541682A (en) * | 2014-10-24 | 2016-05-04 | 沈阳中化农药化工研发有限公司 | Biphenyl compound and application thereof |
-
2018
- 2018-11-29 CN CN201811446264.4A patent/CN111226955B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009023910A (en) * | 2007-07-17 | 2009-02-05 | Kumiai Chem Ind Co Ltd | Biphenyl sulfide compound and insecticidal or acaricidal agent |
| CN101669496A (en) * | 2009-10-16 | 2010-03-17 | 深圳诺普信农化股份有限公司 | Bifenazate and milbemectin miticide composition and application thereof |
| CN101708005A (en) * | 2009-10-29 | 2010-05-19 | 青岛海利尔药业有限公司 | Acaricidal composition containing bifenazate and application thereof |
| CN104663679A (en) * | 2013-11-26 | 2015-06-03 | 中国中化股份有限公司 | Pest-killing and mite-killing composition containing macrolide insecticide |
| CN105541682A (en) * | 2014-10-24 | 2016-05-04 | 沈阳中化农药化工研发有限公司 | Biphenyl compound and application thereof |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2022012483A1 (en) * | 2020-07-17 | 2022-01-20 | 沈阳中化农药化工研发有限公司 | Substituted phenyl sulfide compound and application thereof |
| CN114642203A (en) * | 2020-12-17 | 2022-06-21 | 沈阳中化农药化工研发有限公司 | Insecticidal and acaricidal composition |
| CN114642203B (en) * | 2020-12-17 | 2023-03-24 | 沈阳中化农药化工研发有限公司 | Insecticidal and acaricidal composition |
| WO2022166737A1 (en) * | 2021-02-05 | 2022-08-11 | 沈阳化工大学 | Biphenyl compound containing sulfide (sulfoxide) substitution and use thereof |
| CN115530170A (en) * | 2021-06-29 | 2022-12-30 | 沈阳中化农药化工研发有限公司 | Insecticidal and acaricidal composition |
| CN115530170B (en) * | 2021-06-29 | 2024-03-22 | 沈阳中化农药化工研发有限公司 | Insecticidal and acaricidal composition |
| CN116158429A (en) * | 2021-11-25 | 2023-05-26 | 沈阳中化农药化工研发有限公司 | Stable liquid preparation containing biphenyl compounds |
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