CN111148718B - 用以生产剥离型纳米粒子的机械化学方法 - Google Patents

用以生产剥离型纳米粒子的机械化学方法 Download PDF

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CN111148718B
CN111148718B CN201880046762.1A CN201880046762A CN111148718B CN 111148718 B CN111148718 B CN 111148718B CN 201880046762 A CN201880046762 A CN 201880046762A CN 111148718 B CN111148718 B CN 111148718B
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CN111148718A (zh
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阿波娃·辛哈
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Carbon Cycle Technology Co ltd
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CN201880046762.1A 2017-07-13 2018-07-12 用以生产剥离型纳米粒子的机械化学方法 Active CN111148718B (zh)

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Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10468674B2 (en) 2018-01-09 2019-11-05 South Dakota Board Of Regents Layered high capacity electrodes
EP3997047A4 (en) 2019-07-08 2023-08-02 Alter Biota Inc. PREPARATION OF HYDRATED GRAPHENE OXIDE FOR USE AS A CONCRETE ADMIXTURE
JP2021031328A (ja) * 2019-08-22 2021-03-01 高彰 岡本 グラフェン前駆体の製造システム、グラフェン前駆体の製造方法およびグラフェン前駆体
US20210104720A1 (en) * 2019-10-08 2021-04-08 South Dakota Board Of Regents Electrode materials comprising cold spray doped compositions
JP7410165B2 (ja) * 2019-10-29 2024-01-09 株式会社クレハ 炭素量子ドット含有組成物、およびその製造方法
WO2021084825A1 (ja) * 2019-10-29 2021-05-06 株式会社クレハ 炭素量子ドット含有組成物、およびその製造方法
CN118145918A (zh) * 2019-11-05 2024-06-07 碳循环技术有限公司 包含机械化学羧化矿物填料和水泥和/或沥青粘合剂的组合物
WO2021087605A1 (en) * 2019-11-05 2021-05-14 Carbon Upcycling Technologies Inc. A mechanically carboxylated fly ash, methods of its production and uses thereof
US20230034630A1 (en) * 2021-07-23 2023-02-02 Chromaflo Technologies Corporation Graphene dispersion and functionalization
ES2933047B2 (es) * 2021-07-26 2023-09-14 Fundacion Instituto De Investig Marques De Valdecilla Material compuesto de poliacrilonitrilo y nanoplaquetas de grafeno, procedimiento de obtención y uso como sustrato de cultivos in vitro de células cancerosas
WO2023200905A1 (en) 2022-04-12 2023-10-19 Carbonbuilt Process for production of hydraulic-carbonating binder systems through mechanochemical activation of minerals
US20230399517A1 (en) 2022-06-13 2023-12-14 Carbon Upcycling Technologies Inc. Mechanochemically carbonated magnesium silicate, methods of its production and uses thereof
GB202208582D0 (en) 2022-06-13 2022-07-27 Groundtruth Global Ltd A mechanochemically carbonated magnesium silicate, methods of its production and uses thereof
PL4410759T3 (pl) * 2022-08-17 2025-09-15 Carbon Upcycling Technologies Inc. Mechanochemicznie karbonizowana glina, sposoby jej wytwarzania i jej zastosowania
ES2994883T3 (en) * 2022-08-17 2025-02-03 Carbon Upcycling Tech Inc A mechanochemically carbonated natural pozzolan, methods of its production and uses thereof
PL4324803T3 (pl) * 2022-08-17 2024-11-04 Carbon Upcycling Technologies Inc. Mechanochemicznie karbonizowany żużel, sposób jego wytwarzania i jego zastosowania
WO2025074250A1 (en) * 2023-10-06 2025-04-10 Carbon Upcycling Technologies Inc. Low energy mechanochemical carbon sequestration of solid feedstocks

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060252871A1 (en) * 2005-05-04 2006-11-09 Baird Donald G Process for increasing the exfoliation and dispersion of nanoparticles into polymeric matrices using supercritical carbon dioxide
JP2013100212A (ja) * 2010-11-29 2013-05-23 Sekisui Chem Co Ltd 炭素質材料
CN103706337A (zh) * 2013-12-30 2014-04-09 成都纺织高等专科学校 一种除甲醛纳米混合物及其制备方法
WO2017109693A1 (en) * 2015-12-21 2017-06-29 Universita' Degli Studi Di Roma "La Sapienza" Production of graphene based composite nanostructures obtained through the growth of zinc-oxide nanorods or microrods on unsupported graphene nanoplatelets in suspension

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1579622A (en) * 1925-05-28 1926-04-06 Edna T Rasmussen Vanity cane
IL103641A (en) * 1992-11-04 1996-11-14 Environmental Systems Ltd Expandable graphite compositions for absorption of liquids and method for the manufacture thereof
US6287694B1 (en) 1998-03-13 2001-09-11 Superior Graphite Co. Method for expanding lamellar forms of graphite and resultant product
CN100337742C (zh) * 2003-07-31 2007-09-19 北京化工大学 一种经插层前体制备的高分散铜基氧化催化剂及制备方法
US7785492B1 (en) 2006-09-26 2010-08-31 Nanotek Instruments, Inc. Mass production of nano-scaled platelets and products
BRPI0705815B1 (pt) * 2007-10-25 2018-03-20 Braskem S.A Processo de polimerização de nanopartículas de carga mineral para obtenção de nanocompósitos poliméricos
US9096736B2 (en) * 2010-06-07 2015-08-04 Kabushiki Kaisha Toyota Chuo Kenkyusho Fine graphite particles, graphite particle-dispersed liquid containing the same, and method for producing fine graphite particles
SG186811A1 (en) * 2010-06-25 2013-02-28 Univ Singapore Methods of forming graphene by graphite exfoliation
EA201301031A1 (ru) * 2011-03-15 2014-06-30 ПИРЛЕСС УОРЛДУАЙД, ЛЛСи Простой синтез графена, производных графена и абразивных наночастиц и их различные применения, в том числе в качестве трибологическиполезных присадок к смазочным маслам
KR101910924B1 (ko) 2013-03-08 2018-10-23 유니버시티 오브 센트럴 플로리다 리서치 파운데이션, 인코포레이티드 산업용 대규모 산화 그래핀 제조
US20140272199A1 (en) 2013-03-14 2014-09-18 Yi-Jun Lin Ultrasonic spray coating of conducting and transparent films from combined graphene and conductive nano filaments
GB201304770D0 (en) * 2013-03-15 2013-05-01 Provost Fellows Foundation Scholars And The Other Members Of Board Of A scalable process for producing exfoliated defect-free, non-oxidised 2-dimens ional materials in large quantities
US10886526B2 (en) * 2013-06-13 2021-01-05 Zenlabs Energy, Inc. Silicon-silicon oxide-carbon composites for lithium battery electrodes and methods for forming the composites
ES2534575B1 (es) 2013-09-24 2016-01-14 Consejo Superior De Investigaciones Científicas (Csic) Exfoliación de grafito con disolventes eutécticos profundos
JPWO2015125740A1 (ja) 2014-02-18 2017-03-30 積水化学工業株式会社 薄片化黒鉛の製造方法、薄片化黒鉛及び薄片化黒鉛−樹脂複合材料
KR101576896B1 (ko) * 2014-04-07 2015-12-14 인하대학교 산학협력단 산화철(β-FeOOH)-그래핀 복합체의 제조방법 및 이에 의해 제조되는 산화철(β-FeOOH)-그래핀 복합체
CN106687512B (zh) * 2014-07-17 2019-02-15 凯诺斯私人有限公司 聚合物树脂组合物和用所述组合物形成的制品
WO2016018995A1 (en) * 2014-07-30 2016-02-04 Rutgers, The State University Of New Jersey Graphene-reinforced polymer matrix composites
CN104763427B (zh) * 2015-02-12 2016-11-02 太原理工大学 一种超临界co2预裂煤矿厚硬难垮顶板的方法
CN107277960B (zh) * 2017-05-24 2020-09-11 方大炭素新材料科技股份有限公司 一种降低石墨电极/接头电阻率的方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060252871A1 (en) * 2005-05-04 2006-11-09 Baird Donald G Process for increasing the exfoliation and dispersion of nanoparticles into polymeric matrices using supercritical carbon dioxide
JP2013100212A (ja) * 2010-11-29 2013-05-23 Sekisui Chem Co Ltd 炭素質材料
CN103706337A (zh) * 2013-12-30 2014-04-09 成都纺织高等专科学校 一种除甲醛纳米混合物及其制备方法
WO2017109693A1 (en) * 2015-12-21 2017-06-29 Universita' Degli Studi Di Roma "La Sapienza" Production of graphene based composite nanostructures obtained through the growth of zinc-oxide nanorods or microrods on unsupported graphene nanoplatelets in suspension

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
F.Beckert etal.Mechanochemical Route to Graphene-Supported Iron Catalysts for Olefin Polymerization and in Situ Formation of Carbon/Polyolefin Nanocomposites.《Macromolecules》.2014,第47卷(第20期),第7037页左栏第5段,第7038页左栏第一段、右栏第5段,第7039页左栏第1段和图1、6. *
Mechanochemical Route to Graphene-Supported Iron Catalysts for Olefin Polymerization and in Situ Formation of Carbon/Polyolefin Nanocomposites;F.Beckert etal;《Macromolecules》;20141016;第47卷(第20期);第7037页左栏第5段,第7038页左栏第一段、右栏第5段,第7039页左栏第1段和图1、6 *

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US20230339761A1 (en) 2023-10-26
EP3652109A4 (en) 2021-05-05
EP4282819A3 (en) 2024-02-28
CN111148718A (zh) 2020-05-12
US20210147239A1 (en) 2021-05-20
JP7372239B2 (ja) 2023-10-31
US12234152B2 (en) 2025-02-25
EP3652109A1 (en) 2020-05-20
EP4282819A2 (en) 2023-11-29
US20250154009A1 (en) 2025-05-15
US20230312350A1 (en) 2023-10-05
CA3068161A1 (en) 2019-01-17
US11772976B2 (en) 2023-10-03
JP2020527534A (ja) 2020-09-10

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