CN104004374A - Bedding article capable of releasing anions - Google Patents

Bedding article capable of releasing anions Download PDF

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Publication number
CN104004374A
CN104004374A CN201410233684.XA CN201410233684A CN104004374A CN 104004374 A CN104004374 A CN 104004374A CN 201410233684 A CN201410233684 A CN 201410233684A CN 104004374 A CN104004374 A CN 104004374A
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Prior art keywords
negative ion
bedclothes
propellant
ion propellant
coupling agent
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CN201410233684.XA
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Chinese (zh)
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CN104004374B (en
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不公告发明人
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Quanzhou Xi Bao Home Technology Co., Ltd.
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Quanzhou Heng Ang Trade Co Ltd
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Abstract

The invention discloses a bedding article capable of releasing anions. 1-3% of anion generation agent is added to a foamed material, and the anion generation agent comprises the following components in parts by weight: 10-20 parts of tourmaline ultra-fine powder, 1-2 parts of TiO2 photocatalyst and 0.5-1.5 parts of silane coupling agent. The invention discloses a method for preparing a coupling anion generation agent. The method mainly comprises the following steps: enabling the tourmaline ultra-fine powder to react with a coupling agent under the action of the TiO2 photocatalyst, generating the coupling anion generation agent; mixing the coupled anion generation agent with the foamed material for manufacturing the bedding article, so as to prepare the bedding article by adopting the conventional method. The tourmaline capable of releasing anions is added to the foamed material, and is in an ultra-fine powder state, and the tourmaline is added to the foamed material, so that the specific surface area is large, the manufactured product can release more anions, and physical health is facilitated. The bedding article is simple in production process when health is brought about for people, and is applicable to large-scale popularization and application.

Description

A kind of bedclothes that can anion releasing
Technical field
The invention belongs to bedclothes field, be specifically related to a kind of bedclothes that can anion releasing.
Background technology
The destruction of the environment such as topsoil has been accelerated in the behind of modern social civilization development, and in the body that human body should be held, the restorer of adjustment also fails.According to the data of U.S.'s statistics, 20 beginnings of the century, in atmosphere, the ratio of positive ion and negative ion is 1:1.2, but present ratio is 1.2:1, has destroyed natural ionic equilibrium completely.The increase of positive ion is the progress of modern civilization and the result of pursuing comfortable life, the various coal smokes that produce as automobile exhaust gas, factory, the pollution while burning away the refuse, uses pollution, air-conditioning and the refrigerator of agricultural chemicals and organic compound to make hertzian wave that depletion of the ozone layer, various household electrical appliance produce etc.
Therefore negative ion problem more and more obtains people's concern.In medical circle, it is the effective means that has killing pathogenic bacteria and purify air that negative ion is identified.Negative ion is to 7 of human body systems, and nearly 30 various diseases have inhibition, alleviation and auxiliary therapeutic action, especially more obvious to the health-care effect of human body.Negative ion is known as in medical circle " air VITAMIN ", and it is to neural system, cardiovascular systems, and blood system and respiratory system all have a certain impact, in addition, and effect calm, hypnosis that negative ion also has.
Suck appropriate negative ion every day, of great advantage to health: make people full of vitality, Ginseng Extract and burnout, increase work efficiency; Improve sleep, eliminate neurasthenia; Reduce disease incidence, preventing cold and respiratory tract disease; Improve the symptom of the heart, cerebrovascular disease; Prevention air conditioning disease.
For the content of the middle negative ion of bettering people's living environment, those skilled in the art has done a large amount of effort, as:
For a kind of cushion that can produce negative ion, have massage effect is provided, application number is 201120331572.X, the Chinese patent that patent name is " negative ion massaging seat cushion " discloses negative ion massaging seat cushion: it comprises negative ion pearl, lead-in wire, on negative ion pearl, fairlead is set, lead-in wire connects the some negative ion pearls of braiding and forms cushion.The diameter of described negative ion pearl is 3~15 millimeters.
For the negative ion health mattress of a kind of simple and practical, safety and environmental protection, long service life, and health care useful to people is provided.Application number is 201220126223.9, and the Chinese patent that patent name is " a kind of negative ion health mattress " discloses a kind of negative ion health mattress: described negative ion band is provided with mineral substance anionic particle.Mineral substance negative ion health mattress is used supersonic machine producing the mineral substance such as mineral substance negative ion powder, then with medical adhesive-bonded fabric, packs and form, and with cotton cloth, mineral substance bag is combined into cloth pad.Make spring net and balance net, the cloth pad that can produce mineral substance negative ion is placed on above spring net, and heat and friction generation negative ion by human body, finally used fabric cloth packing, and with slide fastener convenient " negative ion mineral " displacement, extend its work-ing life.
In order to provide a kind of, produce vibration and negative ion, vertebra is remained on to the most comfortable state, good ventilation property is provided and has the pillow of sanatory additional function by using pillow.Application number is 200680000304.1, the Chinese patent that patent name is " producing the pillow of vibration and negative ion " discloses the pillow that produces vibration and negative ion: it comprises negative ion production part, wherein liner coating member is formed on the top of negative ion generation liner and on liner coating member, forms bonding part to be connected to pillow, and described pillow structure is for half round post is to hold described generation of vibration parts and negative ion production part.Situation is that described negative ion production part forms banded liner to join the bonding part being formed in pillow body to, and described liner is coated with the porous material that can control negative ion generation.The powder that the banded liner that another kind of situation is described negative ion production part produces liquid phase negative ion by mixing forms gasket shapes.
For functional electric heating pad with health role is provided, pursue higher quality of life, the theory of environment protection health and up-to-date development in science and technology are introduced into life staying idle at home, application number is 200620003500.1, patent name is " electric pad
" Chinese patent a kind of electric pad is disclosed; comprise the cover made of braided material or analogous material and in its top, bottom or side the mosaic coating coated with fiber and foam materials, characterized by further comprising on its cover or in mosaic coating with can anion releasing and the accessory of function agglomerate, function bag or the functional layer of the tourmalinite powder of far infrared rays.The function agglomerate of described tourmalinite powder, is comprised of ware shape plastic cement buckle closure and particulate state tourmalinite powder, and ware shape plastic cement buckle closure is fixed on cover by binding agent or sweating soldering.The function bag of described tourmalinite powder is comprised of fabric bag and the particulate state tourmalinite powder filling wherein, and function bag fixes on top or the side of mosaic coating by making latrine.The functional layer of described tourmalinite powder refers to through filamentary material and/or foam materials in the described mosaic coating of starching or dip treating and energy anion releasing.
Application number is 200920218659.9, the Chinese patent that patent name is " a kind of health care bed mattress " discloses a kind of health care bed mattress, comprise: pad body and the skin section that is arranged at the bar grating structure on this pad body, wherein, the skin section of described grating structure comprises a plurality of grid that contain jade particle; Described jade particle is to be fixed in described grid by the packing department on it, and is evenly distributed in described grid.Adopt jade particle effectively to conduct heat and heat conduction evenly, simultaneously can anion releasing by jade particle, improved user's experience degree.
Application number is 201120088498.3; the Chinese patent that patent name is " a kind of bamboo charcoal back cushion " discloses a kind of bamboo charcoal back cushion, comprises weighting material and non-woven fabrics, described non-woven fabrics outer cladding layer protective layer; described protective layer is bamboo-carbon fibre layer, and described weighting material is bamboo charcoal particle.The present invention adopts bamboo charcoal particle as weighting material; adopt bamboo-carbon fibre as protective layer simultaneously; make this back cushion not only there is soft comfortable effect; the function also with deodorizing, moisture absorption, far infrared rays and anion releasing, makes that user is also healthy when obtaining comfort has also obtained protection.
Application number is 200720096953.8, the Chinese patent that patent name is " Tourmaline summer cool mattress " discloses Tourmaline summer cool mattress, employing tourmalinite is weighting material, make product there is far-infrared transmitting function and anion emission function, more owing to being to adopt particulate state to increase surface-area, improved far infrared and anion emission effect, increased moisture absorption and inhaled ripe effect.
Application number is 201220532721.3, the Chinese patent that patent name is " a kind of sponge matress with moisture absorption antibacterial and deodouring function " discloses a kind of sponge matress with moisture absorption antibacterial and deodouring function, comprise mattress body and the mattress cover that is covered in mattress body surface, mattress body comprises the first spongy layer and second spongy layer of upper and lower superimposed setting, described the first spongy layer is environmental protection memory sponge layer, the second spongy layer is high-rebound polyurethane spongy layer, the first spongy layer a plurality of pores that gather, fixedly inlay the activated carbon granule extracting from bamboo charcoal in described pore.This structure sponge matress, in environmental protection memory sponge layer, activated carbon granule has superpower adsorption, and the negative ion of its generation can play eliminates the unpleasant odor of human body, the humidity that regulates bedding, clean rooms air etc., also has effect antibacterial, deodorizing simultaneously.
Above patent is mainly to carry out simple structural combining by producing article and the bedclothes of negative ion, although also can reach the object of the middle negative ion of bettering people's living environment, but, the article that can produce negative ion are fixed in articles for use inhomogeneous in bed, easily separated with bedclothes, cause product life to shorten, the defect such as negative ion burst size is few.
Summary of the invention
In order to solve the deficiencies in the prior art, the object of this invention is to provide a kind of negative ion propellant of anion releasing and the material of making bedclothes can combination, negative ion propellant is uniformly distributed in a kind of bedclothes that can anion releasing in the material of making bedclothes.
In order to achieve the above object, the present invention is by the following technical solutions:
A kind of bedclothes that can anion releasing, described bedclothes are by foaming material shaped, described foam material comprises base material and negative ion propellant, described negative ion propellant is dispersed in described base material, and described negative ion propellant surface is carried out the silane coupled surface that makes with silane coupling agent and had oil loving negative ion propellant; In described foam material, the shared weight percent of negative ion propellant is 1-3%, and composition and the weight percent of each composition in negative ion propellant that described negative ion propellant comprises are as follows:
Tourmalinite super-fine powder 10-20 part;
TiO 2photocatalyst 1-2 part;
0.5 ~ 1.5 part of silane coupling agent.
Described foam material is rubber or plastics.
Described silane coupling agent is KH-550.
The particle diameter of described negative ion propellant is 100 nm-6000 nm.
It is characterized in that: TiO 2the particle diameter of photocatalyst is 100 nm-1000 nm.
A preparation method for bedclothes that can anion releasing, it comprises the following steps:
1) by tourmalinite super-fine powder and TiO 2photocatalyst mixes by weight percentage, and high-speed mixing 1-3 hour, obtains uniform compound;
2) compound step 1) being obtained is warming up to 115-125 ° of C, adds silane coupling agent high-speed stirring reaction 0.5-1 hour;
3) reaction solution is cooled to 20 ~ 25 ° of C, obtains through silane coupled negative ion propellant finished product.
In the present invention, tourmalinite super-fine powder has the effect of anion releasing, and because tourmalinite is ultra tiny state, specific surface area is larger, in unit surface, can discharge more negative ion.The present invention also can add other negative ion propellant as required, as strange ice stone, diatomite etc.
TiO in the present invention 2photocatalyst has the tourmalinite of exciting anion releasing effect.
In the present invention, silane resin acceptor kh-550 is commercially available prod.
In the present invention, because negative ion propellant particle is hydrophilic, be difficult for being combined with base material, after coupling modification, negative ion propellant surface becomes lipophilicity, negative ion propellant is combined tightr with base material, to keep the whole better mechanical property of foam material.
In articles for use, for example mattress in its manufacturing processed, adds after negative ion propellant of the present invention in foam material in bed, according to normal working method processing.
A kind of bedclothes that can anion releasing of the present invention, by in foam material, add can anion releasing tourmalinite, and this tourmalinite is super-fine powder state, joined in foam material, its specific surface area is large, the product of manufacturing can discharge more negative ion, is conducive to healthy.The present invention for people, bring healthy in, production technique is simple, is applicable to large-scale promotion application.
Embodiment
Be below several embodiments of the present invention, further illustrate the present invention, but the present invention is not limited only to this.
A kind of bedclothes that can anion releasing of the present invention, described bedclothes are by foaming material shaped, described foam material comprises base material and negative ion propellant, described negative ion propellant is dispersed in described base material, and described negative ion propellant surface is carried out the silane coupled surface that makes with silane coupling agent and had oil loving negative ion propellant; In described foam material, the shared weight percent of negative ion propellant is 1-3%, and composition and the weight percent of each composition in negative ion propellant that described negative ion propellant comprises are as follows:
Tourmalinite super-fine powder 10-20 part;
TiO 2photocatalyst 1-2 part;
0.5 ~ 1.5 part of silane coupling agent.
Described foam material is rubber or plastics.
Described silane coupling agent is KH-550.
The particle diameter of described negative ion propellant is 100 nm-6000 nm.
It is characterized in that: TiO 2the particle diameter of photocatalyst is 100 nm-1000 nm.
A preparation method for bedclothes that can anion releasing, it comprises the following steps:
1) by tourmalinite super-fine powder and TiO 2photocatalyst mixes by weight percentage, and high-speed mixing 1-3 hour, obtains uniform compound;
2) compound step 1) being obtained is warming up to 115-125 ° of C, adds silane coupling agent high-speed stirring reaction 0.5-1 hour;
3) reaction solution is cooled to 20 ~ 25 ° of C, obtains through silane coupled negative ion propellant finished product.
Embodiment 1
Take 10 parts of tourmalinite super-fine powder; TiO 21 part of photocatalyst; 0.5 part of silane coupling agent;
By tourmalinite super-fine powder and TiO 2photocatalyst mixes by weight percentage, high-speed stirring 1-3 hour;
Compound is warming up to 115-125 ° of C, adds silane coupling agent, high-speed stirring reaction 0.5-1 hour;
Reaction solution is cooled to 20 ~ 25 ° of C, obtains through silane coupled negative ion propellant finished product;
Negative ion propellant finished product is evenly mixed with foam material, according to the conventional production method of mattress, produce mattress.
Embodiment 2
Take 20 parts of tourmalinite super-fine powder; 2 parts of TiO2 photocatalysts; 1.5 parts of silane coupling agents;
Method described in employing embodiment 1, can make negative ion propellant finished product;
Negative ion propellant finished product is evenly mixed with pillow material, according to the conventional production method of pillow, produce pillow.
Embodiment 3
Take 15 parts of tourmalinite super-fine powder; 1.5 parts of TiO2 photocatalysts; 1 part of silane coupling agent;
Method described in employing embodiment 1, can make negative ion propellant finished product;
By negative ion propellant finished product with by core material, evenly mixed, according to the conventional production method of quilt, produce quilt.
Embodiment 4
Take 0 part of tourmalinite super-fine powder; 0 part of TiO2 photocatalyst; 0 part of silane coupling agent;
Method described in employing embodiment 1, can make negative ion propellant finished product;
Negative ion propellant finished product is evenly mixed with foam material, according to the conventional production method of mattress, produce mattress.
Embodiment 5
Take 0 part of tourmalinite super-fine powder; 0 part of TiO2 photocatalyst; 0 part of silane coupling agent;
Method described in employing embodiment 1, can make negative ion propellant finished product;
Negative ion propellant finished product is evenly mixed with pillow material, according to the conventional production method of pillow, produce pillow.
Embodiment 6
Take 0 part of tourmalinite super-fine powder; 0 part of TiO2 photocatalyst; 0 part of silane coupling agent;
Method described in employing embodiment 1, can make negative ion propellant finished product;
By negative ion propellant finished product with by core material, evenly mixed, according to the conventional production method of quilt, produce quilt.
Table 1 is the every cm of bedclothes that the embodiment of the present invention 1 ~ 6 is produced 3anion concentration.
Every cm in environment before and after table 1 bedclothes of the present invention are used 3anion concentration contrast
? Mattress Pillow Quilt
Before use 231(embodiment 4) 109(embodiment 5) 125(embodiment 6)
After use 2651(embodiment 1) 1326(embodiment 2) 1534(embodiment 3)
From table 1, can find out, use bedclothes of the present invention, in environment, anion concentration exceeds more than 10 times before using.

Claims (6)

  1. One kind can anion releasing bedclothes, described bedclothes are by foaming material shaped, it is characterized in that: described foam material comprises base material and negative ion propellant, described negative ion propellant is dispersed in described base material, and described negative ion propellant surface is carried out the silane coupled surface that makes with silane coupling agent and had oil loving negative ion propellant; In described foam material, the shared weight percent of negative ion propellant is 1-3%, and composition and the weight percent of each composition in negative ion propellant that described negative ion propellant comprises are as follows:
    Tourmalinite super-fine powder 10-20 part;
    TiO 2photocatalyst 1-2 part;
    0.5 ~ 1.5 part of silane coupling agent.
  2. 2. a kind of bedclothes that can anion releasing according to claim 1, is characterized in that: described foam material is rubber or plastics.
  3. 3. a kind of bedclothes that can anion releasing according to claim 1, is characterized in that: described silane coupling agent is KH-550.
  4. 4. a kind of bedclothes that can anion releasing according to claim 1, is characterized in that: the particle diameter of described negative ion propellant is 100 nm-6000 nm.
  5. 5. a kind of bedclothes that can anion releasing according to claim 1, is characterized in that: TiO 2the particle diameter of photocatalyst is 100 nm-1000 nm.
  6. 6. the preparation method of a kind of bedclothes that can anion releasing as claimed in claim 1, is characterized in that: it comprises the following steps:
    1) by tourmalinite super-fine powder and TiO 2photocatalyst mixes by weight percentage, and high-speed mixing 1-3 hour, obtains uniform compound;
    2) compound step 1) being obtained is warming up to 115-125 ° of C, adds silane coupling agent high-speed stirring reaction 0.5-1 hour;
    3) reaction solution is cooled to 20 ~ 25 ° of C, obtains through silane coupled negative ion propellant finished product.
CN201410233684.XA 2014-05-30 2014-05-30 It is a kind of to discharge the bedding of anion Active CN104004374B (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104958025A (en) * 2015-06-08 2015-10-07 中山市品汇创新专利技术开发有限公司 with far-infrared health-care function
CN104983350A (en) * 2015-06-08 2015-10-21 中山艺展装饰工程有限公司 Novel multifunctional towel tube provided with plush doll
CN105648743A (en) * 2015-12-24 2016-06-08 天津工业大学 Preparation method of tourmalinite modified nanometer titanium dioxide high-performance finishing agent for textile
CN106182553A (en) * 2016-07-15 2016-12-07 白冰川 Production technology for the anion sponge of mattress
CN106866934A (en) * 2017-02-25 2017-06-20 黄小鸿 A kind of purify air exempts from photocatalyst polyurethane foam plastics
CN108478825A (en) * 2018-03-21 2018-09-04 浙江昆能新材料科技有限公司 A kind of antibacterial minerals powder and its preparation method and application

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1421481A (en) * 2001-11-23 2003-06-04 上海金樱环保科技有限公司 Foamed plastics additive with bealth care function and its prepn process
CN102886855A (en) * 2012-09-20 2013-01-23 太原市伦嘉生态健康家居科技有限公司 Method for manufacturing function division foam mat body
CN103122104A (en) * 2011-11-19 2013-05-29 大连得达科技发展有限公司 High-temperature-resistant antibacterial foamed plastic

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1421481A (en) * 2001-11-23 2003-06-04 上海金樱环保科技有限公司 Foamed plastics additive with bealth care function and its prepn process
CN103122104A (en) * 2011-11-19 2013-05-29 大连得达科技发展有限公司 High-temperature-resistant antibacterial foamed plastic
CN102886855A (en) * 2012-09-20 2013-01-23 太原市伦嘉生态健康家居科技有限公司 Method for manufacturing function division foam mat body

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104958025A (en) * 2015-06-08 2015-10-07 中山市品汇创新专利技术开发有限公司 with far-infrared health-care function
CN104983350A (en) * 2015-06-08 2015-10-21 中山艺展装饰工程有限公司 Novel multifunctional towel tube provided with plush doll
CN105648743A (en) * 2015-12-24 2016-06-08 天津工业大学 Preparation method of tourmalinite modified nanometer titanium dioxide high-performance finishing agent for textile
CN106182553A (en) * 2016-07-15 2016-12-07 白冰川 Production technology for the anion sponge of mattress
CN106866934A (en) * 2017-02-25 2017-06-20 黄小鸿 A kind of purify air exempts from photocatalyst polyurethane foam plastics
CN108478825A (en) * 2018-03-21 2018-09-04 浙江昆能新材料科技有限公司 A kind of antibacterial minerals powder and its preparation method and application

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Address after: 362801 Quanzhou Heng ang industry and Trade Co., Ltd. (phase two), southwest side of post peak road, Quangang District, Quanzhou, Fujian

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Address after: 362805 Quanzhou, Heng Fang industrial and Trade Co., Ltd. (phase two), southwest of Yifeng Road, Quangang District, Quanzhou, Fujian.

Patentee after: Quanzhou Xi Bao Home Technology Co., Ltd.

Address before: 362801 Quanzhou, Heng Fang industrial and Trade Co., Ltd. (phase two), southwest of Yifeng Road, Quangang District, Quanzhou, Fujian.

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