WO2018226074A2 - Method for producing germanium ionic solution and germanium ion-containing fiber fabric - Google Patents

Abstract

The present invention relates to a method for producing a germanium ionic solution and a germanium ion-containing fabric and, more specifically, to a method for producing a germanium ionic solution having a high adsorption rate of germanium ions to a fiber fabric and high fastness, and a germanium ion-containing fiber fabric capable of sustaining a beneficial effect by germanium using the same germanium ionic solution. The method for producing a germanium ionic solution of the present invention comprises: a pulverization step of pulverizing inorganic germanium; a mixing step of mixing the inorganic germanium in the powder state with water to form an inorganic germanium solution; and a high-speed stirring ionization step of ionizing the inorganic germanium by rotating the inorganic germanium solution at a high speed by means of an ultra-high speed stirring device.

Description

Germanium ionic liquid production method and fiber fabric containing germanium ions

The present invention relates to a method for producing a germanium ionic liquid and a fabric containing germanium ions, and more particularly, a method for preparing a germanium ionic liquid having high adsorption rate and fastness of germanium ions to a fiber fabric and using germanium ionic liquid It relates to a fiber fabric containing germanium ions in which the beneficial effect can be sustained.

The textile product field has been researched for a long time on the development of new materials with added functionality and sensitivity in accordance with the changing needs of consumers, and researches for technology development have been carried out for a long time. Especially, new functional textile materials which have a useful effect on the human body have been constantly developed. It's coming out.

Among these functional fiber materials, in recent years, materials having far-infrared radiation functions that have useful effects on the human body, such as promoting blood circulation of the human body, have been spotlighted. In general, far-infrared fibers and fabrics have been exposed to body temperature or It emits far-infrared rays in the wavelength range that can be absorbed by the body's body fluids by activating it, which activates body fluids that occupy most of the body and has warmth, heat, and effects on blood circulation and secretes sweat in the body. It is known to play a role in promoting metabolism.

Materials having far-infrared radiation include germanium, elvan, jade, monazaite, tourmaline, charcoal, ocher, and the like, which are coated on the surface of fibers or fabrics or contained in the spinning solution to form filaments with resins. The method contained in a fiber etc. is applied by making it form.

Korean Patent No. 1996-0013468 discloses a bio far-infrared fiber and a textile product using liquid (ionized) bio-ceramics that improve the insulation, flexibility, and the variety of dyeing.

As demonstrated by nuclear magnetic resonance spectroscopy, bio-ceramic is a harmful gas such as microvascular expansion, blood circulation, carbon dioxide and sulfurous acid gas. It releases pollutants such as mercury and lead out of the body, and promotes metabolism, promotes the growth of animals and plants, maintains freshness, ripening and taste of food.

Bio far-infrared fibers and textile products using conventional liquid (ionized) bioceramics are dissolved in sodium silicate, aluminum soda, sodium oxide, sodium thiosulfate, germanium dioxide and refined glucose, and white sugar, mixed and ionized with gold chloride acid. Aged silver nitrate with silver thiosulfate was added to the mixture, and the mixture was left to stand at 15 to 20 ° C for 48 to 72 hours, whereby the metal elements and organic compounds were ionized and mixed by the substitution reaction to mature the raw materials. The liquid acid (ionization) bioceramic stock solution manufactured by this completion is used.

These liquid bioceramic stock solutions are strongly alkaline far-infrared emitters with anionic properties, so liquid bioceramics are highly efficient at both room temperature and room temperature (35 ° C). It has permeability. When the fiber and textile products are immersed in a liquid stock solution at room temperature and dried, the far-infrared radiator penetrated into the textile and textile products by ionization tends to absorb ions in the atmosphere, thereby advancing ionic bonding. Bio far-infrared fibers and textile products which have been fixed to fibers and textile products and are highly functional have been produced.

In addition, Korean Patent Laid-Open Publication No. 2002-0062909 discloses a technique related to far-infrared radiation and smell-treated objects.

According to the conventional far-infrared radiation and smell-treated objects, the far-infrared radiation emitted from the far-infrared radiator provides beneficial effects such as bioactivation, deodorization and sterilization. When the far infrared rays are applied to a living body consisting of water and protein, the body activates when the vibration wave band of the molecular motion of organic compounds forming water or protein is the same as the far infrared wavelength band, and when the far infrared ray penetrates into the living body, a self-heating effect occurs. Induces capacitive expansion, promotes blood vessel circulation, promotes blood circulation, activates tissues, promotes metabolism, releases waste products and harmful metals.

Moreover, far-infrared rays neutralize the cations of odor-causing substances by anionizing air, thereby eliminating odors. When far-infrared rays, which are approximate to the wavelength range of water molecules, are irradiated, water molecules activate dissolved oxygen to destroy food. By inhibiting the penetration of bacteria to maintain the freshness of food for a long time or to accelerate the growth rate by promoting plant growth and metabolic activity.

In order to satisfy the far-infrared radiation function, the conventional far-infrared radiation and smell-treated objects were treated to mix the water-soluble fragrance, microencapsulated flavor and far-infrared radiation raw material, and add a binder to treat the smell and far-infrared radiation. In addition, the objects of far-infrared radiation and fragrance treatment include a fiber fabric and a textile product manufactured by the fabric, natural and artificial leather fabric and a leather product manufactured by the fabric.

The spinning materials coated on the fiber fabric by the above-described conventional technology are low in bonding strength and easily fall off or are separated by washing, so that the lasting stones of the spinning effect may not be expected and sufficient effects cannot be expected.

On the other hand, Korean Patent No. 10-0822719 discloses a far-infrared radiation fiber and a garment made using the same. Conventional far-infrared radiation fiber is deposited by the physical vapor deposition method of the far-infrared radiation material (selenium, titanium, germanium, elvan, ocher, jade, tourmaline, etc.) on the textile fabric so that these far-infrared radiation material is firmly bound to the fiber fabric to ensure durability and durability A technique for imparting chemical properties is proposed.

Conventional far-infrared radiation fiber uses vacuum deposition and sputtering as a physical vapor deposition method, vacuum deposition method by coating the material by evaporating atoms and molecules solidified on the coating material by evaporating the material using resistance heating or electron beam in high vacuum. In sputtering, the inert ions collide with the target due to abnormal discharge caused by the voltage between the high electrodes of several KV in an inert gas atmosphere, and the target material is vacuumed to coagulate and coat the target material.

However, such a conventional vacuum deposition method needs to cause a glow discharge, and the gas is in a plasma state in which ions and electrons are separated. It is not suitable for coating, clothing, etc. because of problems such as reaction or trapping of gas in the layer.

The present invention is to solve the above problems, a method of preparing a germanium ionic liquid that can increase the adsorption rate and the fastness of germanium ions to the fiber fabric and using germanium ionic liquid can be a beneficial effect of germanium can be sustained It is an object to provide a fiber fabric containing ions.

Germanium ionic liquid production method of the present invention to achieve the above object, the step of powdering inorganic germanium; Spraying a solution containing microorganisms on the inorganic germanium powder; Incubating the inorganic germanium powder in an incubator for 4 to 5 days at a temperature of 30 to 32 ° C .; Mixing the inorganic germanium powder with water to make a germanium solution; And increasing the germanium ion concentration by rapidly stirring the germanium solution at 30000 to 50000 rpm.

Specifically, the microorganism is Pantoea ananatis strain.

In addition, the microorganism is a genus Nocardia sp.

The inorganic germanium powder has a particle size of 300 mesh or more.

The germanium powder remaining after the high speed stirring of the germanium solution is completely precipitated to separate the precipitated germanium powder from the germanium solution, and the germanium solution is disinfected and sterilized.

On the other hand, in the fiber fabric containing the germanium ions of the present invention, the germanium ionic liquid prepared by the method of preparing the germanium ionic liquid of claim 1 is coated on the fiber tissue.

The present invention powders inorganic germanium, and then mixes inorganic germanium in powder form with water to make inorganic germanium solution, and rotates the inorganic germanium solution at high speed using ultrafast stirring mechanism to produce inorganic germanium ionic liquid, Adsorption rate and fastness of germanium ions can be increased, and the fiber fabric containing such a germanium ionic liquid can retain the beneficial effect of germanium without the germanium being granulated and leaving the fiber fabric.

1 is an inorganic germanium powder sprayed microorganisms added to the incubator according to an embodiment of the present invention.

Figure 2 is an incubator for culturing microorganisms with inorganic germanium powder according to an embodiment of the present invention.

3 is a germanium solution mixed with inorganic germanium powder according to an embodiment of the present invention.

4 is a germanium solution of the high-speed stirring, precipitation and disinfection of the germanium solution according to an embodiment of the present invention.

5 is a germanium concentration test report contained in the germanium ionic liquid according to an embodiment of the present invention.

6 and 7 is a garment produced by using a fabric fabric coated with germanium ionic liquid according to an embodiment of the present invention.

Germanium ionic liquid production method according to an embodiment of the present invention comprises a germanium powdering step, microbial spraying step, microbial culture step, germanium solution production step, germanium solution high speed stirring step and germanium solution disinfection step.

The germanium powdering step powders the inorganic germanium. The inorganic germanium powder produced in the germanium powdering step has a particle size of 300 mesh or more.

In the microbial spraying step, the inorganic germanium powder is sprayed with a solution containing microorganisms. At this time, the microorganisms used are Pantoea ananatis strains or Nocardia sp.

In the microbial culture step, as shown in FIGS. 1 and 2, the inorganic germanium powder is added to the incubator, and the microorganisms are grown by culturing the microorganisms for 4 to 5 days at a temperature of 30 to 32 ° C.

Microorganisms can be divided into heterotrophic and autotrophic microorganisms, depending on the energy source used. Heterotrophic microorganisms use organics as energy, and autotrophic microorganisms do not use organics as energy.

Autotrophic microorganisms include inorganic nutrient microorganisms that obtain energy from inorganic substances such as sulfur, iron, hydrogen, and ammonia, and photosynthetic microorganisms that obtain energy from light. Oxygen-producing photosynthetic microorganisms that generate oxygen and oxygen do not generate oxygen. There is an anaerobic photosynthetic microorganism.

On the other hand, inorganic germanium is present in combination with oxygen, chlorine, ammonia, etc. in nature.

In the germanium solution manufacturing step, as shown in FIG. 3, the inorganic germanium powder in which the microorganism is cultured is mixed with water (distilled water) to make the germanium solution.

The germanium solution high speed stirring step increases the germanium ion concentration by high speed stirring the germanium solution at 30000 to 50000 rpm.

As the microorganism grows and grows through the microbial culturing step, the ionized organic germanium which is biogermanized into the microorganism is absorbed. In addition, the secretion secreted from the microorganisms during the growth and growth of the microorganisms is not absorbed into the microorganisms of the microorganisms and weakens the binding strength of the remaining inorganic germanium to promote the ionization of the germanium when the germanium solution is stirred at high speed.

The germanium powder remaining after the high speed stirring of the germanium solution is completely precipitated to separate the precipitated germanium powder from the germanium solution, and the germanium solution is disinfected and sterilized. As a result, the germanium ionic liquid is completed as shown in FIG.

The concentration of the germanium ionic liquid thus produced is preferably maintained at 4000 mg / L (ppm) or less . The higher the concentration of the germanium ionic liquid, the more the effect of germanium can be expected. However, when the concentration of the germanium ionic liquid exceeds 4000 mg / L (ppm), the germanium ion is naturally neutralized by the process of neutralizing strongly acidic or strong alkaline substances. This is because sediment may be generated as it is converted into particulate matter.

(Example 1)

Pantoea ananatis B1-9 strain (National Institute of Agricultural Science, RDA, KACC 19138) selected for carrying out the microbial culture step of the present invention is used as a microbial preparation for crop yield enhancement. Such Pantoea ananatis B1-9 can be isolated from the source of leek in the conventional cultivation of green onion in Gyeongnam Myeongji through the conventional method of separating the source bacteria.

Table 1 is a table showing the ion concentration of the germanium ionic liquid according to Example 1.

	Concentration (mg / L)
Experimental Example 1	3916
Experimental Example 2	3023
Experimental Example 3	3714
Experimental Example 4	3721
Experimental Example 5	4111

Ion concentration was measured using an ion chromatography analyzer.

(Example 2)

Nocardia genus H17 selected to carry out the microbial culture step of the present invention can be secured through the selection, separation and identification process from microorganisms collected from soil contaminated with oil. This genus H17 was deposited with KCTC 19514 at the Biological Resources Center (KCTC).

Table 2 is a table showing the ion concentration of the germanium ionic liquid according to Example 2.

	Concentration (mg / L)
Experimental Example 1	3309
Experimental Example 2	4230
Experimental Example 3	2607
Experimental Example 4	3728
Experimental Example 5	3504

Ion concentration was measured using an ion chromatography analyzer.

After incubating the microorganisms with the inorganic germanium powder as shown in Table 1 and Table 2 it can be seen that the germanium concentration of the germanium ionic liquid prepared through the preparation, high speed stirring, precipitation and disinfection of the germanium solution is very high.

5 is a test report measuring the concentration of germanium contained in the germanium ionic liquid prepared according to the embodiment of the present invention commissioned by the Korea Testing Institute. As shown in FIG. 5, the concentration of germanium in the germanium ionic liquid prepared according to the embodiment of the present invention was 3480 mg / L.

On the other hand, even if the normal germanium powder excluding the microbial culture step is simply mixed with water and stirred at high speed, the concentration of germanium ions in the germanium aqueous solution does not exceed 10 mg / L (ppm). It can be seen that such a difference in ion concentration shows a very large difference compared to the germanium ionic liquid prepared according to the embodiment of the present invention.

In addition, although the concentration of germanium ions may be chemically increased by using an acid and a strong alkali material, the germanium ionic liquid of the present invention is coated on a product in direct contact with the body, and the process of neutralization again requires a precipitate in this process. There is a problem that occurs.

In addition, since the liquidity is neutralized when the chemically temporarily liquefied material is coated on the fabric, it is converted into particles. The coating of the liquid material has a problem in that the bonding force is low and the effect by the material does not last.

However, since the present invention does not use a separate chemical method, it can be variously applied to a product used in real life without a separate neutralization process.

On the other hand, the fiber fabric containing a germanium ion according to an embodiment of the present invention is to powder the inorganic germanium as described above, and then mixed with the inorganic germanium in the powder form to make an inorganic germanium solution, the inorganic germanium solution The inorganic germanium ionic liquid prepared by the high speed rotation using the ultrafast stirring mechanism is completed by coating the fiber tissue.

In the germanium ionic liquid according to the embodiment of the present invention, a phenomenon in which ionized germanium is tightly bonded to the fiber tissue may occur so that the effect of germanium may be generated for a long time from the fiber fabric containing germanium ions.

Specifically, germanium is a unique material having both negative and positive electrons, and when such a high concentration of germanium ionic liquid is coated on a fiber fabric, ionic bonds of germanium ions and fiber fabrics are strongly generated, and thus, Very good adhesion of the germanium component to.

In this way, germanium contained in the fiber fabric can absorb and remove harmful electromagnetic waves and static electricity by providing anion that the radiant heat corresponding to a wavelength of 5.6 to 15 microns neutralizes the positive charges generated in connection with the radiation of harmful electromagnetic waves.

In addition, clothing made of germanium-containing fiber fabrics are worn on the body to expand capillaries to facilitate blood circulation, and when worn as clothing that is in close contact with the skin, the performance of far infrared rays can be maximized by skin temperature. In addition, it is possible to increase the amount of oxygen supplied to the skin and the addition of antibacterial activity.

The germanium has four electrons in its atomic structure, and is characterized in that ions are easily coupled at human body temperature to actively move between electron currents. The germanium is out of the four electrons in the body of the outer electrons (-) state to come out and the other three become (+) state to be in harmony with the body.

In addition, germanium acts as an oxygen catalyst to help the body's oxygen activity efficiently, so supplying germanium to the human body reduces the oxygen demand of the cells, thereby promoting the production of endorphins, the natural therapeutic agents of the human body, as oxygen remains in the body. Let's do it. Therefore, it is possible to recover fatigue quickly and to maintain a healthy mind from chronic oxygen deficiency.

In addition, in relation to pain elimination, when a pain sensation occurs in a certain part of the human body, an enzyme called enkiprarines is generated in the brain to dissolve and eliminate the pain suppressing substance, enkeprarin, thereby recognizing the pain. Therefore, most analgesics are temporary agents that inhibit enkeprarines enzymes. When the analgesic drugs are less effective, pain recurs again, and side effects and poisoning symptoms are observed. Appears and has no side effects.

The following is an embodiment of the method for coating the germanium ionic liquid on the fiber fabric. Hereinafter, the described coating method is not limited to the present invention by the following description as one of various embodiments of the present invention.

First, the fabric released by being held in contact with each other and frictionally driven in the opposite direction is passed through the first tank containing the germanium ionic liquid manufactured according to the embodiment of the present invention to pass the germanium ions into the fabric. After impregnating the liquid, the water is passed through a hot air dryer at a predetermined temperature to dehydrate and dry the moisture.

Then, the fabric is dried by passing the dehydrated fabric through a second tank containing germanium ionic liquid, and then coating the germanium ionic liquid on the fabric once more and passing it through a hot air dryer.

In this way, the fabric subjected to the two-stage coating and drying is passed through a third tank containing a coating film reinforcing material (a mixture of water, gypsum powder, acetic acid, etc.) to coat the coating film reinforcing material on the fabric, and then Pass the hot air dryer set to a higher temperature.

When the germanium ionic liquid is coated on the fiber fabric, a cotan liquid in which the germanium ionic liquid and the binder are mixed is used to increase the adsorption force with the fiber fabric. At this time, the germanium ionic liquid prepared according to the embodiment of the present invention can reduce the ratio of the binder in the coating liquid because the binding strength with the fiber fabric itself is very excellent, the existing coating fabric stretched as the ratio of the binder is reduced The phenomenon is reduced, and even after the coating of germanium ionic liquid, the original soft touch can be maintained.

The method for producing a germanium ionic liquid and the fiber fabric containing germanium ions according to the present invention may be carried out by various modifications within the range to which the technical idea of the present invention is not limited.

Claims (5)

1. Powdering inorganic germanium;

   Spraying a solution containing microorganisms on the inorganic germanium powder;

   Injecting the inorganic germanium powder into the incubator and culturing the Pantoea ananatis strain for 4-5 days at a temperature of 30-32 ° C .;

   Mixing the inorganic germanium powder with water to make a germanium solution;

   Increasing the germanium ion concentration by rapidly stirring the germanium solution at 30000 to 50000 rpm; And

   A method of producing a germanium ionic liquid, comprising the step of completely precipitating the germanium powder remaining after the high speed stirring of the germanium solution to separate the germanium powder precipitated from the germanium solution, and disinfecting and disinfecting the germanium solution.
2. Powdering inorganic germanium;

   Spraying a solution containing microorganisms on the inorganic germanium powder;

   Injecting the inorganic germanium powder into the incubator and incubating the Nocardia sp. Strain for 4-5 days at a temperature of 30-32 ° C .;

   Mixing the inorganic germanium powder with water to make a germanium solution;

   Increasing the germanium ion concentration by rapidly stirring the germanium solution at 30000 to 50000 rpm; And

   A method of producing a germanium ionic liquid, comprising the step of completely precipitating the germanium powder remaining after the high speed stirring of the germanium solution to separate the germanium powder precipitated from the germanium solution, and disinfecting and disinfecting the germanium solution.
3. The method according to claim 1 or 2,

   The inorganic germanium powder is a germanium ionic liquid production method, characterized in that having a particle size of 300 mesh or more.
4. The method according to claim 1 or 2,

   Germanium ionic liquid production method characterized in that the germanium contained in the germanium solution is less than 4000mg / L.
5. A fabric fabric containing germanium ions comprising coating a germanium ionic liquid prepared by the method for producing a germanium ionic liquid of claim 1 or 2 on a fibrous structure.

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