CN111087936A - 一种疏水可印刷标签材料及其制备方法 - Google Patents

一种疏水可印刷标签材料及其制备方法 Download PDF

Info

Publication number
CN111087936A
CN111087936A CN201911255669.4A CN201911255669A CN111087936A CN 111087936 A CN111087936 A CN 111087936A CN 201911255669 A CN201911255669 A CN 201911255669A CN 111087936 A CN111087936 A CN 111087936A
Authority
CN
China
Prior art keywords
hydrophobic
coating
inducer
printable
label material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201911255669.4A
Other languages
English (en)
Inventor
欧章魁
唐贤坤
王益刚
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shenzhen Changmao Mucilage Glue New Material Co ltd
Original Assignee
Shenzhen Changmao Mucilage Glue New Material Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shenzhen Changmao Mucilage Glue New Material Co ltd filed Critical Shenzhen Changmao Mucilage Glue New Material Co ltd
Priority to CN201911255669.4A priority Critical patent/CN111087936A/zh
Publication of CN111087936A publication Critical patent/CN111087936A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/20—Adhesives in the form of films or foils characterised by their carriers
    • C09J7/22—Plastics; Metallised plastics
    • C09J7/25—Plastics; Metallised plastics based on macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • C09J7/255—Polyesters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/20—Adhesives in the form of films or foils characterised by their carriers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/40—Adhesives in the form of films or foils characterised by release liners
    • G—PHYSICS
    • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/02—Forms or constructions
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2203/00—Applications of adhesives in processes or use of adhesives in the form of films or foils
    • C09J2203/334—Applications of adhesives in processes or use of adhesives in the form of films or foils as a label
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2467/00—Presence of polyester
    • C09J2467/005—Presence of polyester in the release coating
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2467/00—Presence of polyester
    • C09J2467/006—Presence of polyester in the substrate

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Theoretical Computer Science (AREA)
  • Paints Or Removers (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Laminated Bodies (AREA)

Abstract

本发明提供一种疏水可印刷标签材料及其制备方法，从上到下包括：纳米涂层，PET面材，普通胶水，透明PET离型底；所述纳米涂层的原料包括：聚氨酸甲脂，环氧石墨烯，正硅酸乙酯，诱导剂；所述诱导剂包括：异丙醇铝，β‑环糊精，乙酸乙酯。

Description

一种疏水可印刷标签材料及其制备方法
技术领域
本发明属于膜材料领域，具体涉及一种疏水可印刷标签材料及其制备方法。
背景技术
中国广告外立面最大的污染源是粉尘污染，所以建筑物防污首要的是防止灰尘粘附，自洁涂料将来的方向在超亲水防静电上。
疏水性材料具有广泛的用途，用于各种建筑物的内外墙壁，能够长时间保持墙壁的新鲜度和清洁度。用于各种金属、玻璃、塑料、木制品、油漆等表面。用于汽车的前后风挡玻璃、侧风挡玻璃、后视镜的表面，保证雨天玻璃不挂水视线良好。用于。汽车驾驶室的天棚及地板、脚垫表面，实现长久的自清洁功能，特别是很多汽车脚垫地毯用水冲洗不易晒干，如果用该产品处理后冲洗就不怕湿，因为表面形成的纳米保护膜油水不沾，轻轻甩一下便可使用。用于浴池、卫生间的大理石、瓷砖、玻璃及其它涂层表面实现自洁。用于马桶、洗手池、洁具、家具、地板、窗帘、地毯、墙壁纸、儿童玩具、手机、电脑、冰箱、空调等表面可保持长期的清洁。
发明内容
本发明提供一种具有耐冲击的疏水可印刷标签材料及其制备方法，是一种新型工业生产纳米涂布技术，可进行反复的纳米涂布,能够让的室外广告减少清洁次数，节省成本。
为了实现上述发明目的，本发明采用的技术方案如下：
一种疏水可印刷标签材料，从上到下包括：纳米涂层，PET面材，普通胶水，透明PET离型底；所述纳米涂层的原料包括：聚氨酸甲脂，环氧石墨烯，正硅酸乙酯，诱导剂；所述诱导剂包括：异丙醇铝，β-环糊精，乙酸乙酯。
进一步地，所述聚氨酸甲脂，环氧石墨烯，正硅酸乙酯，诱导剂的比例为100：3.6：2：50。
进一步地，所述诱导剂中异丙醇铝，β-环糊精，乙酸乙酯的比例为2:2:100。
一种疏水可印刷标签材料的制备方法，包括如下步骤：
(1)利用蒸馏烧瓶将聚氨酸甲脂，环氧石墨烯，正硅酸乙酯在纯净水中搅拌混合30min；
(2)加入诱导剂，利用蒸馏冷凝装置在温度为70摄氏度中进行水浴恒温加热，待乙酸乙酯蒸发干净就可以得到一种疏水可印刷涂层液体；
(3)将疏水可印刷涂层液体利用滚轮涂布技术利用网纹轮进行PET面材的表面涂层，干燥后，多次涂布，直到涂层厚度为2μ；
(4)利用逗号涂布头在PET面材另一面进行刮普通胶水24μ；
(5)在普通胶水上用25μm透明PET离型底进行挤压贴合。
本发明的有益效果在于：
本发明的产品
莲花效应主要是指莲叶表面具有超疏水以及自洁的特性，可以通过模拟这一生物表象进行纳米疏水可印刷的制作。水落在该材料表面，水滴接触角大于110度，从外观上看水在该材料表面会形成水珠，如果是在立面上，水珠会在重力的作用下滚落。水落在超疏水材料表面，水滴接触角小于10度，从外观上看即水在该材料表面不会形成水滴而是水膜。
本发明的产品具有如下性质：
1、疏水，进行涂液后表面材料接触角大于60度。
2、一种新型工业生产纳米涂布技术，可进行反复的纳米涂布。有利于多层微分子结构的建立。
3、涂液价格便宜环保，材料仅仅需要常见的一些材料。
具体实施方式
下面结合具体实施例，进一步阐述本发明。应理解，这些实施例仅用于说明本发明，而不用于限制本发明的范围。在不背离本发明的技术解决方案的前提下，对本发明所作的本领域普通技术人员容易实现的任何改动都将落入本发明的权利要求范围之内。
实施例1
一种疏水可印刷标签材料，从上到下包括：纳米涂层，PET面材，普通胶水，透明PET离型底；所述纳米涂层的原料包括：聚氨酸甲脂，环氧石墨烯，正硅酸乙酯，诱导剂；所述诱导剂包括：异丙醇铝，β-环糊精，乙酸乙酯。所述聚氨酸甲脂，环氧石墨烯，正硅酸乙酯，诱导剂的比例为100：3.6：2：50。所述诱导剂中异丙醇铝，β-环糊精，乙酸乙酯的比例为2:2:100。
一种疏水可印刷标签材料的制备方法，包括如下步骤：
(1)利用蒸馏烧瓶将聚氨酸甲脂，环氧石墨烯，正硅酸乙酯在纯净水中搅拌混合30min；
(2)加入诱导剂，利用蒸馏冷凝装置在温度为70摄氏度中进行水浴恒温加热，待乙酸乙酯蒸发干净就可以得到一种疏水可印刷涂层液体；
(3)将疏水可印刷涂层液体利用滚轮涂布技术利用网纹轮进行PET面材的表面涂层，干燥后，多次涂布，直到涂层厚度为2μ；
(4)利用逗号涂布头在PET面材另一面进行刮普通胶水24μ；
(5)在普通胶水上用25μm透明PET离型底进行挤压贴合。
对比例1
与实施例1相同，除了不添加环氧石墨烯，正硅酸乙酯。
对比例2
与实施例1相同，除了不添加正硅酸乙酯。
对比例3
与实施例1相同，除了不添加环氧石墨烯。
对比例4
与实施例1相同，除了不添加异丙醇铝，β-环糊精。
对比例5
与实施例1相同，除了不添加异丙醇铝。
对比例6
与实施例1相同，除了不添加β-环糊精。
将实施例和对比例的产品用接触角测量仪测试接触角，同时在潮湿环境中长时间1个月放置测试吸水率。
表1
接触角 吸水率％
实施例1 82 0.1
对比例1 54 0.2
对比例2 61 0.2
对比例3 63 0.2
对比例4 64 0.9
对比例5 71 0.6
对比例6 73 0.5
通过测试可知，本发明中通过聚氨酸甲酯与环氧石墨烯，正硅酸乙酯进行配合，通过环氧石墨烯，正硅酸乙酯的添加协同提高了疏水效果。同时，通过诱导剂中添加异丙醇铝，β-环糊精，可以明显改善疏水性的同时，进一步改善吸水效果。

Claims (4)

1.一种疏水可印刷标签材料，其特征在于：从上到下包括：纳米涂层，PET面材，普通胶水，透明PET离型底；所述纳米涂层的原料包括：聚氨酸甲脂，环氧石墨烯，正硅酸乙酯，诱导剂；所述诱导剂包括：异丙醇铝，β-环糊精，乙酸乙酯。
2.根据权利要求1所述的一种疏水可印刷标签材料，其特征在于：所述聚氨酸甲脂，环氧石墨烯，正硅酸乙酯，诱导剂的比例为100：3.6：2：50。
3.根据权利要求1所述的一种疏水可印刷标签材料，其特征在于，所述诱导剂中异丙醇铝，β-环糊精，乙酸乙酯的比例为2:2:100。
4.一种疏水可印刷标签材料的制备方法，其特征在于包括如下步骤：
(1)利用蒸馏烧瓶将聚氨酸甲脂，环氧石墨烯，正硅酸乙酯在纯净水中搅拌混合30min；
(2)加入诱导剂，利用蒸馏冷凝装置在温度为70摄氏度中进行水浴恒温加热，待乙酸乙酯蒸发干净就可以得到一种疏水可印刷涂层液体；
(3)将疏水可印刷涂层液体利用滚轮涂布技术利用网纹轮进行PET面材的表面涂层，干燥后，多次涂布，直到涂层厚度为2μ；
(4)利用逗号涂布头在PET面材另一面进行刮普通胶水24μ；
(5)在普通胶水上用25μm透明PET离型底进行挤压贴合。
CN201911255669.4A 2019-12-10 2019-12-10 一种疏水可印刷标签材料及其制备方法 Pending CN111087936A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201911255669.4A CN111087936A (zh) 2019-12-10 2019-12-10 一种疏水可印刷标签材料及其制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201911255669.4A CN111087936A (zh) 2019-12-10 2019-12-10 一种疏水可印刷标签材料及其制备方法

Publications (1)

Publication Number Publication Date
CN111087936A true CN111087936A (zh) 2020-05-01

Family

ID=70394765

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201911255669.4A Pending CN111087936A (zh) 2019-12-10 2019-12-10 一种疏水可印刷标签材料及其制备方法

Country Status (1)

Country Link
CN (1) CN111087936A (zh)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115404013A (zh) * 2022-09-05 2022-11-29 深圳深汕特别合作区昌茂粘胶新材料有限公司 一种抗水防潮、耐酸碱的可印刷高粘保护贴膜

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN203569018U (zh) * 2013-10-18 2014-04-30 深圳昌茂粘胶制品有限公司 一种防污强粘不干胶膜
CN107758715A (zh) * 2017-10-13 2018-03-06 新疆众和股份有限公司 一种制备高结晶度高纯拟薄水铝石的方法
CN109942785A (zh) * 2019-02-26 2019-06-28 昆山嘉力普制版胶粘剂油墨有限公司 一种羧基化氧化石墨烯改性羧酸型水性聚氨酯的制备方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN203569018U (zh) * 2013-10-18 2014-04-30 深圳昌茂粘胶制品有限公司 一种防污强粘不干胶膜
CN107758715A (zh) * 2017-10-13 2018-03-06 新疆众和股份有限公司 一种制备高结晶度高纯拟薄水铝石的方法
CN109942785A (zh) * 2019-02-26 2019-06-28 昆山嘉力普制版胶粘剂油墨有限公司 一种羧基化氧化石墨烯改性羧酸型水性聚氨酯的制备方法

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
扶雄等: "《食用变形淀粉》", 30 March 2016, 中国轻工业出版社 *
石得中: "《世界精细化工产品技术经济手册》", 31 December 1988, 化学工业部科学技术情报研究所 *
窦翔: "《塑料包装印刷与复合技术问答》", 31 August 1994, 印刷工业出版社 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115404013A (zh) * 2022-09-05 2022-11-29 深圳深汕特别合作区昌茂粘胶新材料有限公司 一种抗水防潮、耐酸碱的可印刷高粘保护贴膜

Similar Documents

Publication Publication Date Title
JP6118012B2 (ja) 防曇性膜被覆物品
JP2003113003A (ja) 人工的な表面構造を備えた表面、その製造方法及びその使用
US20110076478A1 (en) Dust-repellent nanoparticle surfaces
CN111087936A (zh) 一种疏水可印刷标签材料及其制备方法
CN101423583B (zh) 无皂乳液型两亲聚合物树脂及其制备和在生产智能呼吸涂料中的应用
CN107254808B (zh) 一种墙纸用表面膜及其制备方法
CN103589261A (zh) 用于建筑外墙的耐候水性多元多彩涂料
Yuan et al. SiO2/TiO2 and PDMS modified self-cleaning coating and its application in decorative UHPC surface
CN109021757B (zh) 一种自清洁涂料及其制备方法和自清洁墙壁装饰品
CN214289543U (zh) 一种pvc塑料板表面擦拭装置
CN109370342A (zh) 一种水性纳米仿瓷涂料及其制备方法
CN103923538A (zh) 一种磨砂型幕墙铝板的制作方法
CN104910805A (zh) 一种用于汽车外表面的陶瓷涂料及其制备方法和应用
JP5065236B2 (ja) 防汚コーティング液、防汚コーティング層形成方法、および防汚コーティング層を有する窯業建材
CN109266141A (zh) 一种自洁型仿石涂料及制备方法
CN1919938A (zh) 干膜后漆膜有荷叶效果、易清洁的墙面漆
CN115404013A (zh) 一种抗水防潮、耐酸碱的可印刷高粘保护贴膜
CN201560508U (zh) 具有超易洗哑光墙面漆层的墙体
CN210679964U (zh) 一种自洁板材
JP2023066681A (ja) 水性塗料組成物、塗装体および塗膜形成方法
CN207988571U (zh) 一种智能电子站牌候车亭
CN201981753U (zh) 一种具有自洁功能的地板
CN205663146U (zh) 一种大理石砖
CN104695287A (zh) 可反复书写墙纸
CN2241721Y (zh) 一种晶光装饰超薄片

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20200501

RJ01 Rejection of invention patent application after publication