CN110872194A - Ceramic ball capable of reducing water molecule agglomeration and preparation method thereof - Google Patents
Ceramic ball capable of reducing water molecule agglomeration and preparation method thereof Download PDFInfo
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- CN110872194A CN110872194A CN201811018671.5A CN201811018671A CN110872194A CN 110872194 A CN110872194 A CN 110872194A CN 201811018671 A CN201811018671 A CN 201811018671A CN 110872194 A CN110872194 A CN 110872194A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/46104—Devices therefor; Their operating or servicing
- C02F1/46176—Galvanic cells
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/48—Treatment of water, waste water, or sewage with magnetic or electric fields
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/66—Treatment of water, waste water, or sewage by neutralisation; pH adjustment
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/04—Clay; Kaolin
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/51—Metallising, e.g. infiltration of sintered ceramic preforms with molten metal
- C04B41/5116—Ag or Au
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
Abstract
The invention discloses a ceramic ball capable of reducing water molecule agglomeration and a preparation method thereof, wherein the ceramic ball comprises a porous ceramic ball and coating slurry; the porous ceramic ball comprises the following components: 38-43 parts of kaolin, 20-25 parts of purple clay, 10-15 parts of montmorillonite, 5-8 parts of silicon oxide, 5-8 parts of hexacyclic stone, 1-2 parts of Kunlun jade and 3-5 parts of Huangheyu; the coating slurry comprises the following components: 10-15 parts of iron tourmaline, 10-15 parts of lithium tourmaline, 10-15 parts of ionic magnesium, 5-8 parts of ionic sodium, 1-2 parts of nano silver, 20-25 parts of medical stone, 20-25 parts of muyu stone and 1-2 parts of adhesive. According to the invention, the iron tourmaline and the lithium tourmaline are made into the coating slurry layer to be coated on the outer layer of the ceramic ball, so that the service life of the ceramic ball can be prolonged, the tourmaline can be fully contacted with water, the water is rapidly subjected to small molecular grouping, and common drinking water is prepared into small molecular grouping water, so that the drinking water has a health care value, and the health care effect is beneficial to human health.
Description
Technical Field
The invention relates to the technical field of water quality improvement, in particular to a ceramic ball capable of reducing water molecule agglomeration and a preparation method thereof.
Background
Small cluster water benefits: regulating acid-base balance, and neutralizing acidic toxin in vivo; can remove free radicals, and has the effects of preventing diseases and resisting aging; promoting metabolism, easily dissolving wastes accumulated in human body due to various reasons and discharging the wastes out of the human body as soon as possible; preventing osteoporosis and promoting the generation of osteoblasts in bones; the alkaline small molecular group water flows out from the cathode, and the PH value is determined by the number of DH roots, so the alkaline small molecular group water has negative potential, and positive charges of a human body can move irregularly and can be rearranged; the basic value of the alkaline functional water is reduced, the oxygen dissolving capacity is strong, more oxygen is brought to each part of the body while the alkaline functional water flows through the body, and the oxygen is indispensable in the life process of human beings, so that the functions of each organ such as the heart, the lung and the like are more active; the functional water accords with the required functions of human physiological activities, and the small molecular group water has high-energy negative charges and strong seepage force, diffusion force and dissolving force. The weak alkaline water has strong dissolving power, emulsifying power, metabolic power and washing power, while the acid water has no functions.
Disclosure of Invention
The technical problem to be solved by the invention is to overcome the defects of the prior art and provide a ceramic ball capable of reducing water molecule agglomeration and a preparation method thereof.
In order to solve the technical problems, the invention provides the following technical scheme:
the invention provides a ceramic ball capable of reducing water molecule agglomeration, which comprises a porous ceramic ball and coating slurry; the porous ceramic ball comprises the following components: 38-43 parts of kaolin, 20-25 parts of purple clay, 10-15 parts of montmorillonite, 5-8 parts of silicon oxide, 5-8 parts of hexacyclic stone, 1-2 parts of Kunlun jade and 3-5 parts of Huangheyu;
the coating slurry comprises the following components: 10-15 parts of iron tourmaline, 10-15 parts of lithium tourmaline, 10-15 parts of ionic magnesium, 5-8 parts of ionic sodium, 1-2 parts of nano silver, 20-25 parts of medical stone, 20-25 parts of muyu stone and 1-2 parts of adhesive.
As a preferred technical scheme of the invention, the porous ceramic ball comprises the following components in percentage by weight: 40 parts of kaolin, 20 parts of purple clay pottery clay, 12 parts of montmorillonite, 8 parts of silicon oxide, 8 parts of medical stone, 8 parts of hexacyclic stone, 1 part of Kunlun jade and 3 parts of Huangheyu;
the coating slurry comprises the following components in percentage by weight: 15 parts of iron tourmaline, 15 parts of lithium tourmaline, 10 parts of ionic magnesium, 8 parts of ionic sodium, 1 part of nano silver, 25 parts of medical stone, 25 parts of muyu stone and 1 part of adhesive.
The invention also provides a preparation method of the ceramic ball, which comprises the following steps:
s1: the following components are respectively weighed according to the following mass percentages: 40 parts of kaolin, 20 parts of purple clay pottery clay, 12 parts of montmorillonite, 8 parts of silicon oxide, 8 parts of medical stone, 8 parts of hexacyclic stone, 1 part of Kunlun jade and 3 parts of Huangheyu;
s2: placing the raw materials weighed in the step S1) into a grinder for crushing, screening to obtain ceramic ball powder which is uniformly mixed, performing pelletizing treatment on the prepared ceramic ball powder to obtain a spherical element blank, drying and then punching the spherical element blank; after punching, putting the spherical element blank into a sintering furnace to calcine for 3 hours at the temperature of 1150-1500 ℃ to prepare a porous ceramic ball;
s3: the following components are respectively weighed according to the following mass percentages: 15 parts of iron tourmaline, 15 parts of lithium tourmaline, 10 parts of ionic magnesium, 8 parts of ionic sodium, 1 part of nano silver, 25 parts of medical stone, 25 parts of muyu stone and 1 part of adhesive;
s4: putting the raw materials weighed in the step S3) into a grinder for crushing, uniformly mixing the crushed raw materials, adding a bonding agent and water, heating to 70 ℃, stirring and pulping to obtain coating slurry, wherein the mass fraction of solid matters in the coating slurry is 70%;
s5: and (3) soaking the porous ceramic ball prepared in the step (S2) into the coating slurry prepared in the step (S4) for coating and sizing, and calcining the porous ceramic ball in a sintering furnace at the temperature of 850-950 ℃ for 1.5-2 h after sizing to prepare the ceramic ball with the water molecules being reduced in agglomeration.
As a preferred technical scheme of the invention, the iron tourmaline and the lithium tourmaline are used after being soaked in clear water for 5-8 days and then are cooked for 30min by boiling water.
As a preferred technical scheme of the invention, the porous ceramic ball is immersed in coating slurry, the coating thickness of the slurry is 1.5mm, and the coating slurry is dried at room temperature after being uniformly coated.
As a preferred technical scheme of the invention, the pulping mode of the coating slurry is frame type and propulsion type composite stirring, the stirring temperature is 45-90 ℃, and the stirring speed is 45-120 RPM.
The invention has the following beneficial effects: tourmaline, also called tourmaline, is called tourmaline as precious stone, and has positive and negative electric nuclei at two ends of its crystal, and 0.06mA micro-current flows on the surface. Tourmaline is the only precious stone with piezoelectric and pyroelectric effects in the world at present, and natural negative ions continuously released by tourmaline can completely relax human body, relieve tension, relieve stress, and have tranquilizing and allaying excitement effects. The tourmaline is charged with electric field and magnetic field, can electrolyze water and make water into small molecules, and has pH value of about 7.2, which can influence the conversion of pH value of water into weak alkaline small molecular group water. According to the invention, the iron tourmaline and the lithium tourmaline are made into the coating slurry layer to be coated on the outer layer of the ceramic ball, so that the service life of the ceramic ball can be prolonged, the tourmaline can be fully contacted with water, the water is rapidly subjected to small molecular grouping, and common drinking water is prepared into small molecular grouping water, so that the drinking water has a health care value, and the health care effect is beneficial to human health.
Detailed Description
The following description of the preferred embodiments of the present invention is provided for the purpose of illustration and description, and is in no way intended to limit the invention.
Example 1: the invention provides a ceramic ball capable of reducing water molecule agglomeration, which comprises a porous ceramic ball and coating slurry; the porous ceramic ball comprises the following components in percentage by weight: 40 parts of kaolin, 20 parts of purple clay pottery clay, 12 parts of montmorillonite, 8 parts of silicon oxide, 8 parts of medical stone, 8 parts of hexacyclic stone, 1 part of Kunlun jade and 3 parts of Huangheyu;
the coating slurry comprises the following components in percentage by weight: 15 parts of iron tourmaline, 15 parts of lithium tourmaline, 10 parts of ionic magnesium, 8 parts of ionic sodium, 1 part of nano silver, 25 parts of medical stone, 25 parts of muyu stone and 1 part of adhesive.
The preparation method of the ceramic ball comprises the following steps:
s1: the following components are respectively weighed according to the following mass percentages: 40 parts of kaolin, 20 parts of purple clay pottery clay, 12 parts of montmorillonite, 8 parts of silicon oxide, 8 parts of medical stone, 8 parts of hexacyclic stone, 1 part of Kunlun jade and 3 parts of Huangheyu;
s2: placing the raw materials weighed in the step S1) into a grinder for crushing, screening to obtain ceramic ball powder which is uniformly mixed, performing pelletizing treatment on the prepared ceramic ball powder to obtain a spherical element blank, drying and then punching the spherical element blank; after punching, putting the spherical element blank into a sintering furnace to calcine for 3 hours at the temperature of 1150-1500 ℃ to prepare a porous ceramic ball;
s3: the following components are respectively weighed according to the following mass percentages: 15 parts of iron tourmaline, 15 parts of lithium tourmaline, 10 parts of ionic magnesium, 8 parts of ionic sodium, 1 part of nano silver, 25 parts of medical stone, 25 parts of muyu stone and 1 part of adhesive;
s4: putting the raw materials weighed in the step S3) into a grinder for crushing, uniformly mixing the crushed raw materials, adding a bonding agent and water, heating to 70 ℃, stirring and pulping to obtain coating slurry, wherein the mass fraction of solid matters in the coating slurry is 70%;
s5: and (3) soaking the porous ceramic ball prepared in the step (S2) into the coating slurry prepared in the step (S4) for coating and sizing, and calcining the porous ceramic ball in a sintering furnace at the temperature of 850-950 ℃ for 1.5-2 h after sizing to prepare the ceramic ball with the water molecules being reduced in agglomeration.
Example 2:
the formula and the processing steps of the example 2 are the same as those of the above example, but the mixture ratio of the two is different.
S1: the following components are respectively weighed according to the following mass percentages: 40 parts of kaolin, 20 parts of purple clay pottery clay, 12 parts of montmorillonite, 8 parts of silicon oxide, 8 parts of medical stone, 8 parts of hexacyclic stone, 1 part of Kunlun jade and 3 parts of Huangheyu;
s2: placing the raw materials weighed in the step S1) into a grinder for crushing, screening to obtain ceramic ball powder which is uniformly mixed, performing pelletizing treatment on the prepared ceramic ball powder to obtain a spherical element blank, drying and then punching the spherical element blank; after punching, putting the spherical element blank into a sintering furnace to calcine for 3 hours at the temperature of 1150-1500 ℃ to prepare a porous ceramic ball;
s3: the following components are respectively weighed according to the following mass percentages: 12.5 parts of iron tourmaline, 12.5 parts of lithium tourmaline, 10 parts of ion magnesium, 8 parts of ion nano, 1 part of nano silver, 27.5 parts of medical stone, 27.5 parts of muyu stone and 1 part of adhesive;
s4: putting the raw materials weighed in the step S3) into a grinder for crushing, uniformly mixing the crushed raw materials, adding a bonding agent and water, heating to 70 ℃, stirring and pulping to obtain coating slurry, wherein the mass fraction of solid matters in the coating slurry is 70%;
s5: and (3) soaking the porous ceramic ball prepared in the step (S2) into the coating slurry prepared in the step (S4) for coating and sizing, and calcining the porous ceramic ball in a sintering furnace at the temperature of 850-950 ℃ for 1.5-2 h after sizing to prepare the ceramic ball with the water molecules being reduced in agglomeration.
Example 3:
the formula and the processing steps of the embodiment 3 are the same as those of the above embodiment, but the mixture ratio of the two is different.
S1: the following components are respectively weighed according to the following mass percentages: 40 parts of kaolin, 20 parts of purple clay pottery clay, 12 parts of montmorillonite, 8 parts of silicon oxide, 8 parts of medical stone, 8 parts of hexacyclic stone, 1 part of Kunlun jade and 3 parts of Huangheyu;
s2: placing the raw materials weighed in the step S1) into a grinder for crushing, screening to obtain ceramic ball powder which is uniformly mixed, performing pelletizing treatment on the prepared ceramic ball powder to obtain a spherical element blank, drying and then punching the spherical element blank; after punching, putting the spherical element blank into a sintering furnace to calcine for 3 hours at the temperature of 1150-1500 ℃ to prepare a porous ceramic ball;
s3: the following components are respectively weighed according to the following mass percentages: 10 parts of iron tourmaline, 10 parts of lithium tourmaline, 10 parts of ion magnesium, 8 parts of ion nano, 1 part of nano silver, 30 parts of medical stone, 30 parts of muyu stone and 1 part of adhesive;
s4: putting the raw materials weighed in the step S3) into a grinder for crushing, uniformly mixing the crushed raw materials, adding a bonding agent and water, heating to 70 ℃, stirring and pulping to obtain coating slurry, wherein the mass fraction of solid matters in the coating slurry is 70%;
s5: and (3) soaking the porous ceramic ball prepared in the step (S2) into the coating slurry prepared in the step (S4) for coating and sizing, and calcining the porous ceramic ball in a sintering furnace at the temperature of 850-950 ℃ for 1.5-2 h after sizing to prepare the ceramic ball with the water molecules being reduced in agglomeration.
The tourmaline is called tourmaline, and both ends of the crystal of the tourmaline are provided with positive and negative electric nuclei, and micro-current of 0.06mA flows on the surface. The natural negative ions continuously released by the tourmaline can completely relax the human body, relieve the tension, relieve the pressure and have the functions of calming and soothing the nerves. The tourmaline is charged with electric field and magnetic field, can electrolyze water and make water into small molecules, and has pH value of about 7.2, which can influence the conversion of pH value of water into weak alkaline small molecular group water.
The ceramic balls prepared in example 1, example 2 and example 3 were each subjected to small molecular grouping for 20min with 100ml of tap water, and the treated tap water was numbered A, B, C, while the control group was untreated 100ml of tap water and numbered D. The four numbered water samples were measured by the nuclear magnetic resonance technique, and the size of the water molecular group was measured by measuring the half width (expressed in Hz) of the vibration frequency of the water. The higher the Hz value is, the larger the water molecular group is, the poorer the quality of the water is; the smaller the Hz value, the smaller the water molecular group, the better the water quality. The following test results were obtained:
| water sample | Hertz (Hz) | Number of water molecules/number |
| A | 57 | 5 |
| B | 63 | 5 |
| C | 85 | 9 |
| D | 118 | 19 |
Experimental results show that the higher the tourmaline content in the ceramic ball, namely the higher the iron tourmaline and the lithium tourmaline content, the stronger the capacity of the ceramic ball to carry out small molecular grouping on water, and the smaller the water molecular group after treatment, the better the quality of the water.
Finally, it should be noted that: although the present invention has been described in detail with reference to the foregoing embodiments, those skilled in the art will understand that various changes, modifications and substitutions can be made without departing from the spirit and scope of the invention as defined by the appended claims. Any modification, equivalent replacement, or improvement made within the spirit and principle of the present invention should be included in the protection scope of the present invention.
Claims (6)
1. A ceramic ball capable of reducing water molecule agglomeration is characterized by comprising a porous ceramic ball and coating slurry; the porous ceramic ball comprises the following components: 38-43 parts of kaolin, 20-25 parts of purple clay, 10-15 parts of montmorillonite, 5-8 parts of silicon oxide, 5-8 parts of hexacyclic stone, 1-2 parts of Kunlun jade and 3-5 parts of Huangheyu;
the coating slurry comprises the following components: 10-15 parts of iron tourmaline, 10-15 parts of lithium tourmaline, 10-15 parts of ionic magnesium, 5-8 parts of ionic sodium, 1-2 parts of nano silver, 20-25 parts of medical stone, 20-25 parts of muyu stone and 1-2 parts of adhesive.
2. The ceramic ball capable of reducing water molecule agglomeration according to claim 1, wherein the porous ceramic ball comprises the following components in percentage by weight: 40 parts of kaolin, 20 parts of purple clay pottery clay, 12 parts of montmorillonite, 8 parts of silicon oxide, 8 parts of medical stone, 8 parts of hexacyclic stone, 1 part of Kunlun jade and 3 parts of Huangheyu;
the coating slurry comprises the following components in percentage by weight: 15 parts of iron tourmaline, 15 parts of lithium tourmaline, 10 parts of ionic magnesium, 8 parts of ionic sodium, 1 part of nano silver, 25 parts of medical stone, 25 parts of muyu stone and 1 part of adhesive.
3. A preparation method of ceramic balls capable of quickly alkalescence water quality is characterized by comprising the following steps:
s1: the following components are respectively weighed according to the following mass percentages: 40 parts of kaolin, 20 parts of purple clay pottery clay, 12 parts of montmorillonite, 8 parts of silicon oxide, 8 parts of medical stone, 8 parts of hexacyclic stone, 1 part of Kunlun jade and 3 parts of Huangheyu;
s2: placing the raw materials weighed in the step S1) into a grinder for crushing, screening to obtain ceramic ball powder which is uniformly mixed, performing pelletizing treatment on the prepared ceramic ball powder to obtain a spherical element blank, drying and then punching the spherical element blank; after punching, putting the spherical element blank into a sintering furnace to calcine for 3 hours at the temperature of 1150-1500 ℃ to prepare a porous ceramic ball;
s3: the following components are respectively weighed according to the following mass percentages: 15 parts of iron tourmaline, 15 parts of lithium tourmaline, 10 parts of ionic magnesium, 8 parts of ionic sodium, 1 part of nano silver, 25 parts of medical stone, 25 parts of muyu stone and 1 part of adhesive;
s4: putting the raw materials weighed in the step S3) into a grinder for crushing, uniformly mixing the crushed raw materials, adding a bonding agent and water, heating to 70 ℃, stirring and pulping to obtain coating slurry, wherein the mass fraction of solid matters in the coating slurry is 70%;
s5: and (3) soaking the porous ceramic ball prepared in the step (S2) into the coating slurry prepared in the step (S4) for coating and sizing, and calcining the porous ceramic ball in a sintering furnace at the temperature of 850-950 ℃ for 1.5-2 h after sizing to prepare the ceramic ball with the water molecules being reduced in agglomeration.
4. The ceramic ball capable of reducing water molecule agglomeration according to claim 1, wherein the iron tourmaline and the lithium tourmaline are used after being soaked in clear water for 5-8 days and then boiled in boiling water for 30 min.
5. The method for preparing ceramic balls capable of reducing water molecule agglomeration according to claim 3, wherein the porous ceramic balls are immersed in coating slurry, the coating thickness of the slurry is 1.5mm, and the coated slurry is dried at room temperature after being uniformly coated.
6. The method for preparing ceramic balls capable of making water molecules agglomerate small according to claim 3, wherein the beating mode of the coating slurry is a composite stirring of frame type and propulsion type, the stirring temperature is 45-90 ℃, and the stirring speed is 45-120 RPM.
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| CN113647345A (en) * | 2021-07-30 | 2021-11-16 | 陵水晨海种业有限公司 | Industrial artificial breeding method for Scorzonera gigas |
| CN113647345B (en) * | 2021-07-30 | 2023-01-03 | 陵水晨海种业有限公司 | Industrial artificial breeding method for Scorzonera gigas |
| CN114057272A (en) * | 2021-11-18 | 2022-02-18 | 王建业 | Ceramsite raw material for weak-base small-molecular-group spin-wave low-deuterium active water and preparation method thereof |
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