CN111154529A - 一种抗硬水型植物油乳化复合剂及其制备 - Google Patents

一种抗硬水型植物油乳化复合剂及其制备 Download PDF

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CN111154529A
CN111154529A CN201911408270.5A CN201911408270A CN111154529A CN 111154529 A CN111154529 A CN 111154529A CN 201911408270 A CN201911408270 A CN 201911408270A CN 111154529 A CN111154529 A CN 111154529A
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hard water
vegetable oil
water resistant
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朱玉健
徐正义
胡林
王欢
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Nanjing Shangqin New Material Technology Co Ltd
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Abstract

本发明公开了一种抗硬水型植物油乳化复合剂，各原料组分按照质量百分比计算，其组成及含量如下：单乙醇胺1‑5%，三乙醇胺1‑5%，高级脂肪酸1‑5%，低泡表面活性剂：25‑50%，抗硬水剂：15‑30%,偶合剂:15‑35%，铝缓蚀剂:1‑5%，杀菌剂1‑5%。还公开了该复合剂的制备方法。本发明产品推荐使用添加量按重量百分比15%添加，另外使用85%植物油搅拌混合均匀制备一种抗硬水型植物油乳化液，该乳化液润滑性能、防锈性能优异，使用寿命较长，能适应南北方不同条件下的水质，抗硬水性能尤其优越。

Description

一种抗硬水型植物油乳化复合剂及其制备
技术领域
本发明涉及金属加工液添加剂技术领域，具体为一种抗硬水型植物油乳化复合剂及其制备。
背景技术
通常，在金属加工过程中为了得到更好的润滑性以及加工工件更好的表面光洁度，会在加工液中添加大量的植物油基大豆油、菜籽油、棕榈油等，而一直以来纯植物油基的乳化油都较难达到很好的稳定乳化状态，即使乳化后当面对不同地区不同硬度水质时，乳液的稳定性、析油析皂以及原液的外观、稳定性等问题都很难达到一个很好的平衡。
因此急需一种抗硬水型的植物油基乳化油复合剂。
发明内容
为解决上述问题，本发明公开了一种抗硬水型植物油乳化复合剂及其制备，该乳化液润滑性能、防锈性能优异，使用寿命较长，能适应南北方不同条件下的水质，抗硬水性能尤其优越。
为了达到以上目的，本发明提供如下技术方案：
一种抗硬水型植物油乳化复合剂，其组成及含量如下：
单乙醇胺1-5％，
三乙醇胺1-5％，
高级脂肪酸1-5％，
低泡表面活性剂：25-50％，
抗硬水剂：15-30％,
铝缓蚀剂:1-5％，
偶合剂：15-35％，
杀菌剂1-5％。
进一步的，所述低泡表面活性剂为直链、支链或者芳香族的脂肪醇聚氧乙烯聚氧丙烯醚。
进一步的，所述抗硬水剂为乙二胺四乙酸、乙二酸四乙酸二钠、脂肪醇聚氧乙烯醚羧酸的一种或几种。
进一步的，所述铝缓蚀剂为磷酸酯。
进一步的，所述偶合剂为格尔伯特醇、丙二醇甲醚、二乙二醇丁醚、失水山梨醇单油酸酯中的一种或几种。
进一步的，所述高级脂肪酸为异壬酸、妥尔油脂肪酸、油酸、以及蓖麻油酸、二聚酸、聚异丁烯丁二酸的一种或几种。
进一步的，所述杀菌剂为杀细菌和真菌的复配物，通常为三嗪、亚甲基二吗啉、苯丙异噻啉酮、甲基苯丙异噻啉酮的一种或几种。
同时，本发明公开了一种抗硬水型植物油乳化复合剂的制备方法，所述方法包括如下步骤：
步骤1：在常温常压下，按照上述物料重量百分比配比，先将单乙醇胺、三乙醇胺和高级脂肪酸酸加入反应釜，加热至50-60℃，持续搅拌约30分钟；
步骤2：在步骤1得到的混合物中，依次加入低泡表面活性剂、抗硬水剂、铝缓蚀剂及偶合剂，在40-50℃搅拌均匀30分钟；
步骤3：最在步骤2得到的混合物中加入杀菌剂，继续搅拌30-45分钟，搅拌均匀至透明均一液体；得到硬水型植物油乳化复合剂。
同时，本发明还公开了一种抗硬水型植物油乳化液，所述乳化液组成及含量如下
抗硬水型植物油乳化复合剂 15％
植物油 85％。
本发明具有如下有益效果：
本发明中，该乳化液润滑性能、防锈性能优异，使用寿命较长，能适应南北方不同条件下的水质，抗硬水性能尤其优越。
通过本发明制备的切削液复合剂可以制备出不含对人体和环境产生不利影响的亚硝酸盐等有毒化学品，不含磺酸钠，不含消泡剂，消泡效果良好，防腐效果良好，能保持较长的使用寿命，润滑性能极佳，尤其在硬水条件下能够保持稳定乳液状态的植物油基乳化切削液。
本发明使用上述的抗硬水型植物油乳化复合剂添加量按重量百分比15％添加，另外使用85％植物油搅拌混合均匀制备一种抗硬水型植物油乳化液一种抗硬水型植物油乳化液，该乳化液润滑性能、防锈性能优异，使用寿命较长，能适应南北方不同条件下的水质，抗硬水性能尤其优越。
具体实施方式
下面结合具体实施方式，进一步阐明本发明，应理解下述具体实施方式仅用于说明本发明而不用于限制本发明的范围。
实施例1
一种抗硬水型植物油乳化复合剂，按重量百分比计由以下组分组成：
Figure BDA0002349267020000021
Figure BDA0002349267020000031
所述制备方法包括如下步骤：
1)将单乙醇胺、三乙醇胺、高级脂肪酸按比例加入反应罐中，在50-60℃条件下搅拌约30分钟；
2)将低泡表面活性剂、抗硬水剂、铝缓蚀剂、偶合剂按质量百分比比例加入到步骤1的混合物中，在40-50℃搅拌20分钟；
3)将杀菌剂在40℃下加入通过步骤2得到的混合物中，搅拌20-25分钟。
实施例2
一种抗硬水型植物油乳化复合剂，按重量百分比计由以下组分组成：
Figure BDA0002349267020000032
所述制备方法包括如下步骤：
1)将单乙醇胺、三乙醇胺、高级脂肪酸按比例加入反应罐中，在50-60℃条件下搅拌约30分钟；
2)将低泡表面活性剂、抗硬水剂、偶合剂按质量百分比比例加入到步骤1的混合物中，在40-50℃搅拌20分钟；
3)冷却至40℃，将杀菌剂加入通过步骤2得到的混合物中，在40℃搅拌20-25分钟。
对实施例1、实施例2的抗硬水植物油基乳化切削液复合剂按照重量百分比15％复合剂添加量+85％大豆油配成乳化切削液后进行了性能测试，性能结果见下表：实施例1添加铝缓蚀剂后可以用于铝加工。
Figure BDA0002349267020000041
在其他实施例中，抗硬水型植物油乳化复合剂，其组成及含量可以如下：
单乙醇胺1-5％，三乙醇胺1-5％，高级脂肪酸1-5％，低泡表面活性剂：25-50％，抗硬水剂：15-30％,，铝缓蚀剂:1-5％，偶合剂：15-35％，杀菌剂1-5％。在其他具体实施时，根据采用上述的含量配比均可，可根据实际需要自行选择，其制备方法和乳化液的制备方法在此不再赘述。
其中，低泡表面活性剂为直链、支链或者芳香族的脂肪醇聚氧乙烯聚氧丙烯醚。抗硬水剂为乙二胺四乙酸、乙二酸四乙酸二钠、脂肪醇聚氧乙烯醚羧酸的一种或几种。铝缓蚀剂为磷酸酯。偶合剂为格尔伯特醇、丙二醇甲醚、二乙二醇丁醚、失水山梨醇单油酸酯中的一种或几种。高级脂肪酸为异壬酸、妥尔油脂肪酸、油酸、以及蓖麻油酸、二聚酸、聚异丁烯丁二酸的一种或几种。杀菌剂为杀细菌和真菌的复配物，通常为三嗪、亚甲基二吗啉、苯丙异噻啉酮、甲基苯丙异噻啉酮的一种或几种。
本发明方案所公开的技术手段不仅限于上述实施方式所公开的技术手段，还包括由以上技术特征任意组合所组成的技术方案。应当指出，对于本技术领域的普通技术人员来说，在不脱离本发明原理的前提下，还可以做出若干改进和润饰，这些改进和润饰也视为本发明的保护范围。

Claims (7)

1.一种抗硬水型植物油乳化复合剂，其特征在于：其组成及含量如下：
单乙醇胺 1-5%，
三乙醇胺 1-5%，
高级脂肪酸 1-5%，
低泡表面活性剂： 25-50%，
抗硬水剂： 15-30%,
偶合剂: 15-35%，
铝缓蚀剂: 1-5%，
杀菌剂 1-5%。
2.如权利要求1所述的一种抗硬水型植物油乳化复合剂，其特征在于：所述高级脂肪酸为异壬酸、妥尔油脂肪酸、油酸、以及蓖麻油酸、二聚酸、聚异丁烯丁二酸的一种或几种。
3.如权利要求1所述的一种抗硬水型植物油乳化复合剂，其特征在于，所述的偶合剂为格尔伯特醇、丙二醇甲醚、二乙二醇丁醚、失水山梨醇单油酸酯中的一种或几种。
4.如权利要求1所述的一种抗硬水型植物油乳化复合剂，其特征在于，所述铝缓蚀剂为磷酸酯；所述低泡表面活性剂为直链、支链或者芳香族的脂肪醇聚氧乙烯、聚氧丙烯醚；所述抗硬水剂为乙二胺四乙酸、乙二酸四乙酸二钠、脂肪醇聚氧乙烯醚羧酸的一种或几种。
5.如权利要求1所述的一种抗硬水型植物油乳化复合剂，其特征在于：所述杀菌剂为杀细菌和真菌的复配物，通常为三嗪、亚甲基二吗啉、苯丙异噻啉酮、甲基苯丙异噻啉酮的一种或几种。
6.一种抗硬水型植物油乳化复合剂的制备方法，其特征在于：所述方法包括如下步骤：
步骤1：在常温常压下，按照物料重量百分比配比，先将单乙醇胺、三乙醇胺和高级脂肪酸酸加入反应釜，加热至50-60℃，持续搅拌约30分钟；
步骤2：在步骤1得到的混合物中，依次加入低泡表面活性剂、抗硬水剂、铝缓蚀剂及偶合剂，在40-50℃搅拌均匀30分钟；
步骤3：最在步骤2得到的混合物中加入杀菌剂，继续搅拌30-45分钟，搅拌均匀至透明均一液体；得到硬水型植物油乳化复合剂。
7.一种抗硬水型植物油乳化复合剂，其特征在于：所述乳化液组成及含量如下
抗硬水型植物油乳化复合剂 15%
植物油 85%。
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113897234A (zh) * 2020-12-31 2022-01-07 南京联智科技有限公司 多效型防锈复合添加剂及其制备方法
CN115820330A (zh) * 2022-12-21 2023-03-21 广东红日星实业有限公司 一种切削液及其制备方法和应用
CN116855293A (zh) * 2022-03-28 2023-10-10 中国石油化工股份有限公司 一种抗硬水乳化复合剂及其制备方法和应用

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101955843A (zh) * 2010-09-28 2011-01-26 上海宏泽化工有限公司 一种乳化切削液复合剂
CN102839038A (zh) * 2012-09-13 2012-12-26 济南库伦特科技有限公司 一种生产乳化油的添加剂组合物及其制备方法和应用
CN104087367A (zh) * 2014-07-29 2014-10-08 马思特（上海）化学有限公司 一种适应重负荷的低泡乳化切削液及其制备方法
CN107236593A (zh) * 2017-07-26 2017-10-10 西安蓉湖新材料开发有限公司 一种机床加工用环保型植物油基乳化切削液

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101955843A (zh) * 2010-09-28 2011-01-26 上海宏泽化工有限公司 一种乳化切削液复合剂
CN102839038A (zh) * 2012-09-13 2012-12-26 济南库伦特科技有限公司 一种生产乳化油的添加剂组合物及其制备方法和应用
CN104087367A (zh) * 2014-07-29 2014-10-08 马思特（上海）化学有限公司 一种适应重负荷的低泡乳化切削液及其制备方法
CN107236593A (zh) * 2017-07-26 2017-10-10 西安蓉湖新材料开发有限公司 一种机床加工用环保型植物油基乳化切削液

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113897234A (zh) * 2020-12-31 2022-01-07 南京联智科技有限公司 多效型防锈复合添加剂及其制备方法
CN116855293A (zh) * 2022-03-28 2023-10-10 中国石油化工股份有限公司 一种抗硬水乳化复合剂及其制备方法和应用
CN115820330A (zh) * 2022-12-21 2023-03-21 广东红日星实业有限公司 一种切削液及其制备方法和应用

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