CN110339146A - A kind of W/O/W foundation emulsion and preparation method thereof - Google Patents
A kind of W/O/W foundation emulsion and preparation method thereof Download PDFInfo
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- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
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- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
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Abstract
The present invention provides a kind of W/O/W foundation emulsions and preparation method thereof.The W/O/W foundation emulsion contains: (1) the first water phase；(2) oily phase, wherein the titanium dioxide that the oleophylic of sorbitan sesquioleate, 3-10wt% containing 0.5-1.5wt% is handled；(3) second water phases, wherein the Phosphoric acid monohexadecyl ester potassium containing 1-2wt%.The foundation emulsion of the method for the present invention preparation, have the salubrious of oil-in-water foundation emulsion, Shui Run, easy makeup effect, have the moist moisturizing of Water-In-Oil foundation emulsion concurrently, adornment imitates the effect that docile lasting, the anti-sweat of waterproof is not easy de- adornment, it is cheap, convenient to use simultaneously, preparation method is simple, realizes preparation while being able to satisfy the purpose of the high-performance foundation emulsion of stemness, oiliness, Combination skin quality.
Description
Technical field
The present invention relates to cosmetic field, it is specifically related to a kind of W/O/W foundation emulsion and preparation method thereof.
Background technique
Foundation cream is to be applied to face, plays a kind of cosmetics of modification and covering.Specifically, foundation cream can be with opposite
Portion carries out the pigmentations such as colour of skin correction, texture amendment, the freckle on covering skin and chloasma, improves the harsh feeling of skin.
It can also scatter isolation ultraviolet, prevent damage of the excessive ultraviolet light to skin.
Existing foundation product is distinguished from product formula, there is full oil, oil-in-water (O/W), Water-In-Oil (W/O) three categories,
In full oil powder bottom covering it is most strong, but unit price is more expensive, and being not suitable for the consumption concept of ordinary consumer, person is few to gather around pump；Water
The sense of oil-in foundation cream skin is slim and graceful, water profit is docile, but non-watertight, is easy floating powder and takes off adornment.The anti-sweat of water-in-oil foundation waterproof is not easy
Floating powder takes off adornment, but skin sense is thick and heavy, and greasy, consumer experience sense is poor.Therefore, market exists and improves to foundation product
Demand.
A kind of W/O/W foundation cream has been made after the studying for a long period of time of this field in the present inventor, has skin
Sense is slim and graceful, water profit is docile, easily the anti-sweat of makeup, waterproof, be not easy the characteristics of floating powder takes off adornment, so as to complete the present invention.
Summary of the invention
The object of the present invention is to provide a kind of novel W/O/W foundation emulsion, have that skin sense is slim and graceful, water profit is docile, easily
The anti-sweat of makeup, waterproof is not easy the characteristics of floating powder takes off adornment, nourishing skin.
For the purpose for realizing foregoing invention, specific technical solution is as follows:
A kind of W/O/W foundation emulsion, contains:
(1) first water phase；
(2) oily phase, wherein the titanium dioxide that the oleophylic of sorbitan sesquioleate, 3-10wt% containing 0.5-1.5wt% is handled；
(3) second water phases, wherein the Phosphoric acid monohexadecyl ester potassium containing 1-2wt%.
In wherein some embodiments, the surface treating agent of the titanium dioxide of the oleophylic processing is triethoxy octyl silicon
Alkane.
In wherein some embodiments, the additive amount of sorbitan sesquioleate is 1wt%, at oleophylic in the oily phase
The additive amount of the titanium dioxide of reason is 3.5wt%.
In wherein some embodiments, the additive amount of Phosphoric acid monohexadecyl ester potassium is 1.5wt% in second water phase.
First water phase of the present invention can contain moisturizing ingredient.In wherein some embodiments, the moisturizing at
Divide and is made of propylene glycol, glycerol.
Oil of the present invention can also mutually contain film forming agent.In wherein some embodiments, the film forming agent is third
Olefin(e) acid (ester) class/polydimethylsiloxanecopolymer copolymer, the addition of the acrylic acid (ester) class/polydimethylsiloxanecopolymer copolymer
Amount is 0.5-2wt%.
Oil of the present invention can also mutually contain moisturizing grease.In wherein some embodiments, the moisturizing grease
Additive amount be 3-8wt%, the moisturizing grease can be by Parleam, isononyl isononanoate, five poly dimethyl silicon of ring
Oxygen alkane composition.
Second water phase of the present invention can contain suspension thickener.In wherein some embodiments, the suspension
The additive amount of thickener is 0.5-1wt%, and the suspension thickener can be xanthan gum.
W/O/W foundation emulsion of the present invention can also contain following component: pearl powder 0.1-5wt%, amber powder
0.1-5wt%。
The embodiment of the invention also provides the preparation methods of the W/O/W foundation emulsion, comprising the following steps:
(1) moisturizing grease, film forming agent, sorbitan sesquioleate stirring and dissolving is uniform, the titanium dioxide of oleophylic processing, glue is added
Body mill grinding 2-3 times, until pigment is completely dispersed uniformly, obtain oily phase；
(2) water of propylene glycol, glycerol, part is uniformly mixed, obtains the first water phase；
(3) under high velocity agitation, the first water phase is slowly dripped in oil inlet phase, high speed homogenization is to homogeneous latex emulsion after dripping off
Obtain water-in-oil emulsion；
(4) Phosphoric acid monohexadecyl ester potassium, suspension thickener and remaining water are mixed, it is equal is heated to 80-85 DEG C of homogenous disperse
It is even, insulated and stirred 10 minutes, obtain the second water phase；
(5) under high velocity agitation, water-in-oil emulsion made from step (3) is slowly dripped into the second water phase, until stir evenly,
Then preservative, essence are added, are uniformly mixed, W/O/W foundation emulsion can be obtained.
Compared with prior art, technical solution provided in an embodiment of the present invention has the benefit that
(1) present invention is a kind of multiple foundation emulsion of W/O/W (W/O/W) type, and condition needed for being formed is extremely harsh, firstly,
Selected W/O emulsifier sorbitan sesquioleate, the first water phase (W1) is wrapped in oily (O), forms W1/O lotion, drop
It is made of some inner aqueous phase drops that are small, being separated from each other, the non-polar end of emulsifier is located at oily phase, and polar end is located at interior water
Phase, under the titanium dioxide auxiliary of oleophylic processing, the interface W1/O forms stable interfacial film, and is stabilization W1/ uniformly, white
O lotion；Then, O/W emulsifier Phosphoric acid monohexadecyl ester potassium is selected, is made the second water phase (W2) with remaining water-soluble material, and
Under stirring rate (800-1500rpm/min) appropriate and proper temperature (75-80 DEG C), W1/O emulsified body is slowly added second
In water phase (W2), finally, carrying out homogeneous with homogeneous rate (500-1200rpm/min) appropriate, stable W1/O/W2 powder is made
Bottom liquid.From embodiment as it can be seen that titanium dioxide, Phosphoric acid monohexadecyl ester that sorbitan sesquioleate, oleophylic that the present invention selects are handled
The W/O/W foundation cream (embodiment 3 and sensory testing part) that potassium is made into has the salubrious of oil-in-water foundation emulsion, water moistens,
Easy makeup effect has the moist moisturizing of Water-In-Oil foundation emulsion concurrently, adornment imitates the effect that docile lasting, the anti-sweat of waterproof is not easy de- adornment.
(2) reasonably combined moisturizing ingredient and moisturizing grease, provide fabulous moist degree and makeup effect, texture are soft
Sliding slim and graceful docile, the moisturizing waterproof of Rinsing, adornment effect is lasting, and product has relatively high stability, in 25 DEG C, 48 DEG C, 5
DEG C, -15 DEG C of condition next months be not in oil slick and layering demulsifying phenomenon.
(3) foundation emulsion of the method for the present invention preparation, has the salubrious of oil-in-water foundation emulsion, Shui Run, easy makeup
Effect, have the moist moisturizing of Water-In-Oil foundation emulsion concurrently, adornment imitate it is docile persistently, the anti-sweat of waterproof be not easy the effect of de- adornment, simultaneously
Cheap, convenient to use, preparation method is simple, realizes preparation while being able to satisfy the high property of stemness, oiliness, Combination skin quality
The purpose of energy foundation emulsion.
Specific embodiment
The present invention is described in further details below by embodiment, these embodiments are only used to illustrate the present invention, and
It does not limit the scope of the invention.
Unless otherwise indicated, all percentage is all based on the total weight of W/O/W foundation emulsion of the present invention.Institute
These weight for relating to ingredients listed are all based on the content of active material, therefore do not include being possibly comprised in commercially available object
Carrier or by-product in matter.
Part material involved in the embodiment of the present invention is described as follows:
The sorbitan sesquioleate, it is big to may come from Britain's standing grain, trade name SP 83；
The Phosphoric acid monohexadecyl ester potassium may come from Dutch Royal DSM, trade name Amphisol K；
The Parleam, also known as synthesis saualane, may come from Japan and go out photochemistry, trade name
Polysynlane 2；
The isononyl isononanoate also known as silk oil, may come from Belgian Ou Lian, trade name ININ；
The film forming agent is diluted in ring five dimethyl silicone polymer by acrylic acid (ester) class/polydimethylsiloxanecopolymer copolymer
In solvent, Japanese SHIN-ETSU HANTOTAI, trade name KP 545 may come from；
The titanium dioxide may come from South Korea ENTOP, trade name TiO2 AS, carry out table through triethoxy octyl silane
Surface treatment, partial size is in 190-210nm；
The propylene glycol, may come from CSPC, and commodity product are PG；
The glycerol may come from Malaysia meaning Mu Li, trade name Glycerin；
The xanthan gum, may come from U.S. Si Bikai can, trade name Keltrol CG-T;
The methyl hydroxybenzoate may come from Switzerland's Clariant, trade name MPB；
The parahydroxyacet-ophenone may come from the fragrant of German moral, trade name Symsave H；
Embodiment 1
A kind of W/O/W foundation emulsion, the component containing following mass percentage: sorbitan sesquioleate 0.5%, spermaceti
Alcohol phosphate potassium 2%, Parleam 1%, isononyl isononanoate 3%, ring five dimethyl silicone polymer 1%, acrylic acid (ester) class/
Polydimethylsiloxanecopolymer copolymer 2%, the titanium dioxide 3% of water-proofing treatment, propylene glycol 5%, glycerol 1%, xanthan gum 1%, methyl hydroxybenzoate
0.05%, parahydroxyacet-ophenone 0.15%, glycerol caprylate 0.2%, decoyl hydroximic acid 0.2%, essence 0.1%, water surplus；Wherein institute
The surface treating agent of the titanium dioxide for the water-proofing treatment stated is triethoxy octyl silane.
The preparation method of W/O/W foundation emulsion described in the present embodiment, comprising the following steps:
(1) by Parleam, isononyl isononanoate, ring five dimethyl silicone polymer, acrylic acid (ester) class/poly dimethyl silicon
Siloxane copolymers, sorbitan sesquioleate stirring and dissolving are uniform, and the titanium dioxide of oleophylic processing is added, and colloid mill is ground 3 times, until
Pigment is completely dispersed uniformly, obtains oily phase；
(2) by propylene glycol, glycerol, 30% water be uniformly mixed, obtain the first water phase；
(3) under high velocity agitation, the first water phase is slowly dripped in oil inlet phase, high speed homogenization is to homogeneous latex emulsion after dripping off
Obtain water-in-oil emulsion；
(4) remaining water, Phosphoric acid monohexadecyl ester potassium, xanthan gum, methyl hydroxybenzoate, parahydroxyacet-ophenone are mixed, is heated to 85 DEG C
Homogenous disperse is uniform, insulated and stirred 10 minutes, obtains the second water phase；
(5) at stirring rate 800rpm/min and 80 DEG C of temperature, with the rate of 2-3g/min by Water-In-Oil made from step (3)
Lotion is slowly dripped into the second water phase, then carries out homogeneous with rate 500rpm/min, until stirring evenly, then by caprylic
Acid esters, decoyl hydroximic acid, essence are added, and are uniformly mixed, W/O/W foundation emulsion can be obtained.
30% water refers to the total weight based on water in the present embodiment step (2).If water additive amount is in formula
5kg, then the weight of 30% water is 1.5kg.The percentage of water involved in step (2) is also based on water in subsequent embodiment 2-5
Total weight.
Embodiment 2
A kind of W/O/W foundation emulsion, the component containing following mass percentage: sorbitan sesquioleate 1.5%, spermaceti
Alcohol phosphate potassium 1%, Parleam 3%, isononyl isononanoate 1%, ring five dimethyl silicone polymer 2%, acrylic acid (ester) class/
Polydimethylsiloxanecopolymer copolymer 0.5%, the titanium dioxide 10% of water-proofing treatment, propylene glycol 1%, glycerol 5%, xanthan gum 0.5%, oxybenzene
Methyl esters 0.05%, parahydroxyacet-ophenone 0.15%, glycerol caprylate 0.2%, decoyl hydroximic acid 0.2%, essence 0.1%, water surplus；Its
Described in water-proofing treatment titanium dioxide surface treating agent be triethoxy octyl silane.
The preparation method of W/O/W foundation emulsion described in the present embodiment, comprising the following steps:
(1) by Parleam, isononyl isononanoate, ring five dimethyl silicone polymer, acrylic acid (ester) class/poly dimethyl silicon
Siloxane copolymers, sorbitan sesquioleate stirring and dissolving are uniform, and the titanium dioxide of oleophylic processing is added, and colloid mill is ground 3 times, until
Pigment is completely dispersed uniformly, obtains oily phase；
(2) by propylene glycol, glycerol, 70% water be uniformly mixed, obtain the first water phase；
(3) under high velocity agitation, the first water phase is slowly dripped in oil inlet phase, high speed homogenization is to homogeneous latex emulsion after dripping off
Obtain water-in-oil emulsion；
(4) remaining water, Phosphoric acid monohexadecyl ester potassium, xanthan gum, methyl hydroxybenzoate, parahydroxyacet-ophenone are mixed, is heated to 80 DEG C
Homogenous disperse is uniform, insulated and stirred 10 minutes, obtains the second water phase；
(5) at stirring rate 1500rpm/min and 75 DEG C of temperature, oil made from step (3) is wrapped with the rate of 2-3g/min
Aqueous emulsion is slowly dripped into the second water phase, then carries out homogeneous with rate 1200rpm/min, until stir evenly, it then will be sweet
Oily caprylate, decoyl hydroximic acid, essence are added, and are uniformly mixed, W/O/W foundation emulsion can be obtained.
Embodiment 3
A kind of W/O/W foundation emulsion, the component containing following mass percentage: sorbitan sesquioleate 1%, cetanol
Phosphate potassium 1.5%, Parleam 2%, isononyl isononanoate 2%, ring five dimethyl silicone polymer 1.5%, acrylic acid (ester)
Class/polydimethylsiloxanecopolymer copolymer 1%, the titanium dioxide 3.5% of water-proofing treatment, propylene glycol 3%, glycerol 3%, xanthan gum 0.7%, hydroxyl
Benzene methyl 0.05%, parahydroxyacet-ophenone 0.15%, glycerol caprylate 0.2%, decoyl hydroximic acid 0.2%, essence 0.1%, water surplus；
Wherein the surface treating agent of the titanium dioxide of the water-proofing treatment is triethoxy octyl silane.
The preparation method of W/O/W foundation emulsion described in the present embodiment, comprising the following steps:
(1) by Parleam, isononyl isononanoate, ring five dimethyl silicone polymer, acrylic acid (ester) class/poly dimethyl silicon
Siloxane copolymers, sorbitan sesquioleate stirring and dissolving are uniform, and the titanium dioxide of oleophylic processing is added, and colloid mill is ground 3 times, until
Pigment is completely dispersed uniformly, obtains oily phase；
(2) by propylene glycol, glycerol, 40% water be uniformly mixed, obtain the first water phase；
(3) under high velocity agitation, the first water phase is slowly dripped in oil inlet phase, high speed homogenization is to homogeneous latex emulsion after dripping off
Obtain water-in-oil emulsion；
(4) remaining water, Phosphoric acid monohexadecyl ester potassium, xanthan gum, methyl hydroxybenzoate, parahydroxyacet-ophenone are mixed, is heated to 83 DEG C
Homogenous disperse is uniform, insulated and stirred 10 minutes, obtains the second water phase；
(5) at stirring rate 1300rpm/min and 78 DEG C of temperature, oil made from step (3) is wrapped with the rate of 2-3g/min
Aqueous emulsion is slowly dripped into the second water phase, then carries out homogeneous with rate 800rpm/min, until stirring evenly, then by glycerol
Caprylate, decoyl hydroximic acid, essence are added, and are uniformly mixed, W/O/W foundation emulsion can be obtained.
Embodiment 4
A kind of W/O/W foundation emulsion, the component containing following mass percentage: sorbitan sesquioleate 1%, cetanol
Phosphate potassium 1.5%, Parleam 2%, isononyl isononanoate 2%, ring five dimethyl silicone polymer 1.5%, acrylic acid (ester)
Class/polydimethylsiloxanecopolymer copolymer 1%, the titanium dioxide 3.5% of water-proofing treatment, propylene glycol 3%, glycerol 3%, xanthan gum 0.7%, hydroxyl
Benzene methyl 0.05%, parahydroxyacet-ophenone 0.15%, glycerol caprylate 0.2%, decoyl hydroximic acid 0.2%, essence 0.1%, pearl powder
0.5%, amber powder 2%, water surplus；Wherein the surface treating agent of the titanium dioxide of the water-proofing treatment is triethoxy octyl silicon
Alkane.
The preparation method of W/O/W foundation emulsion described in the present embodiment, comprising the following steps:
(1) by Parleam, isononyl isononanoate, ring five dimethyl silicone polymer, acrylic acid (ester) class/poly dimethyl silicon
Siloxane copolymers, sorbitan sesquioleate stirring and dissolving are uniform, and the titanium dioxide of oleophylic processing is added, and colloid mill is ground 3 times, until
Pigment is completely dispersed uniformly, obtains oily phase；
(2) by propylene glycol, glycerol, pearl powder, amber powder, 40% water be uniformly mixed, obtain the first water phase；
(3) under high velocity agitation, the first water phase is slowly dripped in oil inlet phase, high speed homogenization is to homogeneous latex emulsion after dripping off
Obtain water-in-oil emulsion；
(4) remaining water, Phosphoric acid monohexadecyl ester potassium, xanthan gum, methyl hydroxybenzoate, parahydroxyacet-ophenone are mixed, is heated to 83 DEG C
Homogenous disperse is uniform, insulated and stirred 10 minutes, obtains the second water phase；
(5) at stirring rate 1300rpm/min and 78 DEG C of temperature, oil made from step (3) is wrapped with the rate of 2-3g/min
Aqueous emulsion is slowly dripped into the second water phase, then carries out homogeneous with rate 800rpm/min, until stirring evenly, then by glycerol
Caprylate, decoyl hydroximic acid, essence are added, and are uniformly mixed, W/O/W foundation emulsion can be obtained.
Embodiment 5
A kind of W/O/W foundation emulsion, the component containing following mass percentage: sorbitan sesquioleate 1%, cetanol
Phosphate potassium 1.5%, Parleam 2%, isononyl isononanoate 2%, ring five dimethyl silicone polymer 1.5%, acrylic acid (ester)
Class/polydimethylsiloxanecopolymer copolymer 1%, the titanium dioxide 3.5% of water-proofing treatment, propylene glycol 3%, glycerol 3%, xanthan gum 0.7%, hydroxyl
Benzene methyl 0.05%, parahydroxyacet-ophenone 0.15%, glycerol caprylate 0.2%, decoyl hydroximic acid 0.2%, essence 0.1%, pearl powder
1%, amber powder 0.5%, water surplus；Wherein the surface treating agent of the titanium dioxide of the water-proofing treatment is triethoxy octyl silicon
Alkane.
Preparation method is the same as embodiment 4.
For the selection for investigating emulsifier of the present invention, spy is provided with comparative example 1-2.
HLB value is to measure the important indicator of emulsifier ability, and the HLB value of Phosphoric acid monohexadecyl ester potassium is about 10, sorb
The HLB value of smooth sesquioleate is about 3.7, and in order to compare, the present inventor spy is provided with comparative example 1 and comparative example 2,
Middle comparative example 1 with HLB value be about 3.8 glyceryl monostearate substitute sorbitan sesquioleate, comparative example 2 with HLB value about
Phosphoric acid monohexadecyl ester potassium is substituted for 10 sorbimacrogol oleate100 (polysorbate -81).
For the selection for investigating titanium dioxide of the present invention, spy is provided with comparative example 3.
For the selection for investigating pearl powder, amber powder of the present invention, spy is provided with comparative example 4.
Comparative example 1
A kind of W/O/W foundation emulsion, the component containing following mass percentage: glyceryl monostearate 1%, cetanol phosphorus
Acid esters potassium 1.5%, Parleam 2%, isononyl isononanoate 2%, ring five dimethyl silicone polymer 1.5%, acrylic acid (ester) class/
Polydimethylsiloxanecopolymer copolymer 1%, the titanium dioxide 3.5% of water-proofing treatment, propylene glycol 3%, glycerol 3%, xanthan gum 0.7%, oxybenzene first
Ester 0.05%, parahydroxyacet-ophenone 0.15%, glycerol caprylate 0.2%, decoyl hydroximic acid 0.2%, essence 0.1%, water surplus；Wherein
The surface treating agent of the titanium dioxide of the water-proofing treatment is triethoxy octyl silane.
Preparation method is the same as embodiment 3.
Comparative example 2
A kind of W/O/W foundation emulsion, the component containing following mass percentage: sorbitan sesquioleate 1%, sorbimacrogol oleate100
1.5%, Parleam 2%, isononyl isononanoate 2%, ring five dimethyl silicone polymer 1.5%, acrylic acid (ester) class/poly- diformazan
Radical siloxane copolymer 1 %, the titanium dioxide 3.5% of water-proofing treatment, propylene glycol 3%, glycerol 3%, xanthan gum 0.7%, methyl hydroxybenzoate
0.05%, parahydroxyacet-ophenone 0.15%, glycerol caprylate 0.2%, decoyl hydroximic acid 0.2%, essence 0.1%, water surplus；Wherein institute
The surface treating agent of the titanium dioxide for the water-proofing treatment stated is triethoxy octyl silane.
Preparation method is the same as embodiment 3.
Comparative example 3
A kind of W/O/W foundation emulsion, the component containing following mass percentage: sorbitan sesquioleate 1%, cetanol
Phosphate potassium 1.5%, Parleam 2%, isononyl isononanoate 2%, ring five dimethyl silicone polymer 1.5%, acrylic acid (ester)
Class/polydimethylsiloxanecopolymer copolymer 1%, the titanium dioxide 3.5% without surface treatment, propylene glycol 3%, glycerol 3%, xanthan gum 0.7%,
Methyl hydroxybenzoate 0.05%, parahydroxyacet-ophenone 0.15%, glycerol caprylate 0.2%, decoyl hydroximic acid 0.2%, essence 0.1%, more than water
Amount；Wherein the surface treating agent of the titanium dioxide of the water-proofing treatment is triethoxy octyl silane.
Preparation method is the same as embodiment 3.
Comparative example 4
A kind of W/O/W foundation emulsion, the component containing following mass percentage: sorbitan sesquioleate 1%, cetanol
Phosphate potassium 1.5%, Parleam 2%, isononyl isononanoate 2%, ring five dimethyl silicone polymer 1.5%, acrylic acid (ester)
Class/polydimethylsiloxanecopolymer copolymer 1%, the titanium dioxide 3.5% of water-proofing treatment, propylene glycol 3%, glycerol 3%, xanthan gum 0.7%, hydroxyl
Benzene methyl 0.05%, parahydroxyacet-ophenone 0.15%, glycerol caprylate 0.2%, decoyl hydroximic acid 0.2%, essence 0.1%, pearl powder
2%, water surplus；Wherein the surface treating agent of the titanium dioxide of the water-proofing treatment is triethoxy octyl silane.
Preparation method is the same as embodiment 4.
Comparative example 5
A kind of W/O/W foundation emulsion, the component containing following mass percentage: sorbitan sesquioleate 1%, cetanol
Phosphate potassium 1.5%, Parleam 2%, isononyl isononanoate 2%, ring five dimethyl silicone polymer 1.5%, acrylic acid (ester)
Class/polydimethylsiloxanecopolymer copolymer 1%, the titanium dioxide 3.5% of water-proofing treatment, propylene glycol 3%, glycerol 3%, xanthan gum 0.7%, hydroxyl
Benzene methyl 0.05%, parahydroxyacet-ophenone 0.15%, glycerol caprylate 0.2%, decoyl hydroximic acid 0.2%, essence 0.1%, amber powder
2%, water surplus；Wherein the surface treating agent of the titanium dioxide of the water-proofing treatment is triethoxy octyl silane.
Preparation method is the same as embodiment 4.
1, stability test
To W/O/W foundation emulsion obtained by embodiment 1-5 and comparative example 1-5 under the conditions of 25 DEG C, 48 DEG C, 5 DEG C, -15 DEG C
Carry out stability test, the time be one month, seen whether layering demulsification, oil slick, obviously it is thinning phenomena such as, to investigate stabilization
Implementations.
The results are shown in Table 1:
1 stability record sheet of table
Know that W/O/W foundation emulsion obtained by 1-5 of the embodiment of the present invention has good stability by upper table 1, in 25 DEG C, 48 DEG C, 5
DEG C, -15 DEG C of condition next months be not in oil slick and layering demulsifying phenomenon.And the comparison of emulsifier or titanium dioxide is substituted
Example 1-3 is then unstable.
2, sensory testing
Smearing test is carried out to sample made from embodiment 3 and commercially available oil-in-water foundation emulsion, Water-In-Oil foundation emulsion.Specific test
Method is to take 0.1g Material as the back of the hand, is looped with the middle finger and the third finger closed up and is applied to absorption, carefully experiences smearing process
In use feeling, and recorded such as the following table 2
Table 2 smears test recording table
As can be seen from Table 2, foundation emulsion obtained by the embodiment of the present invention, has the salubrious of oil-in-water foundation emulsion, Shui Run, easy makeup effect
Fruit has the moist moisturizing of Water-In-Oil foundation emulsion concurrently, adornment imitates the effect that docile lasting, the anti-sweat of waterproof is not easy de- adornment.
3, consumer tests
40 volunteers are convened to carry out the survey of skin coloration to W/O/W foundation emulsion obtained by embodiment 4-5 and comparative example 4-5
Examination.Wherein 40 women of healthy volunteer, average age 25.8 years old, the range of age between 24-28 years old, all subjects by
Examination area skin is divided into 4 groups without obvious scar, pigmentation without any exception.Continuous use product 1 month, every angel
With 1 time, usage amount 0.1g/ people.
Use tristimulus color analysis (Chromameter CR200, Minolta) purchased from Osaka, Japan, anthropological measuring
The cheek of subject uses the skin coloration after preceding and use in product.Each position is surveyed 3 times respectively, takes its average value.Entirely
Continuous mode carries out in good non-wound testing laboratory, temperature (20 ± 2) DEG C, relative humidity 40%~60%.
The arithmetic mean of instantaneous value of 3 parameters such as Chromameter CR200 L*, a*, b* is calculated separately after measurement, is tied
Fruit is as shown in table 3 below:
Wherein L* value becomes larger, then it represents that bleaches, a* value becomes larger, then it represents that partially red, b* value becomes larger, then it represents that partially yellow.
3 skin coloration of table tests table
As shown in Table 3, learn that W/O/W foundation emulsion of the present invention can be bright using colour of skin variation before and after foundation emulsion by test
It is aobvious to improve the colour of skin, whitening function is played, and pearl powder and amber powder use simultaneously, effect is more significant.
Taking the above-mentioned ideal embodiment according to the present invention as inspiration, through the above description, relevant staff is complete
Various changes and amendments can be carried out without departing from the scope of the technological thought of the present invention' entirely.The technology of this invention
Property range is not limited to the contents of the specification, it is necessary to which the technical scope thereof is determined according to the scope of the claim.
Claims (10)
1. a kind of W/O/W foundation emulsion, which is characterized in that contain:
(1) first water phase；
(2) oily phase, wherein the titanium dioxide that the oleophylic of sorbitan sesquioleate, 3-10wt% containing 0.5-1.5wt% is handled；
(3) second water phases, wherein the Phosphoric acid monohexadecyl ester potassium containing 1-2wt%.
2. W/O/W foundation emulsion according to claim 1, which is characterized in that the table of the titanium dioxide of the oleophylic processing
Surface treatment agent is triethoxy octyl silane.
3. W/O/W foundation emulsion according to claim 1, which is characterized in that the smooth sesquialter oil of sorb in the oily phase
The additive amount of acid esters is 1wt%, the additive amount of the titanium dioxide of oleophylic processing is 3.5wt%.
4. W/O/W foundation emulsion according to claim 1, which is characterized in that cetanol phosphorus in second water phase
The additive amount of acid esters potassium is 1.5wt%.
5. W/O/W foundation emulsion according to claim 1, which is characterized in that also contain moisturizer.
6. W/O/W foundation emulsion according to claim 1, which is characterized in that also contain film forming agent.
7. W/O/W foundation emulsion according to claim 1, which is characterized in that also contain moisturizing grease.
8. W/O/W foundation emulsion according to claim 1, which is characterized in that also contain suspension thickener.
9. W/O/W foundation emulsion according to claim 1, which is characterized in that also contain following component: pearl powder
0.1-5wt%, amber powder 0.1-5wt%.
10. a kind of preparation method of the W/O/W foundation emulsion as described in claim any one of 1-9, which is characterized in that including
Following steps:
(1) moisturizing grease, film forming agent, sorbitan sesquioleate stirring and dissolving is uniform, the titanium dioxide of oleophylic processing, glue is added
Body mill grinding 2-3 times, until pigment is completely dispersed uniformly, obtain oily phase；
(2) water of propylene glycol, glycerol, part is uniformly mixed, obtains the first water phase；
(3) under high velocity agitation, the first water phase is slowly dripped in oil inlet phase, high speed homogenization is to homogeneous latex emulsion after dripping off
Obtain water-in-oil emulsion；
(4) Phosphoric acid monohexadecyl ester potassium, suspension thickener and remaining water are mixed, it is equal is heated to 80-85 DEG C of homogenous disperse
It is even, insulated and stirred 10 minutes, obtain the second water phase；
(5) under high velocity agitation, water-in-oil emulsion made from step (3) is slowly dripped into the second water phase, until stir evenly,
Then preservative, essence are added, are uniformly mixed, W/O/W foundation emulsion can be obtained.
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| CN113940899A (en) * | 2021-09-29 | 2022-01-18 | 广州卓芬化妆品有限公司 | Waterproof foundation composition and preparation method thereof |
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