CN110255632B - 用含钌废料制备三氯化钌的方法 - Google Patents
用含钌废料制备三氯化钌的方法 Download PDFInfo
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- CN110255632B CN110255632B CN201910645571.3A CN201910645571A CN110255632B CN 110255632 B CN110255632 B CN 110255632B CN 201910645571 A CN201910645571 A CN 201910645571A CN 110255632 B CN110255632 B CN 110255632B
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- CN
- China
- Prior art keywords
- ruthenium
- containing waste
- trichloride
- roasting
- rucl
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 title claims abstract description 69
- 229910052707 ruthenium Inorganic materials 0.000 title claims abstract description 66
- YBCAZPLXEGKKFM-UHFFFAOYSA-K ruthenium(iii) chloride Chemical compound [Cl-].[Cl-].[Cl-].[Ru+3] YBCAZPLXEGKKFM-UHFFFAOYSA-K 0.000 title claims abstract description 44
- 239000002699 waste material Substances 0.000 title claims abstract description 38
- 238000000034 method Methods 0.000 title claims abstract description 21
- 238000006243 chemical reaction Methods 0.000 claims abstract description 31
- 238000002360 preparation method Methods 0.000 claims abstract description 27
- BZSXEZOLBIJVQK-UHFFFAOYSA-N 2-methylsulfonylbenzoic acid Chemical compound CS(=O)(=O)C1=CC=CC=C1C(O)=O BZSXEZOLBIJVQK-UHFFFAOYSA-N 0.000 claims abstract description 20
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 20
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical compound BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims abstract description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000013078 crystal Substances 0.000 claims abstract description 8
- 238000001035 drying Methods 0.000 claims abstract description 8
- 238000003756 stirring Methods 0.000 claims abstract description 8
- 229910001927 ruthenium tetroxide Inorganic materials 0.000 claims abstract description 7
- 238000007603 infrared drying Methods 0.000 claims abstract description 5
- 238000010438 heat treatment Methods 0.000 claims abstract description 3
- BIXNGBXQRRXPLM-UHFFFAOYSA-K ruthenium(3+);trichloride;hydrate Chemical compound O.Cl[Ru](Cl)Cl BIXNGBXQRRXPLM-UHFFFAOYSA-K 0.000 claims abstract description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 14
- 229910052757 nitrogen Inorganic materials 0.000 claims description 7
- 238000010521 absorption reaction Methods 0.000 claims description 2
- 238000005265 energy consumption Methods 0.000 abstract description 5
- 239000000463 material Substances 0.000 description 15
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 8
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 8
- QZPSXPBJTPJTSZ-UHFFFAOYSA-N aqua regia Chemical compound Cl.O[N+]([O-])=O QZPSXPBJTPJTSZ-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 238000000605 extraction Methods 0.000 description 6
- 239000003054 catalyst Substances 0.000 description 5
- 238000001514 detection method Methods 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- 229910052763 palladium Inorganic materials 0.000 description 4
- 229910052697 platinum Inorganic materials 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000005708 Sodium hypochlorite Substances 0.000 description 3
- 229910052801 chlorine Inorganic materials 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 238000007210 heterogeneous catalysis Methods 0.000 description 1
- 238000007172 homogeneous catalysis Methods 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 238000006317 isomerization reaction Methods 0.000 description 1
- NCPHGZWGGANCAY-UHFFFAOYSA-N methane;ruthenium Chemical compound C.[Ru] NCPHGZWGGANCAY-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 150000003303 ruthenium Chemical class 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G55/00—Compounds of ruthenium, rhodium, palladium, osmium, iridium, or platinum
- C01G55/005—Halides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
Description
项目 | 实施例1 | 实施例2 | 实施例3 | 实施例4 | 对比实施例 |
反应温度/℃ | 100 | 60 | 80 | 70 | 80 |
反应时间/h | 1.5 | 6 | 3 | 2.5 | 8 |
结晶钌含量/% | 37.16 | 37.23 | 37.18 | 37.21 | 37.08 |
产品收率/% | 99.17 | 99.09 | 99.27 | 99.06 | 13.54 |
Claims (5)
Priority Applications (1)
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CN201910645571.3A CN110255632B (zh) | 2019-07-17 | 2019-07-17 | 用含钌废料制备三氯化钌的方法 |
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CN201910645571.3A CN110255632B (zh) | 2019-07-17 | 2019-07-17 | 用含钌废料制备三氯化钌的方法 |
Publications (2)
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CN110255632A CN110255632A (zh) | 2019-09-20 |
CN110255632B true CN110255632B (zh) | 2021-05-25 |
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CN201910645571.3A Expired - Fee Related CN110255632B (zh) | 2019-07-17 | 2019-07-17 | 用含钌废料制备三氯化钌的方法 |
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Families Citing this family (1)
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CN115745031B (zh) * | 2022-11-02 | 2024-02-02 | 金川集团股份有限公司 | 一种三氯化钌的制备方法 |
Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1174477A (en) * | 1966-11-03 | 1969-12-17 | Commissariat Energie Atomique | Method of Decontamination of Media Containing Fission Products. |
CN101462778A (zh) * | 2007-12-20 | 2009-06-24 | 中国蓝星(集团)股份有限公司 | 一种三氯化钌的制备方法 |
CN101519732A (zh) * | 2008-02-26 | 2009-09-02 | 日矿金属株式会社 | 从含有钌的废料中回收钌的方法 |
CN101891261A (zh) * | 2010-08-31 | 2010-11-24 | 郴州高鑫铂业有限公司 | 一种粗钌粉制备三氯化钌的方法 |
US20110165041A1 (en) * | 2008-01-30 | 2011-07-07 | W.C. Heraeus Gmbh | Processess for the recovery of ruthenium from materials containing ruthenium or ruthenium oxides or from ruthenium-containing noble metal ore concentrates |
CN103626240B (zh) * | 2013-12-15 | 2016-03-30 | 郴州高鑫铂业有限公司 | 低浓度复杂含钌废液制备三氯化钌的方法 |
CN106335932A (zh) * | 2016-08-30 | 2017-01-18 | 昆明铂磊科技有限公司 | 一种三氯化钌的生产工艺 |
CN207347184U (zh) * | 2017-09-21 | 2018-05-11 | 昆明铂锐金属材料有限公司 | 一种用于四氧化钌制取三氯化钌的反应容器 |
CN108396145A (zh) * | 2018-02-23 | 2018-08-14 | 鲁西催化剂有限公司 | 一种苯加氢制环己烯催化剂中回收钌的方法 |
-
2019
- 2019-07-17 CN CN201910645571.3A patent/CN110255632B/zh not_active Expired - Fee Related
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1174477A (en) * | 1966-11-03 | 1969-12-17 | Commissariat Energie Atomique | Method of Decontamination of Media Containing Fission Products. |
CN101462778A (zh) * | 2007-12-20 | 2009-06-24 | 中国蓝星(集团)股份有限公司 | 一种三氯化钌的制备方法 |
US20110165041A1 (en) * | 2008-01-30 | 2011-07-07 | W.C. Heraeus Gmbh | Processess for the recovery of ruthenium from materials containing ruthenium or ruthenium oxides or from ruthenium-containing noble metal ore concentrates |
CN101519732A (zh) * | 2008-02-26 | 2009-09-02 | 日矿金属株式会社 | 从含有钌的废料中回收钌的方法 |
CN101891261A (zh) * | 2010-08-31 | 2010-11-24 | 郴州高鑫铂业有限公司 | 一种粗钌粉制备三氯化钌的方法 |
CN103626240B (zh) * | 2013-12-15 | 2016-03-30 | 郴州高鑫铂业有限公司 | 低浓度复杂含钌废液制备三氯化钌的方法 |
CN106335932A (zh) * | 2016-08-30 | 2017-01-18 | 昆明铂磊科技有限公司 | 一种三氯化钌的生产工艺 |
CN207347184U (zh) * | 2017-09-21 | 2018-05-11 | 昆明铂锐金属材料有限公司 | 一种用于四氧化钌制取三氯化钌的反应容器 |
CN108396145A (zh) * | 2018-02-23 | 2018-08-14 | 鲁西催化剂有限公司 | 一种苯加氢制环己烯催化剂中回收钌的方法 |
Non-Patent Citations (2)
Title |
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Density functionalized Ru(NO)(Salen)(Cl)complex:Computational photodynamics and in vitro anticancer facets;Jan Mohammad Mir et al.;《Photodlagnosis and Photodynamic Therapy》;20170722;第19卷;第363-374页 * |
Direct Synthesis of Bis(indolyl)methanes:Ruthenium catalyzed reaction of benzylic alcoholes and indoles;Ning Wang et al.;《Conference on Environmental Pollution and Public Health》;20111231;第238-241页 * |
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TA01 | Transfer of patent application right | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20210111 Address after: Fengshou Industrial Park, Wannian County, Shangrao City, Jiangxi Province (in Jiangxi Xinyu precious metal Co., Ltd.) Applicant after: JIANGXI HANS PRECIOUS METALS Co.,Ltd. Address before: Fengshou Industrial Park, Wannian County, Shangrao City, Jiangxi Province (in Jiangxi Xinyu precious metal Co., Ltd.) Applicant before: Jiangxi Hanhao New Materials Co.,Ltd. |
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GR01 | Patent grant | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Preparation of ruthenium trichloride from ruthenium containing waste Effective date of registration: 20221025 Granted publication date: 20210525 Pledgee: Wannian Sub branch of Shangrao Bank Co.,Ltd. Pledgor: JIANGXI HANS PRECIOUS METALS CO.,LTD. Registration number: Y2022980019692 |
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CF01 | Termination of patent right due to non-payment of annual fee | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20210525 |