CN101544916B - 甲醇、乙醇基车用清洁燃料添加剂及其制备方法 - Google Patents

甲醇、乙醇基车用清洁燃料添加剂及其制备方法 Download PDF

Info

Publication number
CN101544916B
CN101544916B CN 200810064177 CN200810064177A CN101544916B CN 101544916 B CN101544916 B CN 101544916B CN 200810064177 CN200810064177 CN 200810064177 CN 200810064177 A CN200810064177 A CN 200810064177A CN 101544916 B CN101544916 B CN 101544916B
Authority
CN
China
Prior art keywords
weight
parts
agent
automobile
ethanol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN 200810064177
Other languages
English (en)
Other versions
CN101544916A (zh
Inventor
王建业
窦彦东
王海鹏
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Heilongjiang Jianye in Bio Energy Co. Ltd.
Original Assignee
王建业
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 王建业 filed Critical 王建业
Priority to CN 200810064177 priority Critical patent/CN101544916B/zh
Priority to PCT/CN2008/071138 priority patent/WO2009117875A1/zh
Publication of CN101544916A publication Critical patent/CN101544916A/zh
Application granted granted Critical
Publication of CN101544916B publication Critical patent/CN101544916B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/12—Inorganic compounds
    • C10L1/1208—Inorganic compounds elements
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/12—Inorganic compounds
    • C10L1/1266—Inorganic compounds nitrogen containing compounds, (e.g. NH3)
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/16—Hydrocarbons
    • C10L1/1616—Hydrocarbons fractions, e.g. lubricants, solvents, naphta, bitumen, tars, terpentine
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/1802—Organic compounds containing oxygen natural products, e.g. waxes, extracts, fatty oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
    • C10L1/1824—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
    • C10L1/1852—Ethers; Acetals; Ketals; Orthoesters
    • C10L1/1855—Cyclic ethers, e.g. epoxides, lactides, lactones
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/188—Carboxylic acids; metal salts thereof
    • C10L1/1881—Carboxylic acids; metal salts thereof carboxylic group attached to an aliphatic carbon atom
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/19—Esters ester radical containing compounds; ester ethers; carbonic acid esters
    • C10L1/191—Esters ester radical containing compounds; ester ethers; carbonic acid esters of di- or polyhydroxyalcohols
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C10L1/224—Amides; Imides carboxylic acid amides, imides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/226—Organic compounds containing nitrogen containing at least one nitrogen-to-nitrogen bond, e.g. azo compounds, azides, hydrazines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/232—Organic compounds containing nitrogen containing nitrogen in a heterocyclic ring
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/24—Organic compounds containing sulfur, selenium and/or tellurium
    • C10L1/2431—Organic compounds containing sulfur, selenium and/or tellurium sulfur bond to oxygen, e.g. sulfones, sulfoxides
    • C10L1/2437—Sulfonic acids; Derivatives thereof, e.g. sulfonamides, sulfosuccinic acid esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/26—Organic compounds containing phosphorus
    • C10L1/2633—Organic compounds containing phosphorus phosphorus bond to oxygen (no P. C. bond)
    • C10L1/2641—Organic compounds containing phosphorus phosphorus bond to oxygen (no P. C. bond) oxygen bonds only

Abstract

甲醇、乙醇基车用清洁燃料添加剂，从技术上讲，目前国外、国内掺烧50％以上的甲醇或乙醇车用燃料，均需改动发动机和一种专用燃烧高比例醇类燃料的发动机，以适应甲醇、乙醇高辛烷值，低热值的特点。本发明组成包括：助溶剂、馏程调节剂、动力性能增能剂、低温启动剂、防腐、抗溶胀剂，所述的添加剂中助溶剂的重量份数为20～40，馏程调节剂的重量份数为40～60，动力性能增能剂的重量份数为5～10，低温启动剂的重量份数为1～5，防腐、抗溶胀剂的重量份数为0.4～1，抗氧剂的重量份数0.05-0.1，缓释剂的重量份数为5-19。本发明应用于能源领域。

Description

甲醇、乙醇基车用清洁燃料添加剂及其制备方法
技术领域：
本发明涉及一种含甲醇、乙醇基的车用清洁燃料添加剂及其制备方法
背景技术：
在世界能源紧张大背景下，各国都在投入人力物力积极开发替代能源。甲醇清洁燃料汽油、乙醇清洁燃料汽油就是目前市场上替代能源的佼佼者。目前市场上乙醇汽油乙醇掺烧量为10%，甲醇汽油掺烧量为15%，均为低比例掺烧。从国家醇醚燃料和醇醚清洁汽车专业委员会获得信息，国家对高比例掺烧甲醇、乙醇非常重视，是醇类燃料替代化石能源的趋势。即醇掺烧量85～100%，如果从技术上能够实现，可从根本上解决我国能源替代问题，不再需要每年进口60%以上的石油，受国际石油市场制约，对确保国家能源安全具有重要战略意义。煤是制备甲醇的重要原料，我国是产煤大国，原料丰富。乙醇（纤维素酒精）属再生能源，可从稻草、秸秆、木薯、甘蔗、粮食制取。无论是甲醇或是乙醇，原料来源均有保证。
从技术上讲，目前国外、国内掺烧50%以上的甲醇或乙醇车用燃料，均需改动发动机和一种专用燃烧高比例醇类燃料的发动机，以适应甲醇、乙醇高辛烷值，低热值的特点。专用发动机已进入试验运行阶段，尚未达到产业化生产。即使推广尚需一个过程，而且燃油比尚高于汽油60%以上，同时解决不了现有保有量的汽车应用。
发明内容：
本发明的目的是提供一种燃烧汽油的发动机汽车不需改动、可与汽油无限混融、节省能源与甲醇、乙醇（本案特指纤维素酒精）基车用清洁燃料配合使用的添加剂及其制备方法。
上述的目的通过以下的技术方案实现：
一种甲醇、乙醇基车用清洁燃料添加剂，其组成包括：助溶剂、馏程调节剂、动力性能增能剂、低温启动剂、防腐、抗溶胀剂、抗氧剂、缓释剂、燃烧促进剂，所述的添加剂中所述的助溶剂的重量份数为20～40，所述的馏程调节剂的重量份数为40～60，所述的动力性能增能剂的重量份数为5～10，所述的低温启动剂的重量份数为1～5，所述的防腐、抗溶胀剂的重量份数为0.4～1，所述的抗氧剂的重量份数0.05—0.1，所述的缓释剂的重量份数为5-19；
所述的甲醇基车用清洁燃料，所述的助溶剂包括辛醇、异丁醇，所述的辛醇的重量份数为10～30、所述的异丁醇的重量份数为5～20；所述的馏程调节剂为190号溶剂油，其重量份数为40-60；
所述的动力性能增能剂由煤油、水合肼、苯肼、植物油、甲酸、硝酸、异辛酸、二甲酰胺、四氢呋喃，8-羟喹啉组成，其中所述的煤油的重量份数为15—55，所述的水合肼的重量份数为3--8.5、所述的苯肼的重量份数为0.001-0.005、所述的植物油的重量份数为15--23、所述的甲酸的重量份数为8--12、所述的硝酸的重量份数为3—5、所述的异辛酸的重量份数为2—5、所述的二甲酰胺的重量份数为0.07--0.1、所述的四氢呋喃的重量份数为1.5～3、所述的8-羟喹啉的重量份数为1.5～3；所述的燃烧促进剂包括锌的重量份数为0.01～0.1；所述的低温启动剂为石油醚，其重量份数为1～5；所述的防腐、抗溶胀剂包括二烷基贰硫代磷酸锌、磺酸胺，所述的二烷基贰硫代磷酸锌的重量份数为0.12—0.36、所述的磺酸胺的重量份数为0.3～1；
甲醇、乙醇基车用清洁燃料添加剂的制备方法，将所述的助溶剂、所述的馏程调节剂加入罐中，用泵循环，边循环边依次加入所述的动力性能增能剂、所述的低温启动剂、所述的防腐、抗溶胀剂、所述的燃烧促进剂、所述的抗氧剂、所述的缓释剂混合产生化学反应，经过4小时反应后即制成有效的添加剂。
这个技术方案有以下有益效果：
1.本发明在现有保有量的汽车不改动发动机，不需专用发动机，油耗低于专用燃烧醇类燃料发动机30-40%的基础上，实现醇类清洁燃料低比例掺烧至高比例替代传统汽油。
目前国内外现有技术不能实现在不改动发动机情况下高比例掺烧甲醇或乙醇，主要原因是醇的热值低，如甲醇热值仅为汽油的49%，动力不足。本发明采用增能剂，从根本上解决了高比例掺烧醇热值低，动力不足问题。
采用本发明添加剂制备的车用醇基燃料，动力性与高信汽油相当，成本低、经济效益、社会效益非常显著。从技术上讲，目前填补国外、国内高比例醇掺烧90%以内的甲醇或乙醇车用醇类燃料，均不改动发动机而达到同汽油等同的动力性能，以适应甲醇、乙醇高辛烷值，低热值的特点。
本发明的具体实施方式：
实施例1：
一种甲醇、乙醇基车用清洁燃料添加剂，其组成包括：助溶剂、馏程调节剂、动力性能增能剂、低温启动剂、防腐、抗溶胀剂、抗氧剂、缓释剂、燃烧促进剂，所述的添加剂中所述的助溶剂的重量份数为20～40，所述的馏程调节剂的重量份数为40～60，所述的动力性能增能剂的重量份数为5～10，所述的低温启动剂的重量份数为1～5，所述的防腐、抗溶胀剂的重量份数为0.4～1，所述的抗氧剂的重量份数0.05—0.1，所述的缓释剂的重量份数为5-19；
所述的甲醇基车用清洁燃料，所述的助溶剂包括辛醇、异丁醇，所述的辛醇的重量份数为10～30、所述的异丁醇的重量份数为5～20，所述的馏程调节剂为190号溶剂油，其重量份数为20-40，
所述的动力性能增能剂包括煤油、水合肼、苯肼、植物油、甲酸、硝酸、异辛酸、二甲酰胺、四氢呋喃，8-羟喹啉，其中所述的煤油的重量份数为15—55，所述的水合肼的重量份数为3--8.5、所述的苯肼的重量份数为0.001-0.005、所述的植物油的重量份数为15--23、所述的甲酸的重量份数为8--12、所述的硝酸的重量份数为3—5、所述的异辛酸的重量份数为2—5、所述的二甲酰胺的重量份数为0.07--0.1、所述的四氢呋喃的重量份数为1.5～3、所述的8-羟喹啉的重量份数为1.5～3；所述的燃烧促进剂包括锌的重量份数为0.01～0.1；所述的低温启动剂为石油醚，其重量份数为2～10；所述的防腐、抗溶胀剂包括二烷基贰陆代磷酸锌、磺酸胺，所述的二烷基贰陆代磷酸锌的重量份数为0.12—0.36、所述的磺酸胺的重量份数为0.3～1；
甲醇、乙醇基车用清洁燃料添加剂的制备方法，将所述的助溶剂、所述的馏程调节剂加入罐中，用泵循环，边循环边依次加入所述的动力性能增能剂、所述的低温启动剂、所述的防腐、抗溶胀剂、所述的燃烧促进剂、所述的抗氧剂、所述的缓释剂混合产生化学反应，经过4小时反应后即制成有效的添加剂。    
实施例2：
甲醇、乙醇基车用清洁燃料添加剂，其组成包括：助溶剂、馏程调节剂、动力性能增能剂、低温启动剂、防腐、抗溶胀剂、清净分散剂，所述的添加剂中助溶剂的重量份数为20，馏程调节剂的重量份数为40，动力性能增能剂的重量份数为5，低温启动剂的重量份数为1，防腐、抗溶胀剂的重量份数为0.4，抗氧剂的重量份数0.05,缓释剂的重量份数为5。
所述的甲醇基车用清洁燃料，所述的助溶剂包括辛醇、异丁醇，所述的辛醇的重量份数为10、所述的异丁醇的重量份数为5，所述的馏程调节剂为190号溶剂油，其重量份数为20，所述的动力性能增能剂包括煤油、水合肼、苯肼、植物油、甲酸、硝酸、异辛酸、二甲酰胺、四氢呋喃，8-羟喹啉，其中所述的煤油的重量份数为15，所述的水合肼的重量份数为3、所述的苯肼的重量份数为0.001、所述的植物油的重量份数为15、所述的甲酸的重量份数为8、所述的硝酸的重量份数为3、所述的异辛酸的重量份数为2、所述的二甲酰胺的重量份数为0.07、所述的四氢呋喃的重量份数为1.5、所述的8-羟喹啉的重量份数为1.5，所述的燃烧促进剂包括锌的重量份数为0.01，所述的低温启动剂为石油醚，其重量份数为2，所述的抗溶、防腐剂包括二烷基贰陆代磷酸锌、磺酸胺，所述的二烷基贰陆代磷酸锌的重量份数为0.12、所述的重量份数为磺酸胺0.3。
甲醇、乙醇基车用清洁燃料添加剂的制备方法，将助溶剂、馏程调节剂加入罐中，用泵循环，边循环边依次加入增能剂、低温启动剂、抗溶、防腐剂、促进剂、抗氧剂、缓释剂混合产生化学反应，经过4小时反应后即制成有效的添加剂。
实施例3：
甲醇、乙醇基车用清洁燃料添加剂，其组成包括：助溶剂、馏程调节剂、动力性能增能剂、低温启动剂、防腐、抗溶胀剂、清净分散剂，所述的添加剂中助溶剂的重量份数为40，馏程调节剂的重量份数为60，动力性能增能剂的重量份数为10，低温启动剂的重量份数为5，防腐、抗溶胀剂的重量份数为1，抗氧剂的重量份数0.1,缓释剂的重量份数为19。
所述的甲醇基车用清洁燃料，所述的助溶剂包括辛醇、异丁醇，所述的辛醇的重量份数为30、所述的异丁醇的重量份数为20，所述的馏程调节剂为190号溶剂油，其重量份数为40，所述的动力性能增能剂包括煤油、水合肼、苯肼、植物油、甲酸、硝酸、异辛酸、二甲酰胺、四氢呋喃，8-羟喹啉，其中所述的煤油的重量份数为55，所述的水合肼的重量份数为8.5、所述的苯肼的重量份数为0.005、所述的植物油的重量份数为23、所述的甲酸的重量份数为12、所述的硝酸的重量份数为5、所述的异辛酸的重量份数为5、所述的二甲酰胺的重量份数为0.1、所述的四氢呋喃的重量份数为3、所述的8-羟喹啉的重量份数为3，所述的燃烧促进剂包括锌的重量份数为0.1，所述的低温启动剂为石油醚，其重量份数为10，所述的抗溶、防腐剂包括二烷基贰陆代磷酸锌、磺酸胺，所述的二烷基贰陆代磷酸锌的重量份数为0.36、所述的重量份数为磺酸胺1。
甲醇、乙醇基车用清洁燃料添加剂的制备方法，将助溶剂、馏程调节剂加入罐中，用泵循环，边循环边依次加入增能剂、低温启动剂、抗溶、防腐剂、促进剂、抗氧剂、缓释剂混合产生化学反应，经过4小时反应后即制成有效的添加剂。
实施例4：
甲醇、乙醇基车用清洁燃料添加剂，其组成包括：助溶剂、馏程调节剂、动力性能增能剂、低温启动剂、防腐、抗溶胀剂、清净分散剂，所述的添加剂中助溶剂的重量份数为30，馏程调节剂的重量份数为50，动力性能增能剂的重量份数为7，低温启动剂的重量份数为3，防腐、抗溶胀剂的重量份数为0.7，抗氧剂的重量份数0.75,缓释剂的重量份数为12。
所述的甲醇基车用清洁燃料，所述的助溶剂包括辛醇、异丁醇，所述的辛醇的重量份数为20、所述的异丁醇的重量份数为12.5，所述的馏程调节剂为190号溶剂油，其重量份数为30，所述的动力性能增能剂包括煤油、水合肼、苯肼、植物油、甲酸、硝酸、异辛酸、二甲酰胺、四氢呋喃，8-羟喹啉，其中所述的煤油的重量份数为35，所述的水合肼的重量份数为6、所述的苯肼的重量份数为0.003、所述的植物油的重量份数为19、所述的甲酸的重量份数为10、所述的硝酸的重量份数为4、所述的异辛酸的重量份数为3.5、所述的二甲酰胺的重量份数为0.09、所述的四氢呋喃的重量份数为2、所述的8-羟喹啉的重量份数为2，所述的燃烧促进剂包括锌的重量份数为0.05，所述的低温启动剂为石油醚，其重量份数为6，所述的抗溶、防腐剂包括二烷基贰陆代磷酸锌、磺酸胺，所述的二烷基贰陆代磷酸锌的重量份数为0.24、所述的重量份数为磺酸胺0.6。
甲醇、乙醇基车用清洁燃料添加剂的制备方法，将助溶剂、馏程调节剂加入罐中，用泵循环，边循环边依次加入增能剂、低温启动剂、抗溶、防腐剂、促进剂、抗氧剂、缓释剂混合产生化学反应，经过4小时反应后即制成有效的添加剂。

Claims (1)

1.一种甲醇、乙醇基车用清洁燃料添加剂，其组成包括：助溶剂、馏程调节剂、动力性能增能剂、低温启动剂、防腐、抗溶胀剂、抗氧剂、缓释剂、燃烧促进剂，其特征是：所述的添加剂中所述的助溶剂的重量份数为20～40，所述的馏程调节剂的重量份数为40～60，所述的动力性能增能剂的重量份数为5～10，所述的低温启动剂的重量份数为1～5，所述的防腐、抗溶胀剂的重量份数为0.4～1，所述的抗氧剂的重量份数0.05—0.1，所述的缓释剂的重量份数为5-19；
所述的甲醇基车用清洁燃料，所述的助溶剂包括辛醇、异丁醇，所述的辛醇的重量份数为10～30、所述的异丁醇的重量份数为5～20；所述的馏程调节剂为190号溶剂油，其重量份数为40-60；
所述的动力性能增能剂由煤油、水合肼、苯肼、植物油、甲酸、硝酸、异辛酸、二甲酰胺、四氢呋喃，8-羟喹啉组成，其中所述的煤油的重量份数为15—55，所述的水合肼的重量份数为3--8.5、所述的苯肼的重量份数为0.001-0.005、所述的植物油的重量份数为15--23、所述的甲酸的重量份数为8--12、所述的硝酸的重量份数为3—5、所述的异辛酸的重量份数为2—5、所述的二甲酰胺的重量份数为0.07--0.1、所述的四氢呋喃的重量份数为1.5～3、所述的8-羟喹啉的重量份数为1.5～3；所述的燃烧促进剂包括锌的重量份数为0.01～0.1；所述的低温启动剂为石油醚，其重量份数为1～5；所述的防腐、抗溶胀剂包括二烷基贰硫代磷酸锌、磺酸胺，所述的二烷基贰硫代磷酸锌的重量份数为0.12—0.36、所述的磺酸胺的重量份数为0.3～1；
甲醇、乙醇基车用清洁燃料添加剂的制备方法，将所述的助溶剂、所述的馏程调节剂加入罐中，用泵循环，边循环边依次加入所述的动力性能增能剂、所述的低温启动剂、所述的防腐、抗溶胀剂、所述的燃烧促进剂、所述的抗氧剂、所述的缓释剂混合产生化学反应，经过4小时反应后即制成有效的添加剂。    
CN 200810064177 2008-03-26 2008-03-26 甲醇、乙醇基车用清洁燃料添加剂及其制备方法 Active CN101544916B (zh)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN 200810064177 CN101544916B (zh) 2008-03-26 2008-03-26 甲醇、乙醇基车用清洁燃料添加剂及其制备方法
PCT/CN2008/071138 WO2009117875A1 (zh) 2008-03-26 2008-05-29 甲醇、纤维素酒精-乙醇基车用清洁燃料添加剂

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 200810064177 CN101544916B (zh) 2008-03-26 2008-03-26 甲醇、乙醇基车用清洁燃料添加剂及其制备方法

Publications (2)

Publication Number Publication Date
CN101544916A CN101544916A (zh) 2009-09-30
CN101544916B true CN101544916B (zh) 2013-08-14

Family

ID=41112928

Family Applications (1)

Application Number Title Priority Date Filing Date
CN 200810064177 Active CN101544916B (zh) 2008-03-26 2008-03-26 甲醇、乙醇基车用清洁燃料添加剂及其制备方法

Country Status (2)

Country Link
CN (1) CN101544916B (zh)
WO (1) WO2009117875A1 (zh)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102732333A (zh) * 2012-07-11 2012-10-17 温志明 一种b100车用燃料丁醇的制备方法
WO2015139161A1 (zh) * 2014-03-16 2015-09-24 黑龙江建业燃料有限责任公司 甲醇、乙醇基车用清洁燃料添加剂及制备方法
CN109370672A (zh) * 2018-09-20 2019-02-22 哈尔滨市艾川生物能源科技有限公司 醇氢液化气燃料及制备方法
CN110540878A (zh) * 2019-09-19 2019-12-06 深圳市鲁奇科技有限公司 一种甲醇燃料及其制备方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003064567A1 (fr) * 2002-01-31 2003-08-07 Qiang Zhu Carburant complexe contenant de l'alcool, pouvant s'allumer facilement a basse temperature et degageant autant d'energie que de l'essence
CN1621500A (zh) * 2004-11-03 2005-06-01 肖丽 甲醇环保汽油
CN1916126A (zh) * 2006-09-07 2007-02-21 黑龙江建业燃料有限责任公司 一种m80～m90、e80～e90醇基车用燃料添加剂的制备方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6858048B1 (en) * 2001-04-18 2005-02-22 Standard Alcohol Company Of America, Inc. Fuels for internal combustion engines
CN1219858C (zh) * 2004-06-11 2005-09-21 黑龙江建业燃料有限责任公司 一种车用乙醇清洁燃料
CN1226396C (zh) * 2004-06-11 2005-11-09 黑龙江建业燃料有限责任公司 一种醇类清洁燃料
CN1824738A (zh) * 2006-04-05 2006-08-30 黑龙江建业燃料有限责任公司 一种高效醇基汽油燃料添加剂的制备方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003064567A1 (fr) * 2002-01-31 2003-08-07 Qiang Zhu Carburant complexe contenant de l'alcool, pouvant s'allumer facilement a basse temperature et degageant autant d'energie que de l'essence
CN1621500A (zh) * 2004-11-03 2005-06-01 肖丽 甲醇环保汽油
CN1916126A (zh) * 2006-09-07 2007-02-21 黑龙江建业燃料有限责任公司 一种m80～m90、e80～e90醇基车用燃料添加剂的制备方法

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
《车用乙醇汽油分层问题的研究》;龚冬梅等;《河南化工》;20031230(第6期);第11页左栏第2段至第12页左栏第4段 *
黄文轩.《石油添加剂和润滑油的分类》.《润滑剂添加剂应用指南》.中国石化出版社,2003,第341页. *
龚冬梅等.《车用乙醇汽油分层问题的研究》.《河南化工》.2003,(第6期),

Also Published As

Publication number Publication date
WO2009117875A1 (zh) 2009-10-01
CN101544916A (zh) 2009-09-30

Similar Documents

Publication Publication Date Title
Babu et al. Butanol and pentanol: The promising biofuels for CI engines–A review
CN101544915A (zh) 甲醇基车用清洁燃料及其制备方法
CN100591747C (zh) 一种m80～m90、e80～e90醇基车用燃料添加剂的制备方法
CN101343574A (zh) 甲醇合成汽油的配制工艺
CN101220301A (zh) 一种甲醇汽油燃料及其制备方法
CN101544916B (zh) 甲醇、乙醇基车用清洁燃料添加剂及其制备方法
CN102504890A (zh) 一种复合型甲醇柴油及其制备方法
CN101962582B (zh) 一种乙酰丙酸乙酯柴油混合燃料
CN111647447A (zh) 一种费托合成液蜡环保型生物燃料及其制备工艺
CN102977937A (zh) 一种车用混合燃油
CN104726149A (zh) 一种生物基甲醇汽油复合助剂及生物基高比例甲醇汽油
CN102925224A (zh) 一种b5生物柴油调和燃料及其制备方法
CN101709234A (zh) 甲醇柴油复合添加剂及制备方法
CN101445754A (zh) 改善甲醇柴油低温启动性的添加剂
CN101544917A (zh) 乙醇基车用清洁燃料及其制备方法
CN105038873A (zh) 一种醇基柴油添加剂及醇基柴油的制备方法
TÜCCAR et al. Experimental investigation of engine performance and emission characteristics of a diesel engine using blends containing microalgae biodiesel, n-butanol and diesel fuel
CN111171883A (zh) 一种戊酸酯类柴油混合燃料
CN110117507B (zh) 生物基高十六烷值柴油添加剂、其制法及清洁柴油组合物
CN103911185B (zh) 一种甲基汽油及其生产方法
CN100516181C (zh) 一种醇基复合汽油及其制备方法
CN111057597A (zh) 甲醇燃料改性剂、变性甲醇燃料、变性甲醇复合燃料及其制备方法
CN101886004A (zh) 一种甲醇汽油添加剂及其配制的甲醇汽油以及它们的生产方法
CN107099347B (zh) 一种清洁环保的醚基柴油及其制备方法
CN101597524A (zh) 化合柴油

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
EE01 Entry into force of recordation of patent licensing contract

Application publication date: 20090930

Assignee: Jianye Fuel Co., Ltd., Heilongjiang

Assignor: Wang Jianye

Contract record no.: 2013230001800

Denomination of invention: Automobile-used methanol and ethanol-based clean fuel additive and preparation method thereof

Granted publication date: 20130814

License type: Exclusive License

Record date: 20130929

LICC Enforcement, change and cancellation of record of contracts on the licence for exploitation of a patent or utility model
TR01 Transfer of patent right

Effective date of registration: 20170417

Address after: 68 No. 150000 Heilongjiang city of Harbin Province, Binxian Binxi economic and Technological Development Zone Avenue

Patentee after: Heilongjiang Jianye in Bio Energy Co. Ltd.

Address before: 150040, Harbin, Xiangfang District, Heping Road, No., building 12, building 54

Patentee before: Wang Jianye

TR01 Transfer of patent right