CN111073599B - Environment-friendly dust suppressant capable of improving soil quality - Google Patents

Environment-friendly dust suppressant capable of improving soil quality Download PDF

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Publication number
CN111073599B
CN111073599B CN201911357826.2A CN201911357826A CN111073599B CN 111073599 B CN111073599 B CN 111073599B CN 201911357826 A CN201911357826 A CN 201911357826A CN 111073599 B CN111073599 B CN 111073599B
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cellulose
stirring
parts
dust suppressant
environment
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CN111073599A (en
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张江辉
张元利
孙奎府
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Qingdao Shenzhoutong Environmental Protection Technology Co ltd
Qingdao University of Science and Technology
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Qingdao Shenzhoutong Environmental Protection Technology Co ltd
Qingdao University of Science and Technology
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00Materials not provided for elsewhere
    • C09K3/22Materials not provided for elsewhere for dust-laying or dust-absorbing
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F11/00Other organic fertilisers
    • C05F11/02Other organic fertilisers from peat, brown coal, and similar vegetable deposits
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Soil Conditioners And Soil-Stabilizing Materials (AREA)

Abstract

The environment-friendly dust suppressant for improving soil quality comprises the following components in parts by weight: 10-15 parts of cellulose, 10-15 parts of modified starch, 0.4-1 part of potassium humate and 3-6 parts of vegetable gum. The environment-friendly dust suppressant is used for binding and solidifying dust on the surface of bare soil, effectively suppressing dust emission on the surface of bare soil, wherein the dust suppressant comprises natural plant products, can provide nutrition for the growth of later-stage plants after natural degradation, is rich in fulvic acid potassium, is rich in natural organic matters, is rich in various mineral elements and a large amount of nitrogen, phosphorus, potassium and other elements required by the rooting growth of plants, and can jointly promote the growth of plants and cover bare soil vegetation in the later stage of artificial dust suppression.

Description

Environment-friendly dust suppressant capable of improving soil quality
[ field of technology ]
The invention belongs to the technical field of environmental protection products, can effectively improve soil quality and promote vegetation growth in a biological dust suppression process, belongs to the technical field of environmental protection products, and particularly relates to an environment-friendly dust suppressant for improving soil quality.
[ background Art ]
With the continuous deepening of the national treatment of plastic pollution, biological dust suppressants are appeared, which gradually replace green net coverage and become a limited technical choice for construction sites, wharf mines and the like. In the prior dust suppressant use process, the dust suppressant is simply sprayed and covered, the dust suppression effect and the dust suppression service life can meet the related requirements, but the existing dust suppressant plays a role in fixing dust, but can generate a later effect on the environment, for example, the patent with the patent number of 2019101738129 is to mix polyvinyl alcohol, polyurethane resin and the like, add iron green to dye solution, spray the solution on the surface of bare soil, fix the dust by using chemical products, play a role in fixing the dust, but the chemical products aggravate soil hardening, are unfavorable for natural growth of later-stage plants, and possibly mix heavy metal elements in the iron green, so that other environmental risks are brought.
[ invention ]
Aiming at the problems, the invention aims to provide the environment-friendly dust suppressant for improving the soil quality, which is used for binding and solidifying dust on the surface of bare soil, effectively suppressing dust generation on the surface of bare soil, wherein the dust suppressant comprises natural plant products, can provide nutrition for the growth of later-stage plants after natural degradation, is rich in various mineral elements and a large amount of nitrogen, phosphorus, potassium and other elements required by the rooting growth of plants, and can promote the growth of plants and cover bare soil vegetation after dust suppression is not needed.
The invention provides an environment-friendly dust suppressant for improving soil quality, which comprises the following components in parts by weight: 10-15 parts of cellulose, 10-15 parts of modified starch, 0.4-1 part of potassium humate and 3-6 parts of vegetable gum; in the invention, the cellulose increases the viscosity of aqueous solution and is emulsified in the same industry, and the cellulose and the hydrophilic modified starch form a grid structure on the microcosmic scale and are covered on the surface of bare soil; the potassium humate is a main nutrition component and can provide trace elements for plants; the plant gum and cellulose act together to achieve the thickening and bonding effects, and a reticular structure film can be formed on the surface of bare soil; whether grass seeds are added or not can be determined according to actual needs, vegetation can be formed in the later period, and independent planting is not needed;
the proportioning method of the environment-friendly dust suppressant comprises the following steps: weighing cellulose, modified starch, potassium humate and vegetable gum according to the weight ratio, and mixing with water: environment-friendly dust suppressant= (100-150): 1, weighing water, putting the weighed cellulose and modified starch into a stirring kettle, uniformly mixing the weighed cellulose and the modified starch, adding the mixture into the stirring kettle while stirring, and stirring for 5-10 minutes; and adding the weighed vegetable gum in the stirring process, continuously stirring for 10 minutes, finally adding potassium humate, and stirring for 5 minutes until the mixture is uniformly mixed.
In particular, the cellulose is a mixture of carboxymethyl cellulose, hydroxypropyl methyl cellulose, polyanionic cellulose and hydroxyethyl cellulose; in the invention, the cellulose is mainly composed of carboxymethyl cellulose, hydroxypropyl methyl cellulose or hydroxyethyl cellulose which is soluble in water to construct a high molecular chain skeleton.
In particular, the modified starch is cold water soluble starch, in particular one of pregelatinized starch or carboxymethyl starch; the modified starch has hydrophilic groups on the surface, so that the enhanced viscosity has a positive effect on grid construction.
In particular, the potassium fulvate is mineral source potassium fulvate, has positive effects on rooting and growth of plants, promotes greening vegetation coverage of bare soil after dust suppression, and is high-purity mineral source potassium fulvate.
In particular, the vegetable gum is one or more of xanthan gum, carrageenan, guar gum, seaweed gum and agar; in the invention, the vegetable gum and cellulose act together to achieve the thickening and bonding effects, and a net-shaped structure film can be formed on the surface of bare soil.
The invention has the beneficial effects that the invention can provide necessary elements and necessary mineral substances for the vegetation coverage of the bare soil in the later period through the nutrition components of the dust suppressant at the same time of suppressing the dust, promote the rooting growth of the plants, does not need too much human intervention in the whole process, has low cost, combines the dust suppression with the vegetation coverage, and reduces the construction strength.
[ detailed description ] of the invention
The present invention will now be explained in detail with reference to examples and comparative examples for further understanding of the object, function and technical means of the present invention.
Example 1
The environment-friendly dust suppressant for improving soil quality comprises the following components in parts by weight: 10 parts of modified starch, 14 parts of cellulose, 6 parts of vegetable gum and 0.6 part of potassium humate.
The preparation method comprises the following steps:
weighing cellulose, modified starch, potassium humate and vegetable gum according to the weight ratio, and mixing with water: environment-friendly dust suppressant= (100-150): 1, weighing water, putting the weighed cellulose and modified starch into a stirring kettle, uniformly mixing the weighed cellulose and the modified starch, adding the mixture into the stirring kettle while stirring, and stirring for 5-10 minutes; and adding the weighed vegetable gum in the stirring process, continuously stirring for 10 minutes, finally adding potassium humate, and stirring for 5 minutes until the mixture is uniformly mixed.
Example 2
The environment-friendly dust suppressant for improving soil quality comprises the following components in parts by weight: 10 parts of modified starch, 14 parts of cellulose, 5 parts of vegetable gum and 0.6 part of potassium humate.
The preparation method comprises the following steps:
weighing cellulose, modified starch, potassium humate and vegetable gum according to the weight ratio, and mixing with water: environment-friendly dust suppressant = 150:1, weighing water, putting the weighed cellulose and modified starch into a stirring kettle, uniformly mixing the weighed cellulose and the modified starch, adding the mixture into the stirring kettle while stirring, and stirring for 5-10 minutes; and adding the weighed vegetable gum in the stirring process, continuously stirring for 10 minutes, finally adding potassium humate, and stirring for 5 minutes until the mixture is uniformly mixed.
Example 3
The environment-friendly dust suppressant for improving soil quality comprises the following components in parts by weight: 10 parts of modified starch, 14 parts of cellulose, 4 parts of vegetable gum and 0.6 part of potassium humate.
The preparation method comprises the following steps:
weighing cellulose, modified starch, potassium humate and vegetable gum according to the weight ratio, and mixing with water: environment-friendly dust suppressant= (100-150): 1, weighing water, putting the weighed cellulose and modified starch into a stirring kettle, uniformly mixing the weighed cellulose and the modified starch, adding the mixture into the stirring kettle while stirring, and stirring for 5-10 minutes; and adding the weighed vegetable gum in the stirring process, continuously stirring for 10 minutes, finally adding potassium humate, and stirring for 5 minutes until the mixture is uniformly mixed.
Example 4
The environment-friendly dust suppressant for improving soil quality comprises the following components in parts by weight: 10 parts of modified starch, 14 parts of cellulose, 6 parts of vegetable gum and 0.5 part of potassium humate.
The preparation method comprises the following steps:
weighing cellulose, modified starch, potassium humate and vegetable gum according to the weight ratio, and mixing with water: environment-friendly dust suppressant= (100-150): 1, weighing water, putting the weighed cellulose and modified starch into a stirring kettle, uniformly mixing the weighed cellulose and the modified starch, adding the mixture into the stirring kettle while stirring, and stirring for 5-10 minutes; and adding the weighed vegetable gum in the stirring process, continuously stirring for 10 minutes, finally adding potassium humate, and stirring for 5 minutes until the mixture is uniformly mixed.
Example 5
The environment-friendly dust suppressant for improving soil quality comprises the following components in parts by weight: 10 parts of modified starch, 14 parts of cellulose, 6 parts of vegetable gum and 0.4 part of potassium humate.
The preparation method comprises the following steps:
weighing cellulose, modified starch, potassium humate and vegetable gum according to the weight ratio, and mixing with water: environment-friendly dust suppressant= (100-150): 1, weighing water, putting the weighed cellulose and modified starch into a stirring kettle, uniformly mixing the weighed cellulose and the modified starch, adding the mixture into the stirring kettle while stirring, and stirring for 5-10 minutes; and adding the weighed vegetable gum in the stirring process, continuously stirring for 10 minutes, finally adding potassium humate, and stirring for 5 minutes until the mixture is uniformly mixed.
Example 6
The dust suppressant solution of example 1 was diluted 0.5-fold.
Example 7
The dust suppressant solution of example 2 was diluted 0.5-fold.
Example 8
The dust suppressant solution of example 3 was diluted 0.5-fold.
Example 9
The dust suppressant solution of example 4 was diluted 0.5-fold.
Example 10
The dust suppressant solution of example 5 was diluted 0.5-fold.
Comparative example 1
The environment-friendly dust suppressant for improving soil quality comprises the following components in percentage by mass: 10 parts of modified starch, 14 parts of cellulose, 6 parts of vegetable gum and 15 parts of potassium humate.
The preparation method comprises the following steps:
weighing cellulose, modified starch, potassium humate and vegetable gum according to the weight ratio, and mixing with water: environment-friendly dust suppressant= (100-150): 1, weighing water, putting the weighed cellulose and modified starch into a stirring kettle, uniformly mixing the weighed cellulose and the modified starch, adding the mixture into the stirring kettle while stirring, and stirring for 5-10 minutes; and adding the weighed vegetable gum in the stirring process, continuously stirring for 10 minutes, finally adding potassium humate, and stirring for 5 minutes until the mixture is uniformly mixed.
Comparative example 2
The invention relates to an environment-friendly dust suppressant for improving soil quality, which comprises the following components in percentage by mass: 10 parts of modified starch, 14 parts of cellulose, 6 parts of hydroxypropyl methyl cellulose and 0.6 part of potassium humate.
The preparation method comprises the following steps:
weighing modified starch, hydroxypropyl methylcellulose and potassium humate according to the weight ratio, and mixing with water: environment-friendly dust suppressant= (100-150): 1, weighing water, putting the weighed cellulose and modified starch into a stirring kettle, uniformly mixing the weighed cellulose and the modified starch, adding the mixture into the stirring kettle while stirring, and stirring for 5-10 minutes; and adding the weighed hydroxypropyl methylcellulose in the stirring process, continuously stirring for 10 minutes, finally adding potassium humate, and stirring for 5 minutes until the mixture is uniformly mixed.
Comparative example 3
The environment-friendly dust suppressant for improving soil quality comprises the following components in percentage by mass: 10 parts of cationic starch, 14 parts of cellulose, 6 parts of vegetable gum and 15 parts of potassium humate.
The using method comprises the following steps:
weighing cellulose, cationic starch, potassium humate and vegetable gum according to the weight ratio, and mixing with water: environment-friendly dust suppressant= (100-150): 1, weighing water, putting the weighed cellulose and cationic starch into a stirring kettle, uniformly mixing the weighed cellulose and cationic starch, adding the mixture into the stirring kettle while stirring, and stirring for 5-10 minutes; and adding the weighed vegetable gum in the stirring process, continuously stirring for 10 minutes, finally adding potassium humate, and stirring for 5 minutes until the mixture is uniformly mixed.
Comparative example 4
The invention relates to an environment-friendly dust suppressant for improving soil quality, which comprises the following components in percentage by mass: 10 parts of modified starch, 14 parts of cellulose and 6 parts of vegetable gum.
The preparation method comprises the following steps:
weighing modified starch, cellulose and vegetable gum according to the weight powder, and mixing with water: environment-friendly dust suppressant= (100-150): 1, weighing water, putting the weighed cellulose and modified starch into a stirring kettle, uniformly mixing the weighed cellulose and the modified starch, adding the mixture into the stirring kettle while stirring, and stirring for 5-10 minutes; and adding the weighed hydroxypropyl methylcellulose in the stirring process, and continuously stirring for 10 minutes until the mixture is uniformly mixed.
The beneficial effects of the present experiment are described below using experimental data of experimental cases. Wherein, the table 1 is an environment-friendly dust suppressant: the water is prepared according to the concentration ratio of 1:100 and the experimental data table, and the specific results are as follows:
TABLE 1
From the experimental conclusion in table 1, if too much potassium humate is added, the viscosity of the soil surface is smaller and the hardness is higher after the environment-friendly dust suppressant is used, so that the soil is hardened, if no potassium humate is added, the hardness and the crust thickness of the soil surface are both increased after the environment-friendly dust suppressant is used, so that the soil is hardened, and therefore, the addition amount of the potassium humate needs to be controlled between 0.4 and 1 part; if the vegetable gum is removed, the environment-friendly dust suppressant has the advantages of smaller viscosity, smaller hardness and thicker crust thickness on the soil surface, and the soil is hardened after the vegetable gum is removed; if cold water soluble starch (modified starch) is replaced by cationic starch, flocculation occurs in the solution, and after the environment-friendly dust suppressant is used, the viscosity of the soil surface is smaller, the hardness is smaller, so that the ideal dust suppression effect cannot be achieved.
Table 2 is an environmental protection dust suppressant: the water is prepared according to the concentration ratio of 1:150 and the experimental data table, and the specific results are as follows:
TABLE 2
From the experimental conclusion in table 2, if too much potassium fulvate is added, the viscosity of the soil surface is smaller and the hardness is improved after the environment-friendly dust suppressant is used, so that the soil is hardened, if the potassium fulvate is not added, the influence on the soil is small after the diluted environment-friendly dust suppressant solution is used, and the addition amount of the potassium fulvate needs to be controlled between 0.4 and 1 part by combining the results in table 1; if the vegetable gum is removed, the environment-friendly dust suppressant has the advantages of smaller viscosity, smaller hardness and slightly increased crust thickness on the soil surface, and the soil is hardened after the vegetable gum is removed; if cold water soluble starch (modified starch) is replaced by cationic starch, flocculation occurs in the solution, and after the environment-friendly dust suppressant is used, the viscosity of the soil surface is smaller, the hardness is smaller, so that the ideal dust suppression effect cannot be achieved.
The data from the above experiments were averaged over three experiments.
From the appearance color, the added potassium fulvate solution shows black, the color is related to the added potassium fulvate, the more the added potassium fulvate is, the darker the color is, and the viscosity is not greatly influenced by the small amount of the added potassium fulvate.
After the solution is prepared, smell is smelled, and the solution is odorless.
Physicochemical detection is carried out according to the first part of the railway coal transportation dust suppression technical conditions: the detection method and standard of the dust suppressant TB/T3210.1-2009 meet the technical requirements.
It will be understood that modifications and variations will be apparent to those skilled in the art from the foregoing description, and it is intended that all such modifications and variations be included within the scope of the following claims.

Claims (3)

1. The environment-friendly dust suppressant for improving soil quality is characterized by comprising the following components in parts by weight: 10-15 parts of cellulose, 10-15 parts of modified starch, 0.4-1 part of potassium humate and 3-6 parts of vegetable gum;
the modified starch is cold water soluble starch, and is specifically pregelatinized starch or carboxymethyl starch;
the vegetable gum is one or more of xanthan gum, carrageenan, guar gum, seaweed gum and agar;
the proportioning method of the environment-friendly dust suppressant comprises the following steps: weighing cellulose, modified starch, potassium humate and vegetable gum according to the weight ratio, and mixing with water: environment-friendly dust suppressant = 100:1, weighing water, putting the weighed cellulose and modified starch into a stirring kettle, mixing the weighed cellulose and the modified starch, adding the mixture into the stirring kettle while stirring, and stirring for 5-10 minutes; and adding the weighed vegetable gum in the stirring process, continuously stirring for 10 minutes, finally adding potassium humate, and stirring for 5 minutes.
2. The soil improvement environmental protection dust suppressant according to claim 1, wherein said cellulose is a mixture of carboxymethyl cellulose, hydroxypropyl methylcellulose, polyanionic cellulose, hydroxyethyl cellulose.
3. The soil improvement environmental protection dust suppressant according to claim 1, wherein said potassium fulvate is a mineral source potassium fulvate.
CN201911357826.2A 2019-12-25 2019-12-25 Environment-friendly dust suppressant capable of improving soil quality Active CN111073599B (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111662681A (en) * 2020-07-02 2020-09-15 河北宝之宏环保科技有限公司 Crusting type dust suppressant and preparation method thereof
CN113115794A (en) * 2021-04-22 2021-07-16 陕西品物皆春生态科技有限公司 Flocculation inhibitor and preparation method and application thereof
CN113980648B (en) * 2021-11-22 2023-09-08 山东方嘉环境科技有限公司 Dust suppression material
CN113951031A (en) * 2021-12-14 2022-01-21 河南工业大学 Method for inhibiting dust generated on loose ground surface

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Publication number Priority date Publication date Assignee Title
CN103497736A (en) * 2013-08-16 2014-01-08 北京安平联合环保科技有限公司 Dust inhibiting agent used during railway transportation process of powdered materials and preparation method thereof
WO2018176713A1 (en) * 2017-03-27 2018-10-04 日东(青岛)研究院有限公司 Environmentally friendly efficient dust suppression agent, preparation method therefor and use thereof
CN109021924A (en) * 2018-06-06 2018-12-18 北京英华高科技有限公司 A kind of green dust agent and preparation method thereof admittedly
CN109575882A (en) * 2018-12-29 2019-04-05 北京首创博桑环境科技股份有限公司 A kind of inhibition miberal powder and the dust suppressant of exposed ground dust and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103497736A (en) * 2013-08-16 2014-01-08 北京安平联合环保科技有限公司 Dust inhibiting agent used during railway transportation process of powdered materials and preparation method thereof
WO2018176713A1 (en) * 2017-03-27 2018-10-04 日东(青岛)研究院有限公司 Environmentally friendly efficient dust suppression agent, preparation method therefor and use thereof
CN109021924A (en) * 2018-06-06 2018-12-18 北京英华高科技有限公司 A kind of green dust agent and preparation method thereof admittedly
CN109575882A (en) * 2018-12-29 2019-04-05 北京首创博桑环境科技股份有限公司 A kind of inhibition miberal powder and the dust suppressant of exposed ground dust and preparation method thereof

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