CN110494394A - 用于制造过渡金属氢氧化物前体的硝酸盐方法 - Google Patents

用于制造过渡金属氢氧化物前体的硝酸盐方法 Download PDF

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Publication number
CN110494394A
CN110494394A CN201880017972.8A CN201880017972A CN110494394A CN 110494394 A CN110494394 A CN 110494394A CN 201880017972 A CN201880017972 A CN 201880017972A CN 110494394 A CN110494394 A CN 110494394A
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Prior art keywords
nitrate
metal
basic
solution
ammonia
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Chinese (zh)
Inventor
延斯·鲍森
埃里克·罗伯特
德克·瓦努特
丹尼尔·内利斯
兰迪·德帕尔马
金大铉
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Yumikol Corp
Umicore Korea Ltd
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Yumikol Corp
Umicore Korea Ltd
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Priority claimed from PCT/EP2018/056567 external-priority patent/WO2018167224A1/en
Publication of CN110494394A publication Critical patent/CN110494394A/zh
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00Compounds of nickel
    • C01G53/40Complex oxides containing nickel and at least one other metal element
    • C01G53/42Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
    • C01G53/44Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese
    • C01G53/50Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00Compounds of nickel
    • C01G53/80Compounds containing nickel, with or without oxygen or hydrogen, and containing one or more other elements
    • C01G53/82Compounds containing nickel, with or without oxygen or hydrogen, and containing two or more other elements
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01DCOMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D1/00Oxides or hydroxides of sodium, potassium or alkali metals in general
    • C01D1/04Hydroxides
    • C01D1/20Preparation by reacting oxides or hydroxides with alkali metal salts
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B21/00Nitrogen; Compounds thereof
    • C01B21/20Nitrogen oxides; Oxyacids of nitrogen; Salts thereof
    • C01B21/38Nitric acid
    • C01B21/40Preparation by absorption of oxides of nitrogen
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B21/00Nitrogen; Compounds thereof
    • C01B21/20Nitrogen oxides; Oxyacids of nitrogen; Salts thereof
    • C01B21/48Methods for the preparation of nitrates in general
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01CAMMONIA; CYANOGEN; COMPOUNDS THEREOF
    • C01C1/00Ammonia; Compounds thereof
    • C01C1/02Preparation, purification or separation of ammonia
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01DCOMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D1/00Oxides or hydroxides of sodium, potassium or alkali metals in general
    • C01D1/02Oxides
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01DCOMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D1/00Oxides or hydroxides of sodium, potassium or alkali metals in general
    • C01D1/04Hydroxides
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/06Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
    • H01B1/08Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances oxides
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • H01M10/0525Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/485Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
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    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
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    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00Crystal-structural characteristics
    • C01P2002/80Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
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    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/60Particles characterised by their size
    • C01P2004/61Micrometer sized, i.e. from 1-100 micrometer
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    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
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    • C01P2006/40Electric properties
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M2004/026Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/028Positive electrodes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Analytical Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Manufacture And Refinement Of Metals (AREA)
CN201880017972.8A 2017-03-15 2018-03-15 用于制造过渡金属氢氧化物前体的硝酸盐方法 Pending CN110494394A (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201762471575P 2017-03-15 2017-03-15
US62/471,575 2017-03-15
EP17176339.4 2017-06-16
EP17176339 2017-06-16
PCT/EP2018/056567 WO2018167224A1 (en) 2017-03-15 2018-03-15 Nitrate process for manufacturing transition metal hydroxide precursors

Publications (1)

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CN110494394A true CN110494394A (zh) 2019-11-22

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US (1) US11401167B2 (enExample)
EP (1) EP3596015A1 (enExample)
JP (1) JP6721799B2 (enExample)
KR (1) KR102136961B1 (enExample)
CN (1) CN110494394A (enExample)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112133905A (zh) * 2020-09-24 2020-12-25 江西普瑞美新材料科技有限公司 一种长循环高稳定性高镍三元前驱体及其制备方法
CN113087430A (zh) * 2021-03-23 2021-07-09 中国葛洲坝集团水泥有限公司 一种提氨脱硫石膏及其处置利用方法
CN117098727A (zh) * 2021-02-18 2023-11-21 哈茨有限公司 锂及电池化工生产中的硫酸钠副产物加工
CN117446775A (zh) * 2023-10-25 2024-01-26 深圳珈钠能源科技有限公司 一种氮循环工艺制备聚阴离子型正极材料的方法

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10782272B2 (en) * 2017-07-15 2020-09-22 Microvast Power Systems Co., Ltd. Analytical method for precipitated particles during co-precipitation reaction
US11358898B2 (en) * 2017-10-20 2022-06-14 Corning Incorporated Methods to improve ion exchange efficiency of glasses and glass ceramics
CN111477985B (zh) * 2020-04-15 2023-08-15 中南大学 一种回收废旧锂离子电池的方法
CN111807425A (zh) * 2020-08-07 2020-10-23 中国科学院长春应用化学研究所 一种在低氨浓度下制备高性能锂离子电池三元正极材料的方法
US20240270588A1 (en) * 2021-05-25 2024-08-15 Cinis Fertilizer Ab Process for treatment of a sodium sulfate containing residue process stream of a battery manufacturing facility, a battery recycling facility, or a steel production plant
CN114602473B (zh) * 2022-04-20 2024-02-02 兖矿榆林精细化工有限公司 一种制备费托合成催化剂前驱体的方法
CN115321562B (zh) * 2022-07-21 2023-10-17 四川顺应锂材料科技有限公司 一种锂矿硝酸浸出液膜法生产碳酸锂的方法
SE545935C2 (en) * 2022-07-28 2024-03-19 Cinis Fertilizer Ab Process for treatment of a sodium sulfate containing residue process stream of a battery process

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030064288A1 (en) * 2001-10-02 2003-04-03 Jeremy Barker Lithium cell based on lithiated transition metal titanates
CN101391798A (zh) * 2008-10-17 2009-03-25 东南大学 一种掺杂的镍基碱性二次电池正极材料及其制备方法
CN102030375A (zh) * 2010-10-29 2011-04-27 北京矿冶研究总院 一种直接用失效锂离子电池制备钴酸锂的方法
CN102084013A (zh) * 2008-04-14 2011-06-01 詹姆斯·R·阿克瑞奇 从电子废料等废物中可持续回收金属化合物的湿化学方法
CN105594030A (zh) * 2013-09-05 2016-05-18 尤米科尔公司 用于含高锂和锰的阴极材料的碳酸盐前体

Family Cites Families (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60198057A (ja) * 1984-03-22 1985-10-07 Sanyo Electric Co Ltd アルカリ蓄電池用極板の製造方法
US5728367A (en) 1996-06-17 1998-03-17 Motorola, Inc. Process for fabricating a lithiated transition metal oxide
AU744558B2 (en) * 1998-02-09 2002-02-28 H.C. Starck Gmbh & Co. Kg Method for producing lithium-transition metal mixtures
PL195998B1 (pl) * 2000-01-28 2007-11-30 Umicore Nv Sposób rafinowania zanieczyszczonego stopu srebrai złota
US6805785B2 (en) * 2001-08-01 2004-10-19 Matsushita Electric Industrial Co., Ltd. Production method of sintered-type nickel positive electrode for alkaline secondary battery
US7435402B2 (en) * 2002-11-01 2008-10-14 U Chicago Argonne Llc Method and apparatus for preparation of spherical metal carbonates and lithium metal oxides for lithium rechargeable batteries
US7399454B2 (en) 2004-04-29 2008-07-15 Metalox International, Llc Metallurgical dust reclamation process
JP2010034021A (ja) * 2008-07-03 2010-02-12 Sumitomo Chemical Co Ltd 電池廃材からの酸化物含有電池材料の回収方法
US20120028128A1 (en) 2009-03-18 2012-02-02 Santoku Corporation All-solid-state lithium battery
JP5752890B2 (ja) 2009-03-18 2015-07-22 出光興産株式会社 正極合材及びリチウム電池
WO2011056548A2 (en) * 2009-10-27 2011-05-12 Akridge James R Oxygen torch waste reclamation system and acid recovery
US8911902B2 (en) 2010-07-06 2014-12-16 Samsung Sdi Co., Ltd. Nickel-based positive electrode active material, method of preparing the same, and lithium battery using the nickel-based positive electrode active material
KR101220149B1 (ko) * 2011-02-17 2013-01-11 한국지질자원연구원 폐배터리로부터 유가금속 황산용액의 제조방법 및 양극활물질의 제조방법
CN102306765A (zh) 2011-08-18 2012-01-04 合肥国轩高科动力能源有限公司 一种锂离子正极材料镍锰钴的制备方法
WO2013077296A1 (ja) 2011-11-22 2013-05-30 住友金属鉱山株式会社 高純度硫酸ニッケルの製造方法
KR20130059029A (ko) 2011-11-28 2013-06-05 에스케이씨 주식회사 복합 금속 수산화물의 제조방법
JP5869361B2 (ja) * 2012-02-14 2016-02-24 株式会社アルバック Ito粉末の製造方法及びitoスパッタリングターゲットの製造方法
KR101446491B1 (ko) * 2012-03-16 2014-10-06 주식회사 엘지화학 리튬 복합 전이금속 산화물 제조용 전구체 및 그 제조방법
KR101501823B1 (ko) * 2013-02-13 2015-03-12 한국생산기술연구원 리튬이차전지용 양극복합소재 제조방법 및 이를 이용한 전극 제조방법 및 상기 전극의 충방전 방법
JP2015150521A (ja) * 2014-02-17 2015-08-24 泰弘 加藤 廃ガス浄化方法及び装置
JP6287970B2 (ja) * 2014-10-30 2018-03-07 住友金属鉱山株式会社 ニッケル複合水酸化物とその製造方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030064288A1 (en) * 2001-10-02 2003-04-03 Jeremy Barker Lithium cell based on lithiated transition metal titanates
CN102084013A (zh) * 2008-04-14 2011-06-01 詹姆斯·R·阿克瑞奇 从电子废料等废物中可持续回收金属化合物的湿化学方法
CN101391798A (zh) * 2008-10-17 2009-03-25 东南大学 一种掺杂的镍基碱性二次电池正极材料及其制备方法
CN102030375A (zh) * 2010-10-29 2011-04-27 北京矿冶研究总院 一种直接用失效锂离子电池制备钴酸锂的方法
CN105594030A (zh) * 2013-09-05 2016-05-18 尤米科尔公司 用于含高锂和锰的阴极材料的碳酸盐前体

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112133905A (zh) * 2020-09-24 2020-12-25 江西普瑞美新材料科技有限公司 一种长循环高稳定性高镍三元前驱体及其制备方法
CN117098727A (zh) * 2021-02-18 2023-11-21 哈茨有限公司 锂及电池化工生产中的硫酸钠副产物加工
CN113087430A (zh) * 2021-03-23 2021-07-09 中国葛洲坝集团水泥有限公司 一种提氨脱硫石膏及其处置利用方法
CN117446775A (zh) * 2023-10-25 2024-01-26 深圳珈钠能源科技有限公司 一种氮循环工艺制备聚阴离子型正极材料的方法

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US20200031682A1 (en) 2020-01-30
EP3596015A1 (en) 2020-01-22
KR102136961B1 (ko) 2020-07-23
KR20190121857A (ko) 2019-10-28
JP2020511757A (ja) 2020-04-16
US11401167B2 (en) 2022-08-02
JP6721799B2 (ja) 2020-07-15

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Application publication date: 20191122