CN110416310A - A kind of film transistor device and preparation method improving radiation resistance with hydrogen peroxide - Google Patents

A kind of film transistor device and preparation method improving radiation resistance with hydrogen peroxide Download PDF

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Publication number
CN110416310A
CN110416310A CN201910559526.6A CN201910559526A CN110416310A CN 110416310 A CN110416310 A CN 110416310A CN 201910559526 A CN201910559526 A CN 201910559526A CN 110416310 A CN110416310 A CN 110416310A
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China
Prior art keywords
hydrogen peroxide
precursor solution
film transistor
highly doped
silicon substrate
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CN201910559526.6A
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Inventor
方欲晓
赵春
赵策洲
杨莉
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Xian Jiaotong Liverpool University
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Xian Jiaotong Liverpool University
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Priority to CN201910559526.6A priority Critical patent/CN110416310A/en
Publication of CN110416310A publication Critical patent/CN110416310A/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/66007Multistep manufacturing processes
    • H01L29/66969Multistep manufacturing processes of devices having semiconductor bodies not comprising group 14 or group 13/15 materials
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/68Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
    • H01L29/76Unipolar devices, e.g. field effect transistors
    • H01L29/772Field effect transistors
    • H01L29/78Field effect transistors with field effect produced by an insulated gate
    • H01L29/786Thin film transistors, i.e. transistors with a channel being at least partly a thin film
    • H01L29/7869Thin film transistors, i.e. transistors with a channel being at least partly a thin film having a semiconductor body comprising an oxide semiconductor material, e.g. zinc oxide, copper aluminium oxide, cadmium stannate

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  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Ceramic Engineering (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Manufacturing & Machinery (AREA)
  • Thin Film Transistor (AREA)

Abstract

The invention discloses a kind of film transistor devices and preparation method that radiation resistance is improved with hydrogen peroxide, including the gate electrode set gradually from top to bottom, highly doped silicon substrate, and dielectric layer, semiconductor layer, upper metal electrode;The upper metal electrode includes source electrode and drain electrode;Preparation method specific steps include: that precursor solution a) is prepared;B) hydrogen peroxide precursor solution is prepared;C) by hydrogen peroxide precursor solution ultrasonic vibration 15-60 minutes;D) highly doped silicon substrate is cleaned;E) it will be spin-coated on cleaned highly doped silicon substrate with the hydrogen peroxide precursor solution got ready;F) the highly doped silicon substrate of the good hydrogen peroxide precursor solution of spin coating is placed in annealing on hot plate and forms dielectric layer;G) semiconductor layer is prepared;H) upper metal electrode and gate electrode are deposited.This case improves the radiation resistance of film transistor device;Film transistor device it is stable and reliable for performance;It is compatible with traditional handicraft in technique, it can be effectively controlled preparation cost.

Description

A kind of film transistor device and preparation method improving radiation resistance with hydrogen peroxide
Technical field
It is specifically a kind of to improve high dielectric constant material with hydrogen peroxide the present invention relates to a kind of technology of field of microelectronic devices Expect (high-kMaterial) film transistor device (TFT device) radiation resistance method.
Background technique
With the fast development of space technology, space flight strategic arms and microelectric technique, more and more electronic components It is used by space product.It is radiation-sensitive that wherein semiconductor devices (including: semi-conductor discrete device, integrated circuit etc.) is most of Inductor component, radiation environment can generate different degrees of influence to the performance of these devices, or even make its failure.
Space radiation environment is mainly from cosmic ray, solar flare radiation and earth-circling inside and outside Van Allen radiation Band etc..Although radiation dose rate is very low, since it is that a cumulative effect will lead to when dosage rate is accumulated to certain value The performance of electronic device changes, and will lead to complete device failure when serious, makes electronic equipment cisco unity malfunction.
With the raising of device integration and the reduction of operating voltage, device is also big to the susceptibility of single particle effect Amplitude improves, and traditional semiconductor devices based on silica has lower radiation resistance, is not enough to for a long time in spoke It penetrates in environment and reliablely and stablely works.And some high-kSubstitute of the material as silica, radiation resistance are also required to It improves.Therefore it needs for various radiation effects, in the material of device, circuit design, structure design, technique manufacture and encapsulation etc. Links take reinforcement measure, make it have certain radiation resistance.The device of radiation hardening is applied to be radiated in space In environment, the reliability and service life of spacecraft will be improved;It applies in strategic arms, its efficiency will be improved and dashes forward anti- Ability.
Summary of the invention
Object of the present invention is to: one kind being based on high dielectric constant material (high- for existingkMaterial) semiconductor devices deposit Above-mentioned deficiency, propose a kind of high dielectric constant material (high- that radiation resistance is goodkMaterial) film transistor device (TFT device) meets semiconductor devices and needs for a long time under radiation environment the needs of reliable and stable work, while in technique It is compatible with traditional handicraft, control preparation cost.
The technical scheme is that a kind of film transistor device that radiation resistance is improved with hydrogen peroxide, including under To the gate electrode above set gradually, highly doped silicon substrate, dielectric layer, semiconductor layer, upper metal electrode;The upper metal electrode includes Source electrode and drain electrode.
Preferably, the highly doped silicon substrate is the highly doped monocrystalline substrate of p-type<100>crystal orientation.
Preferably, the semiconductor layer material is selected from one of metal oxide.
Preferably, the gate electrode is one of titanium, aluminium, nickel, gold, silver or several laminations.
Preferably, the upper metal electrode is one of titanium, aluminium, nickel, gold, silver or several laminations.
A method of improving the film transistor device of radiation resistance with hydrogen peroxide, specific steps include:
A) presoma drug is dissolved in aqueous solution, obtaining concentration is 0.5-2.5mol/L precursor solution;
B) hydrogen peroxide is added in precursor solution, obtains hydrogen peroxide precursor solution;Hydrogen peroxide concentration is 1-10 mol/L;
C) by hydrogen peroxide precursor solution ultrasonic vibration 15-60 minutes;
D) highly doped silicon substrate is cleaned, highly doped silicon substrate is completely immersed in and is held in the aqueous solution containing 2%-5% hydrofluoric acid, is impregnated After 30-120 seconds, highly doped silicon substrate is rinsed with deionized water and removes remaining impurity and with being dried with nitrogen;
E) it will be spin-coated on cleaned highly doped silicon substrate with the hydrogen peroxide precursor solution got ready, spin speed 3000- 5500 revolutions per seconds, spin-coating time 20-60s;
F) the highly doped silicon substrate of the good hydrogen peroxide precursor solution of spin coating is placed in annealing on hot plate and forms dielectric layer, annealing temperature is 150-300oC, annealing time are 40-80 minutes;
G) semiconductor layer is prepared;
H) upper metal electrode and gate electrode are deposited.
Preferably, the presoma drug is high dielectric constant metal nitrate, in high dielectric constant metal chloride One or more of doping mutually, the presoma drug are one or more of nitrate or villaumite of high dielectric constant metal Doping mutually, the ratio of the total drug concentration of doping metals drug concentration Zhan are 0-50%.
Preferably, the preparation step of the semiconductor layer includes: and semiconductor precursor drug is dissolved in aqueous solution first, It is 0.5-2.5mol/L semiconductor precursor solution that concentration, which is made,;Semiconductor precursor drug be one of metal nitrate or Two or more mutual doping, the ratio of the total drug concentration of doping metals drug concentration Zhan are 0-50%;It is again that semiconductor precursor is molten Liquid ultrasonic vibration 15-60 minutes;Semiconductor precursor solution is spin-coated on the dielectric layer prepared afterwards, spin speed is 3000-5500 revolutions per seconds, spin-coating time 20-60s.
The invention has the advantages that
1, the radiation resistance of film transistor device is improved;
2, film transistor device is stable and reliable for performance;
3, compatible with traditional handicraft in technique, it can be effectively controlled preparation cost.
Detailed description of the invention
The invention will be further described with reference to the accompanying drawings and embodiments:
A kind of structural schematic diagram for the film transistor device improving radiation resistance with hydrogen peroxide described in Fig. 1 this case;
It is a kind of described in Fig. 2 this case to improve aluminium oxide thin tilm capacitor in the film transistor device of radiation resistance with hydrogen peroxide Drift diagram of the flat-band voltage under back bias voltage radiation;
Wherein: 100, source electrode;101, drain electrode;200, semiconductor layer;300, dielectric layer;400, highly doped silicon substrate;500, grid Electrode.
Specific embodiment
Embodiment:
As shown in Fig. 1, a kind of film transistor device improving radiation resistance with hydrogen peroxide, including set gradually from top to bottom Gate electrode 500, highly doped silicon substrate 400, dielectric layer 300, semiconductor layer 200, upper metal electrode;The upper metal electrode includes Source electrode 100 and drain electrode 101;The highly doped silicon substrate is the highly doped monocrystalline substrate of p-type<100>crystal orientation;It is described partly to lead Body layer material is selected from one of metal oxide;The gate electrode is one of titanium, aluminium, nickel, gold, silver or several folded Layer;The upper metal electrode is one of titanium, aluminium, nickel, gold, silver or several laminations.
A method of improving the film transistor device of radiation resistance with hydrogen peroxide, specific steps include:
A) presoma drug is dissolved in aqueous solution, obtains the precursor solution that concentration is 2.5mol/L, presoma drug is nitre Sour aluminium and hafnium chloride doping, the two ratio are 8:2;
B) hydrogen peroxide is added in precursor solution, obtains hydrogen peroxide precursor solution;Hydrogen peroxide concentration is 7.5mol/L;
C) by hydrogen peroxide precursor solution ultrasonic vibration 15 minutes;
D) highly doped silicon substrate is cleaned, the highly doped silicon substrate is the highly doped monocrystalline substrate of p-type<100>crystal orientation, by highly doped silicon Substrate, which is completely immersed in, to be held in the aqueous solution containing 2%-5% hydrofluoric acid, after impregnating 30-120 seconds, rinses highly doped silicon with deionized water Substrate removes remaining impurity and with being dried with nitrogen;
E) it will be spin-coated on cleaned highly doped silicon substrate with the hydrogen peroxide precursor solution got ready, spin speed is 4500 turns/ Second, spin-coating time 40s;
F) the highly doped silicon substrate of the good hydrogen peroxide precursor solution of spin coating is placed in annealing on hot plate and forms dielectric layer, annealing temperature is 300oC, annealing time are 60 minutes;
G) semiconductor layer is prepared, the semiconductor layer material is indium oxide;The preparation step of the semiconductor layer includes: first will Indium nitrate is dissolved in aqueous solution, the semiconductor precursor solution that concentration is 0.5mol/L is made, then by semiconductor precursor solution Ultrasonic vibration 15 minutes;Then semiconductor precursor solution is spin-coated on the dielectric layer prepared, spin speed be 3000 turns/ Second, spin-coating time 20s;
H) deposit upper metal electrode and gate electrode, the gate electrode and upper metal electrode be one of titanium, aluminium, nickel, gold, silver or Several lamination of person;This implementation preference deposited the metal with a thickness of 300nm by mask plate using electron beam evaporation Aluminium, as aluminum metal source electrode 100, aluminum metal drain electrode 101 and aluminum gate electrode 500.
The strong oxidizing property of hydrogen peroxide can accelerate the decomposition of impurity in precursor solution at low temperature and form metal framework Structure, while reducing the content of Lacking oxygen in film improves the quality of film, improve metal-oxide film and silicon substrate it Between interface, to improve the radiation resistance of device.It is radiated from the flat-band voltage of Fig. 2 aluminium oxide thin tilm capacitor in back bias voltage Under drift diagram as can be seen that circular data represent the MOS device containing hydrogen peroxide, flatband voltage shift after irradiation without Significant change, radiation resistance are significantly improved, and triangle data represents the MOS device without hydrogen peroxide, after irradiation Flatband voltage shift produces apparent degeneration.
The above-described embodiments merely illustrate the principles and effects of the present invention, and is not intended to limit the present invention.It is any Those skilled in the art all without departing from the spirit and scope of the present invention, carries out modifications and changes to above-described embodiment. Therefore, such as those of ordinary skill in the art without departing from revealed spirit of the invention under technical idea All equivalent modifications completed or change should be covered by the claims of the present invention.

Claims (8)

1. a kind of film transistor device for improving radiation resistance with hydrogen peroxide, it is characterised in that: including successively setting from top to bottom The gate electrode set, highly doped silicon substrate, dielectric layer, semiconductor layer, upper metal electrode;The upper metal electrode includes source electrode and leakage Electrode.
2. a kind of film transistor device for improving radiation resistance with hydrogen peroxide according to claim 1, it is characterised in that: The highly doped silicon substrate is the highly doped monocrystalline substrate of p-type<100>crystal orientation.
3. a kind of film transistor device for improving radiation resistance with hydrogen peroxide according to claim 1, it is characterised in that: The semiconductor layer material is selected from one of metal oxide.
4. a kind of film transistor device for improving radiation resistance with hydrogen peroxide according to claim 1, it is characterised in that: The gate electrode is one of titanium, aluminium, nickel, gold, silver or several laminations.
5. a kind of film transistor device for improving radiation resistance with hydrogen peroxide according to claim 1, it is characterised in that: The upper metal electrode is one of titanium, aluminium, nickel, gold, silver or several laminations.
6. a kind of preparation method for the film transistor device for improving radiation resistance with hydrogen peroxide, it is characterised in that: specific steps Include:
A) presoma drug is dissolved in aqueous solution, obtaining concentration is 0.5-2.5 mol/L precursor solution;
B) hydrogen peroxide is added in precursor solution, obtains hydrogen peroxide precursor solution;Hydrogen peroxide concentration is 1-10 mol/L;
C) by hydrogen peroxide precursor solution ultrasonic vibration 15-60 minutes;
D) highly doped silicon substrate is cleaned, highly doped silicon substrate is completely immersed in and is held in the aqueous solution containing 2%-5% hydrofluoric acid, is impregnated After 30-120 seconds, highly doped silicon substrate is rinsed with deionized water and removes remaining impurity and with being dried with nitrogen;
E) it will be spin-coated on cleaned highly doped silicon substrate with the hydrogen peroxide precursor solution got ready, spin speed 3000- 5500 revolutions per seconds, spin-coating time 20-60s;
F) the highly doped silicon substrate of the good hydrogen peroxide precursor solution of spin coating is placed in annealing on hot plate and forms dielectric layer, annealing temperature is 150-300oC, annealing time are 40-80 minutes;
G) semiconductor layer is prepared;
H) upper metal electrode and gate electrode are deposited.
7. a kind of preparation method of film transistor device that radiation resistance is improved with hydrogen peroxide according to claim 6, It is characterized by: the presoma drug is that one or more of nitrate or villaumite of high dielectric constant metal are mixed mutually Miscellaneous, the ratio of the total drug concentration of doping metals drug concentration Zhan is 0-50%.
8. a kind of preparation method of film transistor device that radiation resistance is improved with hydrogen peroxide according to claim 6, It is characterized by: the preparation step of the semiconductor layer includes: that semiconductor precursor drug is dissolved in aqueous solution first, it is made Concentration is 0.5-2.5mol/L semiconductor precursor solution;Semiconductor precursor drug is one or both of metal nitrate The above doping mutually, the ratio of the total drug concentration of doping metals drug concentration Zhan are 0-50%;Semiconductor precursor solution is surpassed again Acoustic shock is swung 15-60 minutes;Semiconductor precursor solution is spin-coated on the dielectric layer prepared afterwards, spin speed 3000- 5500 revolutions per seconds, spin-coating time 20-60s.
CN201910559526.6A 2019-06-26 2019-06-26 A kind of film transistor device and preparation method improving radiation resistance with hydrogen peroxide Pending CN110416310A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112382573A (en) * 2020-11-12 2021-02-19 西交利物浦大学 Synapse type thin film transistor based on lithium-doped transparent oxide and preparation method thereof
CN112436060A (en) * 2020-11-23 2021-03-02 西交利物浦大学 Thin film transistor doped with potassium ions and preparation method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20030049590A (en) * 2001-12-15 2003-06-25 주식회사 하이닉스반도체 Method for forming transistor of semiconductor decice
CN105489486A (en) * 2016-01-18 2016-04-13 青岛大学 Method for preparing thin-film transistor based on ultra-thin magnesium oxide high-k dielectric layer
CN109037031A (en) * 2018-07-11 2018-12-18 华东师范大学 A kind of nickel-doped CuO film transistor and preparation method
CN109244239A (en) * 2018-07-18 2019-01-18 华南师范大学 A kind of zirconium doping Organic Thin Film Transistors and preparation method thereof
CN109767988A (en) * 2018-12-25 2019-05-17 西交利物浦大学 Metal oxide thin-film transistor and preparation method thereof
CN210866188U (en) * 2019-06-26 2020-06-26 西交利物浦大学 Thin film transistor device for improving radiation resistance by using hydrogen peroxide

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20030049590A (en) * 2001-12-15 2003-06-25 주식회사 하이닉스반도체 Method for forming transistor of semiconductor decice
CN105489486A (en) * 2016-01-18 2016-04-13 青岛大学 Method for preparing thin-film transistor based on ultra-thin magnesium oxide high-k dielectric layer
CN109037031A (en) * 2018-07-11 2018-12-18 华东师范大学 A kind of nickel-doped CuO film transistor and preparation method
CN109244239A (en) * 2018-07-18 2019-01-18 华南师范大学 A kind of zirconium doping Organic Thin Film Transistors and preparation method thereof
CN109767988A (en) * 2018-12-25 2019-05-17 西交利物浦大学 Metal oxide thin-film transistor and preparation method thereof
CN210866188U (en) * 2019-06-26 2020-06-26 西交利物浦大学 Thin film transistor device for improving radiation resistance by using hydrogen peroxide

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112382573A (en) * 2020-11-12 2021-02-19 西交利物浦大学 Synapse type thin film transistor based on lithium-doped transparent oxide and preparation method thereof
CN112436060A (en) * 2020-11-23 2021-03-02 西交利物浦大学 Thin film transistor doped with potassium ions and preparation method thereof

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