CN111066194A - 再生多硫化物清除层的制造方法以及锂-硫电池 - Google Patents

再生多硫化物清除层的制造方法以及锂-硫电池 Download PDF

Info

Publication number
CN111066194A
CN111066194A CN201880011264.3A CN201880011264A CN111066194A CN 111066194 A CN111066194 A CN 111066194A CN 201880011264 A CN201880011264 A CN 201880011264A CN 111066194 A CN111066194 A CN 111066194A
Authority
CN
China
Prior art keywords
polysulfide
rsl
cnts
sulfur
regenerated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201880011264.3A
Other languages
English (en)
Chinese (zh)
Inventor
卢云峰
徐建国
沈力
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fortchel International Ltd
University of California San Diego UCSD
Original Assignee
Fortchel International Ltd
University of California San Diego UCSD
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fortchel International Ltd, University of California San Diego UCSD filed Critical Fortchel International Ltd
Publication of CN111066194A publication Critical patent/CN111066194A/zh
Pending legal-status Critical Current

Links

Images

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/42Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/4235Safety or regulating additives or arrangements in electrodes, separators or electrolyte
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/58Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/581Chalcogenides or intercalation compounds thereof
    • H01M4/5815Sulfides
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/42Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/4242Regeneration of electrolyte or reactants
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/362Composites
    • H01M4/364Composites as mixtures
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/362Composites
    • H01M4/366Composites as layered products
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/38Selection of substances as active materials, active masses, active liquids of elements or alloys
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/38Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H01M4/381Alkaline or alkaline earth metals elements
    • H01M4/382Lithium
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/62Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/621Binders
    • H01M4/622Binders being polymers
    • H01M4/623Binders being polymers fluorinated polymers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/62Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/624Electric conductive fillers
    • H01M4/625Carbon or graphite
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/62Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/628Inhibitors, e.g. gassing inhibitors, corrosion inhibitors
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/64Carriers or collectors
    • H01M4/66Selection of materials
    • H01M4/661Metal or alloys, e.g. alloy coatings
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/64Carriers or collectors
    • H01M4/66Selection of materials
    • H01M4/663Selection of materials containing carbon or carbonaceous materials as conductive part, e.g. graphite, carbon fibres
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/64Carriers or collectors
    • H01M4/66Selection of materials
    • H01M4/665Composites
    • H01M4/667Composites in the form of layers, e.g. coatings
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/64Carriers or collectors
    • H01M4/70Carriers or collectors characterised by shape or form
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/64Carriers or collectors
    • H01M4/70Carriers or collectors characterised by shape or form
    • H01M4/75Wires, rods or strips
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/64Carriers or collectors
    • H01M4/70Carriers or collectors characterised by shape or form
    • H01M4/76Containers for holding the active material, e.g. tubes, capsules
    • H01M4/762Porous or perforated metallic containers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/409Separators, membranes or diaphragms characterised by the material
    • H01M50/411Organic material
    • H01M50/414Synthetic resins, e.g. thermoplastics or thermosetting resins
    • H01M50/417Polyolefins
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00Electrolytes
    • H01M2300/0088Composites
    • H01M2300/0094Composites in the form of layered products, e.g. coatings
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Composite Materials (AREA)
  • Inorganic Chemistry (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)
  • Cell Separators (AREA)
CN201880011264.3A 2017-02-09 2018-02-07 再生多硫化物清除层的制造方法以及锂-硫电池 Pending CN111066194A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201762456936P 2017-02-09 2017-02-09
US62/456,936 2017-02-09
PCT/US2018/017155 WO2018148233A1 (en) 2017-02-09 2018-02-07 Regenerative polysulfide-scavenging layers enabling lithium-sulfur batteries with high energy density and prolonged cycling life and methods of making same

Publications (1)

Publication Number Publication Date
CN111066194A true CN111066194A (zh) 2020-04-24

Family

ID=63107829

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201880011264.3A Pending CN111066194A (zh) 2017-02-09 2018-02-07 再生多硫化物清除层的制造方法以及锂-硫电池

Country Status (7)

Country Link
US (1) US10985368B2 (https=)
EP (1) EP3580808A4 (https=)
JP (1) JP6980235B2 (https=)
KR (1) KR20190119607A (https=)
CN (1) CN111066194A (https=)
AU (1) AU2018218262A1 (https=)
WO (1) WO2018148233A1 (https=)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112332025A (zh) * 2020-11-10 2021-02-05 南京工业大学 一种锂硫电池用隔膜及其制备方法
CN115832617A (zh) * 2022-11-30 2023-03-21 惠州锂威新能源科技有限公司 一种插层复合薄膜及其制备方法和锂硫电池
CN116936777A (zh) * 2023-09-15 2023-10-24 山东海化集团有限公司 一种锂硫电池正、负极材料及其制备方法和应用

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI681587B (zh) * 2018-01-16 2020-01-01 中央研究院 製造快速充電和長壽鋰-硫電池的方法
KR102680031B1 (ko) * 2018-12-07 2024-06-28 주식회사 엘지에너지솔루션 분리막 및 이를 포함하는 리튬 이차전지
CN111081945A (zh) * 2019-12-20 2020-04-28 河南师范大学 一种锂硫电池用多功能Nb2O5/中空碳纤维复合隔膜涂层材料的制备方法
CN111082063B (zh) * 2019-12-26 2023-03-28 内蒙古民族大学 一种柔性导电碳/金属复合纳米纤维膜及其制备方法和应用、锂硫电池
CN111540868A (zh) * 2020-01-21 2020-08-14 武汉船用电力推进装置研究所(中国船舶重工集团公司第七一二研究所) 一种二维二氧化锰修饰聚丙烯隔膜的制备方法和应用
WO2021182614A1 (ja) * 2020-03-13 2021-09-16 学校法人早稲田大学 二次電池用正極、二次電池用正極の製造方法、二次電池
KR102819965B1 (ko) * 2020-09-04 2025-06-13 주식회사 엘지에너지솔루션 분리막 및 이를 포함하는 이차 전지
CN111916640B (zh) * 2020-09-11 2023-04-28 合肥工业大学 一种锂硫电池WS2/CNTs改性隔膜及其制备方法
CN114420928B (zh) * 2020-10-28 2024-04-19 山东海科创新研究院有限公司 一种具有高性能的锂离子电池用硅碳负极材料及其制备方法、锂离子电池
KR102893939B1 (ko) * 2020-11-13 2025-12-01 한국전기연구원 플렉시블 리튬-황 전지 집전체용 금속나노와이어-탄소나노튜브 복합체
CN114583165A (zh) * 2020-12-01 2022-06-03 河南大学 一种金属/金属氧化物锂硫电池正极骨架结构
US20250015437A1 (en) * 2021-07-07 2025-01-09 Board Of Regents, The University Of Texas System Separators for use in energy storage devices
CN113937418B (zh) * 2021-10-11 2023-11-17 中科南京绿色制造产业创新研究院 一种锂硫电池隔膜及其制备方法和锂硫电池
CN114497888B (zh) * 2022-01-25 2024-04-05 郑州大学 一种锂硫电池隔膜修饰材料的制备方法及其应用
CN114530671B (zh) * 2022-01-25 2024-05-28 广东工业大学 一种基于高比表面积介孔氧化铝的功能性隔膜及其制备方法和应用
CN114605734B (zh) * 2022-02-17 2023-08-01 温州大学 有机小分子嫁接碳纳米管修饰的功能薄膜复合材料及其制备方法和应用
CN114890478A (zh) * 2022-05-13 2022-08-12 武汉科技大学 一种超晶格材料及其制备方法以及在锂硫电池隔膜改性中的应用
CN116159595B (zh) * 2022-12-15 2024-08-06 温州大学 一种改性血蓝蛋白催化剂复合材料及其应用
US20240204355A1 (en) * 2022-12-16 2024-06-20 Lyten, Inc. Protective layer on anode-facing surface of separator for mitigating polysufide shuttling in lithium-based batteries
CN119401056B (zh) * 2024-11-01 2025-09-30 南通大学 具有球链状金属氧化物结构的锂硫电池隔膜及其制备方法
CN120601077B (zh) * 2025-08-07 2025-09-26 苏州工学院 一种橄榄形结构In2Ox修饰的锂硫电池隔膜及其制备方法和应用

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102187413A (zh) * 2008-08-15 2011-09-14 加利福尼亚大学董事会 电化学储能用分级结构纳米线复合物
CN104143630A (zh) * 2013-05-09 2014-11-12 中国科学院大连化学物理研究所 石墨烯-纳米金属氧化物复合材料在锂硫电池中应用
CN104183820A (zh) * 2014-03-03 2014-12-03 河南师范大学 一种锂硫电池正极用膜材料
US20150056387A1 (en) * 2013-08-21 2015-02-26 GM Global Technology Operations LLC Methods for making coated porous separators and coated electrodes for lithium batteries
CN104716382A (zh) * 2013-12-15 2015-06-17 中国科学院大连化学物理研究所 一种锂-硫电池结构
CN105074961A (zh) * 2013-02-05 2015-11-18 Hrl实验室有限责任公司 用于锂-硫电池的隔膜
CN105489818A (zh) * 2015-12-29 2016-04-13 长沙矿冶研究院有限责任公司 锂硫电池用改性隔膜的制备方法、改性隔膜及具有该改性隔膜的锂硫电池
CN105552282A (zh) * 2015-11-13 2016-05-04 北京理工大学 基于功能性碳纤维布作为正极阻挡层的锂硫电池

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8236446B2 (en) 2008-03-26 2012-08-07 Ada Technologies, Inc. High performance batteries with carbon nanomaterials and ionic liquids
WO2012109648A1 (en) 2011-02-11 2012-08-16 The Penn State Research Foundation Carbon-metal oxide-sulfur cathodes for high-performance lithium-sulfur batteries
CN102263257B (zh) 2011-06-28 2013-08-07 中国科学院金属研究所 高能量柔性电极材料及其制备方法和在二次电池中的应用
KR20150045484A (ko) * 2012-08-17 2015-04-28 더 보드 오브 리전츠 오브 더 유니버시티 오브 텍사스 시스템 리튬-황 배터리용 다공성 카본 간층
US9373829B2 (en) * 2013-10-11 2016-06-21 GM Global Technology Operations LLC Porous interlayer for a lithium-sulfur battery
KR101684645B1 (ko) * 2015-01-27 2016-12-07 한국과학기술연구원 바나듐 산화물 제로겔/카본 나노복합체의 제조방법, 이를 포함하는 리튬-황 이차전지 양극 및 이의 제조방법
US9564656B1 (en) 2015-09-14 2017-02-07 Nanotek Instruments, Inc. Process for producing alkali metal or alkali-ion batteries having high volumetric and gravimetric energy densities

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102187413A (zh) * 2008-08-15 2011-09-14 加利福尼亚大学董事会 电化学储能用分级结构纳米线复合物
CN105074961A (zh) * 2013-02-05 2015-11-18 Hrl实验室有限责任公司 用于锂-硫电池的隔膜
CN104143630A (zh) * 2013-05-09 2014-11-12 中国科学院大连化学物理研究所 石墨烯-纳米金属氧化物复合材料在锂硫电池中应用
US20150056387A1 (en) * 2013-08-21 2015-02-26 GM Global Technology Operations LLC Methods for making coated porous separators and coated electrodes for lithium batteries
CN104716382A (zh) * 2013-12-15 2015-06-17 中国科学院大连化学物理研究所 一种锂-硫电池结构
CN104183820A (zh) * 2014-03-03 2014-12-03 河南师范大学 一种锂硫电池正极用膜材料
CN105552282A (zh) * 2015-11-13 2016-05-04 北京理工大学 基于功能性碳纤维布作为正极阻挡层的锂硫电池
CN105489818A (zh) * 2015-12-29 2016-04-13 长沙矿冶研究院有限责任公司 锂硫电池用改性隔膜的制备方法、改性隔膜及具有该改性隔膜的锂硫电池

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112332025A (zh) * 2020-11-10 2021-02-05 南京工业大学 一种锂硫电池用隔膜及其制备方法
CN115832617A (zh) * 2022-11-30 2023-03-21 惠州锂威新能源科技有限公司 一种插层复合薄膜及其制备方法和锂硫电池
CN115832617B (zh) * 2022-11-30 2025-09-02 惠州锂威新能源科技有限公司 一种插层复合薄膜及其制备方法和锂硫电池
CN116936777A (zh) * 2023-09-15 2023-10-24 山东海化集团有限公司 一种锂硫电池正、负极材料及其制备方法和应用
CN116936777B (zh) * 2023-09-15 2023-12-29 山东海化集团有限公司 一种锂硫电池正、负极材料及其制备方法和应用

Also Published As

Publication number Publication date
EP3580808A4 (en) 2020-11-25
WO2018148233A1 (en) 2018-08-16
US10985368B2 (en) 2021-04-20
AU2018218262A1 (en) 2019-08-29
KR20190119607A (ko) 2019-10-22
EP3580808A1 (en) 2019-12-18
JP6980235B2 (ja) 2021-12-15
US20180241039A1 (en) 2018-08-23
JP2020507896A (ja) 2020-03-12

Similar Documents

Publication Publication Date Title
US10985368B2 (en) Regenerative polysulfide-scavenging layers enabling lithium-sulfur batteries with high energy density and prolonged cycling life and methods of making same
Liu et al. Regenerative polysulfide-scavenging layers enabling lithium–sulfur batteries with high energy density and prolonged cycling life
Eftekhari et al. Cathode materials for lithium–sulfur batteries: a practical perspective
Zhuo et al. Facile synthesis of a Co 3 O 4–carbon nanotube composite and its superior performance as an anode material for Li-ion batteries
Zhang et al. 2D materials beyond graphene for high‐performance energy storage applications
Hwang et al. Mesoporous Ge/GeO2/carbon lithium-ion battery anodes with high capacity and high reversibility
Saravanan et al. Mesoporous TiO 2 with high packing density for superior lithium storage
Yang et al. Controlled synthesis of zinc cobalt sulfide nanostructures in oil phase and their potential applications in electrochemical energy storage
Pham et al. Facile synthesis of pyrite (FeS 2/C) nanoparticles as an electrode material for non-aqueous hybrid electrochemical capacitors
Chen et al. One-step synthesis of hollow porous Fe 3 O 4 beads–reduced graphene oxide composites with superior battery performance
Zhou et al. Colloidal WSe 2 nanocrystals as anodes for lithium-ion batteries
Ma et al. High electrical conductivity of 3D mesporous carbon nanocage as an efficient polysulfide buffer layer for high sulfur utilization in lithium-sulfur batteries
JP5675989B2 (ja) リチウム空気二次電池用正極材の製造方法及びリチウム空気二次電池
Liu et al. Efficient separators with fast Li-ion transfer and high polysulfide entrapment for superior lithium-sulfur batteries
KR20170003604A (ko) 리튬-황 배터리용 이작용성 세퍼레이터
Kong et al. Polydopamine-derived porous nanofibers as host of ZnFe 2 O 4 nanoneedles: towards high-performance anodes for lithium-ion batteries
JP2015531968A (ja) リチウム硫黄バッテリのための多孔性炭素内層
US20170092954A1 (en) Multi-layer carbon-sulfur cathodes
US11081688B2 (en) Silicon sealing for high performance battery anode materials
Jacob et al. Binary Cu/ZnO decorated graphene nanocomposites as an efficient anode for lithium ion batteries
Guan et al. Effects of amorphous and crystalline MoO 3 coatings on the Li-ion insertion behavior of a TiO 2 nanotube anode for lithium ion batteries
Kim et al. Bottom-up self-assembly of nano-netting cluster microspheres as high-performance lithium storage materials
Li et al. Carbon nanotubes coupled with metal ion diffusion layers stabilize oxide conversion reactions in high-voltage lithium-ion batteries
Zhao et al. Petal-like Mn-doped α-Ni (OH) 2 nanosheets for high-performance Li–S cathode material
Shaikh et al. A NiS 2/C composite as an innovative anode material for sodium-ion batteries: ex situ XANES and EXAFS studies to investigate the sodium storage mechanism

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20200424