CN111032786A - 水包油型乳液组合物、其制造方法及其用途 - Google Patents
水包油型乳液组合物、其制造方法及其用途 Download PDFInfo
- Publication number
- CN111032786A CN111032786A CN201880055402.8A CN201880055402A CN111032786A CN 111032786 A CN111032786 A CN 111032786A CN 201880055402 A CN201880055402 A CN 201880055402A CN 111032786 A CN111032786 A CN 111032786A
- Authority
- CN
- China
- Prior art keywords
- oil
- component
- emulsion composition
- water
- water emulsion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 158
- 239000007764 o/w emulsion Substances 0.000 title claims abstract description 88
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 26
- 239000002245 particle Substances 0.000 claims abstract description 150
- 239000000839 emulsion Substances 0.000 claims abstract description 115
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 88
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 57
- 239000002537 cosmetic Substances 0.000 claims abstract description 36
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 27
- 239000004094 surface-active agent Substances 0.000 claims abstract description 26
- 230000001804 emulsifying effect Effects 0.000 claims abstract description 19
- 239000000463 material Substances 0.000 claims abstract description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 26
- 238000003756 stirring Methods 0.000 claims description 26
- 238000000034 method Methods 0.000 claims description 24
- 238000004945 emulsification Methods 0.000 claims description 23
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims description 17
- 238000009826 distribution Methods 0.000 claims description 14
- 239000002994 raw material Substances 0.000 claims description 14
- 239000002736 nonionic surfactant Substances 0.000 claims description 12
- 239000011248 coating agent Substances 0.000 claims description 10
- 238000007720 emulsion polymerization reaction Methods 0.000 claims description 10
- 239000000835 fiber Substances 0.000 claims description 9
- 239000002563 ionic surfactant Substances 0.000 claims description 8
- 238000000576 coating method Methods 0.000 claims description 4
- 238000007561 laser diffraction method Methods 0.000 claims description 3
- 238000000790 scattering method Methods 0.000 claims description 3
- 239000012528 membrane Substances 0.000 claims description 2
- 239000011362 coarse particle Substances 0.000 abstract description 11
- -1 silylene group Chemical group 0.000 description 85
- 239000012071 phase Substances 0.000 description 44
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 34
- 235000014113 dietary fatty acids Nutrition 0.000 description 33
- 239000000194 fatty acid Substances 0.000 description 33
- 229930195729 fatty acid Natural products 0.000 description 33
- 239000003921 oil Substances 0.000 description 29
- 235000019198 oils Nutrition 0.000 description 29
- ONLRKTIYOMZEJM-UHFFFAOYSA-N n-methylmethanamine oxide Chemical compound C[NH+](C)[O-] ONLRKTIYOMZEJM-UHFFFAOYSA-N 0.000 description 20
- FFDGPVCHZBVARC-UHFFFAOYSA-N N,N-dimethylglycine Chemical compound CN(C)CC(O)=O FFDGPVCHZBVARC-UHFFFAOYSA-N 0.000 description 18
- 229960003237 betaine Drugs 0.000 description 18
- 150000004665 fatty acids Chemical class 0.000 description 18
- 229920000259 polyoxyethylene lauryl ether Polymers 0.000 description 14
- 125000000217 alkyl group Chemical group 0.000 description 13
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 12
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 12
- 239000000047 product Substances 0.000 description 12
- 125000005372 silanol group Chemical group 0.000 description 12
- 239000002280 amphoteric surfactant Substances 0.000 description 11
- 239000004205 dimethyl polysiloxane Substances 0.000 description 11
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 11
- 238000009472 formulation Methods 0.000 description 11
- 125000000962 organic group Chemical group 0.000 description 11
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 11
- 239000011734 sodium Substances 0.000 description 11
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 10
- 125000004432 carbon atom Chemical group C* 0.000 description 10
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 9
- 239000000654 additive Substances 0.000 description 9
- 239000007864 aqueous solution Substances 0.000 description 9
- 229920001577 copolymer Polymers 0.000 description 9
- 238000010790 dilution Methods 0.000 description 9
- 239000012895 dilution Substances 0.000 description 9
- 229910052708 sodium Inorganic materials 0.000 description 9
- 230000008901 benefit Effects 0.000 description 8
- 239000002518 antifoaming agent Substances 0.000 description 7
- 229910019142 PO4 Inorganic materials 0.000 description 6
- 239000008346 aqueous phase Substances 0.000 description 6
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 235000021317 phosphate Nutrition 0.000 description 6
- 238000003860 storage Methods 0.000 description 6
- 235000013162 Cocos nucifera Nutrition 0.000 description 5
- 244000060011 Cocos nucifera Species 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 239000003676 hair preparation Substances 0.000 description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 239000002685 polymerization catalyst Substances 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 229920002050 silicone resin Polymers 0.000 description 5
- 229920002379 silicone rubber Polymers 0.000 description 5
- TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- 235000021360 Myristic acid Nutrition 0.000 description 4
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 230000000996 additive effect Effects 0.000 description 4
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 4
- 150000008052 alkyl sulfonates Chemical class 0.000 description 4
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 4
- 239000010419 fine particle Substances 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 230000006872 improvement Effects 0.000 description 4
- 230000000379 polymerizing effect Effects 0.000 description 4
- 239000002453 shampoo Substances 0.000 description 4
- 238000010008 shearing Methods 0.000 description 4
- 239000013464 silicone adhesive Substances 0.000 description 4
- 229940117986 sulfobetaine Drugs 0.000 description 4
- 238000003786 synthesis reaction Methods 0.000 description 4
- 239000002562 thickening agent Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 3
- 239000005639 Lauric acid Substances 0.000 description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 235000021355 Stearic acid Nutrition 0.000 description 3
- 125000003545 alkoxy group Chemical group 0.000 description 3
- 239000003945 anionic surfactant Substances 0.000 description 3
- 230000000844 anti-bacterial effect Effects 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000003093 cationic surfactant Substances 0.000 description 3
- 239000002738 chelating agent Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 239000003995 emulsifying agent Substances 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- 125000001183 hydrocarbyl group Chemical group 0.000 description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 3
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 3
- IPCSVZSSVZVIGE-UHFFFAOYSA-N palmitic acid group Chemical group C(CCCCCCCCCCCCCCC)(=O)O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 3
- 238000005498 polishing Methods 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 229920002545 silicone oil Polymers 0.000 description 3
- 239000000600 sorbitol Substances 0.000 description 3
- 239000008117 stearic acid Substances 0.000 description 3
- 239000003760 tallow Substances 0.000 description 3
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
- GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 2
- ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 description 2
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
- 239000005711 Benzoic acid Substances 0.000 description 2
- WSWCOQWTEOXDQX-MQQKCMAXSA-N E-Sorbic acid Chemical compound C\C=C\C=C\C(O)=O WSWCOQWTEOXDQX-MQQKCMAXSA-N 0.000 description 2
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 102000011782 Keratins Human genes 0.000 description 2
- 108010076876 Keratins Proteins 0.000 description 2
- 239000005642 Oleic acid Substances 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000007983 Tris buffer Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000003973 alkyl amines Chemical class 0.000 description 2
- 150000005215 alkyl ethers Chemical class 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 235000001014 amino acid Nutrition 0.000 description 2
- 125000003277 amino group Chemical group 0.000 description 2
- 239000003242 anti bacterial agent Substances 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 229960000686 benzalkonium chloride Drugs 0.000 description 2
- 235000010233 benzoic acid Nutrition 0.000 description 2
- CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical compound [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000003240 coconut oil Substances 0.000 description 2
- 235000019864 coconut oil Nutrition 0.000 description 2
- 238000006482 condensation reaction Methods 0.000 description 2
- 239000006071 cream Substances 0.000 description 2
- 239000000412 dendrimer Substances 0.000 description 2
- 229920000736 dendritic polymer Polymers 0.000 description 2
- FVCOIAYSJZGECG-UHFFFAOYSA-N diethylhydroxylamine Chemical compound CCN(O)CC FVCOIAYSJZGECG-UHFFFAOYSA-N 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical compound CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 description 2
- 125000003700 epoxy group Chemical group 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 239000003365 glass fiber Substances 0.000 description 2
- 125000005843 halogen group Chemical group 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- UTTVXKGNTWZECK-UHFFFAOYSA-N n,n-dimethyloctadecan-1-amine oxide Chemical compound CCCCCCCCCCCCCCCCCC[N+](C)(C)[O-] UTTVXKGNTWZECK-UHFFFAOYSA-N 0.000 description 2
- 239000003002 pH adjusting agent Substances 0.000 description 2
- 239000003346 palm kernel oil Substances 0.000 description 2
- 235000019865 palm kernel oil Nutrition 0.000 description 2
- 230000002688 persistence Effects 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 230000002335 preservative effect Effects 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 125000004469 siloxy group Chemical group [SiH3]O* 0.000 description 2
- 229940037001 sodium edetate Drugs 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 150000003871 sulfonates Chemical class 0.000 description 2
- 235000015961 tonic Nutrition 0.000 description 2
- 230000001256 tonic effect Effects 0.000 description 2
- 125000005389 trialkylsiloxy group Chemical group 0.000 description 2
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N 1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylic acid Chemical class C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- GBXRUYNQDDTQQS-UHFFFAOYSA-N 1-O-dodecylglycerol Chemical compound CCCCCCCCCCCCOCC(O)CO GBXRUYNQDDTQQS-UHFFFAOYSA-N 0.000 description 1
- 229940114072 12-hydroxystearic acid Drugs 0.000 description 1
- SPSPIUSUWPLVKD-UHFFFAOYSA-N 2,3-dibutyl-6-methylphenol Chemical compound CCCCC1=CC=C(C)C(O)=C1CCCC SPSPIUSUWPLVKD-UHFFFAOYSA-N 0.000 description 1
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 description 1
- XPALGXXLALUMLE-UHFFFAOYSA-N 2-(dimethylamino)tetradecanoic acid Chemical compound CCCCCCCCCCCCC(N(C)C)C(O)=O XPALGXXLALUMLE-UHFFFAOYSA-N 0.000 description 1
- KKMIHKCGXQMFEU-UHFFFAOYSA-N 2-[dimethyl(tetradecyl)azaniumyl]acetate Chemical compound CCCCCCCCCCCCCC[N+](C)(C)CC([O-])=O KKMIHKCGXQMFEU-UHFFFAOYSA-N 0.000 description 1
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 description 1
- SYSFRXFRWRDPIJ-UHFFFAOYSA-N 2-hexylbenzenesulfonic acid Chemical compound CCCCCCC1=CC=CC=C1S(O)(=O)=O SYSFRXFRWRDPIJ-UHFFFAOYSA-N 0.000 description 1
- QWHHBVWZZLQUIH-UHFFFAOYSA-N 2-octylbenzenesulfonic acid Chemical compound CCCCCCCCC1=CC=CC=C1S(O)(=O)=O QWHHBVWZZLQUIH-UHFFFAOYSA-N 0.000 description 1
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 1
- SHQRLYGZJPBYGJ-UHFFFAOYSA-N 3-decoxypropane-1,2-diol Chemical compound CCCCCCCCCCOCC(O)CO SHQRLYGZJPBYGJ-UHFFFAOYSA-N 0.000 description 1
- LUCBXPCLWJFUFS-UHFFFAOYSA-N 3-heptoxypropane-1,2-diol Chemical compound CCCCCCCOCC(O)CO LUCBXPCLWJFUFS-UHFFFAOYSA-N 0.000 description 1
- YMTZCQOAGFRQHV-UHFFFAOYSA-N 3-methyl-4,5-dihydro-1,2-thiazole Chemical compound CC1=NSCC1 YMTZCQOAGFRQHV-UHFFFAOYSA-N 0.000 description 1
- GUPXYSSGJWIURR-UHFFFAOYSA-N 3-octoxypropane-1,2-diol Chemical compound CCCCCCCCOCC(O)CO GUPXYSSGJWIURR-UHFFFAOYSA-N 0.000 description 1
- MOMKYJPSVWEWPM-UHFFFAOYSA-N 4-(chloromethyl)-2-(4-methylphenyl)-1,3-thiazole Chemical compound C1=CC(C)=CC=C1C1=NC(CCl)=CS1 MOMKYJPSVWEWPM-UHFFFAOYSA-N 0.000 description 1
- CFKMVGJGLGKFKI-UHFFFAOYSA-N 4-chloro-m-cresol Chemical compound CC1=CC(O)=CC=C1Cl CFKMVGJGLGKFKI-UHFFFAOYSA-N 0.000 description 1
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 1
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- JMHWNJGXUIJPKG-UHFFFAOYSA-N CC(=O)O[SiH](CC=C)OC(C)=O Chemical compound CC(=O)O[SiH](CC=C)OC(C)=O JMHWNJGXUIJPKG-UHFFFAOYSA-N 0.000 description 1
- OLJYCDMIXWARHP-KVVVOXFISA-M CCCCCCCC/C=C\CCCCCCCC(N(CCN(CC([O-])=O)CC(O)=O)CCO)=O.[Na+] Chemical compound CCCCCCCC/C=C\CCCCCCCC(N(CCN(CC([O-])=O)CC(O)=O)CCO)=O.[Na+] OLJYCDMIXWARHP-KVVVOXFISA-M 0.000 description 1
- GARIJODUWKVURG-UHFFFAOYSA-M CCCCCCCCCCCC(N(CCN(CC([O-])=O)CC(O)=O)CCO)=O.[Na+] Chemical compound CCCCCCCCCCCC(N(CCN(CC([O-])=O)CC(O)=O)CCO)=O.[Na+] GARIJODUWKVURG-UHFFFAOYSA-M 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical compound NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 1
- GHXZTYHSJHQHIJ-UHFFFAOYSA-N Chlorhexidine Chemical compound C=1C=C(Cl)C=CC=1NC(N)=NC(N)=NCCCCCCN=C(N)N=C(N)NC1=CC=C(Cl)C=C1 GHXZTYHSJHQHIJ-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- IMQLKJBTEOYOSI-GPIVLXJGSA-N Inositol-hexakisphosphate Chemical compound OP(O)(=O)O[C@H]1[C@H](OP(O)(O)=O)[C@@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@@H]1OP(O)(O)=O IMQLKJBTEOYOSI-GPIVLXJGSA-N 0.000 description 1
- QNAYBMKLOCPYGJ-REOHCLBHSA-N L-alanine Chemical compound C[C@H](N)C(O)=O QNAYBMKLOCPYGJ-REOHCLBHSA-N 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- YYNQEQZCAKHKSF-UHFFFAOYSA-M NCCNC(C([O-])=O)C(O)=O.[Na+] Chemical compound NCCNC(C([O-])=O)C(O)=O.[Na+] YYNQEQZCAKHKSF-UHFFFAOYSA-M 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- IMQLKJBTEOYOSI-UHFFFAOYSA-N Phytic acid Natural products OP(O)(=O)OC1C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C1OP(O)(O)=O IMQLKJBTEOYOSI-UHFFFAOYSA-N 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 108010039491 Ricin Proteins 0.000 description 1
- 229920002385 Sodium hyaluronate Polymers 0.000 description 1
- BCKXLBQYZLBQEK-KVVVOXFISA-M Sodium oleate Chemical compound [Na+].CCCCCCCC\C=C/CCCCCCCC([O-])=O BCKXLBQYZLBQEK-KVVVOXFISA-M 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- XEFQLINVKFYRCS-UHFFFAOYSA-N Triclosan Chemical compound OC1=CC(Cl)=CC=C1OC1=CC=C(Cl)C=C1Cl XEFQLINVKFYRCS-UHFFFAOYSA-N 0.000 description 1
- 230000006750 UV protection Effects 0.000 description 1
- 229930003427 Vitamin E Natural products 0.000 description 1
- JNGWKQJZIUZUPR-UHFFFAOYSA-N [3-(dodecanoylamino)propyl](hydroxy)dimethylammonium Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)[O-] JNGWKQJZIUZUPR-UHFFFAOYSA-N 0.000 description 1
- IHCGOCAGSBOMNM-UHFFFAOYSA-L [Na+].[Na+].C(=O)([O-])C(NCCN)C(=O)[O-] Chemical compound [Na+].[Na+].C(=O)([O-])C(NCCN)C(=O)[O-] IHCGOCAGSBOMNM-UHFFFAOYSA-L 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 235000004279 alanine Nutrition 0.000 description 1
- 239000000783 alginic acid Substances 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 229960001126 alginic acid Drugs 0.000 description 1
- 150000004781 alginic acids Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 125000005037 alkyl phenyl group Chemical group 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 description 1
- 125000004103 aminoalkyl group Chemical group 0.000 description 1
- 235000012538 ammonium bicarbonate Nutrition 0.000 description 1
- 239000001099 ammonium carbonate Substances 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 229940035676 analgesics Drugs 0.000 description 1
- 239000000730 antalgic agent Substances 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 229940121363 anti-inflammatory agent Drugs 0.000 description 1
- 239000002260 anti-inflammatory agent Substances 0.000 description 1
- 230000001166 anti-perspirative effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 239000003213 antiperspirant Substances 0.000 description 1
- 150000001483 arginine derivatives Chemical class 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 239000000022 bacteriostatic agent Substances 0.000 description 1
- 238000003287 bathing Methods 0.000 description 1
- YSJGOMATDFSEED-UHFFFAOYSA-M behentrimonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCCCCC[N+](C)(C)C YSJGOMATDFSEED-UHFFFAOYSA-M 0.000 description 1
- UREZNYTWGJKWBI-UHFFFAOYSA-M benzethonium chloride Chemical compound [Cl-].C1=CC(C(C)(C)CC(C)(C)C)=CC=C1OCCOCC[N+](C)(C)CC1=CC=CC=C1 UREZNYTWGJKWBI-UHFFFAOYSA-M 0.000 description 1
- 229960001950 benzethonium chloride Drugs 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- WGQKYBSKWIADBV-UHFFFAOYSA-N benzylamine Chemical class NCC1=CC=CC=C1 WGQKYBSKWIADBV-UHFFFAOYSA-N 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 235000010338 boric acid Nutrition 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- CZBZUDVBLSSABA-UHFFFAOYSA-N butylated hydroxyanisole Chemical compound COC1=CC=C(O)C(C(C)(C)C)=C1.COC1=CC=C(O)C=C1C(C)(C)C CZBZUDVBLSSABA-UHFFFAOYSA-N 0.000 description 1
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 229960001927 cetylpyridinium chloride Drugs 0.000 description 1
- YMKDRGPMQRFJGP-UHFFFAOYSA-M cetylpyridinium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+]1=CC=CC=C1 YMKDRGPMQRFJGP-UHFFFAOYSA-M 0.000 description 1
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229960003260 chlorhexidine Drugs 0.000 description 1
- 125000004218 chloromethyl group Chemical group [H]C([H])(Cl)* 0.000 description 1
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 description 1
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical class C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 1
- FHRIKCGRMGOMMT-XXAVUKJNSA-L disodium;2-[carboxylatomethyl-[2-[2-hydroxyethyl-[(z)-octadec-9-enoyl]amino]ethyl]amino]acetate Chemical compound [Na+].[Na+].CCCCCCCC\C=C/CCCCCCCC(=O)N(CCO)CCN(CC([O-])=O)CC([O-])=O FHRIKCGRMGOMMT-XXAVUKJNSA-L 0.000 description 1
- RQRIMOACIZTFCP-UHFFFAOYSA-L disodium;2-[carboxylatomethyl-[2-[dodecanoyl(2-hydroxyethyl)amino]ethyl]amino]acetate Chemical compound [Na+].[Na+].CCCCCCCCCCCC(=O)N(CCO)CCN(CC([O-])=O)CC([O-])=O RQRIMOACIZTFCP-UHFFFAOYSA-L 0.000 description 1
- 239000002612 dispersion medium Substances 0.000 description 1
- 239000004664 distearyldimethylammonium chloride (DHTDMAC) Substances 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- CDIPRYKTRRRSEM-UHFFFAOYSA-M docosyl(trimethyl)azanium;bromide Chemical compound [Br-].CCCCCCCCCCCCCCCCCCCCCC[N+](C)(C)C CDIPRYKTRRRSEM-UHFFFAOYSA-M 0.000 description 1
- LXLVSAYIKBYEFM-UHFFFAOYSA-N dodecyl hydroxy hydrogen phosphate Chemical compound CCCCCCCCCCCCOP(O)(=O)OO LXLVSAYIKBYEFM-UHFFFAOYSA-N 0.000 description 1
- DDXLVDQZPFLQMZ-UHFFFAOYSA-M dodecyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)C DDXLVDQZPFLQMZ-UHFFFAOYSA-M 0.000 description 1
- JVQOASIPRRGMOS-UHFFFAOYSA-M dodecyl(trimethyl)azanium;hydroxide Chemical compound [OH-].CCCCCCCCCCCC[N+](C)(C)C JVQOASIPRRGMOS-UHFFFAOYSA-M 0.000 description 1
- 229940060296 dodecylbenzenesulfonic acid Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000010556 emulsion polymerization method Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- SFNALCNOMXIBKG-UHFFFAOYSA-N ethylene glycol monododecyl ether Chemical compound CCCCCCCCCCCCOCCO SFNALCNOMXIBKG-UHFFFAOYSA-N 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 230000003779 hair growth Effects 0.000 description 1
- ACGUYXCXAPNIKK-UHFFFAOYSA-N hexachlorophene Chemical compound OC1=C(Cl)C=C(Cl)C(Cl)=C1CC1=C(O)C(Cl)=CC(Cl)=C1Cl ACGUYXCXAPNIKK-UHFFFAOYSA-N 0.000 description 1
- 229960004068 hexachlorophene Drugs 0.000 description 1
- 238000006459 hydrosilylation reaction Methods 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 1
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 1
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 1
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N malic acid Chemical compound OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- ONHFWHCMZAJCFB-UHFFFAOYSA-N myristamine oxide Chemical compound CCCCCCCCCCCCCC[N+](C)(C)[O-] ONHFWHCMZAJCFB-UHFFFAOYSA-N 0.000 description 1
- NNSWOABHNWRKDR-UHFFFAOYSA-N n',n'-diethylethane-1,2-diamine;octadecanoic acid Chemical compound CCN(CC)CCN.CCCCCCCCCCCCCCCCCC(O)=O NNSWOABHNWRKDR-UHFFFAOYSA-N 0.000 description 1
- RVRFYZGKUZFYAH-UHFFFAOYSA-N n',n'-dimethylpropane-1,3-diamine;octadecanoic acid Chemical compound CN(C)CCCN.CCCCCCCCCCCCCCCCCC(O)=O RVRFYZGKUZFYAH-UHFFFAOYSA-N 0.000 description 1
- GCYGTRJKQWZIPM-UHFFFAOYSA-N n,n,16-trimethylheptadecan-1-amine oxide Chemical compound CC(C)CCCCCCCCCCCCCCC[N+](C)(C)[O-] GCYGTRJKQWZIPM-UHFFFAOYSA-N 0.000 description 1
- DZJFABDVWIPEIM-UHFFFAOYSA-N n,n-bis(2-hydroxyethyl)dodecan-1-amine oxide Chemical compound CCCCCCCCCCCC[N+]([O-])(CCO)CCO DZJFABDVWIPEIM-UHFFFAOYSA-N 0.000 description 1
- BACGZXMASLQEQT-UHFFFAOYSA-N n,n-diethyldecan-1-amine oxide Chemical compound CCCCCCCCCC[N+]([O-])(CC)CC BACGZXMASLQEQT-UHFFFAOYSA-N 0.000 description 1
- IBOBFGGLRNWLIL-UHFFFAOYSA-N n,n-dimethylhexadecan-1-amine oxide Chemical compound CCCCCCCCCCCCCCCC[N+](C)(C)[O-] IBOBFGGLRNWLIL-UHFFFAOYSA-N 0.000 description 1
- RSVIRMFSJVHWJV-UHFFFAOYSA-N n,n-dimethyloctan-1-amine oxide Chemical compound CCCCCCCC[N+](C)(C)[O-] RSVIRMFSJVHWJV-UHFFFAOYSA-N 0.000 description 1
- FLZHCODKZSZHHW-UHFFFAOYSA-N n,n-dipropyltetradecan-1-amine oxide Chemical compound CCCCCCCCCCCCCC[N+]([O-])(CCC)CCC FLZHCODKZSZHHW-UHFFFAOYSA-N 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- WNGXRJQKUYDBDP-UHFFFAOYSA-N n-ethyl-n-methylhexadecan-1-amine oxide Chemical compound CCCCCCCCCCCCCCCC[N+](C)([O-])CC WNGXRJQKUYDBDP-UHFFFAOYSA-N 0.000 description 1
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229940070805 p-chloro-m-cresol Drugs 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 125000005010 perfluoroalkyl group Chemical group 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 238000000614 phase inversion technique Methods 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 229960005323 phenoxyethanol Drugs 0.000 description 1
- 235000011007 phosphoric acid Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 108091008695 photoreceptors Proteins 0.000 description 1
- 239000000467 phytic acid Substances 0.000 description 1
- 235000002949 phytic acid Nutrition 0.000 description 1
- 229940068041 phytic acid Drugs 0.000 description 1
- 229920000223 polyglycerol Polymers 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 235000011118 potassium hydroxide Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical compound CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 description 1
- 229960003656 ricinoleic acid Drugs 0.000 description 1
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- BTURAGWYSMTVOW-UHFFFAOYSA-M sodium dodecanoate Chemical compound [Na+].CCCCCCCCCCCC([O-])=O BTURAGWYSMTVOW-UHFFFAOYSA-M 0.000 description 1
- 229940010747 sodium hyaluronate Drugs 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 229940082004 sodium laurate Drugs 0.000 description 1
- 235000019983 sodium metaphosphate Nutrition 0.000 description 1
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 1
- 235000019830 sodium polyphosphate Nutrition 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- YWIVKILSMZOHHF-QJZPQSOGSA-N sodium;(2s,3s,4s,5r,6r)-6-[(2s,3r,4r,5s,6r)-3-acetamido-2-[(2s,3s,4r,5r,6r)-6-[(2r,3r,4r,5s,6r)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2- Chemical compound [Na+].CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 YWIVKILSMZOHHF-QJZPQSOGSA-N 0.000 description 1
- UNZSHUCNBUBSGW-IFNWOZJISA-M sodium;(9z,12z,15z)-octadeca-9,12,15-trienoate Chemical compound [Na+].CC\C=C/C\C=C/C\C=C/CCCCCCCC([O-])=O UNZSHUCNBUBSGW-IFNWOZJISA-M 0.000 description 1
- BCQBLXIGCYYCSJ-UHFFFAOYSA-M sodium;2-(4,5-dihydroimidazol-1-yl)-4-hydroxybutanoate Chemical compound [Na+].OCCC(C([O-])=O)N1CCN=C1 BCQBLXIGCYYCSJ-UHFFFAOYSA-M 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- SFVFIFLLYFPGHH-UHFFFAOYSA-M stearalkonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 SFVFIFLLYFPGHH-UHFFFAOYSA-M 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 239000003784 tall oil Substances 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 229960000716 tonics Drugs 0.000 description 1
- ICUTUKXCWQYESQ-UHFFFAOYSA-N triclocarban Chemical compound C1=CC(Cl)=CC=C1NC(=O)NC1=CC=C(Cl)C(Cl)=C1 ICUTUKXCWQYESQ-UHFFFAOYSA-N 0.000 description 1
- 229960001325 triclocarban Drugs 0.000 description 1
- 229960003500 triclosan Drugs 0.000 description 1
- SZEMGTQCPRNXEG-UHFFFAOYSA-M trimethyl(octadecyl)azanium;bromide Chemical compound [Br-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C SZEMGTQCPRNXEG-UHFFFAOYSA-M 0.000 description 1
- STYCVOUVPXOARC-UHFFFAOYSA-M trimethyl(octyl)azanium;hydroxide Chemical compound [OH-].CCCCCCCC[N+](C)(C)C STYCVOUVPXOARC-UHFFFAOYSA-M 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 235000019165 vitamin E Nutrition 0.000 description 1
- 229940046009 vitamin E Drugs 0.000 description 1
- 239000011709 vitamin E Substances 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 239000002349 well water Substances 0.000 description 1
- 235000020681 well water Nutrition 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
- A61K8/062—Oil-in-water emulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/40—Mixing liquids with liquids; Emulsifying
- B01F23/41—Emulsifying
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
- B01F27/05—Stirrers
- B01F27/11—Stirrers characterised by the configuration of the stirrers
- B01F27/114—Helically shaped stirrers, i.e. stirrers comprising a helically shaped band or helically shaped band sections
- B01F27/1145—Helically shaped stirrers, i.e. stirrers comprising a helically shaped band or helically shaped band sections ribbon shaped with an open space between the helical ribbon flight and the rotating axis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
- B01F27/80—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis
- B01F27/808—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis with stirrers driven from the bottom of the receptacle
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
- B01F27/80—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis
- B01F27/84—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis with two or more stirrers rotating at different speeds or in opposite directions about the same axis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
- B01F27/80—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis
- B01F27/90—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis with paddles or arms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
- C08J3/03—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/022—Emulsions, e.g. oil in water
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/21—Emulsions characterized by droplet sizes below 1 micron
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
- B01F27/80—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis
- B01F27/92—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis with helices or screws
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
- C08G77/16—Polysiloxanes containing silicon bound to oxygen-containing groups to hydroxyl groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2383/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
- C08J2383/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
- C08J3/03—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
- C08J3/05—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media from solid polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
- C08J3/03—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
- C08J3/07—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media from polymer solutions
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Veterinary Medicine (AREA)
- Public Health (AREA)
- Engineering & Computer Science (AREA)
- Dispersion Chemistry (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Wood Science & Technology (AREA)
- Materials Engineering (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Textile Engineering (AREA)
- Dermatology (AREA)
- Emergency Medicine (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Cosmetics (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
本发明的课题在于提供一种水包油型乳液组合物,其是将高聚合度的有机聚硅氧烷直接乳化而成,实质上不包含粗大粒子,平均粒径小。此外,本发明提供一种使用垂直式分批混合机的所述水包油型乳液组合物的制造方法、及含有该组合物的化妆料原料等用途。本发明是一种水包油型乳液组合物及其用途,该水包油型乳液组合物是乳液,包含(A)整体粘度为1,000,000mPa·s以上或具有可塑度的有机聚硅氧烷或其混合物、(B)表面活性剂、及(C)水,且成分(A)利用成分(B)在水中乳化;乳液粒子的平均粒径处于0.1~7.5μm的范围,具有平均粒径的10倍以上粒径的乳液粒子的含量小于5.0体积%。
Description
技术领域
本发明涉及一种以往方法难以实现的水包油型乳液组合物,其是将高聚合度的有机聚硅氧烷直接乳化而成,实质上不包含粗大粒子,平均粒径小。此外,本发明涉及一种使用垂直式分批混合机的所述水包油型乳液组合物的制造方法、及含有该组合物的化妆料原料、化妆料、皮膜形成剂、涂覆剂、纤维处理剂等用途。
背景技术
有机聚硅氧烷的乳液作为润滑剂、离型剂、纤维处理剂、玻璃纤维处理剂、化妆用基剂、抛光剂、涂料添加剂等广泛用于产业界。尤其是平均粒径小、且粒径分布的幅度窄、不包含粗大粒子的乳液通常有难以产生伴随粒子合一的乳液的相分离,操作作业性及保存稳定性优异的倾向。此外,通过直接乳化法而获得的乳液因为能够直接利用对乳化的有机聚硅氧烷期待的特性,且不经由聚合反应等,所以从可设计实质上不包含低分子量硅氧烷低聚物的乳液粒子的方面来说有时被良好地选择。
另一方面,高聚合度的有机聚硅氧烷(高粘度硅酮油、难以利用旋转粘度计等进行粘度测定且具有可塑度的硅酮胶类、或其混合物)的皮膜形成性、对毛发、纤维等的附着性及处理效率优异,通过用作涂覆剂或涂料添加剂,皮膜的平坦性及平滑性的改善效果等优异,但存在难以直接乳化的问题,提出多种乳化方法(例如专利文献1~2)。
然而,在专利文献1及专利文献2所提出的方法中,只能实现平均粒径小于9μm的硅酮胶的水包油型乳液组合物。例如,专利文献1的实施例中仅公开了具有9.9μm的平均粒径的水包油型乳液组合物,专利文献2的实施例1中仅公开了具有23.4μm或27.9μm的平均粒径的水包油型乳液组合物,并且因为包含许多粒径远远大于平均粒径的粗大粒子,所以有乳液粒子的稳定性差的问题。另外,在专利文献2(实施例2)中,提出通过将高聚合度的硅酮树脂分散于二甲苯溶剂中进行乳化以实现小粒径的乳液,但在该方法中,因为构成乳液粒子的油相的表观粘度大幅度降低,根据情况无法去除用于稀释的溶剂,所以有时无法通过将高聚合度的有机聚硅氧烷添加到乳液中来实现原本期待的技术效果,除此以外,有时无法应用于化妆料原料等用途。
与此相对,专利文献3等中提出一种乳化聚合型水包油型乳液组合物,其通过使反应性的有机聚硅氧烷乳化聚合,从而包含含有高聚合度的有机聚硅氧烷且平均粒径低于1.0μm的乳液粒子。然而,在这些使用乳化聚合反应的水包油型乳液组合物中,因为需要使用聚合反应性的表面活性剂,并且伴随乳化聚合反应而副产的低分子量且挥发性的硅氧烷低聚物大量残存于体系中,所以有可应用的用途及可设计的组成受到限定的问题。
如上所述,仍未实现将小粒径且不包含粗大粒子的高聚合度的有机聚硅氧烷利用直接乳化法而获得,所以不会产生副产挥发性硅氧烷低聚物等问题的水包油型乳液组合物及其优选的制造方法。
另外,例如在专利文献4、5等中公开了用于使油剂直接乳化的垂直式分批混合机,但并未记载或暗示有关高聚合度有机聚硅氧烷的直接乳化法的优点。
背景技术文献
专利文献
专利文献1:日本专利特开平09-124797号公报
专利文献2:日本专利特表2006-528714号公报
专利文献3:日本专利特表2012-526893号公报
专利文献4:日本专利特开2001-239141号公报
专利文献5:日本专利特开2006-263728号公报
发明内容
[发明要解决的问题]
本发明是为了解决所述课题而完成的,其目的在于提供一种水包油型乳液组合物,其是将高聚合度的有机聚硅氧烷直接乳化而成,实质上不包含粗大粒子,平均粒径小。进而,本发明的目的在于提供一种该水包油型乳液组合物的用途及工业上优选的制造方法。
[解决问题的技术手段]
本发明者等人对所述课题进行了锐意研究,结果实现了本发明。即,本发明的目的之一由如下直接乳化型水包油型乳液组合物实现,其特征在于包含高聚合度的有机聚硅氧烷、表面活性剂及水,平均粒径处于0.1~7.5μm的范围,乳液的粒度分布中具有平均粒径的10倍以上粒径的乳液粒子所占的含量小于5.0体积%,构成乳液粒子的油相的25℃下的表观粘度为1,000,000mPa·s以上或具有可塑度。此外,所述课题由含有该水包油型乳液组合物的化妆料原料、化妆料、皮膜形成剂、涂覆剂、纤维处理剂等用途、以及特征在于优选使用垂直式分批混合机将有机聚硅氧烷于水中机械性地乳化而成的该水包油型乳液组合物的制造方法实现。
即,本发明是
“[1]一种水包油型乳液组合物,其特征在于,其是乳液,包含:(A)25℃下的整体粘度为1,000,000mPa·s以上或具有可塑度的有机聚硅氧烷或其混合物100质量份、
(B)至少1种以上的表面活性剂0.1~30质量份、及
(C)水100~2000质量份,且
成分(A)利用成分(B)在水中乳化;
利用激光衍射/散射法测定的乳液粒子的平均粒径处于0.1~7.5μm的范围,
乳液的粒度分布中具有平均粒径的10倍以上粒径的乳液粒子所占的含量小于5.0体积%,
构成乳液粒子的油相(成分(A))的25℃下的表观粘度为1,000,000mPa·s以上或具有可塑度。
[2]根据[1]所记载的水包油型乳液组合物,其中
成分(A)选自:
(A1)25℃下的1,000,000mPa·s以上或具有可塑度的有机聚硅氧烷、或
(A2)25℃下的整体粘度为1,000,000mPa·s以上或具有可塑度的有机聚硅氧烷混合物。
[3]根据[1]或[2]所记载的水包油型乳液组合物,其中成分(A)为25℃下的整体粘度为2,500,000mPa·s以上或具有可塑度的有机聚硅氧烷或其混合物。
[4]根据[1]至[3]中任一项所记载的水包油型乳液组合物,其中构成乳液组合物的油相中的硅氧烷聚合度为3~6的硅氧烷低聚物的含量的和小于1.0质量%。
[5]根据[1]至[4]中任一项所记载的水包油型乳液组合物,其中成分(B)包含(B1)非离子性表面活性剂及(B2)离子性表面活性剂,成分(B1)与成分(B2)的质量比为100∶0~50∶50,且
成分(B)的使用量相对于成分(A)100质量份为0.5~15质量份的范围。
[6]一种化妆料原料,其含有根据[1]至[5]中任一项所记载的水包油型乳液组合物。
[7]一种化妆料,其含有根据[1]至[5]中任一项所记载的水包油型乳液组合物。
[8]一种皮膜形成剂,其含有根据[1]至[5]中任一项所记载的水包油型乳液组合物。
[9]一种涂料或涂覆剂组合物,其含有根据[1]至[5]中任一项所记载的水包油型乳液组合物。
[10]一种纤维处理剂,其含有根据[1]至[5]中任一项所记载的水包油型乳液组合物。
[11]一种根据[1]至[5]中任一项所记载的水包油型乳液组合物的制造方法,其特征在于:使用(B)至少1种以上的表面活性剂,利用垂直式分批混合机,将(A)25℃下的整体粘度为1,000,000mPa·s以上或具有可塑度的有机聚硅氧烷或其混合物在(C)水中机械性地乳化而成。
[12]根据[11]所记载的水包油型乳液组合物的制造方法,其中所述垂直式分批混合机为同心多轴型垂直式分批混合机,该同心多轴型垂直式分批混合机的特征在于:具有配置于同一轴芯上的多个旋转轴,具备配置于至少1个旋转轴上的带状搅拌叶及配置于与所述旋转轴不同的旋转轴上的非带状搅拌叶。
[13]根据[11]或[12]所记载的水包油型乳液组合物的制造方法,其以是利用垂直式分批混合机所进行的直接乳化法为特征,不伴随乳化聚合反应。”。
[发明的效果]
根据本发明,能够提供一种水包油型乳液组合物,其是将高聚合度的有机聚硅氧烷直接乳化而成,实质上不包含粗大粒子,平均粒径小。进而,根据本发明,能够提供包含该水包油型乳液组合物的化妆料原料、化妆料、皮膜形成剂、涂覆剂、纤维处理剂等用途。进而,根据本发明,目的在于对所述水包油型乳液组合物提供工业上优选的制造方法。
附图说明
图1是可用于本发明的垂直式分批混合机的纵剖面图。
具体实施方式
[水包油型乳液组合物]
首先,对本发明的水包油型乳液组合物进行说明。
[(A)有机聚硅氧烷或其混合物]
成分(A)为构成本乳液的乳液粒子的油相成分,且为25℃下的整体粘度为1,000,000mPa·s以上或具有可塑度的有机聚硅氧烷或其混合物。即,(A)成分是生橡胶状的有机聚硅氧烷,于25℃下具有1,000,000mPa·s以上的粘度,或者能测定依据由JIS K6249规定的方法测得的可塑度(在25℃下对4.2g的球状试样施加1kgf的负载3分钟时的值,本发明中简称为“可塑度”),优选可塑度处于50~200的范围,进而优选处于80~180的范围。另外,有时将所述能测定可塑度的生橡胶状的有机聚硅氧烷称为“硅酮胶”。另外,具有可塑度的有机聚硅氧烷一般难以利用旋转粘度计等进行粘度测定,但在25℃下假设测定粘度的情况下,有呈现5,000,000mPa·s以上的高粘度的趋势。
作为成分(A)的有机聚硅氧烷或其混合物除其整体粘度以外没有特别限制,也可为包含硅酮树脂(包括硅酮树脂微粒)或硅酮弹性体(包括硅酮弹性体微粒)的有机聚硅氧烷混合物。此外,在不损害本发明的目的的范围内,本发明所使用的有机聚硅氧烷中,可视需要含有二氧化硅微粒、增稠剂等添加剂,也可为含有有机聚硅氧烷的高粘度的硅酮复合物(包括消泡剂复合物)。一般来说,消泡持续性取决于消泡剂的粘度,越为高粘度且高粘性的消泡剂,持续性越高。认为这些起因于在发泡体系中消泡剂粒子的大小难以发生变化。另一方面,为了表现出消泡性,需要使消泡剂广泛分散于发泡体系中,但难以将这些高粘度、高粘性的消泡剂微细化至最佳粒径加以分散。然而,本发明的水包油型乳液组合物能够形成使用高粘度的消泡剂复合物的稳定且微细的乳液,可期待消泡性能的改善及持续性。但成分(A)不可包含超过本发明的乳液粒子的平均粒径的上限的二氧化硅粒子等添加剂、硅酮树脂粒子或硅酮弹性体粒子。
作为成分(A)的有机聚硅氧烷或其混合物没有特别限定,可在硅氧烷单元间具有二价有机基(包括硅烷撑基、硅苯撑基、或聚氧烷撑基等),也可包含由二价有机基连结的含有聚硅氧烷结构的有机基、含有三(三烷基硅烷氧基)硅烷氧基的有机基、含有碳硅氧烷树枝状聚合物结构的有机基等。进而,作为成分(A)的有机聚硅氧烷或其混合物可具有选自羟基、烷氧基、一价烃基及与一价烃基键结的氢原子的一部分任意地被取代为氨基、环氧基、羧基、卤素原子等而成的有机改性基的官能基,且是优选的。
作为成分(A)的有机聚硅氧烷或其混合物优选可列举由如下通式所示的化合物。
RaSiO(4-a)/2
其中,式中,R为选自羟基、碳原子数1~3的烷氧基、及经取代或未经取代的一价烃基的基,可例示:羟基;甲氧基、乙氧基、丙氧基等烷氧基;甲基、乙基、丙基等碳原子数1~30的烷基;苯基、甲苯基等碳原子数6~30的芳基;苄基等芳烷基、这些基的与碳原子键结的氢原子的一部分或全部被取代为卤素原子而成的氯甲基、3,3,3-三氟丙基等卤化烷基等。此外,a为1.9~2.1的数值。另外,a处于所述范围意味着成分(A)为可具有支链但实质上以包含二有机硅烷氧基单元(D单元)的直链状结构为主的有机聚硅氧烷,其分子结构可列举直链状、一部分分枝的支链状、网状等。这些当中,优选使用直链状的有机聚硅氧烷。此外,其硅氧烷聚合度优选大致3000~20000。
作为该有机聚硅氧烷,例如可列举:两末端经三甲基硅烷氧基封阻的二甲基聚硅氧烷、两末端经硅烷醇基封阻的二甲基聚硅氧烷、两末端经三甲基硅氧烷基封阻的二甲基硅氧烷-苯基甲基硅氧烷共聚物、两末端经硅烷醇基封阻的二甲基硅氧烷-苯基甲基硅氧烷共聚物、两末端经三甲基硅烷氧基封阻的二甲基硅氧烷-二苯基硅氧烷共聚物、两末端经硅烷醇基封阻的二甲基硅氧烷-二苯基硅氧烷共聚物、两末端经三甲基硅烷氧基封阻的二甲基硅氧烷-甲基(3,3,3-三氟丙基)硅氧烷共聚物、两末端经硅烷醇基封阻的二甲基硅氧烷-甲基(3,3,3-三氟丙基)硅氧烷共聚物等。另外,这些有机聚硅氧烷的甲基的一部分可为经碳数为6~20的烷基、碳数3~15的氨基烷基、碳数3~15的全氟烷基、碳数3~15的含有季铵盐基的烷基、环氧基、羧基、与硅原子由二价有机基连结的含有聚硅氧烷结构的有机基、与硅原子由二价有机基连结的含有三(三烷基硅烷氧基)硅烷氧基的有机基、与硅原子由二价有机基连结的含有碳硅氧烷树枝状聚合物结构的有机基等取代的结构,尤其是在用于毛发护理用途的水包油型乳液方面,从对毛发的附着性等观点来看,也可为具有3-氨基丙基、N-(2-氨基乙基)3-氨基丙基等氨基的有机聚硅氧烷。
本发明的水包油型乳液优选为经由直接乳化法,不伴随乳化聚合反应。在该水包油型乳液中,可设计成分(A)及将其乳化而成的乳液粒子的油相中未副产低分子量的硅氧烷低聚物从而实质上不包含这种硅氧烷低聚物的组成。具体来说,通过在利用汽提等手段预先从成分(A)去除低分子量的硅氧烷低聚物后进行乳化,可提供构成乳液组合物的油相中的硅氧烷聚合度为3~6的硅氧烷低聚物的含量的和小于1.0质量%的水包油型乳液组合物,可使该硅氧烷低聚物的含量的和小于0.75质量%、小于0.50质量%、或小于0.10质量%。假设在利用乳化聚合反应获得与成分(A)同等的高聚合度的有机聚硅氧烷的水包油型乳液的情况下,因为乳化聚合反应为平衡反应,所以油相中副产超过1.0质量%的硅氧烷低聚物,并且从乳液粒子分散于水中的结构来讲,有难以将其去除的问题,但于本发明中,如上所述,能够从根本上解决这种课题,且可提供油相中的硅氧烷低聚物的含量的和小于100ppm或者为可检测极限以下的高聚合度的有机聚硅氧烷的水包油型乳液。
这种成分(A)为构成乳液粒子的油相的成分,可为单独的有机聚硅氧烷,也可为所述有机聚硅氧烷等的混合物,但必须该油相的25℃下的表观粘度为1,000,000mPa·s以上或具有可塑度。这意味着成分(A)的整体粘度在直接乳化的前后未发生变化,成分(A)直接构成乳液粒子的油相。另外,乳液粒子的油相的25℃下的表观粘度可通过利用公知的方法将本发明的水包油型乳液进行乳液破坏而提取油相,来确认容易测定或者具有可塑度。
优选成分(A)选自:
(A1)25℃下的粘度为1,000,000mPa·s以上或具有可塑度的有机聚硅氧烷;或
(A2)25℃下的整体粘度为1,000,000mPa·s以上或具有可塑度的有机聚硅氧烷混合物。
进而,优选成分(A)的25℃下的整体粘度为2,500,000mPa·s以上或具有可塑度,也可以粘度为5,000,000mPa·s以上或具有可塑度。最优选为25℃下的整体粘度为5,000,000mPa·s以上或具有可塑度的生橡胶状的有机聚硅氧烷(=硅酮胶)。
另一方面,在本发明的水包油型乳液组合物中,作为成分(A),可使用通过将(A')25℃下的表观粘度小于1,000,000mPa·s的有机聚硅氧烷或其混合物、及聚合反应催化剂投入到乳化机、优选为下述垂直式分批混合机中,在室温或加热条件下进行搅拌而进行聚合反应,合成高聚合度的成分(A)而得的成分。即,在本发明的水包油型乳液组合物中,可在乳化机、优选为下述垂直式分批混合机中实施成分(A)的合成反应,在获得整体粘度为1,000,000mPa·s以上或具有可塑度的有机聚硅氧烷的混合物后,进行其乳化。另外,与成分(A)同样地,成分(A')只要满足所述表观粘度的条件,那么也可为包含硅酮树脂或硅酮弹性体的有机聚硅氧烷混合物。此外,在不损害本发明的目的的范围内,作为成分(A)的原料的成分(A')中可视需要含有二氧化硅微粒、增稠剂等添加剂。
作为合成成分(A)的前驱物的成分(A')可为包含单独或2种以上有机聚硅氧烷的混合物。此外,用于获得成分(A)的聚合反应的种类也没有特别限制,可例示缩合反应、硅氢化反应、自由基聚合反应等。尤其是本发明中的优选乳化机为垂直式分批混合机,通过在乳化机内实施这些合成反应,有可利用同一装置简便地实施成分(A)的合成反应步骤及其乳化步骤的优点。
作为一例,在所述聚合反应为缩合反应的情况下,(A')25℃下的小于1,000,000mPa·s的有机聚硅氧烷或其混合物优选在分子内具有羟基(硅烷醇基)等聚合性的反应性基,例如可列举:25℃下的表观粘度小于1,000,000mPa·s、优选25℃下的表观粘度处于5,000~10,0000mPa·s的范围的两末端经硅烷醇基封阻的二甲基聚硅氧烷、两末端经硅烷醇基封阻的二甲基硅氧烷-苯基甲基硅氧烷共聚物、两末端经硅烷醇基封阻的二甲基硅氧烷-二苯基硅氧烷共聚物、两末端经硅烷醇基封阻的二甲基硅氧烷-甲基(3,3,3-三氟丙基)硅氧烷共聚物等、或其混合物。其它官能基及结构上的特征大致以所述成分(A)为标准,使成分(A')聚合而获得的成分(A)于分子内、尤其是分子链末端具有羟基(硅烷醇基)等乳化聚合性的反应性基,关于其粘度,25℃下的粘度可处于1,000,000mPa·s~5,000,000mPa·s的范围内。
使成分(A')聚合的方法可无限制地利用公知的反应作为具有两末端的硅烷醇基等的有机聚硅氧烷的聚合反应,例如,可以是将离子性表面活性剂用于聚合催化剂的聚合反应。例如,通过在乳化机、优选为垂直式分批混合机中,添加25℃下的粘度小于1,000,000mPa·s的两末端经硅烷醇基封阻的有机聚硅氧烷或其混合物、及烷基苯磺酸水溶液等作为离子性表面活性剂的聚合反应催化剂,在室温~90度的范围下进行搅拌混合,能够以比作为成分(A)的前驱物的有机聚硅氧烷或其混合物高粘度的有机聚硅氧烷或其混合物的形式获得成分(A)。
[(B)表面活性剂]
成分(B)为用于将所述成分(A)于水中乳化的至少1种以上的表面活性剂。成分(B)于本发明的乳液粒子中,通过至少成分(B)的一部分存在于作为油相的成分(A)及作为水相的成分(C)的界面,而形成乳液粒子,形成成分(A)分散于水相中的水包油型乳液。
这种表面活性剂的种类没有特别限制,也可以使用非离子(nonionic)性表面活性剂;选自阴离子性表面活性剂、两性表面活性剂、阳离子性表面活性剂的离子性表面活性剂;半极性表面活性剂的任一种。尤其是在本发明的水包油型乳液组合物为成分(A)利用成分(B)在水中乳化而成的直接乳化型乳液的情况下,与乳化聚合型乳液不同,无需离子性表面活性剂。即,成分(B)包含(B1)非离子性表面活性剂及(B2)离子性表面活性剂,成分(B1)与成分(B2)的质量比可为100∶0~50∶50的范围,可以质量比100∶0、即仅以成分(B1)进行乳化。此外,也可并用这些表面活性剂及半极性表面活性剂。另外,这些表面活性剂的一部分可作为化妆料原料等的洗净成分残存于水相中。另一方面,在本发明的水包油型乳液组合物包含将所述成分(A')于乳化装置内聚合而成的高分子聚硅氧烷即成分(A)的情况下,也可使用离子性表面活性剂作为聚合催化剂。
(B1)非离子性表面活性剂:
作为非离子性表面活性剂,可例示:聚氧烷撑醚类、聚氧烷撑烷基醚类、聚氧烷撑脂肪酸酯类(例如由聚乙二醇(或者环氧乙烷)及高级脂肪酸(例如碳数12~18的直链或支链脂肪酸)构成)、聚氧烷撑脂肪酸二酯类、聚氧烷撑树脂酸酯类、聚氧烷撑(氢化)蓖麻油类、聚氧烷撑烷酚类、聚氧烷撑烷基苯基醚类、聚氧烷撑苯基苯基醚类、聚氧烷撑烷基酯类、聚氧烷撑烷基酯类、山梨醇酐脂肪酸酯、聚氧烷撑山梨醇酐烷基酯类(例如由山梨醇酐、聚乙二醇及高级脂肪酸(例如碳数12~18的直链或支链脂肪酸)构成)、聚氧烷撑山梨醇酐脂肪酸酯类、聚氧烷撑山梨糖醇脂肪酸酯类、聚氧烷撑甘油脂肪酸酯类、聚甘油烷基醚类、聚甘油脂肪酸酯类、蔗糖脂肪酸酯类、脂肪酸烷醇酰胺、烷基葡萄糖苷类、聚氧烷撑脂肪酸联苯醚类、聚丙二醇、二乙二醇、聚氧烷撑改性硅酮、聚甘油基改性硅酮、甘油基改性硅酮、糖改性硅酮、氟系表面活性剂、聚氧乙烯-聚氧丙烯嵌段聚合物、烷基聚氧乙烯-聚氧丙烯嵌段聚合物醚。聚氧烷撑改性硅酮、聚甘油基改性硅酮、甘油基改性硅酮也可良好地使用视需要与亲水基同时施加有烷基支链、直链硅酮支链等而成的硅酮。此外,非离子表面活性剂的HLB可根据乳化条件任意地进行选择。
(B2-1)阴离子性表面活性剂:
作为阴离子性表面活性剂,可例示:饱和或不饱和脂肪酸盐(例如月桂酸钠、硬脂酸钠、油酸钠、次亚麻油酸钠等)、烷基硫酸盐、烷基苯磺酸(例如己基苯磺酸、辛基苯磺酸、十二烷基苯磺酸等)及其盐、聚氧烷撑烷基醚硫酸盐、聚氧烷撑烯基醚硫酸盐、聚氧乙烯烷基硫酸酯盐、磺基琥珀酸烷基酯盐、聚氧烷撑磺基琥珀酸烷基酯盐、聚氧烷撑烷基苯基醚硫酸盐、烷磺酸盐、辛基三甲基铵氢氧化物、十二烷基三甲基铵氢氧化物、烷基磺酸酯、聚氧乙烯烷基苯基醚硫酸盐、聚氧烷撑烷基醚乙酸盐、烷基磷酸盐、聚氧烷撑烷基醚磷酸盐、酰基谷氨酸盐、α-酰基磺酸盐、烷基磺酸盐、烷基烯丙基磺酸盐、α-烯烃磺酸盐、烷基萘磺酸盐、烷磺酸盐、烷基或烯基硫酸盐、烷基酰胺基硫酸盐、烷基或烯基磷酸盐、烷基酰胺基磷酸盐、烷酰基烷基牛磺酸盐、N-酰基氨基酸盐、磺基琥珀酸盐、烷基醚羧酸盐、酰胺基醚羧酸盐、α-磺基脂肪酸酯盐、丙氨酸衍生物、甘氨酸衍生物、精氨酸衍生物。作为盐,可列举钠盐等碱金属盐、镁盐等碱土金属盐、三乙醇胺盐等烷醇胺盐,进而可列举铵盐。
(B2-2)阳离子性表面活性剂:
作为阳离子性表面活性剂,可例示:氯化烷基三甲基铵、氯化硬脂基三甲基铵、氯化月桂基三甲基铵、氯化鲸蜡基三甲基铵、氯化牛油烷基三甲基铵、氯化山萮基三甲基铵、溴化硬脂基三甲基铵、溴化山萮基三甲基铵、氯化二硬脂基二甲基铵、氯化二椰油酰基二甲基铵、氯化二辛基二甲基铵、氯化二椰油酰基二甲基铵、氯化二辛基二甲基铵、氯化二(POE)油基甲基铵(2EO)、氯化苄烷铵、氯化烷基苄烷铵、氯化烷基二甲基苄烷铵、苄索氯铵、氯化硬脂基二甲基苄基铵、羊毛脂衍生季铵盐、硬脂酸二乙基氨基乙基酰胺、硬脂酸二甲氨基丙基酰胺、氯化山萮酸酰胺基丙基二甲基羟基丙基铵、氯化硬脂酰基胆氨基甲酰基甲基吡啶鎓、西吡氯铵、氯化妥尔油烷基苄基羟乙基咪唑啉鎓、苄基铵盐。
(B2-3)两性表面活性剂:
作为两性表面活性剂,可例示:咪唑啉型、酰胺甜菜碱型、烷基甜菜碱型、烷基酰胺甜菜碱型、烷基磺基甜菜碱型、酰胺基磺基甜菜碱型、羟基磺基甜菜碱型、羰基甜菜碱型、磷酸酯甜菜碱型、氨基羧酸型、酰胺基氨基酸型两性表面活性剂。具体来说,可例示:2-十一烷基-N,N,N-(羟乙基羧甲基)-2-咪唑啉钠、2-椰油酰基-2-咪唑啉鎓氢氧化物-1-羧基乙氧基2钠盐等咪唑啉型两性表面活性剂;月桂基二甲氨基乙酸甜菜碱、肉豆蔻基甜菜碱等烷基甜菜碱型两性表面活性剂;椰子油脂肪酸酰胺基丙基二甲氨基乙酸甜菜碱、棕榈仁油脂肪酸酰胺基丙基二甲氨基乙酸甜菜碱、牛油脂肪酸酰胺基丙基二甲氨基乙酸甜菜碱、氢化牛油脂肪酸酰胺基丙基二甲基氨基乙酸甜菜碱、月桂酸酰胺基丙基二甲氨基乙酸甜菜碱、肉豆蔻酸酰胺基丙基二甲氨基乙酸甜菜碱、棕榈酸酰胺基丙基二甲氨基乙酸甜菜碱、硬脂酸酰胺基丙基二甲氨基乙酸甜菜碱、油酸酰胺基丙基二甲氨基乙酸甜菜碱等酰胺甜菜碱型两性表面活性剂;椰子油脂肪酸二甲基磺基丙基甜菜碱等烷基磺基甜菜碱型两性表面活性剂;月桂基二甲氨基羟基磺基甜菜碱等烷基羟基磺基甜菜碱型两性表面活性剂;月桂基羟基磷酸酯甜菜碱等磷酸酯甜菜碱型两性表面活性剂;N-月桂酰基-N'-羟乙基-N'-羧甲基乙二胺钠、N-油酰基-N'-羟乙基-N'-羧甲基乙二胺钠、N-椰油酰基-N'-羟乙基-N'-羧甲基乙二胺钠、N-月桂酰基-N'-羟乙基-N'-羧甲基乙二胺钾、N-油酰基-N'-羟乙基-N'-羧甲基乙二胺钾、N-月桂酰基-N-羟乙基-N'-羧甲基乙二胺钠、N-油酰基-N-羟乙基-N'-羧甲基乙二胺钠、N-椰油酰基-N-羟乙基-N'-羧甲基乙二胺钠、N-月桂酰基-N-羟乙基-N',N'-二羧甲基乙二胺单钠、N-油酰基-N-羟乙基-N',N'-二羧甲基乙二胺单钠、N-椰油酰基-N-羟乙基-N',N'-二羧甲基乙二胺单钠、N-月桂酰基-N-羟乙基-N',N'-二羧甲基乙二胺二钠、N-油酰基-N-羟乙基-N',N'-二羧甲基乙二胺二钠、N-椰油酰基-N-羟乙基-N',N'-二羧甲基乙二胺二钠等酰胺基氨基酸型两性表面活性剂。
(B3)半极性表面活性剂:
作为半极性表面活性剂,可例示烷基胺氧化物型表面活性剂、烷基胺氧化物、烷基酰胺基胺氧化物、烷基羟基胺氧化物等,优选使用碳数10~18的烷基二甲基胺氧化物、碳数8~18的烷氧基乙基二羟乙基胺氧化物等。具体来说,可例示:十二烷基二甲基胺氧化物、二甲基辛基胺氧化物、二乙基癸基胺氧化物、双-(2-羟基乙基)十二烷基胺氧化物、二丙基十四烷基胺氧化物、甲基乙基十六烷基胺氧化物、十二烷基酰胺基丙基二甲基胺氧化物、鲸蜡基二甲基胺氧化物、硬脂基二甲基胺氧化物、牛脂二甲基胺氧化物、二甲基-2-羟基十八烷基胺氧化物、月桂基二甲基胺氧化物、肉豆蔻基二甲基胺氧化物、硬脂基二甲基胺氧化物、异硬脂基二甲基胺氧化物、椰子脂肪酸烷基二甲基胺氧化物、辛酸酰胺基丙基二甲基胺氧化物、癸酸酰胺基丙基二甲基胺氧化物、月桂酸酰胺基丙基二甲基胺氧化物、肉豆蔻酸酰胺基丙基二甲基胺氧化物、棕榈酸酰胺基丙基二甲基胺氧化物、硬脂酸酰胺基丙基二甲基胺氧化物、异硬脂酸酰胺基丙基二甲基胺氧化物、油酸酰胺基丙基二甲基胺氧化物、蓖麻醇酸酰胺基丙基二甲基胺氧化物、12-羟基硬脂酸酰胺基丙基二甲基胺氧化物、椰子脂肪酸酰胺基丙基二甲基胺氧化物、棕榈仁油脂肪酸酰胺基丙基二甲基胺氧化物、蓖麻油脂肪酸酰胺基丙基二甲基胺氧化物、月桂酸酰胺基乙基二甲基胺氧化物、肉豆蔻酸酰胺基乙基二甲基胺氧化物、椰子脂肪酸酰胺基乙基二甲基胺氧化物、月桂酸酰胺基乙基二乙基胺氧化物、肉豆蔻酸酰胺基乙基二乙基胺氧化物、椰子脂肪酸酰胺基乙基二乙基胺氧化物、月桂酸酰胺基乙基二羟乙基胺氧化物、肉豆蔻酸酰胺基乙基二羟乙基胺氧化物、及椰子脂肪酸酰胺基乙基二羟乙基胺氧化物。
这些表面活性剂的使用量没有特别限制,相对于作为成分(A)的有机聚硅氧烷或其混合物100质量份,成分(B)整体为0.1~30质量份的范围,优选0.2~25质量份、0.5~20质量份的范围,也可为0.5~15质量份的范围。另外,成分(B)可在乳化时分开添加,所述量意指水包油型乳液组合物中的成分(B)的合计量。在本发明中,如上所述,即便在表面活性剂的使用量比较少的情况下,也可获得几乎不包含粗大粒子的水包油型乳液组合物。因此,有可避免过度使用表面活性剂,实现良好的水包油型乳液组合物的优点。另一方面,在未使用本发明的乳化方法等的情况下,如果为15质量份的表面活性剂的使用量,那么有乳液中含有大量粗大粒子,实用性的乳化稳定性等显著受损的情况。
[(C)水]
成分(C)为水,形成本发明的水包油型乳液组合物的水相,是利用成分(B)乳化的成分(A)的乳液粒子的分散介质,可包含其它水溶性的任意成分。水优选清洁且不包含阻碍乳化及水包油型乳液组合物的储存稳定性的成分,可例示:离子交换水、蒸馏水、井水、自来水。
关于水的使用量,相对于作为成分(A)的有机聚硅氧烷或其混合物100质量份,为10~2000质量份的范围,可为10~1000质量份的范围,也可为10~500质量份、10~300质量份的范围。此外,在形成本发明的水包油型乳液组合物时,水可作为成分(A)的转相水及乳液形成后的稀释水投入,也可为制成所述(B)表面活性剂的水溶液并依次添加成分(A)的形态。水可作为用于使成分(A)转相为水包油型乳液的转相水而一次性投入,也可少量地阶段性地投入。此外,在形成以成分(A)作为油相的水包油型乳液后,可作为稀释水一次性投入,也可将稀释水每次少量地阶段性地投入。通过阶段性地进行转相水的投入或稀释水的投入,有可更细微地设计由乳化所获得的乳液粒子的平均粒径的情况。
[任意成分]
本发明的水包油型乳液组合物只要不违反本发明的目的,那么可进而包含所需的添加剂。例如,可调配稳定剂、氧化防止剂(抗氧化剂)、增稠剂、pH调整剂、螯合剂、水溶性醇类、防菌防腐剂、抗菌剂等各种添加剂。通过少量调配这些添加剂,有改善水包油型乳液组合物的经时稳定性或者储存稳定性的情况。此外,尤其是在化妆料原料的情况下,通过进而调配香料,有能够掩盖来自表面活性剂等的不良气味的情况。
作为氧化防止剂的例子,可列举:维生素E、丁基羟基苯甲醚、二丁基羟基甲苯、植酸等;作为螯合剂,例如可列举:丙氨酸、乙二胺四乙酸钠盐、多磷酸钠、偏磷酸钠、磷酸等。
作为增稠剂的例子,可列举:羧乙烯聚合物、羟乙基纤维素、羟丙基甲基纤维素、甲基纤维素、海藻酸、聚乙烯醇、聚乙烯吡咯啶酮、透明质酸钠等。
作为螯合剂的例子,可列举:乙二胺四乙酸钠、柠檬酸及其盐等。
作为水溶性醇类,可例示:乙醇、异丙醇(IPA)、丁二醇、丙二醇及甘油。
作为pH调整剂的例子,可列举:乳酸、柠檬酸、乙醇酸、琥珀酸、酒石酸、dl-苹果酸、碳酸钾、碳酸氢钠、碳酸氢铵、盐酸、磷酸、乙酸、硫酸、硼酸、硼砂、氢氧化钠、氢氧化钾、碳酸钠、碳酸氢钠、氨水等。
作为防菌防腐剂,例如可列举:对羟苯甲酸烷基酯、苯甲酸、苯甲酸钠、己二烯酸、己二烯酸钾、苯氧基乙醇等;作为抗菌剂,可列举:苯甲酸、水杨酸、石碳酸、己二烯酸、对羟苯甲酸烷基酯、对氯间甲酚、六氯酚、氯化苄烷铵、氯化氯己定、三氯对称二苯脲、三氯生、感光素等。此外,作为抑菌剂,例如可列举:1-庚基甘油基醚、1-(2-乙基己基)甘油基醚、1-辛基甘油基醚、1-癸基甘油基醚及1-十二烷基甘油基醚等甘油基单烷基醚。
[乳液粒子的平均粒径]
本发明的水包油型乳液组合物的特征在于:具有将作为所述成分(A)的具有高粘度~可塑度的有机聚硅氧烷直接乳化而成的油相,且其乳液粒子的平均粒径小,几乎不含粗大粒子。
具体来说,本发明中的水包油型乳液组合物的利用激光衍射/散射法测定的作为乳液粒子的体积平均粒径算出的平均粒径(以下简称为“平均粒径”)处于0.1~7.5μm的范围,乳液的粒度分布中具有平均粒径的10倍以上粒径的乳液粒子所占的含量小于5.0体积%。乳液粒子的平均粒径更优选0.1~5.5μm的范围,并且具有平均粒径的10倍以上粒径的乳液粒子的含量小于5.0体积%。另外,具有平均粒径的10倍以上粒径的乳液粒子的含量小于5.0体积%意味着在观察本发明的水包油型乳液组合物的粒度分布的情况下,相对于平均粒径的波峰,粒径的分布范围广泛,或者在大粒径侧具有其它波峰,未大量包含相对粗大的乳液粒子,通常在平均粒径附近具有陡峭的粒度分布。另外,通过使用下述制造方法,也能够获得乳液粒子的平均粒径处于0.1~3.5μm的范围,且具有平均粒径的10倍以上粒径的乳液粒子的含量小于5.0体积%的水包油型乳液组合物,但本发明不限定于此。
乳液粒子的平均粒径可进行适当设计,在利用使用下述垂直式分批混合机的制造方法的情况下,可通过添加转相水或稀释水后,使搅拌时间继续直至达到所需的平均粒径及粒径分布等手段而良好地实现。
本发明的水包油型乳液组合物因为如上所述具有微细的平均粒径,不包含粗大的乳液粒子,所以能够使伴随乳液粒子的合一而产生的对保存稳定性的不良影响最小化,作为乳液组合物的储存稳定性、操作作业性及调配稳定性优异。进而,因为可利用直接乳化法获得,所以包含成分(A)的油相的整体粘度(=表观粘度)非常高,且乳液粒子微细且均质,因此在用于化妆料原料等的情况下,有其触感提高性优异,可在毛发(角蛋白)或皮肤上形成包含该油相的均质皮膜的优点。此外,与乳化聚合法不同,因为油相非聚合物,所以能够事先从乳液粒子去除硅氧烷低聚物,关于用于乳化的成分(A),具有可以微细的平均粒径设计具备维持其期待的油剂单独的性质的油相的乳液粒子的实际好处。
[水包油型乳液组合物的制造方法及适合的制造装置]
本发明的水包油型乳液组合物优选为利用垂直式分批混合机,使用成分(B),将所述成分(A)于(C)水中机械性地乳化而成。乳化方法可为转相法或向表面活性剂水溶液中的油相分散法任一种,没有特别限制。此处,垂直式分批混合机为竖式搅拌装置,即便为如本发明的成分(A)那样粘度非常高的有机聚硅氧烷或其混合物,也可于转相后或伴随转相的水相的稀释阶段利用剪力将乳液粒子高度且均质地微细化。
这种垂直式分批混合机的结构例如在所述专利文献4、专利文献5等中被提出,尤其是在本发明中,优选使用具有配置于同一轴芯上的多个旋转轴的竖式同芯多轴搅拌机。该同芯多轴型的垂直式分批混合机与非同芯多轴型的垂直式分批混合机相比,对如成分(A)那样粘度非常高的有机聚硅氧烷或其混合物有可有效地防止附着于容器及搅拌叶,进行高效率且均质的乳化分散的优点。
尤其是本发明中优选的制造装置为同时具备带状搅拌叶及非带状搅拌叶的垂直式分批混合机,有一面连续且均匀地对成分(A)施加强剪力,一面防止成分(A)附着于容器及搅拌叶,且通过从容器底部上翻,能够均质地对容器内整体进行搅拌的优点。此外,这种垂直式分批混合机也可具备辅助性搅拌叶或以分散为目的的分散机、以自壁面刮落成分(A)为目的的刮刀。此外,只要结构上有可能,那么也可具备提高搅拌效率的隔板。
本发明中尤其优选的制造装置为同心多轴型垂直式分批混合机,其特征在于具有配置于同一轴芯上的多个旋转轴,且具备配置于至少1个旋转轴上的带状搅拌叶及配置于与所述旋转轴不同的旋转轴上的非带状搅拌叶,即便是如粘度超过10,000,000mPa·s的硅酮胶,也可提供具备如上所述的微细乳液粒子的水包油型乳液组合物。另外,作为这种装置,可良好地利用由Sumitomo Heavy Industries Process市售的NANOVisK等。
使用所述垂直式分批混合机的水包油型乳液组合物的制造方法优选具备:
步骤1:于所述成分(A)中至少添加成分(B)的至少一部分,进行混合的步骤
步骤2:于步骤1的混合物中添加成分(C)的至少一部分,使用机械力转相为水包油型的乳液形态的步骤
步骤3:任意向步骤2的乳液形态的组合物中进而添加成分(C)并一面使用机械力进行搅拌,一面稀释水相的步骤。
另外,在步骤2及步骤3中,也可添加残余的成分(B)或其它任意成分,在步骤2及步骤3中,也可通过以控制乳液粒子为目的的利用机械力所进行的剪切,而将乳液粒子微细化或者均质化,抑制粗大粒子的产生。进而,在步骤2及步骤3中,可一次性投入转相水或稀释水,也可通过阶段性地投入这些水,将乳液粒子微细化。因为由垂直式分批混合机产生的剪力根据乳化相或者稀释相的粘度而发生变化,所以通过阶段性地投入转相水或稀释水,有即便为相同装置及搅拌速度,也可将乳液粒子进一步微细化或者均质化的情况。
所述各步骤中的搅拌速度及搅拌时间可根据所使用的成分(A)、成分(B)的种类、所需的乳液粒子的大小、制造规模等进行适当选择。尤其是可在制造时,在所述步骤2或步骤3中,进行以调整乳液粒径为目的的搅拌及取样,使制造条件最佳化,且是优选的。
在本发明中,也可包含如下步骤作为任意步骤(步骤1的前步骤):通过将作为成分(A)的前驱物的(A')25℃下的表观粘度小于1,000,000mPa·s的有机聚硅氧烷或其混合物、及聚合反应催化剂投入到垂直式分批混合机中,于室温或加热条件下进行搅拌而进行聚合反应,合成成分(A)。即,在本发明中,成分(A)的合成步骤及上述乳化步骤可全部在垂直式分批混合机中实施。
[水包油型乳液组合物的用途]
本发明的水包油型乳液组合物的用途没有特别限定,可作为润滑剂、离型剂、纤维处理剂、玻璃纤维处理剂、化妆用基剂、抛光剂、涂料添加剂等广泛利用。此外,通过将本发明的水包油型乳液组合物与具有低~中程度的聚合度的其它硅酮乳液及硅酮弹性体粉末并用,也可用作具备抛光效果的划痕复原剂(Scratch Recovery Agent)。
尤其是本发明的水包油型乳液组合物可良好地用作包含该组合物的化妆料原料、化妆料、皮膜形成剂、涂覆剂、纤维处理剂等,尤其是在用于化妆料原料等的情况下,有其触感提高性优异,能够于毛发(角蛋白)或皮肤上形成包含该油相的均质皮膜的优点,并且因为可设计不包含担忧环境影响的低分子量的硅氧烷低聚物的组成,所以化妆料配方的自由度高,并且可调配于范围广泛的化妆料配方中。进而,因为本发明的成分(A)为被广泛用作化妆料原料的硅酮胶等,所以容易设计反映来自油相的附着性或触感提高的化妆料配方,通过替换使用作为以往公知的化妆料原料的包含粗大乳液粒子的硅酮胶乳液的毛发化妆料、皮肤化妆料等加以利用,可期待其触感、使用感、功能等的改善。
可调配本发明的水包油型乳液组合物的化妆料作为具体产品,可例示:皮肤清洁剂产品、护肤产品、彩妆产品、止汗剂产品、防紫外线产品等皮肤用化妆品;毛发用清洁剂产品、整发剂产品、毛发用着色剂产品、养发料产品、护发素产品、护发乳产品、头发护理产品等头发用化妆品;洗浴用化妆品。本发明的医药可例示生发剂、育发剂、镇痛剂、杀菌剂、抗炎症剂、清凉剂、皮肤抗老化剂,但并不限定于这些。
尤其是可调配本发明的水包油型乳液组合物的化妆料为以往公知的调配了硅酮胶的化妆料,是洗发精、护发素、护发乳、头发护理剂等包含水包油型乳液的头发用化妆品,通过使用本发明的水包油型乳液组合物,期待改善硅酮胶对毛发的附着性及均质的皮膜形成性。此外,当然可并用毛发化妆料中通用的各成分。
公开有许多这种包含硅酮胶的毛发化妆料的配方,例如,本案申请人在日本专利特开2012-046508号公报、日本专利特开2012-046507号公报、日本专利特开2013-095835号公报、日本专利特开2013-095834号公报、日本专利特开2013-095695号公报等中提出的毛发化妆料的配方中,在包含高聚合度的有机聚硅氧烷的组成中,可替换该硅酮胶而设计配方。另外,此时,业者可容易地根据所需来设计配方或者制造方法。
实施例
以下示出实施例及比较例,对本发明具体地进行说明,但本发明并不限定于下述实施例。在实施例及比较例中,“份”表示“质量份”。“粘度”表示于25℃下使用旋转式粘度计测得的粘度(动力粘度),可塑度为上述所定义的值。
实施例中,旋转叶的旋转速度表示图1中的非带状叶的旋转速度。同样地,用于直接乳化的粘度5,000,000mPa·s以上(可塑度120)的三甲基封端二甲基聚硅氧烷的硅氧烷低聚物的含量都小于1质量%。
实施例等中制备的水包油型有机聚硅氧烷乳液组合物根据以下的方法进行评价,与其它信息一起示于表1。
[乳液粒子的平均粒径]利用激光衍射/散射式粒度分布测定装置(MicrotracMT3000II,MicrotracBEL公司)测定制备的有机聚硅氧烷乳液组合物的乳液粒子而得的体积平均粒径的值。
[乳液粒子的粒度分布]利用所述装置,确认具有平均粒径的10倍以上粒径的乳液粒子的有无及含量。
[乳液组合物的保存稳定性]将制备的有机聚硅氧烷乳液组合物于200cc容量的玻璃瓶中计量,于25℃下静置2个月。利用目视观察乳液组合物的状态,在形成均匀的单相且未发现分离的情况下,判断为稳定性良好并以“○”表示,在发现两相的分离的情况下评价为稳定性不良并表示为“×”。
[比较例1]在粘度5,000,000mPa·s以上(可塑度120)的三甲基封端二甲基聚硅氧烷100.0份中,添加2种非离子性表面活性剂聚氧乙烯月桂醚(EO加成摩尔数:4摩尔)4.16份、聚氧乙烯月桂醚(EO加成摩尔数:23摩尔)的72质量%水溶液8.10份、少量的水,以牙科混合器进行混合,尝试以作为通过式乳化装置的胶体磨机对该混合物进行乳化处理,但无法处理。
[比较例2]在作为垂直式分批乳化装置的COMBI MIX(Primix制造)中,于粘度5,000,000mPa·s以上(可塑度120)的三甲基封端二甲基聚硅氧烷100.0份中,投入2种非离子性表面活性剂聚氧乙烯月桂醚(EO加成摩尔数:4摩尔)4.16份、聚氧乙烯月桂醚(EO加成摩尔数:23摩尔)的72质量%水溶液8.10份、少量的水并尝试混合,但无法处理。另外,该聚硅氧烷的粘度超过该装置的通常可使用的粘度范围。
[实施例1]在容量5L的垂直式分批混合机(NANOVisK,Sumitomo HeavyIndustries Process Equipment制造)中,在粘度5,000,000mPa·s以上(可塑度120)的三甲基封端二甲基聚硅氧烷100.0份中,添加2种非离子性表面活性剂聚氧乙烯月桂醚(EO加成摩尔数:4摩尔)4.16份、聚氧乙烯月桂醚(EO加成摩尔数:23摩尔)的72质量%水溶液8.10份并进行混合。在该预混料中添加少量的水后,以旋转叶速度7200rpm混合1.5小时后,添加残余的水而获得水包油型乳液。所得的乳液的平均粒径为3.8微米,未检测到具有平均粒径的10倍以上粒径的乳液粒子。
[实施例2]在容量5L的垂直式分批混合机(NANOVisK,Sumitomo HeavyIndustries Process Equipment制造)中,在粘度5,000,000mPa·s以上(可塑度120)的三甲基封端二甲基聚硅氧烷100.0份中,添加2种非离子性表面活性剂聚氧乙烯月桂醚(EO加成摩尔数:4摩尔)4.16份、聚氧乙烯月桂醚(EO加成摩尔数:23摩尔)的72质量%水溶液8.10份并进行混合。在该预混料中添加少量的水后,以旋转叶速度7200rpm混合2小时后,添加残余的水而获得水包油型乳液。所得的乳液的平均粒径为3.4微米,未检测到具有平均粒径的10倍以上粒径的乳液粒子。
[实施例3]在容量5L的垂直式分批混合机(NANOVisK,Sumitomo HeavyIndustries Process Equipment制造)中,在粘度5,000,000mPa·s以上(可塑度120)的三甲基封端二甲基聚硅氧烷100.0份中,添加2种非离子性表面活性剂聚氧乙烯月桂醚(EO加成摩尔数:4摩尔)4.16份、聚氧乙烯月桂醚(EO加成摩尔数:23摩尔)的72质量%水溶液8.10份并进行混合。在该预混料中添加少量的水后,以旋转叶速度7200rpm混合3小时后,添加残余的水而获得水包油型乳液。所得的乳液的平均粒径为3.2微米,未检测到具有平均粒径的10倍以上粒径的乳液粒子。
[实施例4]在容量5L的垂直式分批混合机(NANOVisK,Sumitomo HeavyIndustries Process Equipment制造)中,在粘度5,000,000mPa·s以上(可塑度152)的三甲基封端二甲基聚硅氧烷100.0份中,添加2种非离子性表面活性剂聚氧乙烯月桂醚(EO加成摩尔数:4摩尔)4.16份、聚氧乙烯月桂醚(EO加成摩尔数:23摩尔)的72质量%水溶液8.10份并进行混合。在该预混料中添加少量的水,以与[实施例2]相同的旋转叶速度(旋转叶速度7200rpm)混合4.5小时后,添加残余的水而获得水包油型乳液。所得的乳液的平均粒径为5.1微米,未检测到具有平均粒径的10倍以上粒径的乳液粒子。
[表1]
如表1(实施例1~4)所示,通过粘度5,000,000mPa·s以上(可塑度120或152)的三甲基封端二甲基聚硅氧烷的直接乳化,可获得平均粒径3.2~5.1μm的水包油型乳液组合物,且所得的乳液稳定。此外,其粒度分布实质上不包含平均粒径的10倍以上的粗大的乳液粒子。另外,根据比较例所示的方法,无法实现这些乳液。
[实施例5]在容量5L的垂直式分批混合机(NANOVisK,Sumitomo HeavyIndustries Process Equipment制造)中,合成两末端羟基二甲基聚硅氧烷(粘度120万mPa·s)。继而,在相同垂直式分批混合机中进而添加2种非离子性表面活性剂聚氧乙烯月桂醚(EO加成摩尔数:4摩尔)4.16份、聚氧乙烯月桂醚(EO加成摩尔数:23摩尔)的72质量%水溶液8.10份并进行混合。在该预混料中添加少量的水后,以旋转叶速度3600rpm混合1.5小时后,添加残余的水而获得水包油型乳液。以激光衍射式粒度分布计Mastersizer3000(Malvern公司)测定所得乳液的平均粒径,结果为1.1微米,未检测到具有平均粒径的10倍以上粒径的乳液粒子。
<配方例>
以下,由表2及表3所示的配方表示使用本案实施例的水包油型乳液组合物的毛发化妆料(洗发精)及皮肤化妆料(低粘度爽肤水)。另外,本发明的化妆料并不限定于这些。表中,“份数”为质量份。
<配方例1:洗发精>
[表2]
各成分(显示名称) | 份数 | |
1 | 水 | 32.74 |
2 | 聚季铵盐-10 | 10.00 |
3 | 柠檬酸 | 0.06 |
4 | EDTΑ-2Na | 0.10 |
5 | 甘油 | 1.50 |
6 | 椰油酰胺MEA | 1.00 |
7 | 月桂醇聚醚硫酸Na | 30.00 |
8 | 月桂醇聚醚-6羧酸Na | 10.00 |
9 | 椰油酰胺丙基甜菜碱、NaCl | 10.00 |
10 | 聚季铵盐-7 | 3.00 |
11 | 甲基异噻唑啉 | 0.10 |
12 | 椰油酰胺MEA | 0.50 |
13 | 柠檬酸 | Q.S. |
14 | 实施例1的水包油型乳液 | 0.50 |
<制造方法>
1.将1-6均匀地混合(视需要加热)
2.依序添加7、8、9并进行混合。
3.(在加热的情况下冷却至室温后),添加10、11与12的混合物、14并进行混合。
4.以pH成为5.5~6.5的方式添加14并进行混合。
<配方例2:低粘度爽肤水>
[表3]
<制造方法>
1.将A相的成分均匀地混合。
2.将B相的成分均匀地混合。
3.一面将A相缓慢混合,一面添加B相。
[符号的说明]
1、1' 与旋转轴结合的发动机
2 搅拌容器
3 带状搅拌叶
4 非带状搅拌叶
Claims (13)
1.一种水包油型乳液组合物,其特征在于,其是乳液,包含:(A)25℃下的整体粘度为1,000,000mPa·s以上或具有可塑度的有机聚硅氧烷或其混合物100质量份、
(B)至少1种以上的表面活性剂0.1~30质量份、及
(C)水100~2000质量份,且
成分(A)利用成分(B)在水中乳化;
利用激光衍射/散射法测定的乳液粒子的平均粒径处于0.1~7.5μm的范围,
乳液的粒度分布中具有平均粒径的10倍以上粒径的乳液粒子所占的含量小于5.0体积%,
构成乳液粒子的油相(成分(A))的25℃下的表观粘度为1,000,000mPa·s以上或具有可塑度。
2.根据权利要求1所述的水包油型乳液组合物,其中
成分(A)选自:
(A1)25℃下的1,000,000mPa·s以上或具有可塑度的有机聚硅氧烷、或
(A2)25℃下的整体粘度为1,000,000mPa·s以上或具有可塑度的有机聚硅氧烷混合物。
3.根据权利要求1或2所述的水包油型乳液组合物,其中成分(A)为25℃下的整体粘度为2,500,000mPa·s以上或具有可塑度的有机聚硅氧烷或其混合物。
4.根据权利要求1至3中任一项所述的水包油型乳液组合物,其中构成乳液组合物的油相中的硅氧烷聚合度为3~6的硅氧烷低聚物的含量的和小于1.0质量%。
5.根据权利要求1至4中任一项所述的水包油型乳液组合物,其中成分(B)包含(B1)非离子性表面活性剂及(B2)离子性表面活性剂,成分(B1)与成分(B2)的质量比为100∶0~50∶50,且
成分(B)的使用量相对于成分(A)100质量份为0.5~15质量份的范围。
6.一种化妆料原料,其含有根据权利要求1至5中任一项所述的水包油型乳液组合物。
7.一种化妆料,其含有根据权利要求1至5中任一项所述的水包油型乳液组合物。
8.一种皮膜形成剂,其含有根据权利要求1至5中任一项所述的水包油型乳液组合物。
9.一种涂料或涂覆剂组合物,其含有根据权利要求1至5中任一项所述的水包油型乳液组合物。
10.一种纤维处理剂,其含有根据权利要求1至5中任一项所述的水包油型乳液组合物。
11.一种根据权利要求1至5中任一项所述的水包油型乳液组合物的制造方法,其特征在于:使用(B)至少1种以上的表面活性剂,利用垂直式分批混合机,将(A)25℃下的整体粘度为1,000,000mPa·s以上或具有可塑度的有机聚硅氧烷或其混合物在(C)水中机械性地乳化而成。
12.根据权利要求11所述的水包油型乳液组合物的制造方法,其中所述垂直式分批混合机为同心多轴型垂直式分批混合机,该同心多轴型垂直式分批混合机的特征在于:具有配置于同一轴芯上的多个旋转轴,具备配置于至少1个旋转轴上的带状搅拌叶及配置于与所述旋转轴不同的旋转轴上的非带状搅拌叶。
13.根据权利要求11或12所述的水包油型乳液组合物的制造方法,其以是利用垂直式分批混合机所进行的直接乳化法为特征,不伴随乳化聚合反应。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2017142400 | 2017-07-24 | ||
JP2017-142400 | 2017-07-24 | ||
PCT/JP2018/025908 WO2019021800A1 (ja) | 2017-07-24 | 2018-07-09 | 水中油型エマルジョン組成物、その製造方法およびその用途 |
Publications (1)
Publication Number | Publication Date |
---|---|
CN111032786A true CN111032786A (zh) | 2020-04-17 |
Family
ID=65039726
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201880055402.8A Pending CN111032786A (zh) | 2017-07-24 | 2018-07-09 | 水包油型乳液组合物、其制造方法及其用途 |
Country Status (5)
Country | Link |
---|---|
US (1) | US20200308350A1 (zh) |
EP (1) | EP3660098A4 (zh) |
JP (1) | JP7081894B2 (zh) |
CN (1) | CN111032786A (zh) |
WO (1) | WO2019021800A1 (zh) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113402636A (zh) * | 2021-06-28 | 2021-09-17 | 海南天然橡胶产业集团金橡有限公司 | 一种天然低蛋白浓缩胶乳的制备方法 |
Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5806975A (en) * | 1995-11-01 | 1998-09-15 | Dow Corning Toray Silicone Co., Ltd. | Method for continuous emulsifying organopolysiloxane gums |
CN1222174A (zh) * | 1996-06-12 | 1999-07-07 | 罗狄亚化学公司 | 用于制备具有可调半透明性的硅氧烷弹性体的基于硅氧烷和有机(共)聚合物胶乳的水分散体 |
CN1125843C (zh) * | 1998-12-02 | 2003-10-29 | 陶氏康宁有限公司 | 制备水包硅氧烷乳化液的方法 |
CN1820041A (zh) * | 2003-07-23 | 2006-08-16 | 陶氏康宁公司 | 制备水包硅油乳液的机械转化方法 |
JP2006263728A (ja) * | 2006-05-26 | 2006-10-05 | Shi Mechanical & Equipment Inc | 高粘度・非ニュートン流体用竪型攪拌装置 |
CN1889927A (zh) * | 2003-12-05 | 2007-01-03 | Ge东芝硅树脂株式会社 | 毛发化妆品组合物 |
CN102421828A (zh) * | 2009-05-13 | 2012-04-18 | 陶氏康宁公司 | 聚合和乳化硅氧烷的连续法 |
WO2013065766A1 (en) * | 2011-10-31 | 2013-05-10 | Dow Corning Toray Co., Ltd. | Long chain amide-modified silicone - amino-modified silicone copolymer and uses thereof |
WO2013065767A1 (en) * | 2011-10-31 | 2013-05-10 | Dow Corning Toray Co., Ltd. | Long chain hydrocarbon-modified silicone - amino-modified silicone copolymer and uses thereof |
WO2017002905A1 (ja) * | 2015-07-01 | 2017-01-05 | 住友重機械プロセス機器株式会社 | 撹拌装置 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4788001A (en) * | 1985-04-02 | 1988-11-29 | Dow Corning Corporation | Oil-in-water emulsion |
FR2734273B1 (fr) * | 1995-05-19 | 1997-07-04 | Rhone Poulenc Chimie | Dispersion aqueuse a base de silicones et de latex de (co)polymere(s) organique(s) pour la preparation d'elastomere silicone a translucidite reglable |
US5726270A (en) * | 1996-12-26 | 1998-03-10 | General Electric Company | Process for the synthesis of mono-modal aqueous dispersions of polysiloxanes |
JP2001239141A (ja) | 2000-02-28 | 2001-09-04 | Sumitomo Heavy Ind Ltd | 高粘度・非ニュートン流体用竪型攪拌装置 |
KR101856640B1 (ko) | 2010-07-30 | 2018-05-14 | 다우 코닝 도레이 캄파니 리미티드 | 동시개질된 오가노폴리실록산을 함유하는 모발용 화장료 |
US20130177516A1 (en) | 2010-07-30 | 2013-07-11 | Dow Corning Toray Co., Ltd. | Cosmetic For Hair Containing Sugar Alcohol-Modified Silicone |
JP5877036B2 (ja) | 2011-10-31 | 2016-03-02 | 東レ・ダウコーニング株式会社 | 長鎖アミド変性シリコーン・アミノ変性シリコーン共重合体を含む化粧料 |
CN106687508B (zh) * | 2014-07-23 | 2019-06-14 | 美国陶氏有机硅公司 | 有机硅乳液 |
-
2018
- 2018-07-09 JP JP2019532485A patent/JP7081894B2/ja active Active
- 2018-07-09 CN CN201880055402.8A patent/CN111032786A/zh active Pending
- 2018-07-09 EP EP18839378.9A patent/EP3660098A4/en active Pending
- 2018-07-09 US US16/633,446 patent/US20200308350A1/en active Pending
- 2018-07-09 WO PCT/JP2018/025908 patent/WO2019021800A1/ja unknown
Patent Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5806975A (en) * | 1995-11-01 | 1998-09-15 | Dow Corning Toray Silicone Co., Ltd. | Method for continuous emulsifying organopolysiloxane gums |
CN1222174A (zh) * | 1996-06-12 | 1999-07-07 | 罗狄亚化学公司 | 用于制备具有可调半透明性的硅氧烷弹性体的基于硅氧烷和有机(共)聚合物胶乳的水分散体 |
CN1125843C (zh) * | 1998-12-02 | 2003-10-29 | 陶氏康宁有限公司 | 制备水包硅氧烷乳化液的方法 |
CN1820041A (zh) * | 2003-07-23 | 2006-08-16 | 陶氏康宁公司 | 制备水包硅油乳液的机械转化方法 |
CN1889927A (zh) * | 2003-12-05 | 2007-01-03 | Ge东芝硅树脂株式会社 | 毛发化妆品组合物 |
JP2006263728A (ja) * | 2006-05-26 | 2006-10-05 | Shi Mechanical & Equipment Inc | 高粘度・非ニュートン流体用竪型攪拌装置 |
CN102421828A (zh) * | 2009-05-13 | 2012-04-18 | 陶氏康宁公司 | 聚合和乳化硅氧烷的连续法 |
WO2013065766A1 (en) * | 2011-10-31 | 2013-05-10 | Dow Corning Toray Co., Ltd. | Long chain amide-modified silicone - amino-modified silicone copolymer and uses thereof |
WO2013065767A1 (en) * | 2011-10-31 | 2013-05-10 | Dow Corning Toray Co., Ltd. | Long chain hydrocarbon-modified silicone - amino-modified silicone copolymer and uses thereof |
WO2017002905A1 (ja) * | 2015-07-01 | 2017-01-05 | 住友重機械プロセス機器株式会社 | 撹拌装置 |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113402636A (zh) * | 2021-06-28 | 2021-09-17 | 海南天然橡胶产业集团金橡有限公司 | 一种天然低蛋白浓缩胶乳的制备方法 |
CN113402636B (zh) * | 2021-06-28 | 2022-05-17 | 海南天然橡胶产业集团金橡有限公司 | 一种天然低蛋白浓缩胶乳的制备方法 |
Also Published As
Publication number | Publication date |
---|---|
EP3660098A1 (en) | 2020-06-03 |
JP7081894B2 (ja) | 2022-06-07 |
US20200308350A1 (en) | 2020-10-01 |
EP3660098A4 (en) | 2021-04-21 |
WO2019021800A1 (ja) | 2019-01-31 |
JPWO2019021800A1 (ja) | 2020-08-06 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US10245451B2 (en) | Aminofunctional organosiloxanes | |
US10385212B2 (en) | Silicone emulsions | |
JP5551341B2 (ja) | 水中油型オルガノポリシロキサンエマルジョン組成物、それからなる化粧料原料およびそれを用いた頭髪化粧料の製造方法 | |
US9017650B2 (en) | Emulsions of aminofunctional silicones | |
JP5697150B2 (ja) | シリコーンエマルジョン | |
JP4160165B2 (ja) | ポリオルガノシロキサンエマルジョンおよびそれを用いる化粧料 | |
CN111032786A (zh) | 水包油型乳液组合物、其制造方法及其用途 | |
US20220145076A1 (en) | Silicone Emulsion and Method for Producing Same | |
JP7073319B2 (ja) | 色調の変化を抑えられる、アミノ変性シリコーン含有水中油型エマルジョン組成物、その製造方法、設計方法、および、該組成物を配合した化粧料 | |
JP6187683B2 (ja) | オルガノポリシロキサンエマルション組成物の製造方法 | |
JP2018104358A (ja) | 水中油型シリコーンエマルジョン組成物 | |
JP6387929B2 (ja) | オルガノポリシロキサンエマルション組成物の製造方法 | |
EP3004219B1 (en) | Process for preparing aminofunctional silicone emulsions | |
JPH04134017A (ja) | 毛髪化粧料用高濃度シリコンエマルジョン組成物 | |
JP2014077150A (ja) | 水中油型オルガノポリシロキサンエマルジョン組成物、それからなる化粧料原料およびそれを用いた頭髪化粧料の製造方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination |