CN110393307A - A kind of smokeless tobacco tar and preparation method thereof - Google Patents
A kind of smokeless tobacco tar and preparation method thereof Download PDFInfo
- Publication number
- CN110393307A CN110393307A CN201910837924.XA CN201910837924A CN110393307A CN 110393307 A CN110393307 A CN 110393307A CN 201910837924 A CN201910837924 A CN 201910837924A CN 110393307 A CN110393307 A CN 110393307A
- Authority
- CN
- China
- Prior art keywords
- tobacco tar
- smokeless tobacco
- nicotine
- essence
- nicotine salt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 241000208125 Nicotiana Species 0.000 title claims abstract description 105
- 235000002637 Nicotiana tabacum Nutrition 0.000 title claims abstract description 105
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims abstract description 82
- SNICXCGAKADSCV-JTQLQIEISA-N (-)-Nicotine Chemical compound CN1CCC[C@H]1C1=CC=CN=C1 SNICXCGAKADSCV-JTQLQIEISA-N 0.000 claims abstract description 44
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Natural products CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 claims abstract description 27
- 229960002715 nicotine Drugs 0.000 claims abstract description 27
- 238000000034 method Methods 0.000 claims abstract description 16
- 235000006679 Mentha X verticillata Nutrition 0.000 claims description 10
- 235000002899 Mentha suaveolens Nutrition 0.000 claims description 10
- 235000001636 Mentha x rotundifolia Nutrition 0.000 claims description 10
- 235000005979 Citrus limon Nutrition 0.000 claims description 8
- 244000131522 Citrus pyriformis Species 0.000 claims description 8
- 240000004922 Vigna radiata Species 0.000 claims description 8
- 235000010721 Vigna radiata var radiata Nutrition 0.000 claims description 8
- 235000011469 Vigna radiata var sublobata Nutrition 0.000 claims description 8
- VAUQRLHPXWYZRZ-UHFFFAOYSA-N benzoic acid;3-(1-methylpyrrolidin-2-yl)pyridine Chemical compound OC(=O)C1=CC=CC=C1.CN1CCCC1C1=CC=CN=C1 VAUQRLHPXWYZRZ-UHFFFAOYSA-N 0.000 claims description 7
- HHJJGPDCKPJWIE-UHFFFAOYSA-N 3-hydroxybenzoic acid 3-(1-methylpyrrolidin-2-yl)pyridine Chemical group OC=1C=C(C(=O)O)C=CC1.N1=CC=CC(=C1)C1N(C)CCC1 HHJJGPDCKPJWIE-UHFFFAOYSA-N 0.000 claims description 6
- SDVKWBNZJFWIMO-UHFFFAOYSA-N 2-hydroxypropane-1,2,3-tricarboxylic acid;3-(1-methylpyrrolidin-2-yl)pyridine Chemical compound CN1CCCC1C1=CC=CN=C1.OC(=O)CC(O)(C(O)=O)CC(O)=O SDVKWBNZJFWIMO-UHFFFAOYSA-N 0.000 claims description 4
- JDIZODRSTZHAFD-UHFFFAOYSA-N butanedioic acid;3-(1-methylpyrrolidin-2-yl)pyridine Chemical compound OC(=O)CCC(O)=O.CN1CCCC1C1=CC=CN=C1 JDIZODRSTZHAFD-UHFFFAOYSA-N 0.000 claims description 4
- JULHOSJVFDUONV-UHFFFAOYSA-N 3,5-dihydroxybenzoic acid 3-(1-methylpyrrolidin-2-yl)pyridine Chemical compound OC=1C=C(C(=O)O)C=C(C1)O.N1=CC=CC(=C1)C1N(C)CCC1 JULHOSJVFDUONV-UHFFFAOYSA-N 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 2
- 239000003571 electronic cigarette Substances 0.000 abstract description 23
- 239000003205 fragrance Substances 0.000 abstract description 8
- 230000007794 irritation Effects 0.000 abstract description 7
- 210000003928 nasal cavity Anatomy 0.000 abstract description 4
- 210000004072 lung Anatomy 0.000 abstract description 3
- 230000001839 systemic circulation Effects 0.000 abstract description 2
- 229960004063 propylene glycol Drugs 0.000 description 28
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 25
- 230000000052 comparative effect Effects 0.000 description 20
- 235000019504 cigarettes Nutrition 0.000 description 15
- 239000007789 gas Substances 0.000 description 14
- 235000011187 glycerol Nutrition 0.000 description 11
- 239000000779 smoke Substances 0.000 description 8
- 239000000203 mixture Substances 0.000 description 7
- 230000001953 sensory effect Effects 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- 238000002156 mixing Methods 0.000 description 6
- 238000001514 detection method Methods 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- QLDPCHZQQIASHX-LREBCSMRSA-N C(=O)(O)[C@H](O)[C@@H](O)C(=O)O.N1=CC=CC(=C1)C1N(C)CCC1 Chemical compound C(=O)(O)[C@H](O)[C@@H](O)C(=O)O.N1=CC=CC(=C1)C1N(C)CCC1 QLDPCHZQQIASHX-LREBCSMRSA-N 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- 206010043521 Throat irritation Diseases 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 238000004587 chromatography analysis Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 210000000214 mouth Anatomy 0.000 description 2
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 2
- 238000005070 sampling Methods 0.000 description 2
- 210000000697 sensory organ Anatomy 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- 206010006326 Breath odour Diseases 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 241000208292 Solanaceae Species 0.000 description 1
- 235000002634 Solanum Nutrition 0.000 description 1
- 241000207763 Solanum Species 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229930013930 alkaloid Natural products 0.000 description 1
- 150000003797 alkaloid derivatives Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000000889 atomisation Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000012159 carrier gas Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- PQPVPZTVJLXQAS-UHFFFAOYSA-N hydroxy-methyl-phenylsilicon Chemical compound C[Si](O)C1=CC=CC=C1 PQPVPZTVJLXQAS-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 210000000867 larynx Anatomy 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 230000000116 mitigating effect Effects 0.000 description 1
- 210000001331 nose Anatomy 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000001303 quality assessment method Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 230000014860 sensory perception of taste Effects 0.000 description 1
- 230000000391 smoking effect Effects 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000009747 swallowing Effects 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- 235000019505 tobacco product Nutrition 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/10—Chemical features of tobacco products or tobacco substitutes
- A24B15/16—Chemical features of tobacco products or tobacco substitutes of tobacco substitutes
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/10—Chemical features of tobacco products or tobacco substitutes
- A24B15/16—Chemical features of tobacco products or tobacco substitutes of tobacco substitutes
- A24B15/167—Chemical features of tobacco products or tobacco substitutes of tobacco substitutes in liquid or vaporisable form, e.g. liquid compositions for electronic cigarettes
Abstract
The present invention relates to a kind of smokeless tobacco tar and preparation method thereof, the smokeless tobacco tar is composed of the following components: essence；Nicotine or nicotine salt；And propylene glycol.Smokeless tobacco tar according to the present invention will not generate apparent visible smog when sucking (systemic circulation suction or lung inhale method) by electronic cigarette, and the smokeless tobacco tar has the aesthetic quality of higher quality, especially appearance is bright, fragrance harmony, it is small to the irritation of nasal cavity and throat, pleasant impression is comfortable, and mouthfeel is smooth.
Description
Technical field
The present invention relates to electronic cigarette fields, and in particular, to a kind of smokeless tobacco tar and preparation method thereof, the smokeless tobacco tar
For the raw material of sucking of electronic cigarette, visible smog will not be generated when in use.
Background technique
Electronic cigarette is that a kind of electronic product for imitating cigarette is vaporized the tobacco tar of injection by means such as heating, atomizations
After allow user to suck.In general, electronic cigarette is mainly made of the smoke pipe, atomizer and battery etc. that hold tobacco tar.Atomizer by
Tobacco tar, can be transformed into fog by battery power supply, so that user be allowed to have a kind of similar feeling smoked when sucking.
Currently, global electronic cigarette market development speedup is surprising, America and Europe is main consumption market, and China is then main
Produce the country of electronic cigarette.Electronic cigarette is studied energetically all to supply western market, industry by smoke machine structure, private enterprise in domestic more families
Thriving, electronic cigarette probably replaces conventional cigarette in the near future, becomes mainstream.
Raw material as electronic cigarette --- tobacco tar is to cooperate the electronic atomized liquid that uses of electronic cigarette, mainly include essence,
Nicotine, PG and VG etc., component is apparent, content is controllable, taste is adjustable, thus compared to the cigarette sucked by lighting, electronics
Cigarette more safety and sanitation, can be used as the cigarette substitute of very advantageous.In above-mentioned formula, nicotine (Nicotine), custom
Name nicotine, is the important component of alkaloid and tobacco that one kind is present in plant of Solanaceae (Solanum).In the tobacco tar of electronic cigarette
The middle nicotine that can be added is with the mouthfeel of simulated cigarette；PG is the abbreviation of English propylene glycol, and mainly using 1,2-PD
(not having to 1,3- propylene glycol generally)；VG is the abbreviation of English vegetables glycerol, indicates food grade or the other glycerine of pharmaceutical grade (custom
Claim glycerol), character is sticky, than great.Currently, China is just in strict implement room and the public place regulation that absolutely no smoking,
To mitigate pollution of the secondhand smoke to ambient enviroment, especially prevent the tar generated when cigarette combustion, suspended solid particles, an oxygen
Change the injury to human body such as carbon.
However, the principle of electronic cigarette and cigarette is entirely different, so-called tar, suspended solid can't be generated when sucking
Grain, carbon monoxide etc., in comparison, electronic cigarette are substantially reduced than the harmfulness of conventional cigarette.But electronic cigarette is due to equally can
Smog is generated, can also make surrounding population generate corresponding misunderstanding and puzzlement, cause unnecessary trouble.
Summary of the invention
[technical problem]
To solve the above-mentioned problems, the present invention provides a kind of smokeless tobacco tar and preparation method thereof, the smokeless tobacco tar is used
Raw material is sucked in electronic cigarette, visible smog will not be generated when method is sucked inhaling with systemic circulation suction or lung, and have compared with Gao Pin
The aesthetic quality of matter.
[technical solution]
According to embodiment of the present invention, a kind of smokeless tobacco tar is provided, the smokeless tobacco tar is by following components group
At: essence；Nicotine or nicotine salt；And propylene glycol.
The present inventor passes through discovery of concentrating on studies, and includes glycerol fractions in commercially available routine tobacco tar, and boiling point is high, easy
The moisture absorption can draw the moisture of ambient enviroment when being volatized into air, be allowed to condense into small suspending drops in air, this
It is the main reason for tobacco tar generates smog when sucking.Therefore, inventor's design removes glycerine from tobacco tar component, and closes
Reason chooses remaining ingredient and adjusts its proportion, to eliminate the visible smog that tobacco tar is generated when sucking, avoids influencing other people,
Thus smokeless tobacco tar according to the present invention is obtained.
Specifically, the smokeless tobacco tar is grouped as by the group of following parts by weight:
5.0 to 25.0 parts by weight of essence；
0.1 to 5.0 parts by weight of nicotine or nicotine salt；With
70.0 to 94.9 parts by weight of propylene glycol.
In above-mentioned compositing range, smokeless tobacco tar according to the present invention can greatly eliminate the production of smog when sucking
It is raw, while a possibility that also eliminate other components also and can generate smog, so that smokeless tobacco tar of the invention is real when sucking
Achieve the effect that " smokeless ".
Preferably, the smokeless tobacco tar is grouped as by the group of following parts by weight:
8.0 to 15.0 parts by weight of essence；
1.4 to 3.0 parts by weight of nicotine or nicotine salt；With
82.0 to 90.6 parts by weight of propylene glycol.
In above-mentioned preferred compositing range, smokeless tobacco tar according to the present invention can also be balanced further and be optimized smokeless
Aesthetic quality's (such as appearance, fragrance, harmony, miscellaneous gas, irritation and pleasant impression) of tobacco tar and character (such as dispersibility, stability),
So that the properties of smokeless tobacco tar of the invention are optimal.
In the present invention, the propylene glycol can be 1,2-PD, colorless and odorless, stability is good, dissolubility and point
It is good to dissipate property, the solvent of essence and nicotine salt is used as in smokeless tobacco tar of the invention, and be also used as perfume (or spice) in heated volatilization
The carrier of essence and nicotine salt evolution.Especially since being colourless viscous liquid under 1,2-PD normality, almost tasteless, thin
Hear slightly sweet, and 1,3-PD has saline taste, has hygroscopicity, therefore in comparison, described in the preferred 1,2-PD of the present invention is used as
Propylene glycol.
The nicotine salt can be selected from 3- hydroxybenzoic acid nicotine salt, 3,5- dihydroxy-benzoic acid nicotine salt, fourth
At least one of diacid nicotine salt, benzoic acid nicotine salt and citric acid nicotine salt.By using above-mentioned nicotine salt,
The stability of smokeless tobacco tar can be greatlyd improve, improves pot-life and safety, while can also improve the mouth of smokeless tobacco tar
Sense, reduces nasal cavity and throat irritation, and larynx sense is hit in mitigation.Preferably, the nicotine salt is benzoic acid nicotine salt.
The essence can be that essence commonly used in the art can be according to the needs in market and user by using essence
The taste of smokeless tobacco tar is arbitrarily transformed, meets the taste demand of different crowd.Preferably, essence according to the present invention can be selected from
Mint flavored essence, mung bean taste essence or lemon cola taste essence.
In addition, the described method comprises the following steps the present invention also provides the preparation method of above-mentioned smokeless tobacco tar: will make a reservation for
Essence, nicotine or the nicotine salt and propylene glycol of amount uniformly mix.Preparation method according to the present invention mild condition, does not need
The critical conditions such as high temperature and pressure, but by uniformly mixing, smokeless tobacco tar according to the present invention simple and direct can efficiently be made.
[beneficial effect]
Smokeless tobacco tar according to the present invention will not generate apparent visible smog when sucking, and in appearance, fragrance, humorous
Also quality with higher, especially appearance are bright on the aesthetic qualities such as tune, miscellaneous gas, irritation and pleasant impression, fragrance harmony, to nose
The irritation of chamber and throat is small, and pleasant impression is comfortable, and mouthfeel is smooth.
Specific embodiment
Hereinafter, preferred embodiment is provided to make those skilled in the art more fully understand the present invention.However, this
A little embodiments are for illustration purposes only, and are not intended to limit the invention to these embodiments.
Embodiment 1
The 1,2- propylene glycol of the mint flavored essence of 11.5g, the 3- hydroxybenzoic acid nicotine salt of 2.2g and 86.3g is uniform
Mixing is to be made smokeless tobacco tar A according to the present invention.
Embodiment 2
By the mung bean taste essence of 8.0g, the 3,5- dihydroxy-benzoic acid nicotine salt of 3.0g and the 1,2- propylene glycol of 82.0g
Uniformly mixing is to be made smokeless tobacco tar B according to the present invention.
Embodiment 3
The mung bean taste essence, the nicotine of 1.4g and the 1,2- propylene glycol of 90.6g of 15.0g are uniformly mixed so that basis is made
Smokeless tobacco tar C of the invention.
Embodiment 4
Lemon cola taste essence, the benzoic acid nicotine salt of 1.4g and the 1,2- propylene glycol of 90.6g of 13.5g are uniformly mixed
It closes so that smokeless tobacco tar D according to the present invention is made.
Embodiment 5
The 1,2- propylene glycol of the mint flavored essence of 9.5g, the nicotine of 2.6g and 84.0g is uniformly mixed so that basis is made
Smokeless tobacco tar E of the invention.
Embodiment 6
By the mung bean taste essence of 14.5g, the succinic acid nicotine salt of 2.0g and the 1,2- propylene glycol of 90.0g uniformly mix with
Smokeless tobacco tar F according to the present invention is made.
Embodiment 7
Lemon cola taste essence, the citric acid nicotine salt of 1.4g and the 1,2- propylene glycol of 89.0g of 12.0g are uniformly mixed
It closes so that smokeless tobacco tar G according to the present invention is made.
Embodiment 8
By the 1,2- propylene glycol of the mint flavored essence of 8.3g, the benzoic acid nicotine salt of 3.0g and 86.5g uniformly mix with
Smokeless tobacco tar H according to the present invention is made.
Embodiment 9
The 1,2- propylene glycol of the mung bean taste essence of 5.0g, the 3- hydroxybenzoic acid nicotine salt of 5.0g and 70.0g is uniform
Mixing is to be made smokeless tobacco tar I according to the present invention.
Embodiment 10
Lemon cola taste essence, the nicotine of 0.1g and the 1,2- propylene glycol of 94.9g of 25.0g are uniformly mixed to be made
Smokeless tobacco tar J according to the present invention.
Embodiment 11
By the 1,2- propylene glycol of the mint flavored essence of 20.0g, the citric acid nicotine salt of 4.0g and 80.0g uniformly mix with
Smokeless tobacco tar K according to the present invention is made.
Embodiment 12
By the 1,2- propylene glycol of the mint flavored essence of 6.0g, the benzoic acid nicotine salt of 1.0g and 92.0g uniformly mix with
Smokeless tobacco tar L according to the present invention is made.
Comparative example 1
The glycerine of the mung bean taste essence of 10.0g, the nicotine of 1.5g, the 1,2- propylene glycol of 85.0g and 20g are uniformly mixed
It closes so that tobacco tar M is made.
Comparative example 2
The glycerine of the mint flavored essence of 8.5g, the nicotine of 2.8g, the 1,2- propylene glycol of 70.0g and 40g are uniformly mixed
It closes so that tobacco tar N is made.
Comparative example 3
By the third of the mung bean taste essence of 10.0g, the L-TARTARIC ACID nicotine salt of 2.2g, the 1,2- propylene glycol of 70.0g and 20g
Triol is uniformly mixed so that tobacco tar O is made.
Comparative example 4
The 1,2- propylene glycol of the lemon cola taste essence of 8.0g, the L-TARTARIC ACID nicotine salt of 2.2g and 90.0g is uniform
Mixing is to be made tobacco tar P.
Comparative example 5
By the mint flavored essence of 20.0g, the 3- hydroxybenzoic acid nicotine salt of 1.0g, the 1,2- propylene glycol of 90.0g and 20g
Glycerine uniformly mix be made tobacco tar Q.
Comparative example 6
By the lemon cola taste essence of 5.0g, the succinic acid nicotine salt of 4.0g, the 1,2- propylene glycol of 70.0g and 40g
Glycerine is uniformly mixed so that tobacco tar R is made.
Comparative example 7
The 1,2- propylene glycol of the mint flavored essence of 20.0g, the 3- hydroxybenzoic acid nicotine salt of 6.0g and 65.0g is uniform
Mixing is to be made tobacco tar S.
Comparative example 8
Lemon cola taste essence, the succinic acid nicotine salt of 6.0g and the 1,2- propylene glycol of 65.0g of 5.0g are uniformly mixed
It closes so that tobacco tar T is made.
EXPERIMENTAL EXAMPLE
Since current electronic cigarette has no relevant national standard or industry unified standard, phase of the present invention with reference to cigarette
It closes country or professional standard has been carried out for the smokeless tobacco tar A to L of the embodiment according to the present invention and tobacco tar M of comparative example
To the test of T.
1, aesthetic quality judges
With reference to standard GB/T 5606.4-2005: the mensuration mode of " the 4th part of cigarette: sense organ technical requirements ", to root
Aesthetic quality's judge is carried out according to smokeless tobacco tar of the invention, which is incorporated herein by reference.However, at this
In judge, due to the difference of the raw material of electronic cigarette and cigarette, working principle etc., reference above-mentioned standard judge mode it is same
When, also accordingly based upon electronic cigarette the characteristics of and be made that certain adjustment.Herein, in addition to specifically noted by following present invention
Judge project and operating process except, part identical with above-mentioned national standard is then omitted in the present invention.
Specifically, it is right using electronic cigarette (model: the small cigarette of spark comes from this Ker Co., Ltd) that 15 technical staff that smoke panel test are set
Tobacco tar A to T made from above-described embodiment 1 to 12 and comparative example 1 to 6 is sucked, and using the side of secret marking
Formula provides sensory judgments.Wherein, everybody technical staff that smokes panel test inhales method using lung and sucks 10 mouthfuls to every kind of tobacco tar, every mouthful of interval 10
Second, and the interval time for sucking different tobacco tar is no less than 20 minutes, to avoid influencing each other.Sensory judgments' project and marking mark
It is quasi- as follows:
(1) appearance: visual state when tobacco tar is stood at room temperature, wherein the limpid glossy 5-4 of distinctness point, it is transparent not
Vivid 4-3 points, it is following that muddiness has solid 3 to divide；
(2) fragrance: the fragrance that tobacco tar is realized in sucking process, wherein plentiful exquisiteness 32-28 point is sufficient but slightly
Coarse 28-24 points, thin rougher 24 points or less；
(3) harmony: tobacco tar fragrance harmony one integrated mass in sucking process will not individually protrude the taste of a certain component,
Wherein, very harmony 6-5 points, compared with harmony 5-4 points, still harmony 4 divides following；
(4) miscellaneous gas: the bad breath for the non-tobacco tar itself that tobacco tar generates in sucking process, wherein without miscellaneous gas 12-10
Point, it is micro- to have miscellaneous gas 10-8 points, there is miscellaneous gas 8 to divide following；
(5) irritation: being divided into throat irritation and nasal cavity irritation, refers to the discomfort that tobacco tar generates in sucking process
The degree received, wherein non-stimulated 10-8 points, slightly 8-6 points of stimulation, irritating 6 points or less；
(6) pleasant impression: tobacco tar in sucking process after oral cavity, nasal cavity exhalation, the taste perception that carries over, wherein pure
Net comfortable 25-22 points, suitable 22-20 points more clean, still clean is suitable for 20 points or less.
Above sensory judgments' project score value total score is up to 100 points, and the practical judge total score of each tobacco tar is higher, shows sense organ
Quality is better.
In addition, the present invention also individually sets up the sensory judgments of smog visible level, with to embodiment according to the present invention and
The smokeless degree of the tobacco tar of comparative example is judged:
(7) smog visible level: refer to that tobacco tar generates the degree of visible smog in sucking process, wherein concealed difficulty seeks 5-4
Point, subtle visible 4-3 points, written in water 3-2 points, cloud and mist curls upwards 2-1 points, the clear 1-0 of fog points.
Smog visible level according to the present invention is individually scored, and is not counted in above-mentioned (1) to (6) item sensory judgments' total score
In, intuitively to show the smokeless effect of smokeless tobacco tar according to the present invention.
Everybody smoke panel test every evaluation result of technical staff is summarized and calculated arithmetic mean of instantaneous value, retains one decimal place
Effective digital, to obtain the evaluation result of tobacco tar A to T made from the embodiment of the present invention 1 to 12 and comparative example 1 to 8, such as
Shown in following table 1:
[table 1]
The smokeless tobacco tar A of glycerine is free of made from embodiment according to the present invention 1 to 12 it can be seen from the above table 1
It is hardly visible fog when sucking to L, thus visual " secondhand smoke " can be eliminated, avoids bothering other people, and it is right
Than tobacco tar M to N and Q to the R visible obvious fog when sucking made from embodiment 1 to 2 and 5 to 6 containing glycerine, and suck
Scene of swallowing clouds and blowing out fog when cigarette is no different, it is easy to cause other people misunderstanding.
In addition, compared to tobacco tar M to N and Q to R, smokeless tobacco tar A to L according to the present invention is used according to the above table 1
Specific tobacco tar component, and by the adjusting to essence, propylene glycol and nicotine or the content ratio of its salt, nothing can be made
Also quality with higher, user are eating cigarette tobacco tar on the sensory judgments such as appearance, fragrance, harmony, miscellaneous gas, irritation and pleasant impression
Used time can feel smooth soft and smooth, soft fine and smooth, submissive alcohol just.
2, environmental impact assessment
In order to examine smokeless tobacco tar according to the present invention when sucking other than not generating smog, if can also generate it
Its environment influences, with reference to professional standard YC/T 155-2001: " the measurement gas phase of gas phase nicotine in tobacco and tobacco product air
Chromatography " is sucked the gas phase nicotine content in rear surrounding air to tobacco tar and is detected, side of the sector standard to quote
Formula is incorporated herein.However, in the detection, it can be according to the adjustment for making adaptability the characteristics of electronic cigarette.Herein, in addition to
Except operating process specifically noted by following present invention, part identical with above-mentioned professional standard then gives province in the present invention
Slightly.
Since the composition of electronic cigarette tobacco tar is clear, the harmful substances such as tar, carbon monoxide will not be generated when sucking, thus
The present invention can simplify as the detection to gas phase nicotine in air the environmental impact assessment of tobacco tar.
The environmental impact assessment can be carried out while carrying out above-mentioned sensory quality assessment.Specifically, make the technology of smokeing panel test
Personnel carry out tobacco tar sucking process in specific experimental cabin, and acquire air in cabin after every kind of tobacco tar sucks end 3 minutes
Gas chromatographic detection is carried out, and the air in abundant recovery test cabin before sucking another tobacco tar, excludes doing for previous tobacco tar
It disturbs.Wherein, which is 30m3, air general condition is referred to standard GB/T/T in other structures parameter and cabin
18801-2015 is set.
Specific test process are as follows: with 1L/min under 25 DEG C, the air conditions of 1atm and relative humidity (50 ± 10) %
Sampling rate acquisition tobacco tar suck after air sample 1h, 3 parts of samples of parallel acquisition.Each sample is sent into gas after processing
Detected in chromatography, GC conditions are as follows: (the 5% of 10 μm of coating is poly- for 30m × 0.32 μm (internal diameter) capillary column
Phenyl methyl siloxane film), helium carrier gas flow velocity: 2mL/min, initial furnace temperature: 150 DEG C, temperature programming speed: 5 DEG C/min rises to
180 DEG C, 250 DEG C of injector temperature, sampling volume: 2 μ L, input mode: direct injected, detector: thermionic detector, detection
Device temperature: 300 DEG C, detector sensitivity: 0.1 μ g/mL.The nicotine in each sample is calculated according to YC/T 155-2001
Concentration, parallel sample are averaged, as a result as shown in the following Table 2.
[table 2]
| Tobacco tar | Nicotine concentration (μ g/m3) | |
| Embodiment 1 | A | 0.3 |
| Embodiment 2 | B | 0.1 |
| Embodiment 3 | C | 0.4 |
| Embodiment 4 | D | 0.3 |
| Embodiment 5 | E | 0.2 |
| Embodiment 6 | F | 0.4 |
| Embodiment 7 | G | 0.4 |
| Embodiment 8 | H | 0.3 |
| Embodiment 9 | I | 0.2 |
| Embodiment 10 | J | 0.1 |
| Embodiment 11 | K | 0.3 |
| Embodiment 12 | L | 0.3 |
| Comparative example 1 | M | 2.4 |
| Comparative example 2 | N | 2.2 |
| Comparative example 3 | O | 2.9 |
| Comparative example 4 | P | 1.2 |
| Comparative example 5 | Q | 2.3 |
| Comparative example 6 | R | 2.6 |
| Comparative example 7 | S | 1.3 |
| Comparative example 8 | T | 1.4 |
The smokeless tobacco tar A to L made from embodiment according to the present invention 1 to 12 it can be seen from the above table 2 when sucking not
But not smog is generated, and the gas phase nicotine disseminated in air is also considerably less, it might even be possible to ignore, i.e., will not make
At second-hand smoke pollution, thus it can completely eliminate whether the public can also generate the doubt of serious secondhand smoke to electronic cigarette.In addition,
The above results also indicate that the volatility of smokeless tobacco tar nicotine when sucking according to the present invention is very good, and can be rapidly by people
Body absorbs, thus the amount of sucking of tobacco tar can also be reduced while meeting customer need.
Although illustrate and describing the present invention with specific embodiment, it should be understood by those skilled in the art that
It is that without departing from the spirit and scope of the present invention, can be carried out to technical solution documented by foregoing embodiments
Modification, these modifications should also be as being considered as within the scope of claimed technical solution.
Claims (8)
1. a kind of smokeless tobacco tar, composed of the following components: essence；Nicotine or nicotine salt；And propylene glycol.
2. smokeless tobacco tar according to claim 1, wherein the smokeless tobacco tar is grouped as by the group of following parts by weight:
5.0 to 25.0 parts by weight of essence；
0.1 to 5.0 parts by weight of nicotine or nicotine salt；With
70.0 to 94.9 parts by weight of propylene glycol.
3. smokeless tobacco tar according to claim 2, wherein the smokeless tobacco tar is grouped as by the group of following parts by weight:
8.0 to 15.0 parts by weight of essence；
1.4 to 3.0 parts by weight of nicotine or nicotine salt；With
82.0 to 90.6 parts by weight of propylene glycol.
4. smokeless tobacco tar according to any one of claims 1 to 3, wherein the propylene glycol is 1,2-PD.
5. smokeless tobacco tar according to any one of claims 1 to 3, wherein the nicotine salt is selected from 3- hydroxybenzoic acid
Nicotine salt, 3,5- dihydroxy-benzoic acid nicotine salt, succinic acid nicotine salt, benzoic acid nicotine salt and citric acid nicotine
At least one of salt.
6. smokeless tobacco tar according to claim 5, wherein the nicotine salt is benzoic acid nicotine salt.
7. smokeless tobacco tar according to any one of claims 1 to 3, wherein the essence is selected from mint flavored essence, mung bean taste
Essence or lemon cola taste essence.
8. a kind of preparation method of the described in any item smokeless tobacco tar of claim 1 to 7, the described method comprises the following steps: will
Essence, nicotine or the nicotine salt and propylene glycol of predetermined amount uniformly mix.
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107536099A (en) * | 2017-09-14 | 2018-01-05 | 昌宁德康生物科技（深圳）有限公司 | A kind of nicotine salt and preparation method thereof |
| GB2561266A (en) * | 2017-04-07 | 2018-10-10 | Sensus Investments Ltd | Carrier, apparatus and method |
| CN108887731A (en) * | 2018-08-21 | 2018-11-27 | 深圳瀚星翔科技有限公司 | Nicotine salt, electronics tobacco tar and preparation method thereof |
| CN109619655A (en) * | 2019-01-18 | 2019-04-16 | 深圳市同信兴投资有限公司 | A kind of compound nicotine salt and its solution, preparation method and application |
| CN109820250A (en) * | 2019-03-06 | 2019-05-31 | 云南巴菰生物科技有限公司 | A kind of non smoke type electronic cigarette |
-
2019
- 2019-09-05 CN CN201910837924.XA patent/CN110393307A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2561266A (en) * | 2017-04-07 | 2018-10-10 | Sensus Investments Ltd | Carrier, apparatus and method |
| CN107536099A (en) * | 2017-09-14 | 2018-01-05 | 昌宁德康生物科技（深圳）有限公司 | A kind of nicotine salt and preparation method thereof |
| CN108887731A (en) * | 2018-08-21 | 2018-11-27 | 深圳瀚星翔科技有限公司 | Nicotine salt, electronics tobacco tar and preparation method thereof |
| CN109619655A (en) * | 2019-01-18 | 2019-04-16 | 深圳市同信兴投资有限公司 | A kind of compound nicotine salt and its solution, preparation method and application |
| CN109820250A (en) * | 2019-03-06 | 2019-05-31 | 云南巴菰生物科技有限公司 | A kind of non smoke type electronic cigarette |
Non-Patent Citations (1)
| Title |
|---|
| 沈羡云: "你真的了解电子烟吗？", 《百科知识》 * |
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| WO2021215496A1 (en) * | 2020-04-22 | 2021-10-28 | 日本たばこ産業株式会社 | Heat-not-burn tobacco product, electrically heated tobacco product, and heat-not-burn tobacco material |
| JP7414970B2 (en) | 2020-04-22 | 2024-01-16 | 日本たばこ産業株式会社 | Non-combustible heated tobacco, electrically heated tobacco products, and non-combustible heated tobacco materials |
| JPWO2021215496A1 (en) * | 2020-04-22 | 2021-10-28 | ||
| CN111393410A (en) * | 2020-04-30 | 2020-07-10 | 云南中烟工业有限责任公司 | Preparation method of nicotine-3, 5-dihydroxybenzoate and application of nicotine-3, 5-dihydroxybenzoate in electronic cigarette |
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