CN110734226A - 一种具有超高分叉阈值的微晶玻璃 - Google Patents
一种具有超高分叉阈值的微晶玻璃 Download PDFInfo
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- CN110734226A CN110734226A CN201911222200.0A CN201911222200A CN110734226A CN 110734226 A CN110734226 A CN 110734226A CN 201911222200 A CN201911222200 A CN 201911222200A CN 110734226 A CN110734226 A CN 110734226A
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- glass
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- 239000011521 glass Substances 0.000 title claims abstract description 228
- 239000013078 crystal Substances 0.000 claims abstract description 46
- 238000005728 strengthening Methods 0.000 claims abstract description 12
- 238000002834 transmittance Methods 0.000 claims abstract description 10
- 238000012360 testing method Methods 0.000 claims abstract description 9
- 239000002245 particle Substances 0.000 claims abstract description 6
- 238000001429 visible spectrum Methods 0.000 claims abstract description 3
- 239000002241 glass-ceramic Substances 0.000 claims description 35
- 238000005342 ion exchange Methods 0.000 claims description 30
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 15
- 150000003839 salts Chemical class 0.000 claims description 15
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 14
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 13
- 239000000126 substance Substances 0.000 claims description 13
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 13
- BITYAPCSNKJESK-UHFFFAOYSA-N potassiosodium Chemical group [Na].[K] BITYAPCSNKJESK-UHFFFAOYSA-N 0.000 claims description 12
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 10
- 229910052593 corundum Inorganic materials 0.000 claims description 10
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 10
- 239000011734 sodium Substances 0.000 claims description 9
- 239000000377 silicon dioxide Substances 0.000 claims description 8
- 229910052681 coesite Inorganic materials 0.000 claims description 7
- 229910052906 cristobalite Inorganic materials 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 229910052700 potassium Inorganic materials 0.000 claims description 7
- 229910052682 stishovite Inorganic materials 0.000 claims description 7
- 229910052905 tridymite Inorganic materials 0.000 claims description 7
- 229910000500 β-quartz Inorganic materials 0.000 claims description 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 5
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 5
- 239000011591 potassium Substances 0.000 claims description 5
- 229910052708 sodium Inorganic materials 0.000 claims description 5
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 3
- HEHRHMRHPUNLIR-UHFFFAOYSA-N aluminum;hydroxy-[hydroxy(oxo)silyl]oxy-oxosilane;lithium Chemical compound [Li].[Al].O[Si](=O)O[Si](O)=O.O[Si](=O)O[Si](O)=O HEHRHMRHPUNLIR-UHFFFAOYSA-N 0.000 claims description 3
- CNLWCVNCHLKFHK-UHFFFAOYSA-N aluminum;lithium;dioxido(oxo)silane Chemical compound [Li+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O CNLWCVNCHLKFHK-UHFFFAOYSA-N 0.000 claims description 3
- WVMPCBWWBLZKPD-UHFFFAOYSA-N dilithium oxido-[oxido(oxo)silyl]oxy-oxosilane Chemical compound [Li+].[Li+].[O-][Si](=O)O[Si]([O-])=O WVMPCBWWBLZKPD-UHFFFAOYSA-N 0.000 claims description 3
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 claims description 3
- 229910001676 gahnite Inorganic materials 0.000 claims description 3
- 229910052863 mullite Inorganic materials 0.000 claims description 3
- 229910052670 petalite Inorganic materials 0.000 claims description 3
- 229910052596 spinel Inorganic materials 0.000 claims description 3
- 239000011029 spinel Substances 0.000 claims description 3
- 229910052644 β-spodumene Inorganic materials 0.000 claims description 3
- 239000004699 Ultra-high molecular weight polyethylene Substances 0.000 claims 1
- 229920000785 ultra high molecular weight polyethylene Polymers 0.000 claims 1
- 238000000034 method Methods 0.000 description 15
- 238000002425 crystallisation Methods 0.000 description 11
- 230000008025 crystallization Effects 0.000 description 10
- 230000008569 process Effects 0.000 description 10
- 239000000463 material Substances 0.000 description 7
- 239000006058 strengthened glass Substances 0.000 description 7
- 239000012634 fragment Substances 0.000 description 6
- 229910001416 lithium ion Inorganic materials 0.000 description 6
- 229910001415 sodium ion Inorganic materials 0.000 description 6
- 229910001413 alkali metal ion Inorganic materials 0.000 description 5
- 230000009286 beneficial effect Effects 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 5
- 239000010410 layer Substances 0.000 description 5
- 239000005341 toughened glass Substances 0.000 description 5
- 239000000919 ceramic Substances 0.000 description 4
- VVNXEADCOVSAER-UHFFFAOYSA-N lithium sodium Chemical compound [Li].[Na] VVNXEADCOVSAER-UHFFFAOYSA-N 0.000 description 4
- 238000010899 nucleation Methods 0.000 description 4
- 230000006911 nucleation Effects 0.000 description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 238000003723 Smelting Methods 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 239000005357 flat glass Substances 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- JGRPKOGHYBAVMW-UHFFFAOYSA-N 8-hydroxy-5-quinolinecarboxylic acid Chemical compound C1=CC=C2C(C(=O)O)=CC=C(O)C2=N1 JGRPKOGHYBAVMW-UHFFFAOYSA-N 0.000 description 2
- 241000284156 Clerodendrum quadriloculare Species 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 2
- 239000005345 chemically strengthened glass Substances 0.000 description 2
- 238000004031 devitrification Methods 0.000 description 2
- 239000010432 diamond Substances 0.000 description 2
- 229910003460 diamond Inorganic materials 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Inorganic materials [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Inorganic materials [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- CAOSCCRYLYQBES-UHFFFAOYSA-N 2-[[[4-hydroxy-2-oxo-1-(phenylmethyl)-3-quinolinyl]-oxomethyl]amino]acetic acid Chemical compound O=C1C(C(=O)NCC(=O)O)=C(O)C2=CC=CC=C2N1CC1=CC=CC=C1 CAOSCCRYLYQBES-UHFFFAOYSA-N 0.000 description 1
- 206010011376 Crepitations Diseases 0.000 description 1
- 238000006124 Pilkington process Methods 0.000 description 1
- 208000037656 Respiratory Sounds Diseases 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- -1 alkali metal salt Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000003426 chemical strengthening reaction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000006025 fining agent Substances 0.000 description 1
- 230000009545 invasion Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 239000013081 microcrystal Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000007500 overflow downdraw method Methods 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C10/00—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition
- C03C10/0018—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition containing SiO2, Al2O3 and monovalent metal oxide as main constituents
- C03C10/0027—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition containing SiO2, Al2O3 and monovalent metal oxide as main constituents containing SiO2, Al2O3, Li2O as main constituents
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C21/00—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface
- C03C21/001—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface in liquid phase, e.g. molten salts, solutions
- C03C21/002—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface in liquid phase, e.g. molten salts, solutions to perform ion-exchange between alkali ions
Abstract
Description
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CN202111399148.3A CN113929308B (zh) | 2019-12-03 | 2019-12-03 | 一种具有超高分叉阈值的微晶玻璃 |
CN201911222200.0A CN110734226B (zh) | 2019-12-03 | 2019-12-03 | 一种具有超高分叉阈值的微晶玻璃 |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111847885A (zh) * | 2020-06-09 | 2020-10-30 | 科立视材料科技有限公司 | 一种具有深层高压应力的强化微晶玻璃及其制备方法 |
CN113880438A (zh) * | 2020-07-01 | 2022-01-04 | 华为技术有限公司 | 微晶玻璃和终端 |
CN115594406A (zh) * | 2021-07-08 | 2023-01-13 | 荣耀终端有限公司(Cn) | 化学强化微晶玻璃及其制备方法与应用 |
WO2023011571A1 (zh) * | 2021-08-05 | 2023-02-09 | 重庆鑫景特种玻璃有限公司 | 一种透明微晶玻璃、及其制备方法和用途 |
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US20100119846A1 (en) * | 2007-03-02 | 2010-05-13 | Masahiro Sawada | Reinforced plate glass and method for manufacturing the same |
WO2018143991A1 (en) * | 2017-02-02 | 2018-08-09 | Corning Incorporated | Lithium containing glass or glass ceramic article with modified k2o profile near the glass surface |
CN109320091A (zh) * | 2018-10-26 | 2019-02-12 | 成都创客之家科技有限公司 | 电子设备盖板用微晶玻璃制品和微晶玻璃 |
CN208747932U (zh) * | 2018-05-31 | 2019-04-16 | 深圳市东丽华科技有限公司 | 一种微晶玻璃器件 |
CN110002760A (zh) * | 2019-04-30 | 2019-07-12 | 深圳市东丽华科技有限公司 | 一种含有微纳米晶体的玻璃陶瓷及其制备方法 |
CN110040982A (zh) * | 2019-05-14 | 2019-07-23 | 深圳市东丽华科技有限公司 | 具有复合应力优势的化学强化玻璃及其制备方法与应用 |
CN110104955A (zh) * | 2019-05-27 | 2019-08-09 | 深圳市东丽华科技有限公司 | 一种可化学强化的自结晶玻璃陶瓷及其制备方法 |
CN110128008A (zh) * | 2019-05-16 | 2019-08-16 | 平顶山市东丽华实业有限公司 | 低曲率半径超薄强化玻璃及其制备方法、玻璃器件和素玻璃 |
CN110240419A (zh) * | 2019-06-06 | 2019-09-17 | 深圳市东丽华科技有限公司 | 锂铝硅玻璃、锂铝硅化学强化玻璃及其制备方法与应用 |
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JP4773608B2 (ja) * | 2000-09-28 | 2011-09-14 | 株式会社オハラ | ガラスセラミックス及び温度補償部材 |
CN110436788A (zh) * | 2019-08-21 | 2019-11-12 | 成都光明光电股份有限公司 | 微晶玻璃、微晶玻璃制品及其制造方法 |
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2019
- 2019-12-03 CN CN201911222200.0A patent/CN110734226B/zh active Active
- 2019-12-03 CN CN202111399148.3A patent/CN113929308B/zh active Active
Patent Citations (9)
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US20100119846A1 (en) * | 2007-03-02 | 2010-05-13 | Masahiro Sawada | Reinforced plate glass and method for manufacturing the same |
WO2018143991A1 (en) * | 2017-02-02 | 2018-08-09 | Corning Incorporated | Lithium containing glass or glass ceramic article with modified k2o profile near the glass surface |
CN208747932U (zh) * | 2018-05-31 | 2019-04-16 | 深圳市东丽华科技有限公司 | 一种微晶玻璃器件 |
CN109320091A (zh) * | 2018-10-26 | 2019-02-12 | 成都创客之家科技有限公司 | 电子设备盖板用微晶玻璃制品和微晶玻璃 |
CN110002760A (zh) * | 2019-04-30 | 2019-07-12 | 深圳市东丽华科技有限公司 | 一种含有微纳米晶体的玻璃陶瓷及其制备方法 |
CN110040982A (zh) * | 2019-05-14 | 2019-07-23 | 深圳市东丽华科技有限公司 | 具有复合应力优势的化学强化玻璃及其制备方法与应用 |
CN110128008A (zh) * | 2019-05-16 | 2019-08-16 | 平顶山市东丽华实业有限公司 | 低曲率半径超薄强化玻璃及其制备方法、玻璃器件和素玻璃 |
CN110104955A (zh) * | 2019-05-27 | 2019-08-09 | 深圳市东丽华科技有限公司 | 一种可化学强化的自结晶玻璃陶瓷及其制备方法 |
CN110240419A (zh) * | 2019-06-06 | 2019-09-17 | 深圳市东丽华科技有限公司 | 锂铝硅玻璃、锂铝硅化学强化玻璃及其制备方法与应用 |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111847885A (zh) * | 2020-06-09 | 2020-10-30 | 科立视材料科技有限公司 | 一种具有深层高压应力的强化微晶玻璃及其制备方法 |
CN111847885B (zh) * | 2020-06-09 | 2022-06-07 | 科立视材料科技有限公司 | 一种具有深层高压应力的强化微晶玻璃及其制备方法 |
CN113880438A (zh) * | 2020-07-01 | 2022-01-04 | 华为技术有限公司 | 微晶玻璃和终端 |
CN115594406A (zh) * | 2021-07-08 | 2023-01-13 | 荣耀终端有限公司(Cn) | 化学强化微晶玻璃及其制备方法与应用 |
CN115959831A (zh) * | 2021-07-08 | 2023-04-14 | 荣耀终端有限公司 | 素微晶玻璃、化学强化微晶玻璃及其制备方法与应用 |
WO2023011571A1 (zh) * | 2021-08-05 | 2023-02-09 | 重庆鑫景特种玻璃有限公司 | 一种透明微晶玻璃、及其制备方法和用途 |
Also Published As
Publication number | Publication date |
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CN110734226B (zh) | 2021-12-17 |
CN113929308B (zh) | 2023-09-22 |
CN113929308A (zh) | 2022-01-14 |
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