CN110292040A - A kind of gyplure that luring striped rice borer and lure - Google Patents
A kind of gyplure that luring striped rice borer and lure Download PDFInfo
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- CN110292040A CN110292040A CN201910689464.0A CN201910689464A CN110292040A CN 110292040 A CN110292040 A CN 110292040A CN 201910689464 A CN201910689464 A CN 201910689464A CN 110292040 A CN110292040 A CN 110292040A
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- gyplure
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- hexadecenal
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- rice borer
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01M—CATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
- A01M1/00—Stationary means for catching or killing insects
- A01M1/02—Stationary means for catching or killing insects with devices or substances, e.g. food, pheronones attracting the insects
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/22—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients stabilising the active ingredients
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/02—Acyclic compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N35/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical
- A01N35/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical containing aliphatically bound aldehyde or keto groups, or thio analogues thereof; Derivatives thereof, e.g. acetals
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- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Dentistry (AREA)
- Insects & Arthropods (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention provides a kind of gyplure for luring striped rice borer and lures, are related to insect sex attractant technical field.The active constituent of gyplure of the present invention includes the raw material of following parts by weight: 0.4~200 part of 50 parts of cis- 11- hexadecenal, cis- 4~10 parts of 13- octadecene aldehyde, 4~10 parts of Z-9-hexadecenal and cis- 11- hexadecenol.The gyplure has strong attractant effect for striped rice borer, to safety of human and livestock, no pollution to the environment, and can reduce the use of pesticide.Use cost is lower, easy to operate, can be applied to prediction and the prevention and treatment of striped rice borer, has preferable social economy and ecological benefits.
Description
Technical field
The invention belongs to insect sex attractant technical fields, and in particular to a kind of gyplure for luring striped rice borer and lure.
Background technique
Striped rice borer Chilo suppressalis (Walker) belongs to Insecta, lepidoptera pyralidae, in temperate zone, subtropical zone
Have widely distributed with the torrid zone, is a kind of global rice grub.The distribution of striped rice borer at home almost spreads each rice region, and two
Change snout moth's larva and withered sheath, withered booting, dead ears and insect bite strain are mainly caused to causing harm for rice, makes rice yield sharp fall.Two change
The prevention and treatment of snout moth's larva is usually all using chemical agent, but if things go on like this, striped rice borer inevitably difference occurs to various medicaments
The drug resistance of degree.The striped rice borer of many rice regions produces serious drug resistance, Er Qiesui to conventional use of insecticide
The raising of Global Temperature, the variation of field cropping system and the generation of medicament drug resistance, the prevention and treatment of striped rice borer be faced with danger
Machine, the continuous rising of annual insect population and being continuously increased for control cost, all cause sternly farmers' income and Rice Production
It loses again.It is therefore desirable to actively find a variety of control methods, comprehensive treatment controls a large amount of generations of striped rice borer.
Sex pheromone technology has played important function in striped rice borer integrated pest management.Sex pheromone technology can pass through
Baiting techniques instruct proper timing of insecticide application to monitor the generation phase of striped rice borer, and male and female moth can be additionally reduced by mass trapping
Mating rate, reduce the insect density of next-generation striped rice borer.Sex pheromone of lure ingredient is by cis- both at home and abroad at present
11- hexadecenal (Z11-16:Ald) and cis- 13- octadecene aldehyde (Z13-18:Ald) and Z-9-hexadecenal (Z9-
16:Ald) three kinds of ingredients are constituted.Further study showed that the mass ratio of 3 kinds of main components is 48:6 in sex pheromone of:
5 (the rice-stem borer sex pheromone study on prevention progress insect knowledge .2003 such as Jiao Xiaoguo, Xuan Weijian, Wang Hong support, 40 (3):
193-199).But a large amount of field trial and application discovery, the lure attractant effect of this proportion production is unsatisfactory, especially
It is difficult trapping when population density is low in field to male moth.
Summary of the invention
In view of this, the purpose of the present invention is to provide a kind of gyplure for luring striped rice borer and lures, not only in low worm
The generation dynamic that can be used for monitoring Striped Rice Borer Population under mouth density, can also be prevented and treated by the mass trapping of sex pheromone lure core
Striped rice borer improves agricultural product security, safeguards the stabilization of ecological environment to reduce the use of pesticide.
In order to achieve the above-mentioned object of the invention, the present invention the following technical schemes are provided:
The present invention provides a kind of gyplure for luring striped rice borer, the active constituent of the gyplure includes following parts by weight
Raw material: 50 parts of cis- 11- hexadecenal, cis- 4~10 parts of 13- octadecene aldehyde, 4~10 parts of Z-9-hexadecenal and
0.4~200 part of cis- 11- hexadecenol.
It preferably, further include antioxidant and uvioresistant light stabilizer in the gyplure；The antioxidant with it is cis-
The mass ratio of 11- hexadecenal is 0.002~0.02:1；The uvioresistant light stabilizer and cis- 11- hexadecenal
Mass ratio is 0.002~0.02:1.
Preferably, the antioxidant includes 2,6- di-tert-butyl-4-methy phenol, ditert-butylhydro quinone and antioxygen
Agent 168.
Preferably, the uvioresistant light stabilizer includes hindered amines uvioresistant light stabilizer；The hindered amines
Uvioresistant light stabilizer includes UV-328, UV-531 and UV-P.
The present invention also provides a kind of lure for luring striped rice borer, including the gyplure, the content of the gyplure is
0.05~50mg/ lure.
Preferably, the lure further includes release, and the material of the release includes natural rubber, synthetic rubber, gathers
Ethylene, polyvinyl chloride, resin or mucilage materials.
The present invention provides a kind of gyplure for luring striped rice borer, the active constituent of the gyplure includes following parts by weight
Raw material: 50 parts of cis- 11- hexadecenal, cis- 4~10 parts of 13- octadecene aldehyde, 4~10 parts of Z-9-hexadecenal and
0.4~200 part of cis- 11- hexadecenol.In gyplure of the present invention, cis- 11- hexadecenal, cis- 13- octadecene
Aldehyde is necessary active component, plays remote attracting action, and Z-9-hexadecenal and cis- 11- hexadecenol are through field
It has very strong activity for test confirmation, significantly increases landing and flutter its wings up and down equal behavior reactions of the male moth in short distance.
The present invention also provides a kind of lures comprising the gyplure, are proved by a large amount of field trial, can be substantially
Degree improves the trapping effect of striped rice borer gyplure, is embodied in that trapping amount is big, attractant effect is stablized, and solves current striped rice borer property letter
Cease the bad problem of plain control efficiency；To safety of human and livestock, no pollution to the environment, and the use of pesticide can be reduced；Use cost compared with
Low, easy to operate, prediction and prevention and treatment applied to striped rice borer have preferable social economy and ecological benefits.
Specific embodiment
The present invention provides a kind of gyplure for luring striped rice borer, the active constituent of the gyplure includes following parts by weight
Raw material: 50 parts of cis- 11- hexadecenal, cis- 4~10 parts of 13- octadecene aldehyde, 4~10 parts of Z-9-hexadecenal and
0.4~200 part of cis- 11- hexadecenol.
It include cis- 11- hexadecenal (Z11-16:Ald), the Z11- in the active constituent of gyplure of the present invention
16:Ald can play its remote attracting action.There is no particular determinations in source of the present invention to the Z11-16:Ald, preferably
The Z11-16:Ald n-compound for being purity up to 98% or more.
It include cis- 13- octadecene aldehyde (Z13-18:Ald), the Z13- in the active constituent of gyplure of the present invention
The parts by weight of 18:Ald are preferably 4~8 parts, more preferably 4~6 parts, most preferably 6 parts.Z13-18:Ald of the present invention can
Play its remote attracting action.To the source of the Z13-18:Ald there is no particular determination, preferably purity reaches the present invention
98% or more Z13-18:Ald n-compound.
Include in the active constituent of gyplure of the present invention Z-9-hexadecenal (Z9-16:Ald), the Z9-16:
The parts by weight of Ald are preferably 4~8 parts, more preferably 4~6 parts, most preferably 5 parts.Z9-16:Ald of the present invention can be played
Its short distance attracting action and attractant effect to striped rice borer hero moth can also be enhanced.The present invention carrys out the Z9-16:Ald
Source is there is no particular determination, preferably Z9-16:Ald n-compound of the purity up to 98% or more.
It include cis- 11- hexadecenol (Z11-16:OH), the Z11- in the active constituent of gyplure of the present invention
The parts by weight of 16:OH are preferably 2~100 parts, more preferably 2~80, most preferably 50 parts.Z11-16:OH of the present invention can
The attractant effect to striped rice borer hero moth is remarkably reinforced.There is no particular determinations in source of the present invention to the Z11-16:OH, preferably
The Z11-16:OH n-compound for being purity up to 98% or more.
It is also preferable to include antioxidants and uvioresistant light stabilizer in gyplure of the present invention；The antioxidant with
The mass ratio of cis- 11- hexadecenal is preferably 0.002~0.02:1, more preferably 0.008~0.02:1, most preferably
0.01:1.Antioxidant of the present invention preferably includes 2,6 di tert butyl 4 methyl phenol (BHT), di-tert-butyl to benzene two
One of phenol (DTBHQ) and antioxidant 168 or a variety of mixing.Antioxidant of the present invention can prevent sex pheromone group
The oxidation of aldehydes component in point.There is no particular determinations in source of the present invention to the antioxidant, utilize the routine of this field
Reagent.
The mass ratio of uvioresistant light stabilizer of the present invention and cis- 11- hexadecenal is preferably 0.002~
0.02:1, more preferably 0.008~0.02:1, most preferably 0.01:1.Uvioresistant light stabilizer of the present invention preferably wraps
Include hindered amines uvioresistant light stabilizer；The hindered amines uvioresistant light stabilizer preferably includes UV-328, UV-
531 and UV-P.Uvioresistant light stabilizer of the present invention can keep aldehydes component in sex pheromone component relatively stable.This
There is no particular determinations in source of the invention to the uvioresistant light stabilizer, utilize the conventional reagent of this field.
The present invention also provides a kind of lure for luring striped rice borer, including the gyplure, the content of the gyplure is
0.05~50mg/ lure.It is also preferable to include release, the materials of the release to preferably include naturally for lure of the present invention
Rubber, synthetic rubber, polyethylene, polyvinyl chloride, resin or mucilage materials.Release of the present invention can be described in slow release
Gyplure.
The raw material of the gyplure is each configured to steam hexane solution again, is added to release after mixing in proportion
(after such as sillicon rubber blocking after solvent volatilizees naturally) to obtain the final product.Below with reference to embodiment to the property provided by the invention for luring striped rice borer
Lure and lure are described in detail, but they cannot be interpreted as limiting the scope of the present invention.
Embodiment 1
Test site: the Jiaxing City, Zhejiang Province town Guang Chen.
Reagent: along 11- hexadecenal (Z11-16:Ald) n-compound, along 13- octadecene aldehyde (Z13-18:
Ald) n-compound, suitable 9- hexadecenal (Z9-16:Ald), cis- 11- hexadecenol (Z11-16:OH) standard chemical combination
Object purity is 98% or more.
Lure preparation: will be along 11- hexadecenal, suitable 13- octadecene aldehyde, suitable 9- hexadecenal, cis- 11- 16
Carbene alcohol is each configured to certain density heavy steaming hexane solution.Sillicon rubber blocking is added to after mixing by the mass ratio of setting
To obtain the final product.
Formula: cis- 410 μ g of 11- hexadecenal (Z11-16:Ald) and cis- 13- octadecene aldehyde (Z13-18:Ald)
50 μ g and 40 μ g of Z-9-hexadecenal (Z9-16:Ald) and cis- 25 μ g of 11- hexadecenol (Z11-16:OH)；Uvioresistant
Linear light stabilizer UV-3284.1 μ g, 4.1 μ g of antioxidant BHT.
Comparative example 1
Formula: cis- 410 μ g of 11- hexadecenal (Z11-16:Ald) and cis- 13- octadecene aldehyde (Z13-18:Ald)
40 μ g of 50 μ g and Z-9-hexadecenal (Z9-16:Ald).
The lure that embodiment 1 and comparative example 1 are prepared is tested:
It tests and is carried out on May 3rd~21,2019.5 repetitions are arranged in each processing, select ship type trapper, each
Trapper places a lure.Trapper is set to wheatland, be above the ground level 1.5m, and every mono- trapper of 15m, different disposal is handed over
The quantity for the striped rice borer traped was counted every 2 days every the haftplatte of replacement in 5 days for placement.Every time after investigation, exchange is lured
The position of device is caught, is reduced by a small range striped rice borer quantity variance bring error.
It counts lure and lures the effect of striped rice borer in field, as shown in table 1,
The different sex pheromone lure core formula striped rice borer field attractant effects of table 1 compare
From table 1 it follows that the average induced moth number of embodiment 1 is higher by 72.89% than the average induced moth number of comparative example 1.
Embodiment 2
Test site: the Jiaxing City, Zhejiang Province town Guang Chen.
Lure preparation: will be along 11- hexadecenal, suitable 13- octadecene aldehyde, suitable 9- hexadecenal, cis- 11- 16
Carbene alcohol is each configured to certain density heavy steaming hexane solution.Sillicon rubber blocking is added to after mixing by the mass ratio of setting
To obtain the final product.
Formula: cis- 250 μ g of 11- hexadecenal (Z11-16:Ald) and cis- 13- octadecene aldehyde (Z13-18:Ald)
30 μ g and 25 μ g of Z-9-hexadecenal (Z9-16:Ald) and cis- 500 μ g of 11- hexadecenol (Z11-16:OH)；Uvioresistant
Linear light stabilizer UV-5312.5 μ g, 2.5 μ g of antioxidant BHT.
Comparative example 2
Formula: cis- 250 μ g of 11- hexadecenal (Z11-16:Ald) and cis- 13- octadecene aldehyde (Z13-18:Ald)
25 μ g of 30 μ g and Z-9-hexadecenal (Z9-16:Ald).
The lure that embodiment 2 and comparative example 2 are prepared is tested:
It tests and is carried out 17~May 19 April in 2019.4 repetitions are arranged in each processing, and novel moth class is selected to trap
Device, each trapper place a lure.Trapper is set to wheatland, be above the ground level 1.5m, every mono- trapper of 15m, no
It is alternately placed with processing, the quantity for the striped rice borer traped was counted every 7 days or so.Every time after investigation, the position of trapper is exchanged
It sets, reduces by a small range striped rice borer quantity variance bring error.
It counts lure and lures the effect of striped rice borer in field, as shown in table 2,
The different sex pheromone lure core formula striped rice borer field attractant effects of table 2 compare
From Table 2, it can be seen that the average induced moth number of embodiment 2 is higher by 101.04% than the average induced moth number of comparative example 2.
Embodiment 3
Test site: the Jiaxing City, Zhejiang Province town Guang Chen.
Lure preparation: will be along 11- hexadecenal, suitable 13- octadecene aldehyde, suitable 9- hexadecenal, cis- 11- 16
Carbene alcohol is each configured to certain density heavy steaming hexane solution.Sillicon rubber blocking is added to after mixing by the mass ratio of setting
In to obtain the final product.
Formula: cis- 250 μ g of 11- hexadecenal (Z11-16:Ald) and cis- 13- octadecene aldehyde (Z13-18:Ald)
30 μ g and 25 μ g of Z-9-hexadecenal (Z9-16:Ald) and cis- 1000 μ g of 11- hexadecenol (Z11-16:OH)；Anti- purple
Outside line light stabilizer UV-5312.5 μ g, 2.5 μ g of antioxidant BHT.
Comparative example 3
Formula: cis- 250 μ g of 11- hexadecenal (Z11-16:Ald) and cis- 13- octadecene aldehyde (Z13-18:Ald)
25 μ g of 30 μ g and Z-9-hexadecenal (Z9-16:Ald).
The lure that embodiment 3 and comparative example 3 are prepared is tested:
It tests and is carried out 17~May 19 April in 2019.4 repetitions are arranged in each processing, and novel moth class is selected to trap
Device, each trapper place a lure.Trapper is set to wheatland, be above the ground level 1.5m, every mono- trapper of 15m, no
It is alternately placed with processing, the quantity for the striped rice borer traped was counted every 7 days or so.Every time after investigation, the position of trapper is exchanged
It sets, reduces by a small range striped rice borer quantity variance bring error.
It counts lure and lures the effect of striped rice borer in field, as shown in table 3,
The different sex pheromone lure core formula striped rice borer field attractant effects of table 3 compare
From table 3 it is observed that the average induced moth number of embodiment 3 is higher by 96.01% than the average induced moth number of comparative example 3.
The present invention provides a kind of gyplure for luring striped rice borer and lures, can significantly increase for striped rice borer in addition
Attractant effect to safety of human and livestock, no pollution to the environment, and can reduce the use of pesticide.Use cost is lower, easy to operate,
It can be applied to prediction and the prevention and treatment of striped rice borer, there are preferable social economy and ecological benefits.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
For member, various improvements and modifications may be made without departing from the principle of the present invention, these improvements and modifications are also answered
It is considered as protection scope of the present invention.
Claims (6)
1. a kind of gyplure for luring striped rice borer, which is characterized in that the active constituent of the gyplure includes following parts by weight
Raw material: 50 parts of cis- 11- hexadecenal, cis- 4~10 parts of 13- octadecene aldehyde, 4~10 parts of Z-9-hexadecenal and cis-
0.4~200 part of 11- hexadecenol.
2. gyplure according to claim 1, which is characterized in that further include antioxidant and uvioresistant in the gyplure
Light stabilizer；The mass ratio of the antioxidant and cis- 11- hexadecenal is 0.002~0.02:1；The uvioresistant linear light
The mass ratio of stabilizer and cis- 11- hexadecenal is 0.002~0.02:1.
3. gyplure according to claim 2, which is characterized in that the antioxidant includes 2,6- di-t-butyl -4- methyl
Phenol, ditert-butylhydro quinone and antioxidant 168.
4. gyplure according to claim 2, which is characterized in that the uvioresistant light stabilizer includes the anti-purple of hindered amines
Outside line light stabilizer；The hindered amines uvioresistant light stabilizer includes UV-328, UV-531 and UV-P.
5. a kind of lure for luring striped rice borer, which is characterized in that including any one of Claims 1 to 4 gyplure, the property
The content of lure is 0.05~50mg/ lure.
6. lure according to claim 5, which is characterized in that the lure further includes release, the material of the release
Including natural rubber, synthetic rubber, polyethylene, polyvinyl chloride, resin or mucilage materials.
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| CN201910689464.0A CN110292040A (en) | 2019-07-29 | 2019-07-29 | A kind of gyplure that luring striped rice borer and lure |
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| CN201910689464.0A CN110292040A (en) | 2019-07-29 | 2019-07-29 | A kind of gyplure that luring striped rice borer and lure |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111449066A (en) * | 2020-05-06 | 2020-07-28 | 湖北省农业科学院植保土肥研究所 | Chilo suppressalis sex attractant and Chilo suppressalis sex attractant long-acting volatile core |
| CN111685136A (en) * | 2020-05-22 | 2020-09-22 | 深圳市鑫稻田农业技术科技有限公司 | Compound insect sex pheromone preparation and preparation method thereof |
| CN111713469A (en) * | 2020-05-22 | 2020-09-29 | 深圳市鑫稻田农业技术科技有限公司 | Trapping device with compound insect sex pheromone attracting core and application thereof |
| CN114052014A (en) * | 2021-11-19 | 2022-02-18 | 中捷四方生物科技股份有限公司 | Application of insect sex pheromone cis-13-octadecene aldehyde analogue |
| CN114788522A (en) * | 2022-04-25 | 2022-07-26 | 江苏宁录科技股份有限公司 | Compound sex pheromone solution and slow-release spraying device |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111449066A (en) * | 2020-05-06 | 2020-07-28 | 湖北省农业科学院植保土肥研究所 | Chilo suppressalis sex attractant and Chilo suppressalis sex attractant long-acting volatile core |
| CN111449066B (en) * | 2020-05-06 | 2023-12-01 | 湖北省农业科学院植保土肥研究所 | Chilo suppressalis sex attractant and long-acting volatilizing core thereof |
| CN111685136A (en) * | 2020-05-22 | 2020-09-22 | 深圳市鑫稻田农业技术科技有限公司 | Compound insect sex pheromone preparation and preparation method thereof |
| CN111713469A (en) * | 2020-05-22 | 2020-09-29 | 深圳市鑫稻田农业技术科技有限公司 | Trapping device with compound insect sex pheromone attracting core and application thereof |
| CN114052014A (en) * | 2021-11-19 | 2022-02-18 | 中捷四方生物科技股份有限公司 | Application of insect sex pheromone cis-13-octadecene aldehyde analogue |
| CN114788522A (en) * | 2022-04-25 | 2022-07-26 | 江苏宁录科技股份有限公司 | Compound sex pheromone solution and slow-release spraying device |
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