CN110719924B - 高度不对称的三嵌段聚合物组合物及其制备方法 - Google Patents

高度不对称的三嵌段聚合物组合物及其制备方法 Download PDF

Info

Publication number
CN110719924B
CN110719924B CN201880036704.0A CN201880036704A CN110719924B CN 110719924 B CN110719924 B CN 110719924B CN 201880036704 A CN201880036704 A CN 201880036704A CN 110719924 B CN110719924 B CN 110719924B
Authority
CN
China
Prior art keywords
block
polymer
triblock copolymer
hat
highly asymmetric
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201880036704.0A
Other languages
English (en)
Chinese (zh)
Other versions
CN110719924A (zh
Inventor
D·杜波伊斯
M·杜邦
C·威利斯
R·Q·克卢兹
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kraton Polymers LLC
Original Assignee
Kraton Polymers LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kraton Polymers LLC filed Critical Kraton Polymers LLC
Publication of CN110719924A publication Critical patent/CN110719924A/zh
Application granted granted Critical
Publication of CN110719924B publication Critical patent/CN110719924B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
    • C08F297/046—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes polymerising vinyl aromatic monomers and isoprene, optionally with other conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
    • C08F297/044—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes using a coupling agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L95/00—Compositions of bituminous materials, e.g. asphalt, tar, pitch
    • C08L95/005—Aqueous compositions, e.g. emulsions
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J123/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
    • C09J123/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • C09J153/02—Vinyl aromatic monomers and conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • C09J153/02—Vinyl aromatic monomers and conjugated dienes
    • C09J153/025—Vinyl aromatic monomers and conjugated dienes modified
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2555/00—Characteristics of bituminous mixtures
    • C08L2555/20—Mixtures of bitumen and aggregate defined by their production temperatures, e.g. production of asphalt for road or pavement applications
    • C08L2555/22—Asphalt produced above 140°C, e.g. hot melt asphalt
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2555/00—Characteristics of bituminous mixtures
    • C08L2555/40—Mixtures based upon bitumen or asphalt containing functional additives
    • C08L2555/80—Macromolecular constituents
    • C08L2555/84—Polymers comprising styrene, e.g., polystyrene, styrene-diene copolymers or styrene-butadiene-styrene copolymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L95/00—Compositions of bituminous materials, e.g. asphalt, tar, pitch

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Adhesive Tapes (AREA)
  • Graft Or Block Polymers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
CN201880036704.0A 2017-06-09 2018-06-09 高度不对称的三嵌段聚合物组合物及其制备方法 Active CN110719924B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201762517849P 2017-06-09 2017-06-09
US62/517,849 2017-06-09
PCT/US2018/036794 WO2018227173A1 (en) 2017-06-09 2018-06-09 Highly asymmetric triblock polymer compositions and methods of making same

Publications (2)

Publication Number Publication Date
CN110719924A CN110719924A (zh) 2020-01-21
CN110719924B true CN110719924B (zh) 2023-11-21

Family

ID=64562566

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201880036704.0A Active CN110719924B (zh) 2017-06-09 2018-06-09 高度不对称的三嵌段聚合物组合物及其制备方法

Country Status (6)

Country Link
US (1) US10647805B2 (https=)
EP (1) EP3635021A4 (https=)
JP (1) JP7750645B2 (https=)
CN (1) CN110719924B (https=)
TW (1) TWI774784B (https=)
WO (1) WO2018227173A1 (https=)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102373305B1 (ko) 2018-03-30 2022-03-11 주식회사 엘지화학 블록 공중합체 조성물
EP4039713A4 (en) 2019-09-30 2023-11-15 Zeon Corporation HYDROGENATED BLOCK COPOLYMER COMPOSITION, METHOD FOR PRODUCING SAID COMPOSITION, AND FILM
CN113563549B (zh) * 2020-04-29 2024-05-03 中国石油化工股份有限公司 不对称性支化型聚苯乙烯-b-聚乙烯-丁烯-丙烯-异丙烯多微小嵌段共聚物及制备方法
US11608404B2 (en) * 2020-05-22 2023-03-21 Kraton Corporation Block copolymers and polymer modified bitumen therefrom
JP7491068B2 (ja) * 2020-06-05 2024-05-28 日本ゼオン株式会社 ロール加工性に優れるアクリルゴムベール
WO2025159085A1 (ja) * 2024-01-24 2025-07-31 デンカ株式会社 ペレット、フィルム、及びペレットの製造方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4891410A (en) * 1987-05-02 1990-01-02 Basf Aktiengesellschaft Butadiene/sytrene block copolymers having an asymmetric structure, their preparation and their use as molding materials
CN1854200A (zh) * 2005-04-20 2006-11-01 锦湖石油化学株式会社 一种包含具有不对称聚苯乙烯嵌段的苯乙烯－丁二烯－苯乙烯嵌段共聚物的沥青组合物
CN101031598A (zh) * 2004-09-27 2007-09-05 陶氏环球技术公司 不对称线性渐变单烯基芳烃－共轭二烯烃嵌段共聚物
CN106459328A (zh) * 2014-04-02 2017-02-22 科腾聚合物美国有限责任公司 含有共聚物月桂烯嵌段的嵌段共聚物

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5458792A (en) * 1994-08-11 1995-10-17 Shell Oil Company Asymmetric triblock copolymer viscosity index improver for oil compositions
JP3939781B2 (ja) * 1996-05-15 2007-07-04 日本エラストマー株式会社 アスファルト改質用ブロック共重合体及びアスファルト組成物
DE19828104A1 (de) 1998-06-24 1999-12-30 Basf Ag Verfahren zur Herstellung von schlagzäh modifizierten, thermoplastischen Formmassen
US6987142B2 (en) * 2002-02-07 2006-01-17 Kraton Polymers U.S. Llc Adhesives and sealants from controlled distribution block copolymers
US7125940B2 (en) 2002-12-31 2006-10-24 Kraton Polymers U.S. Llc Conjugated diene polymers and copolymer blocks and process for preparing same
US20080051510A1 (en) * 2004-09-27 2008-02-28 Toney Kenneth A Asymmetric Linear Tapered Monoalkenyl Arene-Conjugated Diene Block Copolymers
RU2405797C2 (ru) 2005-11-14 2010-12-10 Кратон Полимерз Рисёч Б.В. Способ получения композиции битумного вяжущего
US7910794B2 (en) * 2007-03-05 2011-03-22 Adherent Laboratories, Inc. Disposable diaper construction and adhesive
CN101675114B (zh) 2007-05-01 2012-09-26 科腾聚合物美国有限责任公司 沥青粘合剂组合物及其制备方法
KR101220330B1 (ko) * 2010-12-14 2013-01-09 금호석유화학 주식회사 비대칭 블록을 가진 테이퍼 공중합체 및 그를 포함하는 점착제 조성물
US20160340552A1 (en) * 2015-05-18 2016-11-24 Invia Pavement Technologies, LLC Mastic asphalt compositions with coalescents

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4891410A (en) * 1987-05-02 1990-01-02 Basf Aktiengesellschaft Butadiene/sytrene block copolymers having an asymmetric structure, their preparation and their use as molding materials
CN101031598A (zh) * 2004-09-27 2007-09-05 陶氏环球技术公司 不对称线性渐变单烯基芳烃－共轭二烯烃嵌段共聚物
CN1854200A (zh) * 2005-04-20 2006-11-01 锦湖石油化学株式会社 一种包含具有不对称聚苯乙烯嵌段的苯乙烯－丁二烯－苯乙烯嵌段共聚物的沥青组合物
CN106459328A (zh) * 2014-04-02 2017-02-22 科腾聚合物美国有限责任公司 含有共聚物月桂烯嵌段的嵌段共聚物

Also Published As

Publication number Publication date
EP3635021A4 (en) 2021-04-07
TWI774784B (zh) 2022-08-21
TW201903034A (zh) 2019-01-16
WO2018227173A1 (en) 2018-12-13
US10647805B2 (en) 2020-05-12
JP2020523442A (ja) 2020-08-06
JP7750645B2 (ja) 2025-10-07
CN110719924A (zh) 2020-01-21
EP3635021A1 (en) 2020-04-15
US20180355090A1 (en) 2018-12-13

Similar Documents

Publication Publication Date Title
CN110719924B (zh) 高度不对称的三嵌段聚合物组合物及其制备方法
CN100480325C (zh) 来自基团(s-i/b)x聚合物的粘合剂配方
CN102361949B (zh) 标签用胶粘剂组合物
JP3168632B2 (ja) ホットメルト型粘着剤組成物
KR101891044B1 (ko) 무정형 폴리올레핀을 가진 접착제 조성물
JP2020523442A5 (https=)
TWI293977B (en) Low viscosity, hot-melt stable adhesive compositions
EP3092280B1 (en) Hot melt pressure sensitive adhesive and thermoset comprising styrene-butadiene polymers having high vinyl and high di-block
JP6259074B2 (ja) 表面保護フィルム
JP6321207B2 (ja) ポリミルセンを有するブロックコポリマーを含む接着剤組成物
CN1649924A (zh) 在丁二烯嵌段内具有高乙烯基含量的聚(苯乙烯－丁二烯－苯乙烯)聚合物和含所述聚合物的热熔粘合剂组合物
JP2000219860A (ja) 接着剤組成物
WO2017075458A1 (en) Hot melt elastic attachment adhesive for low temperature applications
JPH0598130A (ja) 水素添加ブロツク共重合体組成物及びそのホツトメルト型粘着剤組成物
CN115678470A (zh) 一种自粘膜用共聚物组合物、专用料及其制备和应用
TW201730314A (zh) 嵌段共聚物組成物及黏著劑組成物
CN113302253A (zh) 热熔粘合剂组合物及其制造方法

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant