CN110339111B - Cleaning composition containing mineral hot spring - Google Patents

Cleaning composition containing mineral hot spring Download PDF

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CN110339111B
CN110339111B CN201910652985.9A CN201910652985A CN110339111B CN 110339111 B CN110339111 B CN 110339111B CN 201910652985 A CN201910652985 A CN 201910652985A CN 110339111 B CN110339111 B CN 110339111B
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sodium
extract
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cleaning composition
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CN110339111A (en
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王烯睿
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Yili Miyuequan Bio Tech Co ltd
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Yili Miyuequan Bio Tech Co ltd
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34Alcohols
    • A61K8/345Alcohols containing more than one hydroxy group
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/55Phosphorus compounds
    • A61K8/553Phospholipids, e.g. lecithin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86Polyethers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/965Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution of inanimate origin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • A61K8/9706Algae
    • A61K8/9711Phaeophycota or Phaeophyta [brown algae], e.g. Fucus
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • A61K8/9783Angiosperms [Magnoliophyta]
    • A61K8/9789Magnoliopsida [dicotyledons]
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • A61Q19/005Preparations for sensitive skin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • A61Q19/10Washing or bathing preparations
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/70Biological properties of the composition as a whole
    • A61K2800/72Hypo-allergenic

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Abstract

The invention discloses a cleaning composition containing mineral hot springs, which belongs to the technical field of daily chemicals and comprises the following raw materials in parts by weight: 0.04-0.06 part of chelating agent, 11-13 parts of C10-C14 alkyl alcohol polyether sulfate sodium, 2-4 parts of polyhydric alcohol, 9-11 parts of cocamidopropyl betaine, 0.9-1.1 parts of coconut monoethanolamide, 11-13 parts of potassium cocoyl glycinate, 3.5-4.5 parts of decyl glucoside, 0.1-0.3 part of pH regulator, 0.7-0.9 part of sodium chloride, 0.9-1.1 part of hydrogenated lecithin, 0.4-0.6 part of sodium benzoate, 0.4-0.6 part of phenoxyethanol and ethylhexyl glycerin composite bacteriostatic agent, 0.4-0.6 part of plant composite anti-allergic agent, 0.09-0.11 part of Cladosiphon okamuranus extract, 0.09-0.11 part of essence and 53-55 parts of water. The invention has the advantages of green and healthy, mild and no skin irritation, good dirt-removing power, small irritation to facial skin, good moisture retention, rich trace elements in hot spring water, and capability of permeating into skin to keep the skin healthy and active.

Description

Cleaning composition containing mineral hot spring
Technical Field
The invention belongs to the technical field of daily chemicals, and particularly relates to a cleaning composition containing mineral hot springs.
Background
With the continuous improvement of living standard of people, more and more pay attention to the cleaning of the face, the face cleaning emulsion is gradually accepted by people as a face cleaning agent at present, the face cleaning emulsion is a special face cleaning product for cleaning the skin, not only has good cleaning function, but also has certain nursing function, the decontamination mechanism is to utilize a surfactant to reduce the surface tension of dirt, and remove the dirt through the actions of wetting, dispersing, foaming, emulsifying and the like.
The facial cleanser, also called facial cleanser, is a cleaning product used for cleaning facial dirt such as sweat, dust, color cosmetics and the like. Compared with the soap for cleaning the face, the soap has less irritation to the skin, is easier to wash, and can clean the concave-convex position of the face. Generally, a facial cleanser is a liquid product composed of components such as an oil phase material, a water phase material, a surfactant, a moisturizer, a nutritional agent, and the like. The surfactant in the facial cleanser has the five effects of moistening, dispersing, foaming, decontaminating and emulsifying, and is the main active substance of the facial cleanser. In addition, according to the principle of similarity and compatibility, in the process of washing face, the oil-soluble lipid dirt and redundant grease on the face can be dissolved by the oil phase; the water-phase matter dissolves the water-soluble sweat stain on the face.
The face cleansing cream can be classified into foam type face cleansing cream: contains surfactant, and can be divided into multi-foam type and micro-foam type. The cleaning effect is achieved through the emulsifying capacity of the surfactant to the grease; solvent-based facial cleanser: the oily dirt is removed by the dissolving capacity of oil and oil, and the oily dirt is mainly used for removing the oily dirt, so that the oily dirt is generally some cleansing oil, cleansing cream and the like; non-foaming facial cleanser: not only uses a proper amount of oil but also contains partial surfactant; collagen type facial cleanser: the formula without soap base is adopted, so that the facial mask is mild and comfortable, and can effectively remove facial cutin and dirt including melanin, and the skin can be restored to be transparent and fresh. The nanometer collagen component in the product rapidly permeates into skin, promotes skin metabolism, and simultaneously adds a layer of protective barrier for the face, prevents the loss of moisture of the facial epidermis and the massive permeation of external pollutants, thereby protecting delicate skin from being attacked by harmful factors.
At present, the face cleansing emulsion has various types, and can be divided into two types of soap-based type and non-soap-based type according to the structure of the product, wherein the soap-based type contains fatty acid soap components, has rich foam and is easy to wash, but has larger irritation, facial skin can generate tight feeling after being used, facial sebum membrane can be damaged after long-term use, the facial skin is sensitive and easily damaged by the outside, and the non-soap-based type product is used for cleaning the face, so that the face cleansing emulsion has greasy feeling after being washed, has poor cleansing capability and is difficult to wash; therefore, there is a need to develop a cleansing composition having excellent detergency, less irritation to the facial skin and good moisturizing properties.
Disclosure of Invention
In order to solve the above problems, the present invention provides a cleaning composition comprising a mineral hot spring.
In order to achieve the purpose, the invention provides the following technical scheme:
a cleaning composition containing mineral hot springs comprises the following raw materials in parts by weight: 0.04-0.06 part of chelating agent, 11-13 parts of C10-C14 alkyl alcohol polyether sulfate sodium, 2-4 parts of polyhydric alcohol, 9-11 parts of cocamidopropyl betaine, 0.9-1.1 parts of coconut monoethanolamide, 11-13 parts of potassium cocoyl glycinate, 3.5-4.5 parts of decyl glucoside, 0.1-0.3 part of pH regulator, 0.7-0.9 part of sodium chloride, 0.9-1.1 part of hydrogenated lecithin, 0.4-0.6 part of sodium benzoate, 0.4-0.6 part of phenoxyethanol and ethylhexyl glycerin composite bacteriostatic agent, 0.4-0.6 part of plant composite anti-allergic agent, 0.09-0.11 part of Cladosiphon okamuranus extract, 0.09-0.11 part of essence and 53-55 parts of water.
Preferably, the pH adjusting agent is citric acid.
Preferably, the sodium alkyl alcohol polyether sulfate with C10-C14 is sodium lauryl polyether sulfate.
Preferably, the weight ratio of the C10-C14 alkyl alcohol polyether sulfate sodium to the cocamidopropyl betaine to the decyl glucoside is (11-13): (9-11): 4.
preferably, the chelating agent is disodium EDTA.
Preferably, the polyhydric alcohol is at least one of glycerol, 1, 3-butanediol and dipropylene glycol.
Preferably, the water is thermal spring water.
Preferably, the weight ratio of the cladosporium asteroides extract to the sodium chloride is 1: (0.7-0.9).
Preferably, the essence is at least one of lemon essence, mint essence, litchi essence, strawberry essence, medlar essence, rose essence, banana essence, juicy peach essence and passion flower essence.
Preferably, the plant composite anti-allergy agent comprises the following raw materials: centella asiatica (CENTELLA ASIATICA) extract, rhizoma Polygoni Cuspidati (Polygonum CUSPIDATUM) root extract, radix Scutellariae (Scutellaria BAICALENSIS) root extract, folium Camelliae sinensis (CAMELLIA SINENSIS) extract, radix Glycytthizae (Glycyrrhiza GLABRA) root extract, flos Matricariae Chamomillae (Chamomilla RECUTITA) flower extract, and herba Rosmarini OFFICINALIS (Rosmarinus OFFICINALIS) leaf extract.
The preparation method of the cleaning composition containing the mineral hot spring comprises the following steps:
(1) adding chelating agent into water, adding C10-C14 alkyl alcohol polyether sodium sulfate, stirring and heating to 75-85 ℃;
(2) sequentially adding polyalcohol, cocamidopropyl betaine, coconut monoethanolamide, potassium cocoyl glycinate and decyl glucoside, and stirring to be uniform;
(3) Cooling to 55-65 deg.C, sequentially adding pH regulator and sodium chloride, and stirring to dissolve;
(4) cooling to 35-45 deg.C, sequentially adding hydrogenated lecithin, sodium benzoate, phenoxyethanol and ethylhexylglycerin composite bacteriostatic agent, plant composite anti-allergic agent, Cladosiphon okamuranus Dunn extract, and essence, stirring, filtering with 50-150 mesh filter cloth, and discharging.
A facial cleanser containing mineral hot spring comprises the above cleaning composition containing mineral hot spring.
Has the advantages that: the cleaning composition containing mineral hot springs has the advantages of being green, healthy, mild and non-irritating to skin and the like, can moisturize the skin while cleaning the skin, adopts the amino acid surfactant, is mild and non-irritating to the skin, has good dirt removal capacity, small irritation to the facial skin and good moisture retention, adopts hot spring water as a solvent system, can permeate into the skin to keep the skin healthy and active due to the fact that the hot spring water is rich in multiple trace elements, and can effectively clean the skin, remove dirt on the epidermis, help repair sensitive and damaged skin and achieve the effects of moisturizing, nourishing and moistening the skin by multiple natural extracts.
Detailed Description
The technical features of the technical solutions provided by the present invention are further clearly and completely described below with reference to the specific embodiments, and the scope of protection is not limited thereto.
The words "preferred", "further preferred", and the like, in the context of this invention, refer to embodiments of the invention that may, in some circumstances, provide some benefit. However, other embodiments may be preferred, under the same or other circumstances. Furthermore, the recitation of one or more preferred embodiments does not imply that other embodiments are not useful, nor is it intended to exclude other embodiments from the scope of the invention.
When a range of values is disclosed herein, the range is considered to be continuous and includes both the minimum and maximum values of the range, as well as each value between such minimum and maximum values. Further, when a range refers to an integer, each integer between the minimum and maximum values of the range is included. Further, when multiple range-describing features or characteristics are provided, the ranges may be combined. In other words, unless otherwise indicated, all ranges disclosed herein are to be understood to encompass any and all subranges subsumed therein. For example, a stated range from "1 to 10" should be considered to include any and all subranges between the minimum value of 1 and the maximum value of 10. Exemplary subranges of the range 1 to 10 include, but are not limited to, 1 to 6.1, 3.5 to 7.8, 5.5 to 10, and the like.
A cleaning composition containing mineral hot springs comprises the following raw materials in parts by weight: 0.04-0.06 part of chelating agent, 11-13 parts of C10-C14 alkyl alcohol polyether sulfate sodium, 2-4 parts of polyhydric alcohol, 9-11 parts of cocamidopropyl betaine, 0.9-1.1 parts of coconut monoethanolamide, 11-13 parts of potassium cocoyl glycinate, 3.5-4.5 parts of decyl glucoside, 0.1-0.3 part of pH regulator, 0.7-0.9 part of sodium chloride, 0.9-1.1 part of hydrogenated lecithin, 0.4-0.6 part of sodium benzoate, 0.4-0.6 part of phenoxyethanol and ethylhexyl glycerin composite bacteriostatic agent, 0.4-0.6 part of plant composite anti-allergic agent, 0.09-0.11 part of Cladosiphon okamuranus extract, 0.09-0.11 part of essence and 53-55 parts of water.
In one embodiment, the weight ratio of the sodium C10-C14 alkyl alcohol polyether sulfate, cocamidopropyl betaine, decyl glucoside is (11-13): (9-11): (3.5-4.5).
In one embodiment, the weight ratio of the sodium C10-C14 alkyl alcohol polyether sulfate, cocamidopropyl betaine, and decyl glucoside is (11-13): (9-11): 4.
in one embodiment, the weight ratio of the sodium C10-C14 alkyl alcohol polyether sulfate, cocamidopropyl betaine, decyl glucoside is 12: 10: 4.
In one embodiment, the mineral hot spring-containing cleaning composition comprises the following raw materials in parts by weight: 0.05 part of chelating agent, 12 parts of C10-C14 alkyl alcohol polyether sodium sulfate, 3 parts of polyhydric alcohol, 10 parts of cocamidopropyl betaine, 1 part of coconut monoethanolamide, 12 parts of cocoyl glycine potassium, 4 parts of decyl glucoside, 0.2 part of pH regulator, 0.8 part of sodium chloride, 1 part of hydrogenated lecithin, 0.5 part of sodium benzoate, 0.5 part of phenoxyethanol and ethylhexyl glycerol composite bacteriostatic agent, 0.5 part of plant composite anti-sensitivity agent, 0.1 part of cladosporium asteroides aitchirei extract, 0.1 part of essence and 54.25 parts of water.
Hydrogenated lecithin
Hydrogenated lecithin, which is a partial hydrolysate of lecithin, has improved hydrophilic ability, can promote absorption, reduce skin irritation, and can be used as moisturizer and emulsifier in cosmetics.
In one embodiment, the pH adjusting agent is citric acid.
In one embodiment, the sodium C10-C14 alkyl alcohol polyether sulfate is sodium laureth sulfate.
The inventor adopts an amino acid surfactant which is mild and non-irritating to the skin and has better cleaning power, and in order to further improve the foaming performance of a system, the inventor adds decyl glucoside to be compounded with the amino acid surfactant, but the foaming performance is improved by increasing the amount of the decyl glucoside, but the skin irritation is increased at the same time, and the inventor finds that when the amino acid surfactant is compounded with sodium laureth sulfate, cocamidopropyl betaine and decyl glucoside, the weight ratio is (11-13): (9-11): (3.5-4.5) the cleansing power was improved while the foamability was excellent, and the inventors speculated that it is possible that the addition of decyl glucoside, together with sodium laureth sulfate and cocamidopropyl betaine, caused intermolecular association by hydrogen bonding on the one hand, and caused the different surfactants to be closely arranged due to attraction between positive and negative ions; on the other hand, as the hydrophobic carbon chains of the three are different, the gaps among the polar heads are further reduced through synergistic interaction, the gas is not easy to diffuse, the foam is more stable, the chaos is increased, and the micelle is easier to form. In addition, the content of decyl glucoside is controlled to be about 4 under the action, so that the formed micelle volume is increased, the micelle cannot penetrate into an epidermal layer, and the skin irritation effect is weakened.
In one embodiment, the chelating agent is disodium EDTA.
In one embodiment, the polyol is at least one of glycerol, 1, 3-butanediol, dipropylene glycol.
In one embodiment, the water is thermal spring water.
In one embodiment, the weight ratio of cladosporium asteroides extract to sodium chloride is (0.9-1.1): (0.7-0.9).
In one embodiment, the weight ratio of cladosporium asteroides extract to sodium chloride is 1: (0.7-0.9).
In one embodiment, the weight ratio of cladosporium asteroides extract to sodium chloride is 1: 0.8.
the cladosporium asteroides extract adopted in the invention is rich in various minerals, vitamins, amino acids and other effective components, can deeply repair damaged skin, and in order to improve system viscosity, sodium chloride is added by the inventor to be mainly used as a thickening agent and act with a surfactant, so that the association number is increased.
The inventor finds that hot spring water is adopted as the solvent system of the invention in the research process, because the hot spring water is rich in a plurality of trace elements and can permeate into skin to keep the skin healthy and active, but a large amount of alkali metals in the hot spring water easily react with the surfactant of the invention to inactivate, the action is difficult to control, and the trace elements easily induce the oxidative polymerization or recombination of effective components in the extract of the plant composite anti-allergy agent to change the color and the stability of the system, so that the sodium chloride is required to be controlled within the scope of the invention, a chelating agent is added to coordinate a large amount of alkali metals, the addition of the cladosporium asteroides extract can obviously improve the phenomenon, the inventor thinks that the cladosporium asteroides extract can form a stable chemical structure with the trace elements through coordination and complexation, and avoids the stability reduction caused by the adverse effect generated by the cladosporium extract and the plant composite anti-allergy agent after being placed for a long time, the skin allergy condition protects the physicochemical properties of the trace elements, is convenient for the skin to fully absorb and utilize the trace elements, and ensures that the system is maintained stable.
The inventor unexpectedly found that when the weight ratio of the cladosporium asteroides extract to the sodium chloride is (0.9-1.1): (0.7-0.9) the viscosity increases due to the increase in system stability, and the inventors speculate that alginic acid in the extract has a certain thickening and emulsifying effect due to the cationic crosslinking with sodium chloride. In addition, the mixed micelle of the surfactant and the components are further crosslinked to form a sol system together with the hydrogenated lecithin, so that the foam can be stabilized. In the cleaning process, the Cladosiphon starwort extract and the effective components of the plant composite anti-allergy agent are gradually released from the periphery of the micelle and permeate into the skin to play the effects of moisturizing, relieving and calming.
In one embodiment, the essence is at least one of lemon essence, mint essence, litchi essence, strawberry essence, medlar essence, rose essence, banana essence, juicy peach essence, and passion flower essence.
Composite plant anti-allergic agent
The plant composite anti-allergy agent is a multi-herb anti-allergy agent consisting of various plants, and has the effects of relieving allergy, diminishing inflammation, resisting oxidation, resisting aging, preserving moisture and whitening. The centella asiatica extract can enhance the efficacy of ultraviolet protection and skin whitening, repair and relieve allergic skin, resist oxidation and accelerate wound healing. The rhizoma Polygoni Cuspidati extract contains resveratrol bioactive substances, has good antioxidant activity, and can inhibit melanin formation and whiten skin. The scutellaria baicalensis extract has obvious antioxidant, anti-allergy and antibacterial effects, and can also brighten skin color. The tea extract contains tea polyphenols, caffeine, etc., and has tranquilizing, skin whitening, antiinflammatory, and antiaging effects. The glycyrrhiza glabra extract is a raw material widely used in the world, and has the effects of whitening, relieving the skin, resisting inflammation, sterilizing and the like. The chamomile flower extract has obvious antioxidant capacity, enhances the moisturizing capacity of skin, prevents skin dryness and delays senility. The rosemary extract contains various anti-allergy, soothing and antioxidant components, promotes the recovery of skin vitality, keeps the skin luster and elasticity, and is widely applied to sensitive skin.
In one embodiment, the plant composite anti-allergy agent comprises the following raw materials: centella asiatica (CENTELLA ASIATICA) extract, POLYGONUM CUSPIDATUM (Polygonum CUSPIDATUM) root extract, SCUTELLARIA BAICALENSIS (Scutellaria BAICALENSIS) root extract, Camellia sinensis (CAMELLIA SINENSIS) leaf extract, Glycyrrhiza GLABRA (Glycyrrhiza GLABRA) root extract, Chamomilla RECUTITA (Chamomilla RECUTITA) flower extract, and Rosmarinus OFFICINALIS (Rosmarinus OFFICINALIS) leaf extract. Commercially available products such as those manufactured by chemical technology ltd in the last oceangoing areas can be used: calmyang plant composite anti-allergy agent.
In one embodiment, the above mineral hot spring-containing cleaning composition is prepared by a method comprising the steps of:
(1) adding chelating agent into water, adding C10-C14 alkyl alcohol polyether sodium sulfate, stirring and heating to 75-85 ℃;
(2) sequentially adding polyalcohol, cocamidopropyl betaine, coconut monoethanolamide, potassium cocoyl glycinate and decyl glucoside, and stirring to be uniform;
(3) cooling to 55-65 deg.C, sequentially adding pH regulator and sodium chloride, and stirring to dissolve;
(4) cooling to 35-45 deg.C, sequentially adding hydrogenated lecithin, sodium benzoate, phenoxyethanol and ethylhexylglycerin composite bacteriostatic agent, plant composite anti-allergic agent, Cladosiphon okamuranus Dunn extract, and essence, stirring, filtering with 50-150 mesh filter cloth, and discharging.
In one embodiment, the mineral hot spring containing facial cleanser comprises the mineral hot spring containing cleaning composition.
In one embodiment, the mineral hot spring-containing cleanser has a mineral hot spring-containing cleansing composition in an amount of 80 to 100 wt%.
The present invention will now be described in detail by way of examples, and the starting materials used are commercially available unless otherwise specified.
In the examples, sodium laureth sulfate was supplied by Shanghai Di Ke Fine chemical Co., Ltd, type: AES-70.
In the examples, disodium EDTA was supplied by Shanghai Dike Fine chemical Co., Ltd.
In the examples, coconut monoethanolamide, provided by german chemical company, inc, at sea, type: CMEA.
Examples cocamidopropyl betaine, supplied by seidel chemical company ltd, supra, type: CAB-35.
Decyl glucoside in the examples was supplied by Shanghai Saifu chemical development Co., Ltd.
Examples hydrogenated lecithin, supplied by Shanghai Dry fly chemical Co., Ltd, was obtained in the following manner: e-20.
In the examples, the phenoxyethanol and ethylhexyl glycerin composite bacteriostatic agent is provided by the Shanghai Germany chemical industry Co., Ltd, and the model is as follows: PE 9010.
The plant composite anti-allergic agent in the embodiment is provided by Shanghai Zhou chemical technology Co., Ltd, and has the following model: calmyang, main ingredients: centella asiatica (CENTELLA ASIATICA) extract, rhizoma Polygoni Cuspidati (Polygonum CUSPIDATUM) root extract, radix Scutellariae (Scutellaria BAICALENSIS) root extract, folium Camelliae sinensis (CAMELLIA SINENSIS) extract, radix Glycytthizae (Glycyrrhiza GLABRA) root extract, flos Matricariae Chamomillae (Chamomilla RECUTITA) flower extract, and herba Rosmarini OFFICINALIS (Rosmarinus OFFICINALIS) leaf extract.
The water source of the thermal spring water in the embodiment is a Buboo ditch in Nile county, wherein K+The content of Na is 0.97mg/L+The content of Ca is 0.97mg/L2+The content of Mg is 0.97Mg/L2+The content of Al is 0.97mg/L3+The content of NH is 0.97mg/L4+The content of Mg is 0.97Mg/L3+0.97mg/L, 0.069mg/L lithium, 0.041mg/L strontium, less than 0.002mg/L zinc, less than 0.001mg/L selenium, less than 0.010mg/L copper, 0.003mg/L arsenic, less than 0.0001mg/L mercury, less than 0.002mg/L cadmium, less than 0.010mg/L iron, less than 0.001mg/L lead, less than 0.006mg/L cobalt, less than 0.006mg/L vanadium, less than 0.006mg/L molybdenum, less than 0.044mg/L manganese, less than 0.001mg/L nickel, less than 0.008mg/L nickel, soluble solid 174.8mg/L of metasilicic acid, 50.88mg/L of HCO3 -The content is 24.47mg/L, CO3 2-The content of SO is 15.04mg/L4 2-The content is 37.97mg/L, F-The content is 7.62mg/L, NO3 -The content is 0.38 mg/L.
In the examples, the Cladosiphon okamuranus extract was provided by Shanghai Xi Engineers, Inc. in type: l-1.
In the examples, lemon essence is provided by Yunya spices, Inc., flower in Jiangmen.
Examples
Example 1
The mineral hot spring-containing cleaning composition comprises the following raw materials in parts by weight: 0.05 part of chelating agent, 12 parts of C10-C14 alkyl alcohol polyether sodium sulfate, 3 parts of polyhydric alcohol, 10 parts of cocamidopropyl betaine, 1 part of coconut monoethanolamide, 12 parts of cocoyl glycine potassium, 4 parts of decyl glucoside, 0.2 part of pH regulator, 0.8 part of sodium chloride, 1 part of hydrogenated lecithin, 0.5 part of sodium benzoate, 0.5 part of phenoxyethanol and ethylhexyl glycerol composite bacteriostatic agent, 0.5 part of plant composite anti-sensitivity agent, 0.1 part of cladosporium asteroides aitchirei extract, 0.1 part of essence and 54.25 parts of water.
The pH regulator is citric acid.
The C10-C14 sodium alkyl alcohol polyether sulfate is sodium lauryl polyether sulfate.
The chelating agent is disodium EDTA.
The polyol is glycerol.
The water is thermal spring water.
The essence is lemon essence.
The preparation method of the mineral hot spring-containing cleaning composition comprises the following steps:
(1) adding EDTA disodium into water, adding C10-C14 sodium alkyl alcohol polyether sulfate, stirring and heating to 80 ℃;
(2) sequentially adding polyalcohol, cocamidopropyl betaine, coconut monoethanolamide, potassium cocoyl glycinate and decyl glucoside, and stirring to be uniform;
(3) cooling to 60 ℃, sequentially adding a pH regulator and sodium chloride, and stirring until the pH regulator and the sodium chloride are dissolved uniformly;
(4) cooling to 40 deg.C, sequentially adding hydrogenated lecithin, sodium benzoate, phenoxyethanol and ethylhexylglycerin composite bacteriostatic agent, plant composite anti-allergic agent, Cladosiphon okamuranus Dunn extract, and essence, stirring, filtering with 100 mesh filter cloth, and discharging.
The rotating speed of the stirring is 150 r/min.
Example 2
The mineral hot spring-containing cleaning composition comprises the following raw materials in parts by weight: 0.04 part of chelating agent, 11 parts of C10-C14 alkyl alcohol polyether sodium sulfate, 2 parts of polyhydric alcohol, 9 parts of cocamidopropyl betaine, 0.9 part of coconut monoethanolamide, 11 parts of cocoyl glycine potassium, 3.5 parts of decyl glucoside, 0.1 part of pH regulator, 0.7 part of sodium chloride, 0.9 part of hydrogenated lecithin, 0.4 part of sodium benzoate, 0.4 part of phenoxyethanol and ethylhexyl glycerol composite bacteriostatic agent, 0.4 part of plant composite anti-sensitivity agent, 0.09 part of cladosporium asteroides aitchisonii extract, 0.09 part of essence and 53 parts of water.
The pH regulator is citric acid.
The C10-C14 sodium alkyl alcohol polyether sulfate is sodium lauryl polyether sulfate.
The chelating agent is disodium EDTA.
The polyol is glycerol.
The water is thermal spring water.
The essence is lemon essence.
The preparation method of the cleaning composition containing the mineral hot spring comprises the following steps:
(1) adding EDTA disodium into water, adding C10-C14 sodium alkyl alcohol polyether sulfate, stirring and heating to 80 ℃;
(2) sequentially adding polyalcohol, cocamidopropyl betaine, coconut monoethanolamide, potassium cocoyl glycinate and decyl glucoside, and stirring to be uniform;
(3) cooling to 60 ℃, sequentially adding a pH regulator and sodium chloride, and stirring until the pH regulator and the sodium chloride are dissolved uniformly;
(4) cooling to 40 deg.C, sequentially adding hydrogenated lecithin, sodium benzoate, phenoxyethanol and ethylhexylglycerin composite bacteriostatic agent, plant composite anti-allergic agent, Cladosiphon okamuranus Dunn extract, and essence, stirring, filtering with 100 mesh filter cloth, and discharging.
The rotating speed of the stirring is 150 r/min.
Example 3
The mineral hot spring-containing cleaning composition comprises the following raw materials in parts by weight: 0.06 part of chelating agent, 13 parts of C10-C14 alkyl alcohol polyether sodium sulfate, 4 parts of polyhydric alcohol, 11 parts of cocamidopropyl betaine, 1.1 parts of cocamidoethanol amide, 13 parts of cocoyl glycine potassium, 4.5 parts of decyl glucoside, 0.3 part of pH regulator, 0.9 part of sodium chloride, 1.1 parts of hydrogenated lecithin, 0.6 part of sodium benzoate, 0.6 part of phenoxyethanol and ethylhexyl glycerin composite bacteriostatic agent, 0.6 part of plant composite anti-sensitivity agent, 0.11 part of cladosporium asteroides aitchisonii extract, 0.11 part of essence and 55 parts of water.
The pH regulator is citric acid.
The C10-C14 sodium alkyl alcohol polyether sulfate is sodium lauryl polyether sulfate.
The chelating agent is disodium EDTA.
The polyol is glycerol.
The water is thermal spring water.
The essence is lemon essence.
The preparation method of the cleaning composition containing the mineral hot spring comprises the following steps:
(1) adding EDTA disodium into water, adding C10-C14 sodium alkyl alcohol polyether sulfate, stirring and heating to 80 ℃;
(2) sequentially adding polyalcohol, cocamidopropyl betaine, coconut monoethanolamide, potassium cocoyl glycinate and decyl glucoside, and stirring to be uniform;
(3) cooling to 60 ℃, sequentially adding a pH regulator and sodium chloride, and stirring until the pH regulator and the sodium chloride are dissolved uniformly;
(4) cooling to 40 deg.C, sequentially adding hydrogenated lecithin, sodium benzoate, phenoxyethanol and ethylhexylglycerin composite bacteriostatic agent, plant composite anti-allergic agent, Cladosiphon okamuranus Dunn extract, and essence, stirring, filtering with 100 mesh filter cloth, and discharging.
The rotating speed of the stirring is 150 r/min.
Comparative example 1
The mineral hot spring-containing cleaning composition comprises the following raw materials in parts by weight: 0.05 part of chelating agent, 12 parts of C10-C14 alkyl alcohol polyether sodium sulfate, 3 parts of polyhydric alcohol, 10 parts of cocamidopropyl betaine, 1 part of coconut monoethanolamide, 12 parts of cocoyl glycine potassium, 4 parts of decyl glucoside, 0.2 part of pH regulator, 0.8 part of sodium chloride, 1 part of hydrogenated lecithin, 0.5 part of sodium benzoate, 0.5 part of phenoxyethanol and ethylhexyl glycerol composite bacteriostatic agent, 0.5 part of plant composite anti-sensitivity agent, 0.1 part of cladosporium asteroides aitchirei extract, 0.1 part of essence and 54.25 parts of water.
The pH regulator is citric acid.
The sodium alkyl alcohol polyether sulfate C10-C14 is sodium lauryl polyether sulfate.
The chelating agent is disodium EDTA.
The polyol is glycerol.
The water is common pure water.
The essence is lemon essence.
The preparation method of the cleaning composition containing the mineral hot spring comprises the following steps:
(1) adding EDTA disodium into water, adding C10-C14 sodium alkyl alcohol polyether sulfate, stirring and heating to 80 ℃;
(2) sequentially adding polyalcohol, cocamidopropyl betaine, coconut monoethanolamide, potassium cocoyl glycinate and decyl glucoside, and stirring to be uniform;
(3) cooling to 60 ℃, sequentially adding a pH regulator and sodium chloride, and stirring until the pH regulator and the sodium chloride are dissolved uniformly;
(4) cooling to 40 deg.C, sequentially adding hydrogenated lecithin, sodium benzoate, phenoxyethanol and ethylhexylglycerin composite bacteriostatic agent, plant composite anti-allergic agent, Cladosiphon okamuranus Dunn extract, and essence, stirring, filtering with 100 mesh filter cloth, and discharging.
The rotating speed of the stirring is 150 r/min.
Comparative example 2
The mineral hot spring-containing cleaning composition comprises the following raw materials in parts by weight: 0.05 part of chelating agent, 12 parts of C10-C14 alkyl alcohol polyether sodium sulfate, 3 parts of polyhydric alcohol, 10 parts of cocamidopropyl betaine, 1 part of coconut monoethanolamide, 12 parts of cocoyl glycine potassium, 2 parts of decyl glucoside, 0.2 part of pH regulator, 0.8 part of sodium chloride, 1 part of hydrogenated lecithin, 0.5 part of sodium benzoate, 0.5 part of phenoxyethanol and ethylhexyl glycerol composite bacteriostatic agent, 0.5 part of plant composite anti-sensitivity agent, 0.1 part of cladosporium asteroides aitchirei extract, 0.1 part of essence and 56.25 parts of water.
The pH regulator is citric acid.
The sodium alkyl alcohol polyether sulfate C10-C14 is sodium lauryl polyether sulfate.
The chelating agent is disodium EDTA.
The polyol is glycerol.
The water is thermal spring water.
The essence is lemon essence.
The preparation method of the cleaning composition containing the mineral hot spring comprises the following steps:
(1) adding EDTA disodium into water, adding C10-C14 sodium alkyl alcohol polyether sulfate, stirring and heating to 80 ℃;
(2) sequentially adding polyalcohol, cocamidopropyl betaine, coconut monoethanolamide, potassium cocoyl glycinate and decyl glucoside, and stirring to be uniform;
(3) cooling to 60 ℃, sequentially adding a pH regulator and sodium chloride, and stirring until the pH regulator and the sodium chloride are dissolved uniformly;
(4) cooling to 40 deg.C, sequentially adding hydrogenated lecithin, sodium benzoate, phenoxyethanol and ethylhexylglycerin composite bacteriostatic agent, plant composite anti-allergic agent, Cladosiphon okamuranus Dunn extract, and essence, stirring, filtering with 100 mesh filter cloth, and discharging.
The rotating speed of the stirring is 150 r/min.
Comparative example 3
The mineral hot spring-containing cleaning composition comprises the following raw materials in parts by weight: 0.05 part of chelating agent, 12 parts of C10-C14 sodium alkyl alcohol polyether sulfate, 3 parts of polyhydric alcohol, 10 parts of cocamidopropyl betaine, 1 part of cocamidoethanol amide, 12 parts of potassium cocoyl glycinate, 6 parts of decyl glucoside, 0.2 part of pH regulator, 0.8 part of sodium chloride, 1 part of hydrogenated lecithin, 0.5 part of sodium benzoate, 0.5 part of phenoxyethanol and ethylhexyl glycerol composite bacteriostatic agent, 0.5 part of plant composite anti-sensitivity agent, 0.1 part of cladosporium fortunei extract, 0.1 part of essence and 52.25 parts of water.
The pH regulator is citric acid.
The sodium alkyl alcohol polyether sulfate C10-C14 is sodium lauryl polyether sulfate.
The chelating agent is disodium EDTA.
The polyol is glycerol.
The water is thermal spring water.
The essence is lemon essence.
The preparation method of the cleaning composition containing the mineral hot spring comprises the following steps:
(1) adding EDTA disodium into water, adding C10-C14 sodium alkyl alcohol polyether sulfate, stirring and heating to 80 ℃;
(2) sequentially adding polyalcohol, cocamidopropyl betaine, coconut monoethanolamide, potassium cocoyl glycinate and decyl glucoside, and stirring to be uniform;
(3) cooling to 60 ℃, sequentially adding a pH regulator and sodium chloride, and stirring until the pH regulator and the sodium chloride are dissolved uniformly;
(4) cooling to 40 deg.C, sequentially adding hydrogenated lecithin, sodium benzoate, phenoxyethanol and ethylhexylglycerin composite bacteriostatic agent, plant composite anti-allergic agent, Cladosiphon okamuranus Dunn extract, and essence, stirring, filtering with 100 mesh filter cloth, and discharging.
The rotating speed of the stirring is 150 r/min.
Comparative example 4
The mineral hot spring-containing cleaning composition comprises the following raw materials in parts by weight: 0.05 part of chelating agent, 3 parts of polyhydric alcohol, 16 parts of cocamidopropyl betaine, 1 part of coconut monoethanolamide, 12 parts of potassium cocoyl glycinate, 10 parts of decyl glucoside, 0.2 part of pH regulator, 0.8 part of sodium chloride, 1 part of hydrogenated lecithin, 0.5 part of sodium benzoate, 0.5 part of phenoxyethanol and ethylhexyl glycerol composite bacteriostatic agent, 0.5 part of plant composite anti-sensitivity agent, 0.1 part of cladocera asteroides extract, 0.1 part of essence and 54.25 parts of water.
The pH regulator is citric acid.
The chelating agent is disodium EDTA.
The polyol is glycerol.
The water is thermal spring water.
The essence is lemon essence.
The preparation method of the mineral hot spring-containing cleaning composition comprises the following steps:
(1) adding EDTA disodium into water, stirring and heating to 80 ℃;
(2) sequentially adding polyalcohol, cocamidopropyl betaine, coconut monoethanolamide, potassium cocoyl glycinate and decyl glucoside, and stirring to be uniform;
(3) cooling to 60 ℃, sequentially adding a pH regulator and sodium chloride, and stirring until the pH regulator and the sodium chloride are dissolved uniformly;
(4) cooling to 40 deg.C, sequentially adding hydrogenated lecithin, sodium benzoate, phenoxyethanol and ethylhexylglycerin composite bacteriostatic agent, plant composite anti-allergic agent, Cladosiphon okamuranus Dunn extract, and essence, stirring, filtering with 100 mesh filter cloth, and discharging.
The rotating speed of the stirring is 150 r/min.
Comparative example 5
The mineral hot spring-containing cleaning composition comprises the following raw materials in parts by weight: 0.05 part of chelating agent, 12 parts of C10-C14 alkyl alcohol polyether sodium sulfate, 3 parts of polyhydric alcohol, 14 parts of cocamidopropyl betaine, 1 part of coconut monoethanolamide, 12 parts of cocoyl glycine potassium, 0.2 part of pH regulator, 0.8 part of sodium chloride, 1 part of hydrogenated lecithin, 0.5 part of sodium benzoate, 0.5 part of phenoxyethanol and ethylhexyl glycerol composite bacteriostatic agent, 0.5 part of plant composite anti-sensitivity agent, 0.1 part of cladosporium fortunei extract, 0.1 part of essence and 54.25 parts of water.
The pH regulator is citric acid.
The sodium alkyl alcohol polyether sulfate C10-C14 is sodium lauryl polyether sulfate.
The chelating agent is disodium EDTA.
The polyol is glycerol.
The water is thermal spring water.
The essence is lemon essence.
The preparation method of the cleaning composition containing the mineral hot spring comprises the following steps:
(1) adding EDTA disodium into water, adding C10-C14 sodium alkyl alcohol polyether sulfate, stirring and heating to 80 ℃;
(2) sequentially adding polyalcohol, cocamidopropyl betaine, coconut monoethanolamide and potassium cocoyl glycinate, and stirring to be uniform;
(3) cooling to 60 ℃, sequentially adding a pH regulator and sodium chloride, and stirring until the pH regulator and the sodium chloride are dissolved uniformly;
(4) cooling to 40 deg.C, sequentially adding hydrogenated lecithin, sodium benzoate, phenoxyethanol and ethylhexylglycerin composite bacteriostatic agent, plant composite anti-allergic agent, Cladosiphon okamuranus Dunn extract, and essence, stirring, filtering with 100 mesh filter cloth, and discharging.
The rotating speed of the stirring is 150 r/min.
Comparative example 6
The mineral hot spring-containing cleaning composition comprises the following raw materials in parts by weight: 0.05 part of chelating agent, 12 parts of C10-C14 sodium alkyl polyether sulfate, 3 parts of polyhydric alcohol, 10 parts of cocamidopropyl betaine, 1 part of coconut monoethanolamide, 12 parts of potassium cocoyl glycinate, 4 parts of decyl glucoside, 0.2 part of pH regulator, 9400.8 parts of carbomer, 1 part of hydrogenated lecithin, 0.5 part of sodium benzoate, 0.5 part of phenoxyethanol and ethylhexyl glycerol composite bacteriostatic agent, 0.5 part of plant composite anti-sensitivity agent, 0.1 part of cladosporium asteroides aitchireilianum extract, 0.1 part of essence and 54.25 parts of water.
The pH regulator is citric acid.
The sodium alkyl alcohol polyether sulfate C10-C14 is sodium lauryl polyether sulfate.
The chelating agent is disodium EDTA.
The polyol is glycerol.
The water is thermal spring water.
The essence is lemon essence.
The preparation method of the cleaning composition containing the mineral hot spring comprises the following steps:
(1) adding EDTA disodium into water, adding C10-C14 sodium alkyl alcohol polyether sulfate, stirring and heating to 80 ℃;
(2) sequentially adding polyalcohol, cocamidopropyl betaine, coconut monoethanolamide, potassium cocoyl glycinate and decyl glucoside, and stirring to be uniform;
(3) cooling to 60 deg.C, sequentially adding pH regulator and carbomer 940, and stirring to dissolve;
(4) cooling to 40 deg.C, sequentially adding hydrogenated lecithin, sodium benzoate, phenoxyethanol and ethylhexylglycerin composite bacteriostatic agent, plant composite anti-allergic agent, Cladosiphon okamuranus Dunn extract, and essence, stirring, filtering with 100 mesh filter cloth, and discharging.
The rotating speed of the stirring is 150 r/min.
Comparative example 7
The mineral hot spring-containing cleaning composition comprises the following raw materials in parts by weight: 0.05 part of chelating agent, 12 parts of C10-C14 alkyl alcohol polyether sodium sulfate, 3 parts of polyhydric alcohol, 10 parts of cocamidopropyl betaine, 1 part of coconut monoethanolamide, 12 parts of potassium cocoyl glycinate, 4 parts of decyl glucoside, 0.2 part of pH regulator, 0.8 part of sodium chloride, 1 part of hydrogenated lecithin, 0.5 part of sodium benzoate, 0.5 part of phenoxyethanol and ethylhexyl glycerol composite bacteriostatic agent, 0.5 part of plant composite anti-sensitivity agent, 0.1 part of essence and 54.35 parts of water.
The pH regulator is citric acid.
The sodium alkyl alcohol polyether sulfate C10-C14 is sodium lauryl polyether sulfate.
The chelating agent is disodium EDTA.
The polyol is glycerol.
The water is thermal spring water.
The essence is lemon essence.
The preparation method of the cleaning composition containing the mineral hot spring comprises the following steps:
(1) adding EDTA disodium into water, adding C10-C14 sodium alkyl alcohol polyether sulfate, stirring and heating to 80 ℃;
(2) sequentially adding polyalcohol, cocamidopropyl betaine, coconut monoethanolamide, potassium cocoyl glycinate and decyl glucoside, and stirring to be uniform;
(3) cooling to 60 ℃, sequentially adding a pH regulator and sodium chloride, and stirring until the pH regulator and the sodium chloride are dissolved uniformly;
(4) cooling to 40 deg.C, sequentially adding hydrogenated lecithin, sodium benzoate, phenoxyethanol and ethylhexylglycerin composite bacteriostatic agent, plant composite anti-allergic agent and essence, stirring, filtering with 100 mesh filter cloth, and discharging.
The rotating speed of the stirring is 150 r/min.
Comparative example 8
The mineral hot spring-containing cleaning composition comprises the following raw materials in parts by weight: 0.05 part of chelating agent, 12 parts of C10-C14 alkyl alcohol polyether sodium sulfate, 3 parts of polyhydric alcohol, 10 parts of cocamidopropyl betaine, 1 part of coconut monoethanolamide, 12 parts of cocoyl glycine potassium, 4 parts of decyl glucoside, 0.2 part of pH regulator, 0.4 part of sodium chloride, 1 part of hydrogenated lecithin, 0.5 part of sodium benzoate, 0.5 part of phenoxyethanol and ethylhexyl glycerol composite bacteriostatic agent, 0.5 part of plant composite anti-sensitivity agent, 0.1 part of cladosporium asteroides aitchirei extract, 0.1 part of essence and 54.65 parts of water.
The pH regulator is citric acid.
The sodium alkyl alcohol polyether sulfate C10-C14 is sodium lauryl polyether sulfate.
The chelating agent is disodium EDTA.
The polyol is glycerol.
The water is thermal spring water.
The essence is lemon essence.
The preparation method of the cleaning composition containing the mineral hot spring comprises the following steps:
(1) adding EDTA disodium into water, adding C10-C14 sodium alkyl alcohol polyether sulfate, stirring and heating to 80 ℃;
(2) sequentially adding polyalcohol, cocamidopropyl betaine, coconut monoethanolamide, potassium cocoyl glycinate and decyl glucoside, and stirring to be uniform;
(3) cooling to 60 ℃, sequentially adding a pH regulator and sodium chloride, and stirring until the pH regulator and the sodium chloride are dissolved uniformly;
(4) cooling to 40 deg.C, sequentially adding hydrogenated lecithin, sodium benzoate, phenoxyethanol and ethylhexylglycerin composite bacteriostatic agent, plant composite anti-allergic agent, Cladosiphon okamuranus Dunn extract, and essence, stirring, filtering with 100 mesh filter cloth, and discharging.
The rotating speed of the stirring is 150 r/min.
Comparative example 9
The mineral hot spring-containing cleaning composition comprises the following raw materials in parts by weight: 0.05 part of chelating agent, 12 parts of C10-C14 alkyl alcohol polyether sodium sulfate, 3 parts of polyhydric alcohol, 10 parts of cocamidopropyl betaine, 1 part of coconut monoethanolamide, 12 parts of cocoyl glycine potassium, 4 parts of decyl glucoside, 0.2 part of pH regulator, 1.2 parts of sodium chloride, 1 part of hydrogenated lecithin, 0.5 part of sodium benzoate, 0.5 part of phenoxyethanol and ethylhexyl glycerol composite bacteriostatic agent, 0.5 part of plant composite anti-sensitivity agent, 0.1 part of cladosporium asteroides aitchirei extract, 0.1 part of essence and 54.05 parts of water.
The pH regulator is citric acid.
The C10-C14 sodium alkyl alcohol polyether sulfate is sodium lauryl polyether sulfate.
The chelating agent is disodium EDTA.
The polyol is glycerol.
The water is thermal spring water.
The essence is lemon essence.
The preparation method of the cleaning composition containing the mineral hot spring comprises the following steps:
(1) adding EDTA disodium into water, adding C10-C14 sodium alkyl alcohol polyether sulfate, stirring and heating to 80 ℃;
(2) sequentially adding polyalcohol, cocamidopropyl betaine, coconut monoethanolamide, potassium cocoyl glycinate and decyl glucoside, and stirring to be uniform;
(3) cooling to 60 ℃, sequentially adding a pH regulator and sodium chloride, and stirring until the pH regulator and the sodium chloride are dissolved uniformly;
(4) cooling to 40 deg.C, sequentially adding hydrogenated lecithin, sodium benzoate, phenoxyethanol and ethylhexylglycerin composite bacteriostatic agent, plant composite anti-allergic agent, Cladosiphon okamuranus Dunn extract, and essence, stirring, filtering with 100 mesh filter cloth, and discharging.
The rotating speed of the stirring is 150 r/min.
Evaluation of Performance
The mineral spring-containing cleaning compositions prepared in examples and comparative examples were subjected to the following tests. The test results are shown in Table 1.
1. Temperature cycle stability testing method
The test objects were filled into glass tubes and stored under temperature cycling (2 cycles/day at 5 ℃ to 45 ℃, 2 hours at 45 ℃) and the appearance state was compared at 2 month intervals with 25 ℃ storage. The evaluation criteria were:
a: the appearance of the preserved object is not changed;
b: slight cloudiness was observed with the preserved material;
c: the preserve was observed to separate, precipitate or solidify.
2. Viscosity measuring method
The samples were previously incubated to 25 ℃ and measured using an NDJ-8S rotary digital viscometer. The test was repeated 5 times for each sample and averaged.
3. Method for measuring foam quantity and foam holding capacity
The skin using the samples was evaluated by five professional judges. The amount of foam and the foam-retaining ability were evaluated according to the following methods and scores. And calculating the average value of the evaluation scores of five judges.
Evaluation of foam amount (fraction)
5: is very large;
4: slightly larger;
3: generally;
2: slightly smaller;
1: is small.
Evaluation of foam Retention ability (score)
5: the foam retention capacity is very high;
4: the foam retention capacity is slightly higher;
3: generally;
2: slightly lower foam retention;
1: no foam retention ability.
4. And (3) safety evaluation:
selecting sensitive skin to satisfy TEWL>15g/h/m2X test subjects with stratum corneum water content are randomly divided into x groups, each group contains 30 persons, and the age range is 25-55 years old; the safety of the sample on the skin of a human body is observed through a human body trial test, and the test sample is evaluated to have good safety by referring to the skin adverse reaction grading standard of the human body trial test specified in 2015 edition of technical Specification for cosmetic safety. Grading: grade 0 is no reaction; grade 1 is faint erythema; grade 2 is erythema, infiltration, papule; grade 3 erythema, edema, pimple, blister; grade 4 is erythema, edema, bulla.
Table 1: test result table
Figure BDA0002135898220000191
The foregoing examples are merely illustrative and serve to explain some of the features of the method of the present invention. The appended claims are intended to claim as broad a scope as is contemplated, and the examples presented herein are merely illustrative of selected implementations in accordance with all possible combinations of examples. Accordingly, it is applicants' intention that the appended claims are not to be limited by the choice of examples illustrating features of the invention. Also, where numerical ranges are used in the claims, subranges therein are included, and variations in these ranges are also to be construed as possible being covered by the appended claims.

Claims (7)

1. The mineral hot spring-containing cleaning composition is characterized by comprising the following raw materials in parts by weight: 0.04-0.06 part of chelating agent, 11-13 parts of C10-C14 alkyl alcohol polyether sulfate sodium, 2-4 parts of polyhydric alcohol, 9-11 parts of cocamidopropyl betaine, 0.9-1.1 parts of coconut monoethanolamide, 11-13 parts of potassium cocoyl glycinate, 3.5-4.5 parts of decyl glucoside, 0.1-0.3 part of pH regulator, 0.7-0.9 part of sodium chloride, 0.9-1.1 part of hydrogenated lecithin, 0.4-0.6 part of sodium benzoate, 0.4-0.6 part of phenoxyethanol and ethylhexyl glycerin composite bacteriostatic agent, 0.4-0.6 part of plant composite anti-allergic agent, 0.09-0.11 part of Cladosiphon okamuranus extract, 0.09-0.11 part of essence and 53-55 parts of water;
The weight ratio of the C10-C14 sodium alkyl alcohol polyether sulfate, the cocamidopropyl betaine and the decyl glucoside is (11-13): (9-11): (3.5-4.5);
the weight ratio of the cladosporium asteroides extract to the sodium chloride is (0.9-1.1): (0.7-0.9);
the C10-C14 sodium alkyl alcohol polyether sulfate is sodium lauryl polyether sulfate;
the chelating agent is EDTA disodium;
the water is thermal spring water.
2. The mineral spa-containing cleaning composition of claim 1, wherein the pH adjusting agent is citric acid.
3. The mineral spa-containing cleaning composition of claim 1, wherein the polyol is at least one of glycerin, 1, 3-butylene glycol, and dipropylene glycol.
4. The mineral spa-containing cleaning composition of claim 1, wherein the fragrance is at least one of lemon fragrance, peppermint fragrance, litchi fragrance, strawberry fragrance, wolfberry fragrance, rose fragrance, banana fragrance, juicy peach fragrance, and passion flower fragrance.
5. The mineral spa-containing cleaning composition according to any one of claims 1-4, wherein the botanical composite anti-sensitivity agent comprises the following raw materials: centella asiatica extract, polygonum cuspidatum root extract, scutellaria baicalensis root extract, tea leaf extract, glycyrrhiza glabra root extract, chamomile flower extract and rosemary leaf extract.
6. A method of making a mineral spring-containing cleaning composition as claimed in any one of claims 1 to 4, comprising the steps of:
(1) adding chelating agent into water, adding C10-C14 alkyl alcohol polyether sodium sulfate, stirring and heating to 75-85 ℃;
(2) sequentially adding polyalcohol, cocamidopropyl betaine, coconut monoethanolamide, potassium cocoyl glycinate and decyl glucoside, and stirring to be uniform;
(3) cooling to 55-65 deg.C, sequentially adding pH regulator and sodium chloride, and stirring to dissolve;
(4) cooling to 35-45 deg.C, sequentially adding hydrogenated lecithin, sodium benzoate, phenoxyethanol and ethylhexylglycerin composite bacteriostatic agent, plant composite anti-allergic agent, Cladosiphon okamuranus Dunn extract, and essence, stirring, filtering with 50-150 mesh filter cloth, and discharging.
7. A mineral spring-containing facial cleanser comprising the mineral spring-containing cleaning composition according to any one of claims 1 to 5.
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