CN106976284A - 一种耐磨玻璃钢板材 - Google Patents

一种耐磨玻璃钢板材 Download PDF

Info

Publication number
CN106976284A
CN106976284A CN201710336985.9A CN201710336985A CN106976284A CN 106976284 A CN106976284 A CN 106976284A CN 201710336985 A CN201710336985 A CN 201710336985A CN 106976284 A CN106976284 A CN 106976284A
Authority
CN
China
Prior art keywords
parts
reinforced plastic
plastic plate
plate layer
abrasion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201710336985.9A
Other languages
English (en)
Other versions
CN106976284B (zh
Inventor
周建军
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nantong Drayson Composites Co Ltd
Original Assignee
Nantong Drayson Composites Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nantong Drayson Composites Co Ltd filed Critical Nantong Drayson Composites Co Ltd
Priority to CN201710336985.9A priority Critical patent/CN106976284B/zh
Publication of CN106976284A publication Critical patent/CN106976284A/zh
Application granted granted Critical
Publication of CN106976284B publication Critical patent/CN106976284B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00—Layered products comprising a layer of natural or synthetic rubber
    • B32B25/14—Layered products comprising a layer of natural or synthetic rubber comprising synthetic rubber copolymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00—Layered products comprising a layer of natural or synthetic rubber
    • B32B25/10—Layered products comprising a layer of natural or synthetic rubber next to a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02—Organic and inorganic ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/28—Nitrogen-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/12—Esters; Ether-esters of cyclic polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/06—Unsaturated polyesters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10—Inorganic fibres
    • B32B2262/101—Glass fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10—Inorganic fibres
    • B32B2262/106—Carbon fibres, e.g. graphite fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2264/00—Composition or properties of particles which form a particulate layer or are present as additives
    • B32B2264/10—Inorganic particles
    • B32B2264/107—Ceramic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2270/00—Resin or rubber layer containing a blend of at least two different polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B32B2307/306—Resistant to heat
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/554—Wear resistance
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C08K2003/265—Calcium, strontium or barium carbonate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/28—Nitrogen-containing compounds
    • C08K2003/282—Binary compounds of nitrogen with aluminium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Laminated Bodies (AREA)

Abstract

本发明公开了一种耐磨玻璃钢板材，包括玻璃钢板材层，玻璃钢板材层上端面通过胶黏剂粘合上面板，玻璃钢板材层下端面通过胶黏剂粘合下面板，上面板上端面设置碳纤维加强筋网，碳纤维加强筋网上端面设置耐磨层，下面板下端面涂覆耐磨复合涂料，本发明制备工艺简单，具有抗压、耐磨、耐高温的优点，延长了玻璃钢板材的使用寿命。

Description

一种耐磨玻璃钢板材
技术领域
本发明涉及玻璃钢板材技术领域，具体为一种耐磨玻璃钢板材。
背景技术
玻璃钢板材以其独具的强耐腐蚀性能、内表面光滑、输送能耗低、使用寿命长、运输安装方便、不需维修及综合造价低等诸多优势在石油、电力、化工、造纸、城市给排水、工厂污水处理、海水淡化、煤气输送等行业取得了广泛的应用。而现有技术中的玻璃钢板材耐磨性和抗压性能均较差，使用寿命短。
发明内容
本发明的目的在于提供一种耐磨玻璃钢板材，以解决上述背景技术中提出的问题。
为实现上述目的，本发明提供如下技术方案：一种耐磨玻璃钢板材, 包括玻璃钢板材层，所述玻璃钢板材层上端面通过胶黏剂粘合上面板，所述玻璃钢板材层下端面通过胶黏剂粘合下面板，所述上面板上端面设置碳纤维加强筋网，所述碳纤维加强筋网上端面设置耐磨层，所述下面板下端面涂覆耐磨复合涂料。
优选的，所述玻璃钢板材层组分按重量份数包括不饱和聚酯树脂20-40份、酚醛树脂15-25份、环氧树脂5-15份、玻璃纤维8-18份、碳化硅微粉8-20份、纳米陶瓷颗粒5-15份、硅烷偶联剂2-8份、环己酮5-10份、氧化锆2-8份、可膨胀石墨5-10份、轻质碳酸钙2-10份、硼砂1-4份以及硅藻土2-6份。
优选的，所述耐磨层由羧基液态丁腈橡胶40%、邻苯二甲酸正丁酯15%、固化剂5%、二氧化钛20%、氮化铝10%和碳化硅10%组成。
优选的，所述玻璃钢板材层组分优选的成分配比为：不饱和聚酯树脂30份、酚醛树脂20份、环氧树脂10份、玻璃纤维13份、碳化硅微粉14份、纳米陶瓷颗粒10份、硅烷偶联剂5份、环己酮8份、氧化锆5份、可膨胀石墨8份、轻质碳酸钙6份、硼砂3份以及硅藻土4份。
优选的，所述玻璃钢板材层的制备工艺包括以下步骤：
A、将不饱和聚酯树脂、酚醛树脂、环氧树脂、玻璃纤维、碳化硅微粉、纳米陶瓷颗粒混合后加入混炼机中混炼，混炼温度为60℃-90℃，混炼时间为20min-40min，得到混合物A；
B、在混合物A中加入硅烷偶联剂、环己酮、氧化锆、可膨胀石墨、轻质碳酸钙、硼砂以及硅藻土，混合后加入搅拌机中进行低速搅拌，搅拌机转速为200-500转/分，搅拌时间为10min-20min，得到混合物B；
C、将步骤B得到的混合物加入预成型模中进行预成型；
D、将预成型物放入成型加热模具中，在牵引机的牵引下通过加热连续固化成型，得到玻璃钢板材层。
与现有技术相比，本发明的有益效果是：本发明制备工艺简单，本发明采用的玻璃钢板材层具有抗压、耐磨、耐高温的优点，能够延长玻璃钢板材的整体使用寿命；设置的碳纤维加强筋网韧性高、强度大、承压能力强，能够防止玻璃钢板材出现开裂现象；另外在碳纤维加强筋网上端面设置耐磨层，采用的耐磨层具有良好的耐磨性能，且附着力强、涂层薄且密，同时具有一定的防腐作用，进一步提高了玻璃钢板材的综合性能。
附图说明
图1为本发明剖视图。
具体实施方式
下面将结合本发明实施例中的附图，对本发明实施例中的技术方案进行清楚、完整地描述，显然，所描述的实施例仅仅是本发明一部分实施例，而不是全部的实施例。基于本发明中的实施例，本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例，都属于本发明保护的范围。
请参阅图1，本发明提供一种技术方案：一种耐磨玻璃钢板材, 包括玻璃钢板材层1，所述玻璃钢板材层1上端面通过胶黏剂粘合上面板2，所述玻璃钢板材层1下端面通过胶黏剂粘合下面板3，所述上面板2上端面设置碳纤维加强筋网4，所述碳纤维加强筋网4上端面设置耐磨层5，所述下面板3下端面涂覆耐磨复合涂料6。
本实施例中，玻璃钢板材层1组分按重量份数包括不饱和聚酯树脂20-40份、酚醛树脂15-25份、环氧树脂5-15份、玻璃纤维8-18份、碳化硅微粉8-20份、纳米陶瓷颗粒5-15份、硅烷偶联剂2-8份、环己酮5-10份、氧化锆2-8份、可膨胀石墨5-10份、轻质碳酸钙2-10份、硼砂1-4份以及硅藻土2-6份；耐磨层5由羧基液态丁腈橡胶40%、邻苯二甲酸正丁酯15%、固化剂5%、二氧化钛20%、氮化铝10%和碳化硅10%组成。
实施例一：
玻璃钢板材层1组分按重量份数包括不饱和聚酯树脂20份、酚醛树脂15份、环氧树脂5份、玻璃纤维8份、碳化硅微粉8份、纳米陶瓷颗粒5份、硅烷偶联剂2份、环己酮5份、氧化锆2份、可膨胀石墨5份、轻质碳酸钙2份、硼砂1份以及硅藻土2份。
本实施例中，玻璃钢板材层1的制备工艺包括以下步骤：
A、将不饱和聚酯树脂、酚醛树脂、环氧树脂、玻璃纤维、碳化硅微粉、纳米陶瓷颗粒混合后加入混炼机中混炼，混炼温度为60℃，混炼时间为20min，得到混合物A；
B、在混合物A中加入硅烷偶联剂、环己酮、氧化锆、可膨胀石墨、轻质碳酸钙、硼砂以及硅藻土，混合后加入搅拌机中进行低速搅拌，搅拌机转速为200转/分，搅拌时间为10min，得到混合物B；
C、将步骤B得到的混合物加入预成型模中进行预成型；
D、将预成型物放入成型加热模具中，在牵引机的牵引下通过加热连续固化成型，得到玻璃钢板材层。
实施例二：
玻璃钢板材层1组分按重量份数包括不饱和聚酯树脂40份、酚醛树脂25份、环氧树脂15份、玻璃纤维18份、碳化硅微粉20份、纳米陶瓷颗粒15份、硅烷偶联剂8份、环己酮10份、氧化锆8份、可膨胀石墨10份、轻质碳酸钙10份、硼砂4份以及硅藻土6份。
本实施例中，玻璃钢板材层1的制备工艺包括以下步骤：
A、将不饱和聚酯树脂、酚醛树脂、环氧树脂、玻璃纤维、碳化硅微粉、纳米陶瓷颗粒混合后加入混炼机中混炼，混炼温度为90℃，混炼时间为40min，得到混合物A；
B、在混合物A中加入硅烷偶联剂、环己酮、氧化锆、可膨胀石墨、轻质碳酸钙、硼砂以及硅藻土，混合后加入搅拌机中进行低速搅拌，搅拌机转速为500转/分，搅拌时间为20min，得到混合物B；
C、将步骤B得到的混合物加入预成型模中进行预成型；
D、将预成型物放入成型加热模具中，在牵引机的牵引下通过加热连续固化成型，得到玻璃钢板材层。
实施例三：
玻璃钢板材层1组分按重量份数包括不饱和聚酯树脂25份、酚醛树脂17份、环氧树脂8份、玻璃纤维10份、碳化硅微粉10份、纳米陶瓷颗粒7份、硅烷偶联剂3份、环己酮6份、氧化锆3份、可膨胀石墨6份、轻质碳酸钙3份、硼砂2份以及硅藻土3份。
本实施例中，玻璃钢板材层1的制备工艺包括以下步骤：
A、将不饱和聚酯树脂、酚醛树脂、环氧树脂、玻璃纤维、碳化硅微粉、纳米陶瓷颗粒混合后加入混炼机中混炼，混炼温度为65℃，混炼时间为25min，得到混合物A；
B、在混合物A中加入硅烷偶联剂、环己酮、氧化锆、可膨胀石墨、轻质碳酸钙、硼砂以及硅藻土，混合后加入搅拌机中进行低速搅拌，搅拌机转速为250转/分，搅拌时间为12min，得到混合物B；
C、将步骤B得到的混合物加入预成型模中进行预成型；
D、将预成型物放入成型加热模具中，在牵引机的牵引下通过加热连续固化成型，得到玻璃钢板材层。
实施例四：
玻璃钢板材层1组分按重量份数包括不饱和聚酯树脂35份、酚醛树脂22份、环氧树脂14份、玻璃纤维15份、碳化硅微粉15份、纳米陶瓷颗粒13份、硅烷偶联剂7份、环己酮8份、氧化锆7份、可膨胀石墨9份、轻质碳酸钙8份、硼砂3份以及硅藻土5份。
本实施例中，玻璃钢板材层1的制备工艺包括以下步骤：
A、将不饱和聚酯树脂、酚醛树脂、环氧树脂、玻璃纤维、碳化硅微粉、纳米陶瓷颗粒混合后加入混炼机中混炼，混炼温度为80℃，混炼时间为35min，得到混合物A；
B、在混合物A中加入硅烷偶联剂、环己酮、氧化锆、可膨胀石墨、轻质碳酸钙、硼砂以及硅藻土，混合后加入搅拌机中进行低速搅拌，搅拌机转速为400转/分，搅拌时间为16min，得到混合物B；
C、将步骤B得到的混合物加入预成型模中进行预成型；
D、将预成型物放入成型加热模具中，在牵引机的牵引下通过加热连续固化成型，得到玻璃钢板材层。
实施例五：
玻璃钢板材层1组分按重量份数包括不饱和聚酯树脂30份、酚醛树脂20份、环氧树脂10份、玻璃纤维13份、碳化硅微粉14份、纳米陶瓷颗粒10份、硅烷偶联剂5份、环己酮8份、氧化锆5份、可膨胀石墨8份、轻质碳酸钙6份、硼砂3份以及硅藻土4份。
本实施例中，玻璃钢板材层1的制备工艺包括以下步骤：
A、将不饱和聚酯树脂、酚醛树脂、环氧树脂、玻璃纤维、碳化硅微粉、纳米陶瓷颗粒混合后加入混炼机中混炼，混炼温度为75℃，混炼时间为30min，得到混合物A；
B、在混合物A中加入硅烷偶联剂、环己酮、氧化锆、可膨胀石墨、轻质碳酸钙、硼砂以及硅藻土，混合后加入搅拌机中进行低速搅拌，搅拌机转速为350转/分，搅拌时间为15min，得到混合物B；
C、将步骤B得到的混合物加入预成型模中进行预成型；
D、将预成型物放入成型加热模具中，在牵引机的牵引下通过加热连续固化成型，得到玻璃钢板材层。
将本发明各实施例制得的玻璃钢板材与常规方法制得的玻璃钢板材进行抗冲磨强度、抗压强度实验，得到数据如下表：
抗冲磨强度（h(kg/m2） 抗压强度（Mpa）
常规方法 7.5 40.6
实施例一 12.2 79.2
实施例二 12.5 79.5
实施例三 12.1 79.8
实施例四 12.0 79.6
实施例五 12.9 80.9
由以上表格数据可知，实施例五制得的玻璃钢板材能够达到最佳效果。
本发明制备工艺简单，本发明采用的玻璃钢板材层具有抗压、耐磨、耐高温的优点，能够延长玻璃钢板材的整体使用寿命；设置的碳纤维加强筋网韧性高、强度大、承压能力强，能够防止玻璃钢板材出现开裂现象；另外在碳纤维加强筋网上端面设置耐磨层，采用的耐磨层具有良好的耐磨性能，且附着力强、涂层薄且密，同时具有一定的防腐作用，进一步提高了玻璃钢板材的综合性能。
尽管已经示出和描述了本发明的实施例，对于本领域的普通技术人员而言，可以理解在不脱离本发明的原理和精神的情况下可以对这些实施例进行多种变化、修改、替换和变型，本发明的范围由所附权利要求及其等同物限定。

Claims (5)

1.一种耐磨玻璃钢板材, 包括玻璃钢板材层（1），其特征在于：所述玻璃钢板材层（1）上端面通过胶黏剂粘合上面板（2），所述玻璃钢板材层（1）下端面通过胶黏剂粘合下面板（3），所述上面板（2）上端面设置碳纤维加强筋网（4），所述碳纤维加强筋网（4）上端面设置耐磨层（5），所述下面板（3）下端面涂覆耐磨复合涂料（6）。
2.根据权利要求1所述的一种耐磨玻璃钢板材，其特征在于：所述玻璃钢板材层(1)组分按重量份数包括不饱和聚酯树脂20-40份、酚醛树脂15-25份、环氧树脂5-15份、玻璃纤维8-18份、碳化硅微粉8-20份、纳米陶瓷颗粒5-15份、硅烷偶联剂2-8份、环己酮5-10份、氧化锆2-8份、可膨胀石墨5-10份、轻质碳酸钙2-10份、硼砂1-4份以及硅藻土2-6份。
3.根据权利要求1所述的一种耐磨玻璃钢板材，其特征在于：所述耐磨层(5)由羧基液态丁腈橡胶40%、邻苯二甲酸正丁酯15%、固化剂5%、二氧化钛20%、氮化铝10%和碳化硅10%组成。
4.根据权利要求1所述的一种耐磨玻璃钢板材，其特征在于：所述玻璃钢板材层(1)组分优选的成分配比为：不饱和聚酯树脂30份、酚醛树脂20份、环氧树脂10份、玻璃纤维13份、碳化硅微粉14份、纳米陶瓷颗粒10份、硅烷偶联剂5份、环己酮8份、氧化锆5份、可膨胀石墨8份、轻质碳酸钙6份、硼砂3份以及硅藻土4份。
5.根据权利要求1所述的一种耐磨玻璃钢板材，其特征在于：所述玻璃钢板材层(1)的制备工艺包括以下步骤：
A、将不饱和聚酯树脂、酚醛树脂、环氧树脂、玻璃纤维、碳化硅微粉、纳米陶瓷颗粒混合后加入混炼机中混炼，混炼温度为60℃-90℃，混炼时间为20min-40min，得到混合物A；
B、在混合物A中加入硅烷偶联剂、环己酮、氧化锆、可膨胀石墨、轻质碳酸钙、硼砂以及硅藻土，混合后加入搅拌机中进行低速搅拌，搅拌机转速为200-500转/分，搅拌时间为10min-20min，得到混合物B；
C、将步骤B得到的混合物加入预成型模中进行预成型；
D、将预成型物放入成型加热模具中，在牵引机的牵引下通过加热连续固化成型，得到玻璃钢板材层。
CN201710336985.9A 2017-05-14 2017-05-14 一种耐磨玻璃钢板材 Active CN106976284B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710336985.9A CN106976284B (zh) 2017-05-14 2017-05-14 一种耐磨玻璃钢板材

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710336985.9A CN106976284B (zh) 2017-05-14 2017-05-14 一种耐磨玻璃钢板材

Publications (2)

Publication Number Publication Date
CN106976284A true CN106976284A (zh) 2017-07-25
CN106976284B CN106976284B (zh) 2018-11-09

Family

ID=59342768

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710336985.9A Active CN106976284B (zh) 2017-05-14 2017-05-14 一种耐磨玻璃钢板材

Country Status (1)

Country Link
CN (1) CN106976284B (zh)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110776727A (zh) * 2019-11-19 2020-02-11 佛山市壹诺复合材料有限公司 一种表面粗糙的耐磨的玻璃钢平板制作工艺
CN110774675A (zh) * 2019-11-12 2020-02-11 河北华强科技开发有限公司 一种耐火玻璃钢复合板及其制作方法
CN112876284A (zh) * 2021-02-22 2021-06-01 康红伟 一种耐热陶瓷板结构
CN113187073A (zh) * 2021-01-29 2021-07-30 南通德瑞森复合材料有限公司 一种玻璃钢u型排水沟

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101157795A (zh) * 2007-09-30 2008-04-09 潘锦荣 一种树脂混合料及用其制备的玻璃钢型材
CN101597391A (zh) * 2009-06-12 2009-12-09 浙江荣康密封件有限公司 一种高耐磨丁腈橡胶硫化胶及其制备方法
CN201513663U (zh) * 2009-10-12 2010-06-23 深圳市彩阳电力技术有限公司 橡胶玻璃钢复合耐磨弯管
CN102558610A (zh) * 2010-12-30 2012-07-11 秦皇岛耀华玻璃钢股份公司 一种增强型复合填料及其玻璃钢制品的制备方法
CN204431849U (zh) * 2015-01-26 2015-07-01 图木舒克华强复合材料有限公司 一种高强度玻璃钢管道
CN105504679A (zh) * 2015-12-03 2016-04-20 青岛宏宇环保空调设备有限公司 一种新型玻璃钢材料

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101157795A (zh) * 2007-09-30 2008-04-09 潘锦荣 一种树脂混合料及用其制备的玻璃钢型材
CN101597391A (zh) * 2009-06-12 2009-12-09 浙江荣康密封件有限公司 一种高耐磨丁腈橡胶硫化胶及其制备方法
CN201513663U (zh) * 2009-10-12 2010-06-23 深圳市彩阳电力技术有限公司 橡胶玻璃钢复合耐磨弯管
CN102558610A (zh) * 2010-12-30 2012-07-11 秦皇岛耀华玻璃钢股份公司 一种增强型复合填料及其玻璃钢制品的制备方法
CN204431849U (zh) * 2015-01-26 2015-07-01 图木舒克华强复合材料有限公司 一种高强度玻璃钢管道
CN105504679A (zh) * 2015-12-03 2016-04-20 青岛宏宇环保空调设备有限公司 一种新型玻璃钢材料

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110774675A (zh) * 2019-11-12 2020-02-11 河北华强科技开发有限公司 一种耐火玻璃钢复合板及其制作方法
CN110776727A (zh) * 2019-11-19 2020-02-11 佛山市壹诺复合材料有限公司 一种表面粗糙的耐磨的玻璃钢平板制作工艺
CN113187073A (zh) * 2021-01-29 2021-07-30 南通德瑞森复合材料有限公司 一种玻璃钢u型排水沟
CN112876284A (zh) * 2021-02-22 2021-06-01 康红伟 一种耐热陶瓷板结构

Also Published As

Publication number Publication date
CN106976284B (zh) 2018-11-09

Similar Documents

Publication Publication Date Title
CN106976284B (zh) 一种耐磨玻璃钢板材
CN103482904B (zh) 一种改性环氧砂浆抗冲磨修补材料
CN102079881A (zh) 高强度热固性分子基复合材料及其应用
CN103727203B (zh) 复合齿轮和齿轮轴
CN107189354A (zh) 一种石墨烯纳米片增强碳纤维复合材料的制备方法
CN105174763B (zh) 一种用于道面、桥面和工业地坪的环境友好型再生合成纤维增强混凝土
CN107418032A (zh) 一种含石墨烯/纤维增强复合材料及其制备方法
CN202158099U (zh) 一种金属法兰和碳纤维复合材料传动轴的连接结构
CN101358008A (zh) 一种埋地聚乙烯排水管材专用料的制备方法
CN111057369A (zh) 一种碳纤维增强聚酰胺复合材料预浸润玄武岩纤维布及其制备方法
CN107286693A (zh) 一种石墨烯改性树脂/纤维复合材料及其制备方法
CN106397932A (zh) 一种玻璃钢检查井用复合材料及其制备方法
CN107740629B (zh) 碳纤维拉挤板增强输电线路用复合材料杆塔及其制备方法
CN102359696A (zh) 管道翻转修复用薄型内衬软管
CN114773814B (zh) 玻璃钢管道用不饱和聚酯树脂材料及其制备方法
CN111719239A (zh) 一种高强度抗老化玻璃纤维棉毡
Ramakrishna et al. Flexural, compression, chemical resistance, and morphology studies on granite powder‐filled epoxy and acrylonitrile butadiene styrene‐toughened epoxy matrices
CN219969093U (zh) 一种0°或90°连续纤维增强的cf-smc片材
CN107215018A (zh) 一种玻璃钢复合板
CN107286695A (zh) 一种多层石墨烯改性树脂/纤维复合材料及其制备方法
CN108192217A (zh) 一种纤维增强热塑性模压化粪池及其生产方法
CN103880314A (zh) 一种纤维增强混凝土的成型方法
CN112279556B (zh) 一种高抗冲击整体式h管结构件
CN102952369A (zh) 改性热固性超高分子环氧树脂铁路专用弹条型扣件挡板座
CN1141505C (zh) 纳米高性能树脂复合材料管道及其制法

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant