CN110835559A - 一种新能源复合柴油 - Google Patents

一种新能源复合柴油 Download PDF

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CN110835559A
CN110835559A CN201810944371.3A CN201810944371A CN110835559A CN 110835559 A CN110835559 A CN 110835559A CN 201810944371 A CN201810944371 A CN 201810944371A CN 110835559 A CN110835559 A CN 110835559A
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diesel oil
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C10L10/12—Use of additives to fuels or fires for particular purposes for improving the cetane number
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/16—Hydrocarbons
    • C10L1/1616—Hydrocarbons fractions, e.g. lubricants, solvents, naphta, bitumen, tars, terpentine
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
    • C10L1/1824—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/188—Carboxylic acids; metal salts thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2230/00—Function and purpose of a components of a fuel or the composition as a whole
    • C10L2230/04—Catalyst added to fuel stream to improve a reaction
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2230/00—Function and purpose of a components of a fuel or the composition as a whole
    • C10L2230/22—Function and purpose of a components of a fuel or the composition as a whole for improving fuel economy or fuel efficiency
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
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  • General Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

本发明公开了一种新能源复合柴油，本发明由以下组分组成：主要以柴油、油酸、甲醇为主要原料,加入适量十六烷值增效剂复合而成。冬季用少量催化剂来调整复合柴油的冷凝点指标。可以调制出 0#～‑35# 复合柴油。其特点是：充分利用了石油副产品及可再生的生物燃料，有利于节约资源，提高利用率,起到了节能减排净化空气的效果。其理化指标稳定，质量达到国家同标号柴油的质量标准。可与国标柴油以任意比例混合使用，也可以单独使用。

Description

一种新能源复合柴油
技术领域
本发明属于燃料油脂技术领域，更具体涉及到的是液体燃料，一种新能源复合柴油。
背景技术
柴油是压燃式发动机（即柴油机）燃料，也是消耗量最大的石油产品之一。由于柴油机较汽油机热效率高，功率大，燃料单耗低，比较经济，故应用日趋广泛。它主要作为拖拉机、大型汽车、内燃机车及土建、农用机械的动力。柴油是复杂的烃类混合物，碳原子数约为10～22。主要由原油蒸馏，催化裂化，加氢裂化，减粘裂化，焦化等过程生产的柴油馏分调配而成，柴油是从石油中提取得到，是日常生活中最常使用的燃油，且随着经济的发展，对于柴油的需求量越来越大，石油属于不可再生的资源，因此，研发出新能源复合柴油，以达到节省资源的目的，是业界同仁认为的共同目标，目前迫在眉睫的事情必须努力去做。
专利号为200910203186的中国发明专利公开了“合成柴油”，其由合成燃料剂、合成母液及合成添加剂组成，其存在的主要不足在于：组分来源较为特别，实用范围很窄，实用性不强；燃烧不充分，且稳定性不够。
专利号为201110244283的中国专利公开了一种合成柴油及其制备方法，其由废油、抽余油、脂肪酸酯及催化添加剂组成，其存在的主要不足在于：组分较少，相互之间不能形成协同效应；燃料消耗高，燃烧值低，燃烧不充分且容易积炭。
发明内容
本发明的目的在于克服现有技术存在的不足，提供一种新能源复合柴油。为达到上述目的，本发明采取了如下的技术方案：一种新能源复合柴油，以重量份计，由以下组分组成：柴油 20～60，油酸10～30，甲醇40～85，十六烷值提高剂0.1～0.5，催化剂0.1～0.5，将所有组分依次投入反应釜中（催化剂除外），反应温度在60～70℃之间,搅拌50～60分钟，降至常温后加入催化剂继续搅拌至完全反应，直至清澈透亮，出釜灌装，即得成品。
上述技术方案中，一种新能源复合柴油的配方为：柴油 20～60，油酸10～30，甲醇40～85，十六烷值提高剂0.1～0.5，催化剂0.1～0.5的重量比混合而成。将所有组分依次投入反应釜中（催化剂除外），反应温度在60～70℃之间,搅拌50～60分钟，与现有技术相比，本发明具有如下特点：一、原材料广泛易得，成本较低，制造工艺简单，不需要炼制； 二、在大量的实际应用过程中反应发动机噪音降低了、尾气不再有那么难闻的臭味了、车辆也有劲了（在我自己的柴油发电机上长期使用，也验证了以上说法）；三、使用方便安全，提高了燃烧值，降低了燃料消耗，使燃油燃烧充分了不产生积炭，符合了国家节能、环保的要求。
具体实施方式以下结合具体实施例来对本发明作进一步的描述。
实施例1：
一种新能源复合柴油，以重量份计，由以下组分组成：柴油 20，油酸30，甲醇55，十六烷值提高剂0.5，催化剂0.1，将所有组分依次投入反应釜中（催化剂除外），反应温度在60～70℃之间,搅拌50～60分钟，降至常温后加入催化剂继续搅拌至完全反应，直至清澈透亮，出釜灌装，即得成品。
实施例2：
一种新能源复合柴油，以重量份计，由以下组分组成：柴油 25，油酸25，甲醇50，十六烷值提高剂0.4，催化剂0.2，将所有组分依次投入反应釜中（催化剂除外），反应温度在60～70℃之间,搅拌50～60分钟，降至常温后加入催化剂继续搅拌至完全反应，直至清澈透亮，出釜灌装，即得成品。
实施例3：
一种新能源复合柴油，以重量份计，由以下组分组成：柴油 30，油酸25，甲醇45，十六烷值提高剂0.3，催化剂0.3，将所有组分依次投入反应釜中（催化剂除外），反应温度在60～70℃之间,搅拌50～60分钟，降至常温后加入催化剂继续搅拌至完全反应，直至清澈透亮，出釜灌装，即得成品。
实施例4：
一种新能源复合柴油，以重量份计，由以下组分组成：柴油 35，油酸25，甲醇65，十六烷值提高剂0.2，催化剂0.4，将所有组分依次投入反应釜中（催化剂除外），反应温度在60～70℃之间,搅拌50～60分钟，降至常温后加入催化剂继续搅拌至完全反应，直至清澈透亮，出釜灌装，即得成品。
实施例5：
一种新能源复合柴油，以重量份计，由以下组分组成：柴油60，油酸10，甲醇85，十六烷值提高剂0.1，催化剂0.5，将所有组分依次投入反应釜中（催化剂除外），反应温度在60～70℃之间,搅拌50～60分钟，降至常温后加入催化剂继续搅拌至完全反应，直至清澈透亮，出釜灌装，即得成品。

Claims (4)

1.一种新能源复合柴油，其特征在于以重量份计，由以下组分组成：柴油 20～60，油酸10～30，甲醇40～85，十六烷值提高剂0.1～0.5，催化剂0.1～0.5，将所有组分依次投入反应釜中（催化剂除外），反应温度在60～70℃之间,搅拌50～60分钟，降至常温后加入催化剂继续搅拌至完全反应，直至清澈透亮，出釜灌装，即得成品。
2.根据权利要求1中所述柴油是有20～60柴油组分组成的，将所有组分依次投入反应釜中（催化剂除外），反应温度在60～70℃之间,搅拌50～60分钟，降至常温后加入催化剂继续搅拌至完全反应，直至清澈透亮，出釜灌装，即得成品。
3.根据权利要求1中所述柴油是有10～30的油酸组分组成的柴油，将所有组分依次投入反应釜中（催化剂除外），反应温度在60～70℃之间,搅拌50～60分钟，降至常温后加入催化剂继续搅拌至完全反应，直至清澈透亮，出釜灌装，即得成品。
4.根据权利要求1中所述柴油是有40～85的甲醇组分组成的柴油，将所有组分依次投入反应釜中（催化剂除外），反应温度在60～70℃之间,搅拌50～60分钟，降至常温后加入催化剂继续搅拌至完全反应，直至清澈透亮，出釜灌装，即得成品。
CN201810944371.3A 2018-08-19 2018-08-19 一种新能源复合柴油 Pending CN110835559A (zh)

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