CN110452761A - 用于热轧型材轧制的环保油基型金属润滑剂及制备方法 - Google Patents

用于热轧型材轧制的环保油基型金属润滑剂及制备方法 Download PDF

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CN110452761A
CN110452761A CN201910683092.0A CN201910683092A CN110452761A CN 110452761 A CN110452761 A CN 110452761A CN 201910683092 A CN201910683092 A CN 201910683092A CN 110452761 A CN110452761 A CN 110452761A
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improver
oil
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hot
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张岩
张栋
原思宇
马普生
李博雍
张宝峰
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Angang Future Iron & Steel Research Institute Co Ltd
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Abstract

本发明涉及用于热轧型材轧制的环保油基型金属润滑剂及制备方法，按重量份包括以下组分：基础油60‑62份；油性剂20‑25份；摩擦改进剂4‑6份；极压抗磨剂2‑4份；抗氧剂0.5‑1份；防锈剂0.3‑0.5份；纳米石墨2‑3.5份；制备方法，将基础油、油性剂、摩擦改进剂、防锈剂、极压抗磨剂、抗氧剂、油性剂加入到调合釜中，加热到45～55℃，保温搅拌40～50分钟，再加入纳米石墨搅拌均匀后经检验出料。优点是：耐高温和抗氧化，润滑性好，不腐蚀金属，耐高温遇热不冒烟，废液排放量少，具有节能减排、无毒无害无污染、抗磨抗高温、提高型材质量的特点。

Description

用于热轧型材轧制的环保油基型金属润滑剂及制备方法
技术领域
本发明属于热轧型材轧制润滑领域，尤其涉及一种用于热轧型材轧制的环保油基型金属润滑剂。
背景技术
目前国内钢铁领域，传统的热轧型材轧制是用水做冷却介质，因无润滑介质存在，造成轧机耗电量大、浪费能源、轧辊磨损严重、氧化铁皮增多、废液排放量大等诸多问题。现有油基型润滑剂应用在热轧和冷轧板材轧制领域，通过与水及其添加剂配合形成半稳定状态的乳化液，喷射到辊缝与带钢之间起到润滑作用。由于热轧型材轧制(特别是重轨)温度高负荷小，且受孔型影响及轧机空间所限，另外，型材在轧制过程中采用润滑技术后变形复杂，润滑效果影响因素多，不易控制产品尺寸规格，所以轧制润滑技术在型材轧制中还没有成熟应用。
发明内容
为克服现有技术的不足，本发明的目的是提供一种用于热轧型材轧制的环保油基型金属润滑剂，耐高温和抗氧化，不腐蚀金属，当润滑油降解时，由于润滑性能降低不会导致被润滑的型钢的磨损；实现节能减排、无毒无害无污染、抗磨抗高温、提高型材质量。
用于热轧型材轧制的环保油基型金属润滑剂，按重量份包括以下组分：
基础油 60-62份；
油性剂 20-25份；
摩擦改进剂 4-6份；
极压抗磨剂 2-4份；
抗氧剂 0.5-1份；
防锈剂 0.3-0.5份；
纳米石墨 2-3.5份；
基础油为矿物油，矿物油40℃运动粘度为70-80cSt，100℃运动粘度为10-15cSt，硫含量小于15000ppm；油性剂为脂肪酸酯，脂肪酸酯为由脂肪醇与脂肪酸合成的酯，脂肪酸酯是油酸乙醇酯、椰子油脂肪酸季戊四醇酯、棕榈油脂肪酸三羟甲基丙烷酯、硬脂酸乙酯中的至少一种；摩擦改进剂为二烷基二硫代磷酸锌；极压抗磨剂为亚磷酸二丁酯、磷酸三甲酚酯、硫化异丁烯中的至少一种；抗氧剂为碱土金属水杨酸盐、苯骈三氮唑、N-苯基-α萘胺中的至少一种；防锈剂为烯基丁二酸、石油磺酸钠或环烷酸锌中的至少一种。
用于热轧型材轧制的环保油基型金属润滑剂的制备方法，将基础油、油性剂、摩擦改进剂、防锈剂、极压抗磨剂、抗氧剂、油性剂加入到调合釜中，加热到45～55℃，保温搅拌40～50分钟，再加入纳米石墨搅拌均匀后经检验出料。
其中，金属润滑剂以基础油和油性剂起到主要润滑功能，摩擦改进剂和极压抗磨剂的加入能有效防止金属磨损，抗氧剂和防锈剂起到耐热抗氧化和防止金属表面产生锈蚀的作用，同时，石墨颗粒能够依靠性能优异的固体粒子也起到在高温状态下很好的减摩作用。
与现有技术相比，本发明的有益效果是：
本发明的润滑剂耐高温和抗氧化，润滑性好，不腐蚀金属，耐高温遇热不冒烟，废液排放量少，具有节能减排、无毒无害无污染、抗磨抗高温、提高型材质量的特点，使用本润滑剂，当润滑剂降解时，由于润滑性能降低不会导致被润滑的型钢的磨损。适合在热轧型材全孔型轧制润滑，在大型万能轧机UF机架应用测试，无论是减少轧制负荷还是打磨辊系次数方面，都取得了良好的效果。
具体实施方式
下面对本发明进行详细地描述，但是应该指出本发明的实施不限于以下的实施方式。
用于热轧型材轧制的环保油基型金属润滑剂，按重量份包括以下组分：
基础油 60-62份；
油性剂 20-25份；
摩擦改进剂 4-6份；
极压抗磨剂 2-4份；
抗氧剂 0.5-1份；
防锈剂 0.3-0.5份；
纳米石墨(2500目-3000目) 2-3.5份；
基础油为矿物油，矿物油40℃运动粘度为70-80cSt，100℃运动粘度为10-15cSt，硫含量小于15000ppm；油性剂为脂肪酸酯，脂肪酸酯为由脂肪醇与脂肪酸合成的酯，脂肪酸酯是油酸乙醇酯、椰子油脂肪酸季戊四醇酯、棕榈油脂肪酸三羟甲基丙烷酯、硬脂酸乙酯中的至少一种；摩擦改进剂为二烷基二硫代磷酸锌；极压抗磨剂为亚磷酸二丁酯、磷酸三甲酚酯、硫化异丁烯中的至少一种；抗氧剂为碱土金属水杨酸盐、苯骈三氮唑、N-苯基-α萘胺中的至少一种；防锈剂为烯基丁二酸、石油磺酸钠或环烷酸锌中的至少一种。
用于热轧型材轧制的环保油基型金属润滑剂的制备方法，将基础油、油性剂、摩擦改进剂、防锈剂、极压抗磨剂、抗氧剂、油性剂加入到调合釜中，加热到45～55℃，保温搅拌40～50分钟，再加入纳米石墨搅拌均匀后经检验出料。
实施例
将基础油、油性剂、摩擦改进剂、防锈剂、极压抗磨剂、抗氧剂和防锈剂加入到调合釜中，加热到45～55℃，保温搅拌40～50分钟，再加入纳米石墨颗粒(2500目)搅拌均匀。具体的组份及含量见表3。使用过程中，表现出良好的润滑性能，润滑油在轧辊上铺展性能好，轧制过程中操作平稳，型材规格易于控制，表面光亮，残留物少。
表3
成品的理化指标如表1：
表1
项目 技术要求
外观颜色 黄色透明或棕黄色透明
外观清澈程度 清澈
物理特征 液体
酸值指标，meq/kg 0～4.5
皂化值指标，mgKOH/g 45～125
硫含量，ppm 8000～15000
磷含量，ppm 45～345
氯含量(纯油)，ppm ≤8.5
倾点℃ -30～-20
水分(卡尔费休)，ppm 125～560
40℃流体黏度，mm<sup>2</sup>/s 25～75
100℃流体黏度，mm<sup>2</sup>/s 4.5-13.5
黏度指数 100-170
200℃的极端润滑测试见表2
表2
本发明针对热轧型材轧制的环保油基金属润滑剂，将纳米颗粒技术融入轧制润滑剂中，解决了传统型材轧制无润滑剂存在的问题，实现了低能耗、低污染、低排放、高环保的现代文明生产的要求，具有耐高温，可以提高耐磨性能、不断地自修复破损的摩擦副表面、延长轧辊的使用寿命、提高轧材的表面光洁度。本发明环保油基金属热轧轧制润滑剂是一种无烟无味、无毒无害的产品。

Claims (2)

1.用于热轧型材轧制的环保油基型金属润滑剂，其特征在于，按重量份包括以下组分：
基础油 60-62份；
油性剂 20-25份；
摩擦改进剂 4-6份；
极压抗磨剂 2-4份；
抗氧剂 0.5-1份；
防锈剂 0.3-0.5份；
纳米石墨 2-3.5份；
基础油为矿物油，矿物油40℃运动粘度为70-80cSt，100℃运动粘度为10-15cSt，硫含量小于15000ppm；油性剂为脂肪酸酯，脂肪酸酯为由脂肪醇与脂肪酸合成的酯，脂肪酸酯是油酸乙醇酯、椰子油脂肪酸季戊四醇酯、棕榈油脂肪酸三羟甲基丙烷酯、硬脂酸乙酯中的至少一种；摩擦改进剂为二烷基二硫代磷酸锌；极压抗磨剂为亚磷酸二丁酯、磷酸三甲酚酯、硫化异丁烯中的至少一种；抗氧剂为碱土金属水杨酸盐、苯骈三氮唑、N-苯基-α萘胺中的至少一种；防锈剂为烯基丁二酸、石油磺酸钠或环烷酸锌中的至少一种。
2.根据权利要求1所述的用于热轧型材轧制的环保油基型金属润滑剂的制备方法，其特征在于，将基础油、油性剂、摩擦改进剂、防锈剂、极压抗磨剂、抗氧剂、油性剂加入到调合釜中，加热到45～55℃，保温搅拌40～50分钟，再加入纳米石墨搅拌均匀后经检验出料。
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113134767A (zh) * 2021-04-28 2021-07-20 太原理工大学 一种改善波纹辊热轧金属板材表面质量的纳米润滑方法
CN113444559A (zh) * 2021-07-30 2021-09-28 奎克化学（中国）有限公司 一种电池箔轧制添加剂及其制备方法和应用
CN114351201A (zh) * 2021-12-17 2022-04-15 无锡苏盛金属制品有限公司 一种钢带表面防锈处理工艺
WO2023091808A1 (en) * 2021-11-17 2023-05-25 Afton Chemical Corporation Engine oil formulation with improved sequence viii performance

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1923987A (zh) * 2005-08-31 2007-03-07 中国石油化工股份有限公司 含纳米抗磨剂的热轧油组合物
CN101338240A (zh) * 2008-08-15 2009-01-07 鞍山海华油脂化学有限公司 合成环保型热轧油及其制备方法
CN101870907A (zh) * 2010-06-23 2010-10-27 河南省长城特种润滑脂有限公司 高温润滑脂及制备方法
US20100298180A1 (en) * 2006-12-01 2010-11-25 Henkel Corporation Anti-seize composition with nano-sized lubricating solid particles
CN103450967A (zh) * 2013-08-16 2013-12-18 上海应用技术学院 一种油溶性纳米石墨及其制备方法和应用
CN103789067A (zh) * 2014-01-15 2014-05-14 北京科技大学 一种含油溶性纳米Cu的铜箔轧制液及其制备方法
CN106675729A (zh) * 2016-12-19 2017-05-17 钦州市科学技术开发中心 一种金属轧制油及其制备方法
CN107474914A (zh) * 2017-07-19 2017-12-15 沈阳迈腾石化有限公司 一种全合成极压开式齿轮油及其合成方法

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1923987A (zh) * 2005-08-31 2007-03-07 中国石油化工股份有限公司 含纳米抗磨剂的热轧油组合物
US20100298180A1 (en) * 2006-12-01 2010-11-25 Henkel Corporation Anti-seize composition with nano-sized lubricating solid particles
CN101338240A (zh) * 2008-08-15 2009-01-07 鞍山海华油脂化学有限公司 合成环保型热轧油及其制备方法
CN101870907A (zh) * 2010-06-23 2010-10-27 河南省长城特种润滑脂有限公司 高温润滑脂及制备方法
CN103450967A (zh) * 2013-08-16 2013-12-18 上海应用技术学院 一种油溶性纳米石墨及其制备方法和应用
CN103789067A (zh) * 2014-01-15 2014-05-14 北京科技大学 一种含油溶性纳米Cu的铜箔轧制液及其制备方法
CN106675729A (zh) * 2016-12-19 2017-05-17 钦州市科学技术开发中心 一种金属轧制油及其制备方法
CN107474914A (zh) * 2017-07-19 2017-12-15 沈阳迈腾石化有限公司 一种全合成极压开式齿轮油及其合成方法

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
吕兆岐等 主编: "《润滑油品研究与应用指南》", 30 November 1997, 中国石化出版社 *
孙建林: "《轧制工艺润滑原理、技术与应用》", 31 January 2004, 冶金工业出版社 *
胡邦喜 主编: "《设备润滑基础（第2版）》", 31 January 2002, 冶金工业出版社 *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113134767A (zh) * 2021-04-28 2021-07-20 太原理工大学 一种改善波纹辊热轧金属板材表面质量的纳米润滑方法
CN113444559A (zh) * 2021-07-30 2021-09-28 奎克化学（中国）有限公司 一种电池箔轧制添加剂及其制备方法和应用
WO2023091808A1 (en) * 2021-11-17 2023-05-25 Afton Chemical Corporation Engine oil formulation with improved sequence viii performance
US11773343B2 (en) 2021-11-17 2023-10-03 Afton Chemical Corporation Engine oil formulation with improved Sequence VIII performance
CN114351201A (zh) * 2021-12-17 2022-04-15 无锡苏盛金属制品有限公司 一种钢带表面防锈处理工艺

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