CN110774675A - 一种耐火玻璃钢复合板及其制作方法 - Google Patents
一种耐火玻璃钢复合板及其制作方法 Download PDFInfo
- Publication number
- CN110774675A CN110774675A CN201911099163.9A CN201911099163A CN110774675A CN 110774675 A CN110774675 A CN 110774675A CN 201911099163 A CN201911099163 A CN 201911099163A CN 110774675 A CN110774675 A CN 110774675A
- Authority
- CN
- China
- Prior art keywords
- layer
- glass fiber
- fiber reinforced
- reinforced plastic
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011152 fibreglass Substances 0.000 title claims abstract description 72
- 230000009970 fire resistant effect Effects 0.000 title claims abstract description 47
- 239000002131 composite material Substances 0.000 title claims abstract description 45
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 19
- 239000010410 layer Substances 0.000 claims abstract description 112
- 238000005336 cracking Methods 0.000 claims abstract description 34
- 239000004744 fabric Substances 0.000 claims abstract description 28
- 230000001070 adhesive effect Effects 0.000 claims abstract description 27
- 239000000853 adhesive Substances 0.000 claims abstract description 26
- 239000002344 surface layer Substances 0.000 claims abstract description 24
- 239000011248 coating agent Substances 0.000 claims abstract description 13
- 238000000576 coating method Methods 0.000 claims abstract description 13
- 229920000049 Carbon (fiber) Polymers 0.000 claims abstract description 4
- 239000004917 carbon fiber Substances 0.000 claims abstract description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical group C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 38
- 239000003365 glass fiber Substances 0.000 claims description 30
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 29
- 239000003063 flame retardant Substances 0.000 claims description 26
- 239000000835 fiber Substances 0.000 claims description 23
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 23
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 23
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 22
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims description 22
- 239000003822 epoxy resin Substances 0.000 claims description 22
- 229920001568 phenolic resin Polymers 0.000 claims description 22
- 239000005011 phenolic resin Substances 0.000 claims description 22
- 229920000647 polyepoxide Polymers 0.000 claims description 22
- 239000004408 titanium dioxide Substances 0.000 claims description 19
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 15
- 239000006004 Quartz sand Substances 0.000 claims description 13
- 239000000945 filler Substances 0.000 claims description 13
- -1 polytetrafluoroethylene Polymers 0.000 claims description 13
- 239000000919 ceramic Substances 0.000 claims description 12
- 229910052751 metal Inorganic materials 0.000 claims description 12
- 239000002184 metal Substances 0.000 claims description 12
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 12
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 12
- 230000002745 absorbent Effects 0.000 claims description 11
- 239000002250 absorbent Substances 0.000 claims description 11
- 229920006305 unsaturated polyester Polymers 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 10
- 230000008569 process Effects 0.000 claims description 10
- 229920006337 unsaturated polyester resin Polymers 0.000 claims description 10
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 9
- DZUDZSQDKOESQQ-UHFFFAOYSA-N cobalt hydrogen peroxide Chemical compound [Co].OO DZUDZSQDKOESQQ-UHFFFAOYSA-N 0.000 claims description 8
- 235000012239 silicon dioxide Nutrition 0.000 claims description 8
- 239000000377 silicon dioxide Substances 0.000 claims description 8
- 238000003723 Smelting Methods 0.000 claims description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 229910000531 Co alloy Inorganic materials 0.000 claims description 4
- 229920002430 Fibre-reinforced plastic Polymers 0.000 claims description 4
- QXZUUHYBWMWJHK-UHFFFAOYSA-N [Co].[Ni] Chemical compound [Co].[Ni] QXZUUHYBWMWJHK-UHFFFAOYSA-N 0.000 claims description 4
- 239000012790 adhesive layer Substances 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- 238000007731 hot pressing Methods 0.000 claims description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 3
- 239000004814 polyurethane Substances 0.000 claims description 3
- 229920002635 polyurethane Polymers 0.000 claims description 3
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 3
- 125000001246 bromo group Chemical group Br* 0.000 claims description 2
- 239000012768 molten material Substances 0.000 claims description 2
- 230000007797 corrosion Effects 0.000 abstract description 4
- 238000005260 corrosion Methods 0.000 abstract description 4
- 238000010521 absorption reaction Methods 0.000 abstract description 3
- 239000000463 material Substances 0.000 description 6
- 229910052736 halogen Inorganic materials 0.000 description 3
- 150000002367 halogens Chemical class 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
- 239000012796 inorganic flame retardant Substances 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 229920001225 polyester resin Polymers 0.000 description 2
- 239000004645 polyester resin Substances 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 239000012779 reinforcing material Substances 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- BZQKBFHEWDPQHD-UHFFFAOYSA-N 1,2,3,4,5-pentabromo-6-[2-(2,3,4,5,6-pentabromophenyl)ethyl]benzene Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1CCC1=C(Br)C(Br)=C(Br)C(Br)=C1Br BZQKBFHEWDPQHD-UHFFFAOYSA-N 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 235000019738 Limestone Nutrition 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- YUWBVKYVJWNVLE-UHFFFAOYSA-N [N].[P] Chemical compound [N].[P] YUWBVKYVJWNVLE-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010612 desalination reaction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 230000033116 oxidation-reduction process Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229910052903 pyrophyllite Inorganic materials 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011208 reinforced composite material Substances 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 125000004469 siloxy group Chemical group [SiH3]O* 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
- 238000005491 wire drawing Methods 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
- B32B27/20—Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/40—Layered products comprising a layer of synthetic resin comprising polyurethanes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/42—Layered products comprising a layer of synthetic resin comprising condensation resins of aldehydes, e.g. with phenols, ureas or melamines
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
- B32B3/26—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
- B32B3/266—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by an apertured layer, the apertures going through the whole thickness of the layer, e.g. expanded metal, perforated layer, slit layer regular cells B32B3/12
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
- B32B37/1284—Application of adhesive
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
- B32B37/24—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer not being coherent before laminating, e.g. made up from granular material sprinkled onto a substrate
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/06—Unsaturated polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
- B32B37/24—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer not being coherent before laminating, e.g. made up from granular material sprinkled onto a substrate
- B32B2037/243—Coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/02—Coating on the layer surface on fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/26—Polymeric coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/10—Inorganic fibres
- B32B2262/106—Carbon fibres, e.g. graphite fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/306—Resistant to heat
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/306—Resistant to heat
- B32B2307/3065—Flame resistant or retardant, fire resistant or retardant
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/54—Yield strength; Tensile strength
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/554—Wear resistance
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/558—Impact strength, toughness
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/582—Tearability
- B32B2307/5825—Tear resistant
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/71—Resistive to light or to UV
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/752—Corrosion inhibitor
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0856—Iron
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2289—Oxides; Hydroxides of metals of cobalt
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Laminated Bodies (AREA)
Abstract
本发明涉及玻璃钢技术领域，是一种耐火玻璃钢复合板及其制作方法。包括耐火玻璃钢层、防裂层、表层、带孔布、底层，所述耐火玻璃钢层一侧通过胶黏剂粘合防裂层，所述防裂层上设置表层，所述耐火玻璃钢层另一侧敷设有带孔布，所述带孔布上涂覆所述底层；所述防裂层为碳纤维加强筋网；所述表层为耐磨复合层；所述底层为涂覆耐磨复合层。本发明采用的耐火玻璃钢层有较高的耐高温、耐火、阻燃性，能够延长玻璃钢板材的整体使用寿命；设置的带孔布、防裂层的韧性高、抗拉强度大，能够防止玻璃钢板材出现开裂现象；表层和底层设置耐磨复合层，具有良好的耐磨性能、强度、防腐，并具有紫外线吸收能力，进一步提高了玻璃钢的使用寿命和综合性能。
Description
技术领域
本发明涉及玻璃钢技术领域，更具体的，是一种耐火玻璃钢复合板及其制作方法。
背景技术
玻璃钢复合板材以其独具的强耐腐蚀性能、内表面光滑、输送能耗低、使用寿命长、运输安装方便、不需维修及综合造价低等诸多优势在石油、电力、化工、造纸、城市给排水、工厂污水处理、海水淡化、煤气输送等行业取得了广泛的应用。
发明内容
本发明的目的在于提供一种耐高温、耐火、阻燃性较好的玻璃钢复合板，以及其制作方法。
为实现上述目的，本发明提供如下技术方案：
一种耐火玻璃钢复合板，包括耐火玻璃钢层、防裂层、表层、带孔布、底层，所述耐火玻璃钢层一侧通过胶黏剂粘合防裂层，所述防裂层上设置表层，所述耐火玻璃钢层另一侧敷设有带孔布，所述带孔布上涂覆所述底层；所述防裂层为碳纤维加强筋网；所述表层为耐磨复合层；所述底层为涂覆耐磨复合层；
所述耐火玻璃钢层包括，不饱和聚酯树脂、酚醛树脂、环氧树脂、玻璃纤维、硅烷偶联剂、碳化硅、氧化铝、石英砂、阻燃剂、金属填料；按照重量份数包括如下份数组分：不饱和聚酯树脂30-40份、酚醛树脂15-25份、环氧树脂5-15份、玻璃纤维8-15份、硅烷偶联剂2-8份、碳化硅8-20份、氧化铝8-20份、石英砂25-50份、二氧化硅4-10份、二氧化钴4-8份、二氧化钛4-8份、阻燃剂1-8份、金属填料1-5份。
进一步的，所述金属填料为细度在200-500目之间的铜粉、铁粉、钨粉或者镍钴合金中的一种或者多种。
进一步的，所述阻燃剂选用溴系列阻燃剂。
进一步的，所述表层和底层所述耐磨复合层包含：环氧树脂、酚醛树脂、玻璃纤维增强不饱和聚酯、聚四氟乙烯纤维、二氧化钛、陶瓷纤维、碳化硅、紫外线吸收剂；按照重量份数包括如下份数组分：所述环氧树脂为51-60份，所述酚醛树脂为21-25份，所述玻璃纤维增强不饱和聚酯为41-60份，所述聚四氟乙烯纤维为18-25份，所述二氧化钛为2-8份，所述陶瓷纤维为5-10份，所述碳化硅为2-5份、紫外线吸收剂1-10份。
进一步的，所述的耐火玻璃钢复合板的制作工艺包括：
制作耐火玻璃钢层；
耐火玻璃钢层一侧通过胶黏剂粘合防裂层；
耐火玻璃钢层另一侧通过胶黏剂粘合敷设带孔布；
防裂层上通过胶黏剂涂覆表层；
带孔布上通过胶黏剂涂覆底层；
热压固化。
进一步的，所述耐火玻璃钢层的制作包括步骤：
不饱和聚酯树脂、酚醛树脂、环氧树脂、玻璃纤维、碳化硅、氧化铝、石英砂、二氧化硅、二氧化钴、二氧化钛加入熔炼机中熔炼成熔融物一；
在熔融物一中加入硅烷偶联剂、阻燃剂、金属填料，搅拌为混合融体；
混合融体加入预成型模中进行预成型；
将预成型物加热连续固化成型。
进一步的，所述耐磨复合层的制作包括步骤：
环氧树脂、酚醛树脂、玻璃纤维增强不饱和聚酯、聚四氟乙烯纤维、二氧化钛、陶瓷纤维、碳化硅、紫外线吸收剂加入熔炼机中熔炼成熔融物二，
熔融物二加入预成型模中进行预成型；
将预成型物加热连续固化成型。
进一步的，所述耐火玻璃钢层涂覆胶黏剂包括步骤：
用刮板将聚氨酯胶满批1-3mm厚的胶粘层，然后用有齿形板的有齿形的一边以直线或其它形拉出条纹状，刮板平面相交呈40度-50度；
按排列顺序将防裂层或带孔布粘贴于胶黏剂层上，在胶黏剂固化前调整防裂层或带孔布的位置。
本申请的有益效果：本发明耐火玻璃钢复合板制备工艺简单，本发明采用的耐火玻璃钢层有较高的耐高温、耐火、阻燃的优点，能够延长玻璃钢板材的整体使用寿命；设置的带孔布、防裂层韧性高、抗拉强度大，提高复合材料的韧性、强度，能够防止玻璃钢板材出现开裂现象；表层和底层设置耐磨复合层，具有良好的耐磨性能、强度、防腐，并具有紫外线吸收能力，进一步提高了玻璃钢的使用寿命和综合性能。
附图说明
图1为本申请的一个实施例的结构组成示意图。
图中：
1-表层包括
2-防裂层
3-耐火玻璃钢层
4-带孔布
5-底层。
具体实施方式
下面将结合本发明实施例中的附图，对本发明实施例中的技术方案进行清楚、完整地描述，显然，所描述的实施例仅仅是本发明一部分实施例，而不是全部的实施例。基于本发明中的实施例，本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例，都属于本发明保护的范围。
请参阅附图，本发明为了一种耐火玻璃钢复合板，包括耐火玻璃钢层、防裂层、表层、带孔布、底层，所述耐火玻璃钢层一侧通过胶黏剂粘合防裂层，所述防裂层上设置表层，所述耐火玻璃钢层另一侧敷设有带孔布，所述带孔布上涂覆所述底层；所述防裂层为碳纤维加强筋网；所述表层为耐磨复合层；所述底层为涂覆耐磨复合层。
所述耐火玻璃钢层包括，不饱和聚酯树脂、酚醛树脂、环氧树脂、玻璃纤维、硅烷偶联剂、碳化硅、氧化铝、石英砂、阻燃剂、金属填料。
玻璃纤维是叶腊石、石英砂、石灰石、白云石、硼钙石、硼镁石七种矿石为原料经高温熔制、拉丝、络纱、织布等工艺制造成的，具有耐热性强、抗腐蚀性好、抗拉强度大，机械强度高，用作复合材料中的增强材料。
硅烷偶联剂用于玻璃纤维增强塑料，硅烷氧基对无机物具有反应性，有机官能基对有机物具有反应性或相容性，当硅烷偶联剂介于无机和有机界面之间，可形成有机基体-硅烷偶联剂-无机基体的结合层，改善无机填料与树脂之间的相容性；能改善填料在树脂中的分散性及粘合力，改善玻璃纤维和树脂的粘合性能，提高玻璃纤维增强复合材料的强度；硅烷偶联剂还能与界面发生化学反应，使耐火玻璃钢层与胶黏剂更好的结合，从而提高胶接强度。
碳化硅、氧化铝、石英砂具有较好的耐火耐高温性能。
阻燃剂主要是针对高分子材料的阻燃设计的。通过添加型阻燃剂经由机械混合方法加入到聚合物中，使耐火玻璃钢层具有阻燃性的。目前添加型阻燃剂主要有有机阻燃剂和无机阻燃剂，卤系阻燃剂(有机氯化物和有机溴化物)和非卤。有机是以溴系、磷氮系、氮系和红磷及化合物为代表的一些阻燃剂，无机主要是三氧化二锑、氢氧化镁、氢氧化铝，硅系等阻燃体系。本实施例中，选用含卤素的阻燃剂溴系列阻燃剂，在热塑性树脂中具备阻燃效率高，制得的材料力学性能好，如十溴二苯乙烷。
表层和底层的耐磨复合层包含：环氧树脂、酚醛树脂、玻璃纤维增强不饱和聚酯、聚四氟乙烯纤维、二氧化钛、陶瓷纤维、碳化硅、紫外线吸收剂。
不仅具有较高的耐磨性能，还通过采用不饱和聚酯树脂及其他辅助材料做为固化体系，使用玻璃纤维、聚四氟乙烯、陶瓷纤维做为增强材料，生产高性能复合线性材料，通过合理的配方体系提高产品的强度。添加的紫外线吸收剂是一种光稳定剂，能吸收阳光及荧光光源中的紫外线部分，而本身不发生变化。由于太阳光线中含有大量对有色物体有害的紫外光，其波长约290-460纳米，这些有害的紫外光通过化学上的氧化还原作用，使颜色分子最后分解褪色。使用紫外线吸收剂对受保护的物体实施有效的防止，或削弱其对颜色的破坏。紫外线吸收剂热稳定性好，即使在加工中也不会因热而变化，热挥发性小，化学稳定性好；不与制品中材料组分发生不利反应；混溶性好，可均匀地分散在材料中；且不溶或难溶于水，在表层和底层的耐磨复合层中提升玻璃钢复合板起到保护作用。
所述耐火玻璃钢层按照重量份数包括如下份数组分：不饱和聚酯树脂30-40份、酚醛树脂15-25份、环氧树脂5-15份、玻璃纤维8-15份、硅烷偶联剂2-8份、碳化硅8-20份、氧化铝8-20份、石英砂25-50份、二氧化硅4-10份、二氧化钴4-8份、二氧化钛4-8份、阻燃剂1-8份、金属填料1-5份。所述金属填料为细度在200-500目之间的铜粉、铁粉、钨粉或者镍钴合金中的一种或者多种。
实施例1如下：
| 饱和聚酯树脂 | 30份 | 石英砂 | 42份 |
| 酚醛树脂 | 22份 | 二氧化硅 | 5份 |
| 环氧树脂 | 12份 | 二氧化钴 | 5份 |
| 玻璃纤维 | 12份 | 二氧化钛 | 5份 |
| 硅烷偶联剂 | 8份 | 阻燃剂 | 5份 |
| 碳化硅 | 12份 | 铁粉 | 5份 |
| 氧化铝 | 8份 |
实施例2如下：
| 饱和聚酯树脂 | 38份 | 石英砂 | 30份 |
| 酚醛树脂 | 18份 | 二氧化硅 | 8份 |
| 环氧树脂 | 8份 | 二氧化钴 | 8份 |
| 玻璃纤维 | 12份 | 二氧化钛 | 8份 |
| 硅烷偶联剂 | 8份 | 阻燃剂 | 2份 |
| 碳化硅 | 15份 | 铁粉 | 2份 |
| 氧化铝 | 15份 | 镍钴合金 | 2份 |
所述表层和底层所述耐磨复合层按照重量份数包括如下份数组分：所述环氧树脂为51-60份，所述酚醛树脂为21-25份，所述玻璃纤维增强不饱和聚酯为41-60份，所述聚四氟乙烯纤维为18-25份，所述二氧化钛为2-8份，所述陶瓷纤维为5-10份，所述碳化硅为2-5份、紫外线吸收剂1-10份。
实施例1如下：
| 环氧树脂 | 51份 | 二氧化钛 | 3份 |
| 酚醛树脂 | 22份 | 陶瓷纤维 | 8份 |
| 玻璃纤维增强不饱和聚酯 | 55份 | 碳化硅 | 5份 |
| 聚四氟乙烯纤维 | 20份 | 紫外线吸收剂 | 2份 |
实施例2如下：
| 环氧树脂 | 58份 | 二氧化钛 | 4份 |
| 酚醛树脂 | 22份 | 陶瓷纤维 | 5份 |
| 玻璃纤维增强不饱和聚酯 | 45份 | 碳化硅 | 4份 |
| 聚四氟乙烯纤维 | 22份 | 紫外线吸收剂 | 8份 |
耐火玻璃钢复合板的制作工艺包括：制作耐火玻璃钢层；耐火玻璃钢层一侧通过胶黏剂粘合防裂层；耐火玻璃钢层另一侧通过胶黏剂粘合敷设带孔布；防裂层上通过胶黏剂涂覆表层；带孔布上通过胶黏剂涂覆底层；热压固化。
所述耐火玻璃钢层的制作包括步骤：不饱和聚酯树脂、酚醛树脂、环氧树脂、玻璃纤维、碳化硅、氧化铝、石英砂、二氧化硅、二氧化钴、二氧化钛加入熔炼机中熔炼成熔融物一；在熔融物一中加入硅烷偶联剂、阻燃剂、金属填料、紫外线吸收剂，搅拌为混合融体；混合融体加入预成型模中进行预成型；将预成型物加热连续固化成型。熔炼温度为70℃-95℃，混炼时间为30min-60min，搅拌为混合融体过程中保持加热维持温度；预成型物放入成型加热模具中，在牵引机的牵引下通过加热连续固化成型，得到耐火玻璃钢层面板。
所述耐磨复合层的制作包括步骤：环氧树脂、酚醛树脂、玻璃纤维增强不饱和聚酯、聚四氟乙烯纤维、二氧化钛、陶瓷纤维、碳化硅加入熔炼机中熔炼成熔融物二，熔融物二加入预成型模中进行预成型；将预成型物加热连续固化成型。
所述耐火玻璃钢层涂覆胶黏剂包括步骤：用刮板将聚氨酯胶满批1-3mm厚的胶粘层，然后用有齿形板的有齿形的一边以直线或其它形拉出条纹状，刮板平面相交呈40度-50度；按排列顺序将防裂层或带孔布粘贴于胶黏剂层上，在胶黏剂固化前调整防裂层或带孔布的位置。
本发明耐火玻璃钢复合板制备工艺简单，本发明采用的耐火玻璃钢层有较高的耐高温、耐火、阻燃的优点，能够延长玻璃钢板材的整体使用寿命；设置的带孔布、防裂层韧性高、抗拉强度大，提高复合材料的韧性、强度，能够防止玻璃钢板材出现开裂现象；表层和底层设置耐磨复合层，具有良好的耐磨性能、强度、防腐，并具有紫外线吸收能力，进一步提高了玻璃钢的使用寿命和综合性能。
对于本领域的普通技术人员而言，上述已经展示和描述了本发明的实施例，就实现上述所述的功能技术特点，在程序编程和技术运算实现层面都不存在难度，对于可以理解在不脱离本发明的原理和精神的情况下可以对这些实施例进行多种变化、修改、替换和变型，本发明的范围由所附权利要求及其等同物限定。
Claims (8)
1.一种耐火玻璃钢复合板，包括耐火玻璃钢层、防裂层、表层、带孔布、底层，所述耐火玻璃钢层一侧通过胶黏剂粘合防裂层，所述防裂层上设置表层，所述耐火玻璃钢层另一侧敷设有带孔布，所述带孔布上涂覆所述底层；所述防裂层为碳纤维加强筋网；所述表层为耐磨复合层；所述底层为涂覆耐磨复合层；
所述耐火玻璃钢层包括，不饱和聚酯树脂、酚醛树脂、环氧树脂、玻璃纤维、硅烷偶联剂、碳化硅、氧化铝、石英砂、阻燃剂、金属填料；按照重量份数包括份数组分：不饱和聚酯树脂30-40份、酚醛树脂15-25份、环氧树脂5-15份、玻璃纤维8-15份、硅烷偶联剂2-8份、碳化硅8-20份、氧化铝8-20份、石英砂25-50份、二氧化硅4-10份、二氧化钴4-8份、二氧化钛4-8份、阻燃剂1-8份、金属填料1-5份。
2.根据权利要求1所述的一种耐火玻璃钢复合板，其特征在于：所述金属填料为细度在200-500目之间的铜粉、铁粉、钨粉或镍钴合金中的一种或多种。
3.根据权利要求2所述的一种耐火玻璃钢复合板，其特征在于：所述阻燃剂选用溴系列阻燃剂。
4.根据权利要求3所述的一种耐火玻璃钢复合板，其特征在于：所述表层和底层所述耐磨复合层包含：环氧树脂、酚醛树脂、玻璃纤维增强不饱和聚酯、聚四氟乙烯纤维、二氧化钛、陶瓷纤维、碳化硅、紫外线吸收剂；按照重量份数包括份数组分：所述环氧树脂为51-60份，所述酚醛树脂为21-25份，所述玻璃纤维增强不饱和聚酯为41-60份，所述聚四氟乙烯纤维为18-25份，所述二氧化钛为2-8份，所述陶瓷纤维为5-10份，所述碳化硅为2-5份、紫外线吸收剂1-10份。
5.一种耐火玻璃钢复合板的制作工艺，其特征在于：如权利要求4所述的耐火玻璃钢复合板的制作工艺包括：
制作耐火玻璃钢层；
耐火玻璃钢层一侧通过胶黏剂粘合防裂层；
耐火玻璃钢层另一侧通过胶黏剂粘合敷设带孔布；
防裂层上通过胶黏剂涂覆表层；
带孔布上通过胶黏剂涂覆底层；
热压固化。
6.根据权利要求5所述的一种耐火玻璃钢复合板的制作工艺，其特征在于：所述耐火玻璃钢层的制作包括步骤：
不饱和聚酯树脂、酚醛树脂、环氧树脂、玻璃纤维、碳化硅、氧化铝、石英砂、二氧化硅、二氧化钴、二氧化钛加入熔炼机中熔炼成熔融物一；
在熔融物一中加入硅烷偶联剂、阻燃剂、金属填料，搅拌为混合融体；
混合融体加入预成型模中进行预成型；
将预成型物加热连续固化成型。
7.根据权利要求5所述的一种耐火玻璃钢复合板的制作工艺，其特征在于：所述耐磨复合层的制作包括步骤：
环氧树脂、酚醛树脂、玻璃纤维增强不饱和聚酯、聚四氟乙烯纤维、二氧化钛、陶瓷纤维、碳化硅、紫外线吸收剂加入熔炼机中熔炼成熔融物二，
熔融物二加入预成型模中进行预成型；
将预成型物加热连续固化成型。
8.根据权利要求5所述的一种耐火玻璃钢复合板的制作工艺，其特征在于：所述耐火玻璃钢层涂覆胶黏剂包括步骤：
用刮板将聚氨酯胶满批1-3mm的胶粘层，然后用有齿形板的有齿形的一边以直线拉出条纹状，刮板平面相交呈40度-50度；
按排列顺序将防裂层或带孔布粘贴于胶黏剂层上，在胶黏剂固化前调整防裂层或带孔布的位置。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911099163.9A CN110774675A (zh) | 2019-11-12 | 2019-11-12 | 一种耐火玻璃钢复合板及其制作方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911099163.9A CN110774675A (zh) | 2019-11-12 | 2019-11-12 | 一种耐火玻璃钢复合板及其制作方法 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110774675A true CN110774675A (zh) | 2020-02-11 |
Family
ID=69390366
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201911099163.9A Pending CN110774675A (zh) | 2019-11-12 | 2019-11-12 | 一种耐火玻璃钢复合板及其制作方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110774675A (zh) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111218125A (zh) * | 2020-03-05 | 2020-06-02 | 华威博奥(文安)电力设备有限公司 | 一种有机耐火隔热材料及其制备方法 |
| CN116444281A (zh) * | 2023-06-13 | 2023-07-18 | 内蒙古建筑职业技术学院(内蒙古自治区建筑职工培训中心) | 一种硫酸钠耐火材料 |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2093592U (zh) * | 1991-06-10 | 1992-01-22 | 吴锦志 | 新型阻燃玻璃钢浴缸体外壳水池体外壳 |
| CN103183906A (zh) * | 2011-12-27 | 2013-07-03 | 常熟市亚美模特儿衣架有限公司 | 阻燃的酚醛玻璃钢复合材料 |
| CN104558643A (zh) * | 2013-10-14 | 2015-04-29 | 青岛市首胜实业有限公司 | 耐火玻璃钢的制备方法 |
| CN206124365U (zh) * | 2016-10-12 | 2017-04-26 | 王建涛 | 铝箔玻璃钢板 |
| CN106917952A (zh) * | 2017-05-10 | 2017-07-04 | 马鞍山市润启新材料科技有限公司 | 一种新型建材管 |
| CN106976284A (zh) * | 2017-05-14 | 2017-07-25 | 南通德瑞森复合材料有限公司 | 一种耐磨玻璃钢板材 |
| CN107119721A (zh) * | 2017-05-14 | 2017-09-01 | 南通德瑞森复合材料有限公司 | 一种高强度玻璃钢井盖 |
| CN107674395A (zh) * | 2017-11-17 | 2018-02-09 | 成都双瑞暖通设备有限公司 | 一种耐高温玻璃钢 |
| CN108047673A (zh) * | 2017-12-15 | 2018-05-18 | 常熟市金亿复合材料有限公司 | 一种玻璃钢耐腐蚀复合板 |
-
2019
- 2019-11-12 CN CN201911099163.9A patent/CN110774675A/zh active Pending
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2093592U (zh) * | 1991-06-10 | 1992-01-22 | 吴锦志 | 新型阻燃玻璃钢浴缸体外壳水池体外壳 |
| CN103183906A (zh) * | 2011-12-27 | 2013-07-03 | 常熟市亚美模特儿衣架有限公司 | 阻燃的酚醛玻璃钢复合材料 |
| CN104558643A (zh) * | 2013-10-14 | 2015-04-29 | 青岛市首胜实业有限公司 | 耐火玻璃钢的制备方法 |
| CN206124365U (zh) * | 2016-10-12 | 2017-04-26 | 王建涛 | 铝箔玻璃钢板 |
| CN106917952A (zh) * | 2017-05-10 | 2017-07-04 | 马鞍山市润启新材料科技有限公司 | 一种新型建材管 |
| CN106976284A (zh) * | 2017-05-14 | 2017-07-25 | 南通德瑞森复合材料有限公司 | 一种耐磨玻璃钢板材 |
| CN107119721A (zh) * | 2017-05-14 | 2017-09-01 | 南通德瑞森复合材料有限公司 | 一种高强度玻璃钢井盖 |
| CN107674395A (zh) * | 2017-11-17 | 2018-02-09 | 成都双瑞暖通设备有限公司 | 一种耐高温玻璃钢 |
| CN108047673A (zh) * | 2017-12-15 | 2018-05-18 | 常熟市金亿复合材料有限公司 | 一种玻璃钢耐腐蚀复合板 |
Non-Patent Citations (1)
| Title |
|---|
| 段慎修: "《矿山井筒装备防腐蚀技术》", 31 July 1992, 炭工业出版社 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111218125A (zh) * | 2020-03-05 | 2020-06-02 | 华威博奥(文安)电力设备有限公司 | 一种有机耐火隔热材料及其制备方法 |
| CN116444281A (zh) * | 2023-06-13 | 2023-07-18 | 内蒙古建筑职业技术学院(内蒙古自治区建筑职工培训中心) | 一种硫酸钠耐火材料 |
| CN116444281B (zh) * | 2023-06-13 | 2023-09-26 | 内蒙古建筑职业技术学院(内蒙古自治区建筑职工培训中心) | 一种硫酸钠耐火材料 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN110774675A (zh) | 一种耐火玻璃钢复合板及其制作方法 | |
| CN108239319A (zh) | 连续纤维增强热塑性树脂预浸带和格栅及其制备方法 | |
| CN105909704B (zh) | 一种散热性优良的复合刹车片 | |
| CN112009038A (zh) | 一种结构阻燃功能性复合材料及其制备方法 | |
| CN104387719A (zh) | 纤维增强酚醛树脂基复合材料及其制备方法 | |
| CN113544197A (zh) | 阻燃性复合材料 | |
| CN102502164A (zh) | 一种玄武岩纤维阻燃输送带及其制备方法 | |
| CN202152393U (zh) | 玄武岩纤维无捻粗纱布 | |
| CN109851280B (zh) | 一种用含砷废渣、浮选尾矿制备复合石英石板的方法 | |
| WO2017140125A1 (zh) | 一种由带导流层的预织件制成的非金属防腐采光板的制造方法 | |
| CN106189214A (zh) | 一种高强度mc尼龙改性纤维复合基材的制备方法 | |
| KR20200040699A (ko) | 페놀성 몰딩 물질 | |
| CN104774393A (zh) | 一种高流动性、高模量耐高温帆布粘合胶料及其制备方法 | |
| Sharma | An introduction to basalt rock fiber and comparative analysis of engineering properties of BRF and other natural composites | |
| CN106221199A (zh) | 一种高强度石墨烯尼龙复合结砖制备方法 | |
| CN106187140A (zh) | 一种复合吸尘型石墨烯米改性硅酸钙砖及其生产方法 | |
| CN105206952A (zh) | 玻璃钢外壳 | |
| CN106243701A (zh) | 一种耐高温膨胀复合环保建筑基材的制备方法 | |
| CN102477223A (zh) | 耐高温聚合物超硬耐磨复合材料及其制备方法 | |
| CN109706728A (zh) | 一种液体成型工艺用高效阻燃纤维织物及其制备方法 | |
| CN108440953A (zh) | 一种阻燃、抗静电复合材料及其制备方法 | |
| CN114426404A (zh) | 一种连续玄武岩纤维复合橡胶输送带及其制备方法 | |
| Deshmukh | Basalt-The Technical Fibre. | |
| CN216032921U (zh) | 一种玄武岩纤维与玻璃纤维多层复合绝缘板 | |
| CN116144118B (zh) | 一种耐高温输送带的橡胶材料及其制备方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20200211 |