CN109252247A - A kind of graphene biology diatom composite fibre and its preparation method and application - Google Patents

A kind of graphene biology diatom composite fibre and its preparation method and application Download PDF

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Publication number
CN109252247A
CN109252247A CN201811085303.2A CN201811085303A CN109252247A CN 109252247 A CN109252247 A CN 109252247A CN 201811085303 A CN201811085303 A CN 201811085303A CN 109252247 A CN109252247 A CN 109252247A
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parts
staple fiber
graphene
composite fibre
fibre
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王宝林
王金泉
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Qingdao Yu Wang Intelligent Technology Bed Co Ltd
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Qingdao Yu Wang Intelligent Technology Bed Co Ltd
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    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/18Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from other substances
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/02Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from cellulose, cellulose derivatives, or proteins

Abstract

The invention discloses a kind of graphene biology diatom composite fibres, including following parts by weight product form: 50-60 parts of Arenga engleri Beccari coconut palm palm fibre staple fiber, 5-10 parts of jute staple fiber, 5-10 parts of bamboo charcoal staple fiber, 5-10 parts of animal wool staple fiber, 1-10 parts of graphene, 2-10 parts of diatomite, 1-2 parts of tourmaline powder, 2-5 parts of surfactant.Graphene biology diatom composite fibre layer not only has elastic reaction, also has moisture-proof, anti-corrosion, indeformable, Anti-moth-eating, ventilative, antibacterial, purification air, eliminates peculiar smell, breathing damping, releasing negative oxygen ion, many beneficial effects not being covered with dust.The elastic layer of mattress in the present invention uses polyurethane foam elastic, and polyurethane foam elastic has more micropores, resilience strong, many advantages, such as being unlikely to deform, can greatly prolong the service life of mattress.

Description

A kind of graphene biology diatom composite fibre and its preparation method and application
Technical field
The present invention relates to a kind of fiber and its preparation method and application, in particular to a kind of graphene biology diatom complex is fine Dimension and its preparation method and application.
Background technique
Diatom ooze product has unique " molecular sieve " structure, with extremely strong physical adsorbability and ion exchange function Can, the harmful substances such as free formaldehyde, benzene, the ammonia in air can be effectively removed and because of gas caused by pet, smoking, rubbish Taste can play the role of purifying the air of a room.Diatom ooze is made of inorganic material, therefore is not burnt, even if fire occurs, Will not emerge any smog being harmful to the human body.When temperature rises to 1300 DEG C Celsius, only there is molten in diatom ooze State will not generate the smog such as pernicious gas.With the variation of Various Seasonal and morning and evening ambient air temperature, diatom ooze be can be absorbed Or release moisture, indoor air humidity is automatically adjusted, relative equilibrium is made up to.Especially coastal cities and southern air are wetter The city of profit, adjusting indoor air humidity effect is obvious, and it is worried to reduce wet air bring.The main component silicon of diatom ooze The pyroconductivity of diatomaceous earth is very low, is ideal heat preserving and insulating material in itself, has extraordinary thermal and insulating performance, heat-insulated effect Fruit is 6 times of condition of equivalent thickness cement mortar.Unique " molecular sieve " structure of diatom ooze, can produce after touching the moisture in air Raw " water fall effect ", to constantly release the negative oxygen ion beneficial to human body.
Graphene has become the biomaterial of a new generation.It is that a kind of only monoatomic thickness, bi-dimensional cellular are netted The nano material of structure, its appearance, which has attracted the concern of entire scientific circles and rapidly become, is studied wide carbon materials Material.Since 2004 are found, graphene and its derivative (graphene oxide of graphene oxide and reduction) because of it solely Special optics, machinery, electronics, heat and magnetic characteristic receives the pay attention to day by day on biomedical boundary.For example, graphene oxide is graphite The soluble derivative of alkene, due to the multiple functionalized of it and with the efficient surface load of various biomolecule, obtained biological skill The extensive research in art field, this kind of biocompatible carbon-based material can promote the growth of stem cell and it induced to compose to various cells System's differentiation.In addition, graphene promotes the ability of osteoblast differentiation to make a kind of brand-new material that osteanagenesis is studied.This Outside, graphene have many noticeable optical properties, in recent years the researcher of IBM it has been found that graphene can absorb and The far infrared of radiation up to 40%.Human body is also a natural infrared emitter, and emission band is very wide, no matter the colour of skin How, the emissivity of skin of living body is 98%.Human body is again simultaneously good far infrared absorber, and absorption bands are with 3-15 It is just the effect wave band in graphene far infrared based on micron.The mechanism of absorption of human body far infrared is by human body group The carbon-carbon bond in cellular elements knitted, carbon-hydrogen link, the stretching vibration of oxygen-hydrogen bond etc., resonance wave is most of at 3-15 microns, It is identical with amplitude with the wavelength of far infrared, cause sympathetic response of resonating.The 8-15 micron far infrared wave of graphene heating transmitting, can have Activate the functions such as the biomolecule such as soma nucleic acid protein.In addition to this, also there is far infrared improvement blood of human body to follow Ring, improve arthralgia, adjust autonomic nerve, anti-inflammatory, enhance organism metabolism, cosmetologys etc. it is many beneficial to imitating Fruit.
Composite material is by two or more materials of different nature, by the method for combination process, at macroscopical (microcosmic) On the heterogeneous material that is composed.Compound purpose is the chief taken in performance, and the shortage of benefit has reached mutually collaboration or full The needs of certain specific function of foot.The present invention is intended to provide a kind of modified graphene biology diatom composite fibre and preparation method thereof And application.
The earlier application of the application is 201810372846.6, provide a kind of graphene biology diatom composite fibre and its Preparation method and application, the application are further improved on this basis, improve the durability and health properties of fiber.
Summary of the invention
The present invention is directed at least solve one of the technical problems existing in the prior art.The invention discloses a kind of modified stones Black alkene biology diatom composite fibre and its preparation method and application, with excellent performance and health-care effect.
Entire physics circle has been shaken immediately after the discovery of Grim group within graphene 2004.Graphene successfully prepares After, unique structure and excellent performance have attracted large quantities of researchers, subsequent graphite in worldwide at once The odd number solution of the various great glamours of alkene and application value is found in succession.The unique molecular structure of graphene determines it very Outstanding mechanics, electricity, magnetics, calorifics and optical property etc..
Unique " molecular sieve " structure of diatom ooze, can generate " water fall effect " after touching the moisture in air, thus Constantly release the negative oxygen ion beneficial to human body.
Tourmaline cell bath originates from South Korea, evolves into high-tech today, high-effect, multipurpose from ancient yellow mud sweat steaming Cell of new generation bath.My company and Cooperation in Korea, increase exploitation dynamics on this basis, become expensive noble's consumption The inTouch Lab that most people is enjoyed, foreign countries are all an invention at home for this, while investment is also greatly reduced to operator, This purpose develops the innovation that will necessarily cause a concept of health, and tourmaline, which experiences room, to be processed using " liquid " tourmaline Various construction materials, the thermostatic chamber built up, room temperature control between 35 degree~42 degree.By heating and keeping the temperature, " liquid " is electrical The energy of stone quickly, can be released consumingly in the form of far infrared, anion and micro-current, what they were collectively formed Energy field can provide energy to human body indirectly by air, so that human body cell is converted into motion state by dormant state, accelerate Vivotoxin is discharged in the blood circulation and metabolism of human body, and balanced human's pH value supplements new nutriment, to rise To the effect of health care and treatment.Tourmaline sweat-steaming house has apparent effect to human health, beauty, weight-reducing is improved.To heart and brain Vascular diseases, respiratory disease, the nervous system disease, gastrointestinal system disease, diabetes, various gynecological diseases, male Physiological maladies, various cancers and various chronic diseases, hypoimmunity etc. can play the prevention and treatment that drug is unable to reach Effect.
The technical solution of the present invention is as follows:
A kind of graphene biology diatom composite fibre, including following parts by weight product form: Arenga engleri Beccari coconut palm palm fibre staple fiber 50-60 Part, 5-10 parts of jute staple fiber, 5-10 parts of bamboo charcoal staple fiber, 5-10 parts of animal wool staple fiber, 1-10 parts of graphene, diatomite 2- 10 parts, 1-2 parts of tourmaline powder, 2-5 parts of surfactant.
Preferably, the particle size range of the diatomite is at 35~60 μm.
Preferably, the animal wool staple fiber is wool staple fiber.
Preferably, the surfactant be neopelex, glycerin monostearate, fatty acid sorbitan, At least one of polysorbate.
Tourmaline powder is the powder that obtains by mechanical crushing tourmaline raw ore after removing impurity.By processing The tourmaline powder of purification negative ion production with higher and far infrared transmissivity.Tourmaline is also Tourmaline.Tourmaline (tourmaline), the general name of family's cyclic structure silicate mineral of crystal category trigonal system.In formula R represent metal sun from Son constitutes black crystals tourmaline when R is Fe2+.Tourmaline crystal is in the column of nearly triangle, and both ends crystalline form is different, column Mask longitudinal grin is often in the form of a column, is needle-shaped, radial and blocky aggregate.Glassy lustre, fracture resinous luster are translucent to transparent. Mohs hardness 7-7.5, specific gravity 2.98-3.20.There are piezoelectricity and pyroelectricity.
Applicants have discovered that graphene and tourmaline proportion under specified conditions, can generate good health-care effect, especially It is to have unexpected improvement to hypertension.
The preparation method of the graphene biology diatom composite fibre, includes the following steps:
(1) weigh raw material: according to parts by weight, 50-60 parts of Arenga engleri Beccari coconut palm palm fibre staple fiber, 5-10 parts of jute staple fiber, bamboo charcoal are short 5-10 parts of fiber, 5-10 parts of animal wool staple fiber, 1-10 parts of graphene, 2-10 parts of diatomite, 1-2 parts of tourmaline powder, surface are living 2-5 parts of agent of property;
(2) hydrogenperoxide steam generator and sodium hydroxide solution the pretreatment of Arenga engleri Beccari coconut palm palm fibre staple fiber: are added to Arenga engleri Beccari coconut palm palm fibre In staple fiber, 40-60 DEG C of reaction temperature, ultrasonic vibration 60-120s, filtering is rinsed, drying;
(3) permeabilization processing: jute staple fiber and bamboo charcoal staple fiber are mixed, above-mentioned total weight of fiber 10-20% is added Water, ultrasonic vibration 20-30s pours into high steam pot mesohigh and boils 5-10min after having shaken;
(4) it mixes: by animal wool staple fiber, diatomite, graphene, surfactant and step (2) permeabilization processing Fiber afterwards is stirred mixed processing;
(5) mixed raw material shredding: is subjected to shredding by opener;
(6) it combs: the mixture after shredding is subjected to fiber combing;
(7) finished product: graphene biology diatom composite fibre will be made by spinning machine after step (6) combing.
Application of the graphene biology diatom composite fibre on household items, can specifically apply in mattress, sand Hair, on cushion and clothes, bedding, wall Soft Roll, on car room Soft Roll.
A kind of graphene biology diatom composite fibre mattress, including mattress body, the mattress body is from top to bottom successively Including elastic layer, graphene biology diatom composite fibre layer and skin-friendly layer, the graphene biology diatom composite fibre layer is by passing through Line and weft weave.
Preferably, the elastic layer includes that the tight of the cylindrical-shaped structure in dust-proof fastening cover is covered and be set to dust-proof fasten Several polyurethane foam elastics of solid matter column, are fixed between several described polyurethane foam elastics by fastener Together, the polyurethane foam elastic can be vertically or horizontally arranged successively.
Preferably, a kind of graphene biology diatom composite fibre mattress according to claim 8 stated, feature Be: the graphene biology diatom composite fibre layer with a thickness of 3-8cm, the skin-friendly layer with a thickness of 2-5cm.
Sponge, latex cotton, hard cotton, nylon fiber, plant fiber, animal origin etc. can be made graphite by the present invention Alkene, diatom, electrical stone material are used for mattress inner cushion layer.Or it is made into bedding and is placed on above mattress and use.
The beneficial effects obtained by the present invention are as follows are as follows:
1. graphene biology diatom composite fibre in the present invention, in Arenga engleri Beccari coconut palm palm fibre staple fiber, jute staple fiber, the short fibre of bamboo charcoal Dimension on the basis of animal wool staple fiber, is added with graphene and diatomite in component, increase purification air, eliminate peculiar smell, Damping, releasing negative oxygen ion, many beneficial effects not being covered with dust are breathed, function is more complete, and the scope of application is more extensive.
2. graphene biology diatom composite fibre of the invention is during preparation, first by the short fibre of original Arenga engleri Beccari coconut palm palm fibre Dimension carries out decolorization, takes off the brownish red of itself, then carries out subsequent mixing again, and preparation method is simple, and product is whole Color is more beautiful.
3. the graphene biology diatom composite fibre mattress construction in the present invention is simple, the graphene biology diatom in mattress Composite fibre layer not only has an elastic reaction, also have moisture-proof, anti-corrosion, indeformable, Anti-moth-eating, it is ventilative, antibacterial, purify air, Eliminate peculiar smell, breathing damping, releasing negative oxygen ion, many beneficial effects not being covered with dust.The elastic layer of mattress in the present invention Using polyurethane foam elastic, polyurethane foam elastic has more micropores, resilience strong, many advantages, such as being unlikely to deform, The service life of mattress can be greatly prolonged.
Embodiment
Embodiment 1:
A kind of preparation method of graphene biology diatom composite fibre, includes the following steps:
(1) raw material is weighed: according to parts by weight, 50 parts of Arenga engleri Beccari coconut palm palm fibre staple fiber, 10 parts of jute staple fiber, bamboo charcoal staple fiber 10 Part, 5 parts of animal wool staple fiber, 10 parts of graphene, 10 parts of diatomite, 1 part of tourmaline powder, 5 parts of surfactant;
(2) hydrogenperoxide steam generator and sodium hydroxide solution the pretreatment of Arenga engleri Beccari coconut palm palm fibre staple fiber: are added to Arenga engleri Beccari coconut palm palm fibre In staple fiber, 40 DEG C of reaction temperature, ultrasonic vibration 60s, filtering is rinsed, drying;
(3) permeabilization processing: jute staple fiber and bamboo charcoal staple fiber are mixed, above-mentioned total weight of fiber 10% is added Water, ultrasonic vibration 20s pour into high steam pot mesohigh and boil 5min after having shaken;
(4) it mixes: by animal wool staple fiber, diatomite, graphene, surfactant and step (2) permeabilization processing Fiber afterwards is stirred mixed processing;
(5) mixed raw material shredding: is subjected to shredding by opener;
(6) it combs: the mixture after shredding is subjected to fiber combing;
(7) finished product: graphene biology diatom composite fibre will be made by spinning machine after step (6) combing.
Application of the graphene biology diatom composite fibre on household items, can specifically apply in mattress, sand Hair, on cushion and clothes, bedding, wall Soft Roll, on car room Soft Roll.
A kind of graphene biology diatom composite fibre mattress, including mattress body, the mattress body is from top to bottom successively Including elastic layer, graphene biology diatom composite fibre layer and skin-friendly layer, the graphene biology diatom composite fibre layer is by passing through Line and weft weave.
Embodiment 2:
A kind of preparation method of graphene biology diatom composite fibre, includes the following steps:
(1) raw material is weighed: according to parts by weight, 60 parts of Arenga engleri Beccari coconut palm palm fibre staple fiber, 5-10 parts of jute staple fiber, bamboo charcoal staple fiber 10 parts, 10 parts of animal wool staple fiber, 3 parts of graphene, 5 parts of diatomite, 1 part of tourmaline powder, 3 parts of surfactant;
(2) hydrogenperoxide steam generator and sodium hydroxide solution the pretreatment of Arenga engleri Beccari coconut palm palm fibre staple fiber: are added to Arenga engleri Beccari coconut palm palm fibre In staple fiber, 60 DEG C of reaction temperature, ultrasonic vibration 120s, filtering is rinsed, drying;
(3) permeabilization processing: jute staple fiber and bamboo charcoal staple fiber are mixed, above-mentioned total weight of fiber 20% is added Water, ultrasonic vibration 30s pour into high steam pot mesohigh and boil 10min after having shaken;
(4) it mixes: by animal wool staple fiber, diatomite, graphene, surfactant and step (2) permeabilization processing Fiber afterwards is stirred mixed processing;
(5) mixed raw material shredding: is subjected to shredding by opener;
(6) it combs: the mixture after shredding is subjected to fiber combing;
(7) finished product: graphene biology diatom composite fibre will be made by spinning machine after step (6) combing.
Application of the graphene biology diatom composite fibre on household items, can specifically apply in mattress, sand Hair, on cushion and clothes, bedding, wall Soft Roll, on car room Soft Roll.
A kind of graphene biology diatom composite fibre mattress, including mattress body, the mattress body is from top to bottom successively Including elastic layer, graphene biology diatom composite fibre layer and skin-friendly layer, the graphene biology diatom composite fibre layer is by passing through Line and weft weave.
Embodiment 3:
A kind of preparation method of graphene biology diatom composite fibre, includes the following steps:
(1) raw material is weighed: according to parts by weight, 50-60 parts of Arenga engleri Beccari coconut palm palm fibre staple fiber, 8 parts of jute staple fiber, bamboo charcoal staple fiber 7 parts, 8 parts of animal wool staple fiber, 4 parts of graphene, 5 parts of diatomite, 1.5 parts of tourmaline powder, 3 parts of surfactant;
(2) hydrogenperoxide steam generator and sodium hydroxide solution the pretreatment of Arenga engleri Beccari coconut palm palm fibre staple fiber: are added to Arenga engleri Beccari coconut palm palm fibre In staple fiber, 50 DEG C of reaction temperature, ultrasonic vibration 100s, filtering is rinsed, drying;
(3) permeabilization processing: jute staple fiber and bamboo charcoal staple fiber are mixed, above-mentioned total weight of fiber 15% is added Water, ultrasonic vibration 25s pour into high steam pot mesohigh and boil 10min after having shaken;
(4) it mixes: by animal wool staple fiber, diatomite, graphene, surfactant and step (2) permeabilization processing Fiber afterwards is stirred mixed processing;
(5) mixed raw material shredding: is subjected to shredding by opener;
(6) it combs: the mixture after shredding is subjected to fiber combing;
(7) finished product: graphene biology diatom composite fibre will be made by spinning machine after step (6) combing.
Application of the graphene biology diatom composite fibre on household items, can specifically apply in mattress, sand Hair, on cushion and clothes, bedding, wall Soft Roll, on car room Soft Roll.
A kind of graphene biology diatom composite fibre mattress, including mattress body, the mattress body is from top to bottom successively Including elastic layer, graphene biology diatom composite fibre layer and skin-friendly layer, the graphene biology diatom composite fibre layer is by passing through Line and weft weave.
Embodiment 4:
A kind of preparation method of graphene biology diatom composite fibre, includes the following steps:
(1) raw material is weighed: according to parts by weight, 58 parts of Arenga engleri Beccari coconut palm palm fibre staple fiber, 7 parts of jute staple fiber, bamboo charcoal staple fiber 7 Part, 8 parts of animal wool staple fiber, 2 parts of graphene, 4 parts of diatomite, 1.8 parts of tourmaline powder, 2-5 parts of surfactant;
(2) hydrogenperoxide steam generator and sodium hydroxide solution the pretreatment of Arenga engleri Beccari coconut palm palm fibre staple fiber: are added to Arenga engleri Beccari coconut palm palm fibre In staple fiber, 50 DEG C of reaction temperature, ultrasonic vibration 100s, filtering is rinsed, drying;
(3) permeabilization processing: jute staple fiber and bamboo charcoal staple fiber are mixed, above-mentioned total weight of fiber 18% is added Water, ultrasonic vibration 25s pour into high steam pot mesohigh and boil 6min after having shaken;
(4) it mixes: by animal wool staple fiber, diatomite, graphene, surfactant and step (2) permeabilization processing Fiber afterwards is stirred mixed processing;
(5) mixed raw material shredding: is subjected to shredding by opener;
(6) it combs: the mixture after shredding is subjected to fiber combing;
(7) finished product: graphene biology diatom composite fibre will be made by spinning machine after step (6) combing.
Application of the graphene biology diatom composite fibre on household items, can specifically apply in mattress, sand Hair, on cushion and clothes, bedding, wall Soft Roll, on car room Soft Roll.
A kind of graphene biology diatom composite fibre mattress, including mattress body, the mattress body is from top to bottom successively Including elastic layer, graphene biology diatom composite fibre layer and skin-friendly layer, the graphene biology diatom composite fibre layer is by passing through Line and weft weave.
Embodiment 5:
The present embodiment further adds medical stone powder.
A kind of preparation method of graphene biology diatom composite fibre, includes the following steps:
(1) raw material is weighed: according to parts by weight, 59 parts of Arenga engleri Beccari coconut palm palm fibre staple fiber, 7 parts of jute staple fiber, bamboo charcoal staple fiber 7 Part, 7 parts of animal wool staple fiber, 7 parts of graphene, 8 parts of diatomite, tourmaline powder 1.8 parts, 1.5 parts medical stone powders, surfactants 2-5 parts;
(2) hydrogenperoxide steam generator and sodium hydroxide solution the pretreatment of Arenga engleri Beccari coconut palm palm fibre staple fiber: are added to Arenga engleri Beccari coconut palm palm fibre In staple fiber, 60 DEG C of reaction temperature, ultrasonic vibration 60s, filtering is rinsed, drying;
(3) permeabilization processing: jute staple fiber and bamboo charcoal staple fiber are mixed, above-mentioned total weight of fiber 10% is added Water, ultrasonic vibration 26s pour into high steam pot mesohigh and boil 5min after having shaken;
(4) it mixes: by animal wool staple fiber, diatomite, graphene, surfactant and step (2) permeabilization processing Fiber afterwards is stirred mixed processing;
(5) mixed raw material shredding: is subjected to shredding by opener;
(6) it combs: the mixture after shredding is subjected to fiber combing;
(7) finished product: graphene biology diatom composite fibre will be made by spinning machine after step (6) combing.
Application of the graphene biology diatom composite fibre on household items, can specifically apply in mattress, sand Hair, on cushion and clothes, bedding, wall Soft Roll, on car room Soft Roll.
A kind of graphene biology diatom composite fibre mattress, including mattress body, the mattress body is from top to bottom successively Including elastic layer, graphene biology diatom composite fibre layer and skin-friendly layer, the graphene biology diatom composite fibre layer is by passing through Line and weft weave.
Embodiment 6:
Sponge, latex cotton, hard cotton, nylon fiber, plant fiber, animal origin etc. can be made graphite by the present invention Alkene, diatom, electrical stone material are used for mattress inner cushion layer.Or it is made into bedding and is placed on above mattress and use.Graphite in the present invention Alkene biology diatom composite fibre mattress construction is simple, and the graphene biology diatom composite fibre layer in mattress not only has elastic work With, also have moisture-proof, anti-corrosion, indeformable, Anti-moth-eating, it is ventilative, antibacterial, purification air, eliminate peculiar smell, breathing damping, release bear Oxonium ion, many beneficial effects not being covered with dust.The elastic layer of mattress in the present invention uses polyurethane foam elastic, poly- ammonia Ester foaming elastic has more micropores, resilience strong, and many advantages, such as being unlikely to deform, can greatly prolong mattress uses the longevity Life.Applicants have discovered that graphene and tourmaline proportion under specified conditions, can generate good health-care effect, especially to height Blood pressure has unexpected improvement.
Take healthy Wistar rat 50, male and female and half, 200~250g of weight, conventinal breeding, free feeding, drinking-water one It is observed after week, it is without exception, two groups: 6 are randomly divided into as Normal group, 44 are modeling group, and two groups are raised with basal feed, Wherein modeling group adds 0.9% sodium chloride solution in basal feed, i.e., feed with high salt.Rat blood pressure and weight are measured weekly, After obviously increasing and stablize to the 6th week or so animal blood pressure, start subsequent experimental study.
30 are selected from the successful Hypertensive Rats of modeling, is equally divided into 5 groups, every group 6.
Simulation Hypertension intervention method: being made into 3 cm thicks with the graphene biology diatom composite fibre of embodiment 1-5, and 50 Centimetres * 50 centimetres of cushion, is placed in 50 centimetres * 50 centimetres * 50 centimetres of model cage and is paved with, 8 points to second of every night Its 6:00 AM, for every mouse at model cage 10 hours, other times observed mattress to hypertension model in common cage The influence of mouse.
Periodically the activity condition of each experimental group rat is examined daily, and records the food-intake and water inlet of rat Amount, the same time weighs rat body weight and measurement rat blood pressure daily.Rat tail artery blood pressure is measured with method of indirectly measuring blood pressure, and is remembered Record measurement result.Rejecting abnormalities numerical value, all experimental datas are all made of SPSS17.0 and are analyzed, as a result with " mean ± mark It is quasi- poor " it indicates, t inspection is carried out to data.
The influence of Hypertensive Rats systolic pressure is as shown in the table:
Table 1
Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5
Initial blood pressure 169±9 167±10 168±9 170±7 168±8
7th day 158±10 159±12 153±9 158±6 132±9
30th day 148±11 146±12 148±9 146±8 129±7
As it can be seen that the systolic pressure of model group can be significantly reduced in mattress of the invention.Applicants have discovered that under specified conditions Graphene and tourmaline proportion (other match the effect that can't be significantly improved hypertension), can generate good health care effect Fruit especially has unexpected improvement to hypertension.
The influence of Hypertensive Rats diastolic pressure is as shown in the table:
Table 2
Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5
Initial blood pressure 100±11 99±10 101±7 98±7 100±8
7th day 83±9 85±11 88±12 89±7 72±13
30th day 80±11 86±8 87±9 88±7 64±9
As it can be seen that the diastolic pressure of model group can be significantly reduced in mattress of the invention.Applicants have discovered that under specified conditions Graphene and tourmaline proportion (can generate good health-care effect, especially have unexpected improvement to hypertension, add Effect is more preferable after entering the medical stone of special ratios.
In the description of this specification, reference term " one embodiment ", " some embodiments ", " example ", " specifically show The description of example " or " some examples " etc. means specific features, structure, material or spy described in conjunction with this embodiment or example Point is included at least one embodiment or example of the invention.In the present specification, schematic expression of the above terms are not Centainly refer to identical embodiment or example.Moreover, particular features, structures, materials, or characteristics described can be any One or more embodiment or examples in can be combined in any suitable manner.
Although an embodiment of the present invention has been shown and described, it will be understood by those skilled in the art that: not A variety of change, modification, replacement and modification can be carried out to these embodiments in the case where being detached from the principle of the present invention and objective, this The range of invention is defined by the claims and their equivalents.

Claims (10)

1. a kind of graphene biology diatom composite fibre, including following parts by weight product form: Arenga engleri Beccari coconut palm palm fibre staple fiber 50-60 Part, 5-10 parts of jute staple fiber, 5-10 parts of bamboo charcoal staple fiber, 5-10 parts of animal wool staple fiber, 1-10 parts of graphene, diatomite 2- 10 parts, 1-2 parts of tourmaline powder, 2-5 parts of surfactant.
2. composite fibre described in claim 1, it is characterised in that:
The particle size range of the diatomite is at 35~60 μm.
3. composite fibre described in claim 1, it is characterised in that:
The animal wool staple fiber is wool staple fiber.
4. composite fibre described in claim 1, it is characterised in that:
The surfactant is neopelex, in glycerin monostearate, fatty acid sorbitan, polysorbate It is at least one.
5. a kind of preparation method of graphene biology diatom composite fibre, includes the following steps:
(1) raw material is weighed: according to parts by weight, 50-60 parts of Arenga engleri Beccari coconut palm palm fibre staple fiber, 5-10 parts of jute staple fiber, bamboo charcoal staple fiber 5-10 parts, 5-10 parts of animal wool staple fiber, 1-10 parts of graphene, 2-10 parts of diatomite, 1-2 parts of tourmaline powder, surfactant 2-5 parts;
(2) hydrogenperoxide steam generator and sodium hydroxide solution the pretreatment of Arenga engleri Beccari coconut palm palm fibre staple fiber: are added to the short fibre of Arenga engleri Beccari coconut palm palm fibre In dimension, 40-60 DEG C of reaction temperature, ultrasonic vibration 60-120s, filtering is rinsed, drying;
(3) permeabilization processing: jute staple fiber and bamboo charcoal staple fiber being mixed, the water of above-mentioned total weight of fiber 10-20% is added, Ultrasonic vibration 20-30s pours into high steam pot mesohigh and boils 5-10min after having shaken;
(4) it mixes: after animal wool staple fiber, diatomite, graphene, surfactant and step (2) permeabilization processing Fiber is stirred mixed processing;
(5) mixed raw material shredding: is subjected to shredding by opener;
(6) it combs: the mixture after shredding is subjected to fiber combing;
(7) finished product: graphene biology diatom composite fibre will be made by spinning machine after step (6) combing.
6. -4 any a kind of application of graphene biology diatom composite fibre according to claim 1, it is characterised in that: described Application of the graphene biology diatom composite fibre on household items, can specifically apply on mattress, sofa, cushion, with And on clothes, bedding, wall Soft Roll, car room Soft Roll.
7. a kind of graphene biology diatom composite fibre mattress, it is characterised in that: including mattress body, the mattress body is under To upper successively including elastic layer, the described in any item graphene biology diatom composite fibre layers of claim 1-4 and skin-friendly layer, institute Graphene biology diatom composite fibre layer is stated to be woven by warp and weft.
8. a kind of graphene biology diatom composite fibre mattress according to claim 7, it is characterised in that: the elastic layer Several compact arranged polyurethane foam bullets including dust-proof fastening cover and the cylindrical-shaped structure being set in dust-proof fastening cover Property column is fixed together between several described polyurethane foam elastics by fastener, the polyurethane foam elastic It can vertically or horizontally be arranged successively.
9. a kind of graphene biology diatom composite fibre mattress according to claim 7, it is characterised in that: the graphene Biological diatom composite fibre layer with a thickness of 3-8cm, the skin-friendly layer with a thickness of 2-5cm.
10. a kind of preparation method of graphene biology diatom composite fibre, includes the following steps:
(1) weigh raw material: according to parts by weight, 59 parts of Arenga engleri Beccari coconut palm palm fibre staple fiber, 7 parts of bamboo charcoal staple fiber, is moved 7 parts of jute staple fiber 7 parts of object hair staple fiber, 7 parts of graphene, 8 parts of diatomite, tourmaline powder 1.8 parts, 1.5 parts medical stone powders, surfactant 2-5 Part;
(2) hydrogenperoxide steam generator and sodium hydroxide solution the pretreatment of Arenga engleri Beccari coconut palm palm fibre staple fiber: are added to the short fibre of Arenga engleri Beccari coconut palm palm fibre In dimension, 60 DEG C of reaction temperature, ultrasonic vibration 60s, filtering is rinsed, drying;
(3) permeabilization processing: jute staple fiber and bamboo charcoal staple fiber being mixed, the water of above-mentioned total weight of fiber 10% is added, and surpassed 26s is swung in acoustic shock, and high steam pot mesohigh is poured into after having shaken and boils 5min;
(4) it mixes: after animal wool staple fiber, diatomite, graphene, surfactant and step (2) permeabilization processing Fiber is stirred mixed processing;
(5) mixed raw material shredding: is subjected to shredding by opener;
(6) it combs: the mixture after shredding is subjected to fiber combing;
(7) finished product: graphene biology diatom composite fibre will be made by spinning machine after step (6) combing.
CN201811085303.2A 2018-09-18 2018-09-18 A kind of graphene biology diatom composite fibre and its preparation method and application Pending CN109252247A (en)

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