CN110295493A - 一种酚醛树脂改性牛皮胶提高蚕丝耐磨性的方法 - Google Patents
一种酚醛树脂改性牛皮胶提高蚕丝耐磨性的方法 Download PDFInfo
- Publication number
- CN110295493A CN110295493A CN201910597402.7A CN201910597402A CN110295493A CN 110295493 A CN110295493 A CN 110295493A CN 201910597402 A CN201910597402 A CN 201910597402A CN 110295493 A CN110295493 A CN 110295493A
- Authority
- CN
- China
- Prior art keywords
- silk
- temperature
- phenolic resin
- resin modified
- animal glue
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08H—DERIVATIVES OF NATURAL MACROMOLECULAR COMPOUNDS
- C08H1/00—Macromolecular products derived from proteins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
- D06M10/04—Physical treatment combined with treatment with chemical compounds or elements
- D06M10/06—Inorganic compounds or elements
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
- D06M10/04—Physical treatment combined with treatment with chemical compounds or elements
- D06M10/08—Organic compounds
- D06M10/10—Macromolecular compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/01—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with hydrogen, water or heavy water; with hydrides of metals or complexes thereof; with boranes, diboranes, silanes, disilanes, phosphines, diphosphines, stibines, distibines, arsines, or diarsines or complexes thereof
- D06M11/05—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with hydrogen, water or heavy water; with hydrides of metals or complexes thereof; with boranes, diboranes, silanes, disilanes, phosphines, diphosphines, stibines, distibines, arsines, or diarsines or complexes thereof with water, e.g. steam; with heavy water
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/58—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
- D06M11/59—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides with ammonia; with complexes of organic amines with inorganic substances
- D06M11/60—Ammonia as a gas or in solution
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/68—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof
- D06M11/72—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof with metaphosphoric acids or their salts; with polyphosphoric acids or their salts; with perphosphoric acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/84—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising combined with mechanical treatment
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
- D06M13/148—Polyalcohols, e.g. glycerol or glucose
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
- D06M13/2243—Mono-, di-, or triglycerides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/35—Abrasion, pilling or fibrillation resistance
Abstract
本发明公布了一种酚醛树脂改性牛皮胶提高蚕丝耐磨性的方法,包括以下步骤:(1)将牛皮胶溶于水蒸煮,并加入复合酶剂酶解,并分别加入半乳糖醛酸和安卡青霉素、尿素和硫代硫酸钠处理,然后加入水溶性酚醛树脂和纳米二氧化钛粉搅拌混合;(2)使用醋酸溶液和磁化水对摊晒蚕丝熏蒸处理,然后使用汽油加压蒸煮;(3)表面处理,使用表面处理剂溶液、氨气和电离空气对蚕丝进行处理;(4)先将蚕丝进行变温处理,然后进行磁化烘干;(5)对蚕丝分别使用电离渗透和磁化渗透进行渗透;(6)使用乙醇蒸汽对蚕丝清洗,再进行高速磨洗。
Description
技术领域
本发明属于蚕丝加工技术领域,具体涉及一种酚醛树脂改性牛皮胶提高蚕丝耐磨性的方法。
背景技术
蚕丝为将蚕茧通过煮茧、缫丝、复摇和整理等工艺加工后而形成的天然纤维,我国是最早利用蚕丝的国家,具史料记载约在4700年前中国古人就已经开始利用蚕丝制作丝线和编织纺织品,商周时期就已经出现利用蚕丝加工制成罗、绫、纱等纺织品;蚕丝中富含丰富的蛋白质成分,使其加工的纺织品具有柔软、保暖,对皮肤无刺激性,并且具有加高的透气性、轻便性和弹性效果,可用于加工多种服饰面料,生产高档成衣制品,我国著名的“丝绸之路”就是以蚕丝所加工的丝绸面料为核心的贸易往来,极大的提高了各地域之间的文化和贸易交流。蚕丝虽然具有较高的穿着性、舒适性,但由于蚕丝主要成为蚕丝蛋白,由蚕丝所加工而成的丝绸在不能使用机洗方式清洗,主要由于蚕丝的耐磨性较差,并在机洗或手洗过程中很容易产生毛球,从而降低了蚕丝纺织品穿着性和使用性能。
发明内容
本发明的目的:蚕丝虽然具有较高的穿着性、舒适性,但由于蚕丝主要成为蚕丝蛋白,由蚕丝所加工而成的丝绸在不能使用机洗方式清洗,主要由于蚕丝的耐磨性较差,并在机洗或手洗过程中很容易产生毛球,从而降低了蚕丝纺织品穿着性和使用性能。为解决上述问题,本发明提供了一种酚醛树脂改性牛皮胶提高蚕丝耐磨性的方法。
本发明是通过以下技术方案实现的:
一种酚醛树脂改性牛皮胶提高蚕丝耐磨性的方法,包括以下步骤:
(1)改性:取牛皮胶加入其质量10-14倍的去离子水沸水蒸煮25-30min,冷却后加入复合酶剂低温酶解6-8h,然后再分别加入去离子水质量1.4%-3.2%半乳糖醛酸和质量为0.1%-0.4%的安卡青霉素混合后进行搅拌蒸煮,再向其中分别加入尿素和硫代硫酸钠,转至反应釜中抽至真空,然后充满氮气静置反应3-4h,压强2.3-4.1Mpa,并使用超声波间隔振荡20-25min,得处理牛皮胶溶液;然后向处理牛皮胶溶液中加入其质量5.1%-6.8%的水溶性酚醛树脂和0.3%-0.6%的纳米二氧化钛粉,在温度77-85℃、转速18000-21000r/min中搅拌混合27-35min,并静置保温3-4h,烘干后得酚醛树脂改性牛皮胶粉;
(2)整形脱脂:打开摊晒架并将蚕丝通过摊晒框架圆弧形定位槽进行波纹型缠绕,并使用紧固螺栓装置进行固定,得摊晒蚕丝;将摊晒蚕丝悬挂于熏蒸室内,先使用醋酸溶液熏蒸32-39min,再使用磁化水熏蒸40-50min,熏蒸温度均为45-52℃,湿度保持在90%以上,得熏蒸蚕丝,然后将熏蒸蚕丝浸入汽油中加压蒸煮17-23min,乙醇清洗后得脱脂蚕丝;
(3)表面处理:将脱脂蚕丝浸入表面处理剂溶液在温度51-57℃、压强2-3Mpa条件下循环浸渍,循环泵流量为7-9L/min,取出后烘干置于反应釜,先通入反应釜容积17%-21%的氨气氨化反应32-41min,然后抽除氨气再通入反应釜容积34%-46%的电离空气离子处理1-2h,得表面处理蚕丝;
(4)磁化烘干:将表面处理蚕丝放入极速变温箱进行变温处理,先在72-79℃高温静置5-7min,然后降温至-17—-12℃低温静置3-5min,交替进行高温静置和低温静置14-17次,得变温处理蚕丝;然后将变温处理蚕丝降温至0℃,保温33-39min,使用频率为1.7-2.5Mhz的磁化器在45-51℃磁化烘干,至水份含量2%-3%,,得磁化烘干蚕丝;
(5)渗透:向电离槽中加入水质量7%-11%的酚醛树脂改性牛皮胶粉搅拌溶解,密闭后通交流电电离渗透,先进行低电压低温恒压电离32-36min,再进行高电压高温恒压电离25-29min,然后进行高电压高温高压电离17-23min,电流均为2-3A,清洗后烘干,得电离渗透蚕丝;配制质量浓度为41%-46%的酚醛树脂改性牛皮胶粉溶液,将电离渗透蚕丝浸入其中进行磁化渗透43-54min,清洗后得磁化渗透蚕丝;
(6)清洗固化:使用无水乙醇热蒸汽对磁化渗透蚕丝清洗20-30min,然后将清洗后的蚕丝浸入磨洗溶液在4200-4700r/min转速下高速磨洗30-37min,清洗烘干,得耐磨型蚕丝。
步骤(1)所述的复合酶剂,其中氨基酸脱羧酶、酪氨酸酶和羧酸酯酶质量配比为4-7:1-2:0.3-0.6,其加入量为去离子水质量的2.3%-3.6%;所述的低温酶解,其温度为13-19℃。
步骤(1)所述的搅拌蒸煮,其转速为1400-1700r/min,温度为73-81℃。
步骤(1)所述的尿素,其加入量为去离子水质量的4.2%-5.6%;所述的硫代硫酸钠,其加入量为去离子水质量的0.8%-1.6%。
步骤(2)所述的摊晒架,其由摊晒框架和紧固螺栓装置组成,摊晒框架为长方形结构,位于摊晒架中部并可根据实际情况调整摊晒框架数量,并在摊晒框架两端设置多个圆弧形定位槽,紧固螺栓装置位于摊晒架两侧。
步骤(2)所述的醋酸溶液,其质量浓缩为7%-13%;所述的加压蒸煮,其压强为3-4Mpa,温度为60-65℃。
步骤(3)所述的氨化反应和离子处理,其温度为57-64℃。
步骤(3)所述的表面处理剂溶液,其各配制成分质量计份为:去离子水50-60份、季戊四醇3-7份、过磷酸钙2.1-4.6份、螯合铁1.2-2.4份、聚丙烯酸钠2-5份、柠檬酸钠1-3份、单宁2-4份、甲壳素1-2份、单甘脂0.5-1份。
步骤(5)所述的低电压低温恒压电离,其电压为70-78V,温度为62-67℃,压强为2-3Mpa;所述的高电压高温恒压电离,其电压为124-137V,温度为85-92℃,压强为2-3Mpa;所述的高电压高温高压电离,其电压为124-137V,温度为85-92℃,压强为3-5Mpa;所述的磁化渗透,其磁化器频率为3.7-4.5Mhz,温度为78-86℃。
步骤(6)所述的磨洗溶液,其配制成分质量计份为:去离子水30-40份、改性纳米二氧化锆7-10份、改性纳米陶瓷3-5份;所述的改性纳米二氧化锆和改性纳米陶瓷,为将纳米二氧化锆和纳米陶瓷置于球磨机中球磨3-4h,并在温度210-260℃煅烧1-2h,冷却后分别得改性纳米二氧化锆和改性纳米陶瓷。
本发明相比现有技术具有以下优点:改性方法,通过对牛皮胶进行蒸煮和酶解方法可在一定程度上降低牛皮胶的分子量,从而提高牛皮胶对蚕丝的渗透作用,而使用半乳糖醛酸和安卡霉素,可中和部分羟基和提高牛皮胶活性,提高其与酚醛树脂的结合性能,并通过尿素和硫代硫酸钠的氨化和氧化作用,提高牛皮胶分子的结构紧密性和渗透性能,而加入水性酚醛树脂和纳米二氧化钛通过高速搅拌与经处理后的牛皮胶混合,形成通过分子范德华力相互结合的络合分子结构, 从而进一步增强了蚕丝的耐磨属性;整形脱脂,通过摊晒架使蚕丝可以均摊在摊晒框上,从而通过提高蚕丝与外界的接触面积,从而提高处理效果,而通过醋酸溶液和磁化水对蚕丝进行处理,可起到软化和初步活化的效果,提高蚕丝对处理剂成分的吸收能力;表面处理方法,通过表面处理剂、氨化反应和离子处理方法,可提高蚕丝表面及深层次细胞的活性,从而提高对处理有效成分的吸收能力,增强蚕丝的耐磨性;磁化烘干,通过在不断极速交替的高低变温过程中,蚕丝受温度影响从而出现热胀冷缩,提高蚕丝细胞的韧性和通透性,在0℃水分子出现膨胀、结合性能下降,通过磁化器烘干处理,可有效降低蚕丝中水分含量,提高对处理成分的吸收能力;渗透方法,先通过低电压低温恒压电离可促进蚕丝表面对酚醛树脂改性牛皮胶的吸收,并通过逐渐提高电压、温度和压力方法促进酚醛树脂改性牛皮胶对蚕丝内部的渗透作用,再通过强磁场和高浓度的酚醛树脂改性牛皮胶溶液方法提高对蚕丝的渗透作用,提高蚕丝的耐磨性;清洗固化,通过乙醇蒸汽对蚕丝表面未渗透部分成分进行清洗,并通过磨洗溶液中的改性纳米二氧化锆和改性纳米陶瓷在溶剂中高速旋转对蚕丝表面进行打磨,并且经改性后的二氧化锆和陶瓷颗粒为圆形结构,并不会对蚕丝造成实质性损伤,提高了蚕丝表面的光滑性和韧性,并可在蚕丝表层附着起到固化作用。
具体实施方式
实施例1:
一种酚醛树脂改性牛皮胶提高蚕丝耐磨性的方法,包括以下步骤:
(1)改性:取牛皮胶加入其质量11倍的去离子水沸水蒸煮26min,冷却后加入复合酶剂低温酶解6.5h,然后再分别加入去离子水质量1.5%半乳糖醛酸和质量为0.2%的安卡青霉素混合后进行搅拌蒸煮,再向其中分别加入尿素和硫代硫酸钠,转至反应釜中抽至真空,然后充满氮气静置反应3.5h,压强2.4Mpa,并使用超声波间隔振荡21min,得处理牛皮胶溶液;然后向处理牛皮胶溶液中加入其质量5.2%的水溶性酚醛树脂和0.32%的纳米二氧化钛粉,在温度78℃、转速18100r/min中搅拌混合28min,并静置保温3.5h,烘干后得酚醛树脂改性牛皮胶粉;
(2)整形脱脂:打开摊晒架并将蚕丝通过摊晒框架圆弧形定位槽进行波纹型缠绕,并使用紧固螺栓装置进行固定,得摊晒蚕丝;将摊晒蚕丝悬挂于熏蒸室内,先使用醋酸溶液熏蒸33min,再使用磁化水熏蒸41min,熏蒸温度均为46℃,湿度保持在90%以上,得熏蒸蚕丝,然后将熏蒸蚕丝浸入汽油中加压蒸煮18min,乙醇清洗后得脱脂蚕丝;
(3)表面处理:将脱脂蚕丝浸入表面处理剂溶液在温度52℃、压强2.1Mpa条件下循环浸渍,循环泵流量为7.2L/min,取出后烘干置于反应釜,先通入反应釜容积18%的氨气氨化反应33min,然后抽除氨气再通入反应釜容积35%的电离空气离子处理1.5h,得表面处理蚕丝;
(4)磁化烘干:将表面处理蚕丝放入极速变温箱进行变温处理,先在73℃高温静置5min,然后降温至-13℃低温静置3min,交替进行高温静置和低温静置15次,得变温处理蚕丝;然后将变温处理蚕丝降温至0℃,保温34min,使用频率为1.8Mhz的磁化器在46℃磁化烘干,至水份含量2.2%,,得磁化烘干蚕丝;
(5)渗透:向电离槽中加入水质量7.3%的酚醛树脂改性牛皮胶粉搅拌溶解,密闭后通交流电电离渗透,先进行低电压低温恒压电离33min,再进行高电压高温恒压电离26min,然后进行高电压高温高压电离18min,电流均为2.2A,清洗后烘干,得电离渗透蚕丝;配制质量浓度为42%的酚醛树脂改性牛皮胶粉溶液,将电离渗透蚕丝浸入其中进行磁化渗透44min,清洗后得磁化渗透蚕丝;
(6)清洗固化:使用无水乙醇热蒸汽对磁化渗透蚕丝清洗21min,然后将清洗后的蚕丝浸入磨洗溶液在4250r/min转速下高速磨洗31min,清洗烘干,得耐磨型蚕丝。
步骤(1)所述的复合酶剂,其中氨基酸脱羧酶、酪氨酸酶和羧酸酯酶质量配比为4.1:1.2:0.34,其加入量为去离子水质量的2.4%;所述的低温酶解,其温度为14℃。
步骤(1)所述的搅拌蒸煮,其转速为1420r/min,温度为74℃。
步骤(1)所述的尿素,其加入量为去离子水质量的4.3%;所述的硫代硫酸钠,其加入量为去离子水质量的0.9%。
步骤(2)所述的摊晒架,其由摊晒框架和紧固螺栓装置组成,摊晒框架为长方形结构,位于摊晒架中部并可根据实际情况调整摊晒框架数量,并在摊晒框架两端设置多个圆弧形定位槽,紧固螺栓装置位于摊晒架两侧。
步骤(2)所述的醋酸溶液,其质量浓缩为7.2%;所述的加压蒸煮,其压强为3.1Mpa,温度为61℃。
步骤(3)所述的氨化反应和离子处理,其温度为58℃。
步骤(3)所述的表面处理剂溶液,其各配制成分质量计份为:去离子水51份、季戊四醇3.2份、过磷酸钙2.2份、螯合铁1.3份、聚丙烯酸钠2.4份、柠檬酸钠1.5份、单宁2.3份、甲壳素1.2份、单甘脂0.6份。
步骤(5)所述的低电压低温恒压电离,其电压为71V,温度为63℃,压强为2.2Mpa;所述的高电压高温恒压电离,其电压为125V,温度为86℃,压强为2.2Mpa;所述的高电压高温高压电离,其电压为125V,温度为86℃,压强为3.4Mpa;所述的磁化渗透,其磁化器频率为3.8Mhz,温度为79℃。
步骤(6)所述的磨洗溶液,其配制成分质量计份为:去离子水31份、改性纳米二氧化锆8份、改性纳米陶瓷3.2份;所述的改性纳米二氧化锆和改性纳米陶瓷,为将纳米二氧化锆和纳米陶瓷置于球磨机中球磨3.5h,并在温度212℃煅烧1.5h,冷却后分别得改性纳米二氧化锆和改性纳米陶瓷。
实施例2:
一种酚醛树脂改性牛皮胶提高蚕丝耐磨性的方法,包括以下步骤:
(1)改性:取牛皮胶加入其质量13倍的去离子水沸水蒸煮29min,冷却后加入复合酶剂低温酶解7.5h,然后再分别加入去离子水质量3.1%半乳糖醛酸和质量为0.38%的安卡青霉素混合后进行搅拌蒸煮,再向其中分别加入尿素和硫代硫酸钠,转至反应釜中抽至真空,然后充满氮气静置反应4h,压强4.0Mpa,并使用超声波间隔振荡24min,得处理牛皮胶溶液;然后向处理牛皮胶溶液中加入其质量6.7%的水溶性酚醛树脂和0.57%的纳米二氧化钛粉,在温度84℃、转速20900r/min中搅拌混合34min,并静置保温4h,烘干后得酚醛树脂改性牛皮胶粉;
(2)整形脱脂:打开摊晒架并将蚕丝通过摊晒框架圆弧形定位槽进行波纹型缠绕,并使用紧固螺栓装置进行固定,得摊晒蚕丝;将摊晒蚕丝悬挂于熏蒸室内,先使用醋酸溶液熏蒸38min,再使用磁化水熏蒸49min,熏蒸温度均为51℃,湿度保持在90%以上,得熏蒸蚕丝,然后将熏蒸蚕丝浸入汽油中加压蒸煮22min,乙醇清洗后得脱脂蚕丝;
(3)表面处理:将脱脂蚕丝浸入表面处理剂溶液在温度56℃、压强2.9Mpa条件下循环浸渍,循环泵流量为8.7L/min,取出后烘干置于反应釜,先通入反应釜容积20.5%的氨气氨化反应40min,然后抽除氨气再通入反应釜容积45%的电离空气离子处理2h,得表面处理蚕丝;
(4)磁化烘干:将表面处理蚕丝放入极速变温箱进行变温处理,先在78℃高温静置7min,然后降温至-16℃低温静置5min,交替进行高温静置和低温静置17次,得变温处理蚕丝;然后将变温处理蚕丝降温至0℃,保温38min,使用频率为2.4Mhz的磁化器在50℃磁化烘干,至水份含量2.9%,,得磁化烘干蚕丝;
(5)渗透:向电离槽中加入水质量10.8%的酚醛树脂改性牛皮胶粉搅拌溶解,密闭后通交流电电离渗透,先进行低电压低温恒压电离35min,再进行高电压高温恒压电离28min,然后进行高电压高温高压电离22min,电流均为2.8A,清洗后烘干,得电离渗透蚕丝;配制质量浓度为45%的酚醛树脂改性牛皮胶粉溶液,将电离渗透蚕丝浸入其中进行磁化渗透53min,清洗后得磁化渗透蚕丝;
(6)清洗固化:使用无水乙醇热蒸汽对磁化渗透蚕丝清洗29min,然后将清洗后的蚕丝浸入磨洗溶液在4650r/min转速下高速磨洗36min,清洗烘干,得耐磨型蚕丝。
步骤(1)所述的复合酶剂,其中氨基酸脱羧酶、酪氨酸酶和羧酸酯酶质量配比为6.5:1.8:0.56,其加入量为去离子水质量的3.5%;所述的低温酶解,其温度为18℃。
步骤(1)所述的搅拌蒸煮,其转速为1690r/min,温度为80℃。
步骤(1)所述的尿素,其加入量为去离子水质量的5.5%;所述的硫代硫酸钠,其加入量为去离子水质量的1.5%。
步骤(2)所述的摊晒架,其由摊晒框架和紧固螺栓装置组成,摊晒框架为长方形结构,位于摊晒架中部并可根据实际情况调整摊晒框架数量,并在摊晒框架两端设置多个圆弧形定位槽,紧固螺栓装置位于摊晒架两侧。
步骤(2)所述的醋酸溶液,其质量浓缩为12.7%;所述的加压蒸煮,其压强为3.8Mpa,温度为64℃。
步骤(3)所述的氨化反应和离子处理,其温度为63℃。
步骤(3)所述的表面处理剂溶液,其各配制成分质量计份为:去离子水58份、季戊四醇6.5份、过磷酸钙4.5份、螯合铁2.3份、聚丙烯酸钠4.9份、柠檬酸钠2.7份、单宁3.6份、甲壳素1.8份、单甘脂0.9份。
步骤(5)所述的低电压低温恒压电离,其电压为77V,温度为66℃,压强为2.8Mpa;所述的高电压高温恒压电离,其电压为136V,温度为91℃,压强为2.9Mpa;所述的高电压高温高压电离,其电压为136V,温度为91℃,压强为4.8Mpa;所述的磁化渗透,其磁化器频率为4.4Mhz,温度为85℃。
步骤(6)所述的磨洗溶液,其配制成分质量计份为:去离子水39份、改性纳米二氧化锆9.5份、改性纳米陶瓷4.8份;所述的改性纳米二氧化锆和改性纳米陶瓷,为将纳米二氧化锆和纳米陶瓷置于球磨机中球磨4h,并在温度255℃煅烧2h,冷却后分别得改性纳米二氧化锆和改性纳米陶瓷。
对比1:本对比1与实施例1比较,未使用步骤(1)中复合酶剂,其他步骤与实施例1相同。
对比2:本对比2与实施例2比较,未使用步骤(1)中半乳糖醛酸和安卡霉素,其他步骤与实施例2相同。
对比3:本对比3与实施例1比较,未使用步骤(1)中尿素和硫代硫酸钠,其他步骤与实施例1相同。
对比4:本对比4与实施例2比较,未使用步骤(1)中水溶性酚醛树脂和牛皮胶,其他步骤与实施例2相同。
对比5:本对比5与实施例1比较,未使用步骤(2)中摊晒架,其他步骤与实施例1相同。
对比6:本对比6与实施例2比较,未使用步骤(2)中加压蒸煮方法,其他步骤与实施例2相同。
对比7:本对比7与实施例1比较,未使用步骤(3)中表面处理剂溶液,其他步骤与实施例1相同。
对比8:本对比8与实施例2比较,未使用步骤(3)中氨化反应和离子处理,其他步骤与实施例8相同。
对比9:本对比9与实施例1比较,未使用步骤(4)中变温处理,其他步骤与实施例1相同。
对比10:本对比10与实施例2比较,未使用步骤(4)中磁化烘干,其他步骤与实施例2相同。
对比11:本对比11与实施例1比较,未使用步骤(5)中电离渗透方法,其他步骤与实施例1相同。
对比12:本对比12与实施例2比较,未使用步骤(5)中磁化渗透方法,其他步骤与实施例2相同。
对比13:本对比13与实施例1比较,未使用步骤(6)中高速磨洗方法,其他步骤与实施例1相同。
对照组:采用传统加工工艺对蚕丝进行加工处理,作为参照。
采用实施例1、实施例2、对比1至对比13及对照组中方法对蚕丝进行加工,所采用蚕丝在品种、规格以及之前加工方法均相同;对各组中加工蚕丝进行测试,统计弹性回复率、断裂强度、伸长率和起球率(机洗8次)进行数据对比。
实验数据:表1
项目 | 弹性回复率% | 断裂强度cN/dtex | 伸长率% | 起球率% |
实施例1 | 78 | 4.26 | 15.89 | 2.56 |
实施例2 | 77 | 4.21 | 16.01 | 2.49 |
对比1 | 75 | 4.14 | 15.77 | 2.37 |
对比2 | 75 | 4.12 | 15.8 | 3.69 |
对比3 | 75 | 4.13 | 15.54 | 3.29 |
对比4 | 66 | 3.43 | 14.21 | 9.69 |
对比5 | 76 | 4.16 | 15.58 | 2.49 |
对比6 | 75 | 4.18 | 15.92 | 2.42 |
对比7 | 75 | 4.18 | 15.66 | 4.06 |
对比8 | 75 | 4.16 | 15.66 | 3.91 |
对比9 | 74 | 4.13 | 15.14 | 2.51 |
对比10 | 76 | 4.14 | 15.89 | 2.43 |
对比11 | 71 | 3.89 | 15.02 | 7.06 |
对比12 | 72 | 3.94 | 15.44 | 6.19 |
对比13 | 74 | 4.15 | 15.5 | 4.66 |
对照组 | 59 | 2.87 | 11.21 | 19.13 |
综合结果:本发明蚕丝加工方法,与对照组比较,弹性回复率提高了19%,断裂强度提高了1.39cN/dtex,伸长率提高了4.8%,并且机洗后起球率降低了16.64%;本发明蚕丝加工方法,有效提高了蚕丝的耐磨性、断裂强度和伸长率,提高了蚕丝的耐用性和可加工性,并有效降低了蚕丝纺织品机洗后起球率,提高了洗涤便利性。
Claims (10)
1.一种酚醛树脂改性牛皮胶提高蚕丝耐磨性的方法,其特征在于,包括以下步骤:
(1)改性:取牛皮胶加入其质量10-14倍的去离子水沸水蒸煮25-30min,冷却后加入复合酶剂低温酶解6-8h,然后再分别加入去离子水质量1.4%-3.2%半乳糖醛酸和质量为0.1%-0.4%的安卡青霉素混合后进行搅拌蒸煮,再向其中分别加入尿素和硫代硫酸钠,转至反应釜中抽至真空,然后充满氮气静置反应3-4h,压强2.3-4.1Mpa,并使用超声波间隔振荡20-25min,得处理牛皮胶溶液;然后向处理牛皮胶溶液中加入其质量5.1%-6.8%的水溶性酚醛树脂和0.3%-0.6%的纳米二氧化钛粉,在温度77-85℃、转速18000-21000r/min中搅拌混合27-35min,并静置保温3-4h,烘干后得酚醛树脂改性牛皮胶粉;
(2)整形脱脂:打开摊晒架并将蚕丝通过摊晒框架圆弧形定位槽进行波纹型缠绕,并使用紧固螺栓装置进行固定,得摊晒蚕丝;将摊晒蚕丝悬挂于熏蒸室内,先使用醋酸溶液熏蒸32-39min,再使用磁化水熏蒸40-50min,熏蒸温度均为45-52℃,湿度保持在90%以上,得熏蒸蚕丝,然后将熏蒸蚕丝浸入汽油中加压蒸煮17-23min,乙醇清洗后得脱脂蚕丝;
(3)表面处理:将脱脂蚕丝浸入表面处理剂溶液在温度51-57℃、压强2-3Mpa条件下循环浸渍,循环泵流量为7-9L/min,取出后烘干置于反应釜,先通入反应釜容积17%-21%的氨气氨化反应32-41min,然后抽除氨气再通入反应釜容积34%-46%的电离空气离子处理1-2h,得表面处理蚕丝;
(4)磁化烘干:将表面处理蚕丝放入极速变温箱进行变温处理,先在72-79℃高温静置5-7min,然后降温至-17—-12℃低温静置3-5min,交替进行高温静置和低温静置14-17次,得变温处理蚕丝;然后将变温处理蚕丝降温至0℃,保温33-39min,使用频率为1.7-2.5Mhz的磁化器在45-51℃磁化烘干,至水份含量2%-3%,,得磁化烘干蚕丝;
(5)渗透:向电离槽中加入水质量7%-11%的酚醛树脂改性牛皮胶粉搅拌溶解,密闭后通交流电电离渗透,先进行低电压低温恒压电离32-36min,再进行高电压高温恒压电离25-29min,然后进行高电压高温高压电离17-23min,电流均为2-3A,清洗后烘干,得电离渗透蚕丝;配制质量浓度为41%-46%的酚醛树脂改性牛皮胶粉溶液,将电离渗透蚕丝浸入其中进行磁化渗透43-54min,清洗后得磁化渗透蚕丝;
(6)清洗固化:使用无水乙醇热蒸汽对磁化渗透蚕丝清洗20-30min,然后将清洗后的蚕丝浸入磨洗溶液在4200-4700r/min转速下高速磨洗30-37min,清洗烘干,得耐磨型蚕丝。
2.如权利要求1所述的酚醛树脂改性牛皮胶提高蚕丝耐磨性的方法,其特征在于,步骤(1)所述的复合酶剂,其中氨基酸脱羧酶、酪氨酸酶和羧酸酯酶质量配比为4-7:1-2:0.3-0.6,其加入量为去离子水质量的2.3%-3.6%;所述的低温酶解,其温度为13-19℃。
3.如权利要求1所述的酚醛树脂改性牛皮胶提高蚕丝耐磨性的方法,其特征在于,步骤(1)所述的搅拌蒸煮,其转速为1400-1700r/min,温度为73-81℃。
4.如权利要求1所述的酚醛树脂改性牛皮胶提高蚕丝耐磨性的方法,其特征在于,步骤(1)所述的尿素,其加入量为去离子水质量的4.2%-5.6%;所述的硫代硫酸钠,其加入量为去离子水质量的0.8%-1.6%。
5.如权利要求1所述的酚醛树脂改性牛皮胶提高蚕丝耐磨性的方法,其特征在于,步骤(2)所述的摊晒架,其由摊晒框架和紧固螺栓装置组成,摊晒框架为长方形结构,位于摊晒架中部并可根据实际情况调整摊晒框架数量,并在摊晒框架两端设置多个圆弧形定位槽,紧固螺栓装置位于摊晒架两侧。
6.如权利要求1所述的酚醛树脂改性牛皮胶提高蚕丝耐磨性的方法,其特征在于,步骤(2)所述的醋酸溶液,其质量浓缩为7%-13%;所述的加压蒸煮,其压强为3-4Mpa,温度为60-65℃。
7.如权利要求1所述的酚醛树脂改性牛皮胶提高蚕丝耐磨性的方法,其特征在于,步骤(3)所述的氨化反应和离子处理,其温度为57-64℃。
8.如权利要求1所述的酚醛树脂改性牛皮胶提高蚕丝耐磨性的方法,其特征在于,步骤(3)所述的表面处理剂溶液,其各配制成分质量计份为:去离子水50-60份、季戊四醇3-7份、过磷酸钙2.1-4.6份、螯合铁1.2-2.4份、聚丙烯酸钠2-5份、柠檬酸钠1-3份、单宁2-4份、甲壳素1-2份、单甘脂0.5-1份。
9.如权利要求1所述的酚醛树脂改性牛皮胶提高蚕丝耐磨性的方法,其特征在于,步骤(5)所述的低电压低温恒压电离,其电压为70-78V,温度为62-67℃,压强为2-3Mpa;所述的高电压高温恒压电离,其电压为124-137V,温度为85-92℃,压强为2-3Mpa;所述的高电压高温高压电离,其电压为124-137V,温度为85-92℃,压强为3-5Mpa;所述的磁化渗透,其磁化器频率为3.7-4.5Mhz,温度为78-86℃。
10.如权利要求1所述的酚醛树脂改性牛皮胶提高蚕丝耐磨性的方法,其特征在于,步骤(6)所述的磨洗溶液,其配制成分质量计份为:去离子水30-40份、改性纳米二氧化锆7-10份、改性纳米陶瓷3-5份;所述的改性纳米二氧化锆和改性纳米陶瓷,为将纳米二氧化锆和纳米陶瓷置于球磨机中球磨3-4h,并在温度210-260℃煅烧1-2h,冷却后分别得改性纳米二氧化锆和改性纳米陶瓷。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201910597402.7A CN110295493A (zh) | 2019-07-04 | 2019-07-04 | 一种酚醛树脂改性牛皮胶提高蚕丝耐磨性的方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201910597402.7A CN110295493A (zh) | 2019-07-04 | 2019-07-04 | 一种酚醛树脂改性牛皮胶提高蚕丝耐磨性的方法 |
Publications (1)
Publication Number | Publication Date |
---|---|
CN110295493A true CN110295493A (zh) | 2019-10-01 |
Family
ID=68030181
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201910597402.7A Withdrawn CN110295493A (zh) | 2019-07-04 | 2019-07-04 | 一种酚醛树脂改性牛皮胶提高蚕丝耐磨性的方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN110295493A (zh) |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102021835A (zh) * | 2009-09-11 | 2011-04-20 | 缪煜 | 防起毛树脂整理剂 |
CN107083569A (zh) * | 2017-05-10 | 2017-08-22 | 安徽三利丝绸集团有限公司 | 一种桑蚕丝的高品质加工处理方法 |
CN107287877A (zh) * | 2017-06-28 | 2017-10-24 | 合肥市聚丰制丝有限责任公司 | 一种改善蚕丝性能的方法 |
CN107956126A (zh) * | 2017-11-27 | 2018-04-24 | 无锡昊瑜节能环保设备有限公司 | 一种真丝织物抗皱整理工艺 |
CN109235020A (zh) * | 2018-08-17 | 2019-01-18 | 安徽三利丝绸集团有限公司 | 一种提高桑蚕丝耐酸碱能力的处理方法 |
-
2019
- 2019-07-04 CN CN201910597402.7A patent/CN110295493A/zh not_active Withdrawn
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102021835A (zh) * | 2009-09-11 | 2011-04-20 | 缪煜 | 防起毛树脂整理剂 |
CN107083569A (zh) * | 2017-05-10 | 2017-08-22 | 安徽三利丝绸集团有限公司 | 一种桑蚕丝的高品质加工处理方法 |
CN107287877A (zh) * | 2017-06-28 | 2017-10-24 | 合肥市聚丰制丝有限责任公司 | 一种改善蚕丝性能的方法 |
CN107956126A (zh) * | 2017-11-27 | 2018-04-24 | 无锡昊瑜节能环保设备有限公司 | 一种真丝织物抗皱整理工艺 |
CN109235020A (zh) * | 2018-08-17 | 2019-01-18 | 安徽三利丝绸集团有限公司 | 一种提高桑蚕丝耐酸碱能力的处理方法 |
Non-Patent Citations (2)
Title |
---|
吴志刚 等: ""环保酚醛树脂改性大豆蛋白胶粘剂的研究"", 《粘接》 * |
柯华 等: ""织物抗起毛起球性能及测试等级的影响因素"", 《针织工业》 * |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN105839419B (zh) | 一种多酚改性载纳米银抗菌织物的制备方法 | |
WO2019011265A1 (zh) | 一种抗菌羽绒的制备方法 | |
CN105113245A (zh) | 一种抗皱抗菌防紫外线免烫真丝衬衫的处理方法 | |
CN110004728B (zh) | 一种蓬松保暖防霉的羽绒被的制备工艺 | |
CN109487551B (zh) | 一种植物源复合功能本草棉纤维及其制备方法 | |
CN102704270B (zh) | 织物保湿整理剂 | |
CN101974850A (zh) | 一种生态免烫真丝绸面料制备方法 | |
CN110777466A (zh) | 石墨烯羊毛呢绒面料的制造方法及获得的面料 | |
CN110735316A (zh) | 一种抗菌针织布料及其生产方法 | |
CN111420561A (zh) | 一种抗菌水软化纳滤膜的制备方法和由其制备的抗菌水软化纳滤膜 | |
CN110295493A (zh) | 一种酚醛树脂改性牛皮胶提高蚕丝耐磨性的方法 | |
JP3262875B2 (ja) | 茶染め繊維製品の製造法 | |
CN113389048A (zh) | 抗病毒面料的加工方法 | |
CN112522832A (zh) | 一种复合纳米抗菌纤维纱网面料及其制备工艺 | |
CN107227505A (zh) | 一种大豆蛋白纤维毛巾的制备方法 | |
CN108085752A (zh) | 竹纤维高效高质加工方法 | |
CN107201662A (zh) | 一种利用tg酶和漆酶处理羊毛织物的多功能整理方法 | |
CN102517914A (zh) | 一种具有净化皮肤作用的毛巾及其制备方法 | |
CN110453511A (zh) | 一种羊毛精纺面料的金莲花染色方法 | |
CN108660756A (zh) | 一种棉织物的抗皱整理方法 | |
CN109487558A (zh) | 一种吸湿抗菌棉麻纤维及其制备方法 | |
CN108893993A (zh) | 一种生物改性抗菌棉纤维及其制备方法 | |
CN108823792A (zh) | 一种医用无纺布的制备方法 | |
CN113652870A (zh) | 一种蚕丝蛋白多功能整理剂的制作方法及其在涤纶织物上的应用 | |
CN103243506A (zh) | 一种磨毛天丝面料的制作方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
WW01 | Invention patent application withdrawn after publication | ||
WW01 | Invention patent application withdrawn after publication |
Application publication date: 20191001 |