CN110250083A - A kind of seawater fish jar with purification of water quality ability makes scape stone and preparation method thereof - Google Patents
A kind of seawater fish jar with purification of water quality ability makes scape stone and preparation method thereof Download PDFInfo
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- CN110250083A CN110250083A CN201910371888.2A CN201910371888A CN110250083A CN 110250083 A CN110250083 A CN 110250083A CN 201910371888 A CN201910371888 A CN 201910371888A CN 110250083 A CN110250083 A CN 110250083A
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 108
- 239000004575 stone Substances 0.000 title claims abstract description 45
- 241000251468 Actinopterygii Species 0.000 title claims abstract description 42
- 239000013535 sea water Substances 0.000 title claims abstract description 34
- 238000000746 purification Methods 0.000 title claims abstract description 28
- 238000002360 preparation method Methods 0.000 title claims abstract description 22
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 51
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims abstract description 48
- 239000012153 distilled water Substances 0.000 claims abstract description 26
- 239000000758 substrate Substances 0.000 claims abstract description 23
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000007822 coupling agent Substances 0.000 claims abstract description 15
- 229960000935 dehydrated alcohol Drugs 0.000 claims abstract description 12
- 238000007146 photocatalysis Methods 0.000 claims abstract description 9
- 230000001699 photocatalysis Effects 0.000 claims abstract description 9
- 235000019441 ethanol Nutrition 0.000 claims description 25
- 238000001035 drying Methods 0.000 claims description 22
- 238000002604 ultrasonography Methods 0.000 claims description 15
- 229960004756 ethanol Drugs 0.000 claims description 14
- 238000004519 manufacturing process Methods 0.000 claims description 11
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 10
- 239000007788 liquid Substances 0.000 claims description 10
- 239000011259 mixed solution Substances 0.000 claims description 10
- 239000010865 sewage Substances 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- 239000000725 suspension Substances 0.000 claims description 10
- 239000003643 water by type Substances 0.000 claims description 10
- 235000014653 Carica parviflora Nutrition 0.000 claims description 7
- 241000243321 Cnidaria Species 0.000 claims description 6
- 241000195493 Cryptophyta Species 0.000 claims description 5
- 230000015572 biosynthetic process Effects 0.000 claims description 5
- 230000001680 brushing effect Effects 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 5
- 238000005520 cutting process Methods 0.000 claims description 5
- 238000000605 extraction Methods 0.000 claims description 5
- 229910052736 halogen Inorganic materials 0.000 claims description 5
- 150000002367 halogens Chemical class 0.000 claims description 5
- 238000005286 illumination Methods 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- 230000007935 neutral effect Effects 0.000 claims description 5
- 238000005201 scrubbing Methods 0.000 claims description 5
- 239000000243 solution Substances 0.000 claims description 5
- 238000005507 spraying Methods 0.000 claims description 5
- 239000004408 titanium dioxide Substances 0.000 claims description 5
- 238000001354 calcination Methods 0.000 claims description 4
- 239000010936 titanium Substances 0.000 claims description 4
- 229910052719 titanium Inorganic materials 0.000 claims description 4
- 238000009210 therapy by ultrasound Methods 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims 1
- 241000894006 Bacteria Species 0.000 abstract description 14
- 239000000463 material Substances 0.000 abstract description 11
- 241000108664 Nitrobacteria Species 0.000 abstract description 4
- 238000006555 catalytic reaction Methods 0.000 abstract description 2
- 238000009364 mariculture Methods 0.000 abstract description 2
- 238000001228 spectrum Methods 0.000 abstract description 2
- 238000000354 decomposition reaction Methods 0.000 description 7
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 238000004172 nitrogen cycle Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 3
- 230000009471 action Effects 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
- JVMRPSJZNHXORP-UHFFFAOYSA-N ON=O.ON=O.ON=O.N Chemical compound ON=O.ON=O.ON=O.N JVMRPSJZNHXORP-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000006396 nitration reaction Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 230000000384 rearing effect Effects 0.000 description 2
- 241001148471 unidentified anaerobic bacterium Species 0.000 description 2
- 239000002028 Biomass Substances 0.000 description 1
- 244000132059 Carica parviflora Species 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- HGWOWDFNMKCVLG-UHFFFAOYSA-N [O--].[O--].[Ti+4].[Ti+4] Chemical compound [O--].[O--].[Ti+4].[Ti+4] HGWOWDFNMKCVLG-UHFFFAOYSA-N 0.000 description 1
- MMDJDBSEMBIJBB-UHFFFAOYSA-N [O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[NH6+3] Chemical compound [O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[NH6+3] MMDJDBSEMBIJBB-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000004099 anaerobic respiration Effects 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- 230000000721 bacterilogical effect Effects 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 230000001546 nitrifying effect Effects 0.000 description 1
- 229910000069 nitrogen hydride Inorganic materials 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- 230000029553 photosynthesis Effects 0.000 description 1
- 238000010672 photosynthesis Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000029058 respiratory gaseous exchange Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01K—ANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
- A01K63/00—Receptacles for live fish, e.g. aquaria; Terraria
- A01K63/04—Arrangements for treating water specially adapted to receptacles for live fish
- A01K63/045—Filters for aquaria
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C5/00—Processes for producing special ornamental bodies
- B44C5/06—Natural ornaments; Imitations thereof
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Environmental Sciences (AREA)
- Marine Sciences & Fisheries (AREA)
- Animal Husbandry (AREA)
- Biodiversity & Conservation Biology (AREA)
- Farming Of Fish And Shellfish (AREA)
Abstract
The invention discloses a kind of seawater fish jars with purification of water quality ability to make scape stone and preparation method thereof, belong to culture of ornamental fish field of water quality purification, it includes modified nano-titanium dioxide, distilled water, dehydrated alcohol, TC-201 titanate coupling agent and one plot of substrate reef which, which makes scape stone,.Traditional photocatalysis filter material (nano-titanium dioxide) and traditional used in mariculture landscape filter material (making scape stone) (making scape stone while and the good attachment base of nitrobacteria) are combined together by the present invention, both the water purification ability of catalysis material efficient pollution-free had been possessed, separate space is not needed again to be aided with intensive ultraviolet light irradiation (seawater fish tank lighting system is usually full spectrum, and it is big to make scape stone area, it does not need additionally to increase ultraviolet light source), the demand of Berlin system is also met simultaneously, the scape stone of making for having loaded nano-titanium dioxide remains to adhere to a certain amount of bacterium, make to have reached compatibility by Berlin fish culture and photocatalysis water-purifying material of ecological circulation bacterium water purification.
Description
Technical field
The invention belongs to culture of ornamental fish water purification technology fields, and in particular to a kind of sea with purification of water quality ability
Water fish cylinder makes scape stone and preparation method thereof.
Background technique
In ornamental type raising water environment (aquarium water environment) and intensive cultivation water environment (aquatic products industry water environment), nitrogen
Element main source is the decomposition of residual feed residue, biological excrement, untreated biological corpse and killed bacterial etc..
The decomposition of organic matter mainly consists of two parts: physical decomposition and biological decomposition.
Bulk itrogenous organic substance in water is under the agitation of middle rank repeatedly of water flow, silt and biology gradually by physical decomposition
For organic debris.These organic debrises enter biological decomposition link under the action of microorganism.In the first rank of the link
Section --- in the oxidation of coal stage, organic debris is gradually decomposed and is generated carbon dioxide and ammonia nitrogen (NH3-N), the substance often with
The form of NH4+NH3 discharges in water.
Second stage is referred to as the nitrifying process of ammonia nitrogen, and ammonia nitrogen (aerobic) under the action of nitrite bacteria is oxidized decomposition
For nitrite (NO2-) and continue (to nitrify and breathe) (aerobic) oxygenolysis under the action of nitrobacteria to be nitrate
(NO3-).Because oxygen is indispensable ingredient in the reaction of second stage, therefore it also referred to as likes the oxygen stage, and participates in it
In bacterium be collectively referred to as aerophile bacteria.
And in the oxygen-free environment of water body, it may occur that the phase III dominated by denitrifying bacteria --- denitrification rank
Section.The denitrifying bacteria of anaerobism will remove the oxygen in nitrate (NO3-) by anaerobic respiration (denitrification) in this stage
So that it is reduced to nitrite (NO2-), is further reduced to the ammonia or nitrogen of free state.According to the characteristic in this stage, I
Be usually referred to as anaerobic stages (reduction phase), and the bacterium participated also is collectively referred to as anaerobic bacteria.Phase III
It is the pith of water body nitrogen cycle, the itrogenous organic substance in water is finally discharged in gaseous form for it, therefore it is also claimed
For denitrogenation effect.
Currently, the features such as Shui nationality raising has intensive, high-density rearing, and breeding species are various.Due to mass rearing person
It covets and biomass and largely launches bait, to make a large amount of organic debrises accumulate, so that the happiness oxygen bacterium in the happiness oxygen stage
It is chronically at overload state.
This state can make the happiness oxygen stage seriously be obstructed, and nitration reaction is difficult to go on smoothly.This will lead in nitration reaction
A variety of harmful intermediate organic products based on nitrite nitrogen, ammonia nitrogen can not decompose, and pass through denitrification (anaerobism rank
Section) it accumulates repeatedly.Organic product can cause to seriously endanger to aquatic organism among these nocuousness, and wherein ammonia nitrogen can invade mucosal injury
Fish gill tissue, and nitrite nitrogen is mainly the breathing for hindering biology, also can seriously hinder the nitrification of nitrobacteria.Although
Nitrate nitrogen acts on toxicity to fish smaller.But the photosynthesis that zooxanthellae in coral can be interfered when its excessive accumulation, causes
Coral bleaching is dead.
Since cultivation know-how is limited, culturists usually unilaterally with fish to cultivate core, have ignored water quality and bacterium
The importance of class, What is more due to being influenced by traditional concept, and bacterium is defined as nuisance simply, in water a large amount of additions
Class medicament is sterilized, aerophile bacteria vital in water quality nitrogen cycle and anaerobic bacteria are killed together with pathogenic bacteria, finally led
Cause nitrogen cycle in water that can not carry out, ammonia nitrogen largely accumulates and fish death is made to cause expensive losses.
To solve variety of problems present in water circulation system and nitrogen cycle, raiser and culturists develop a variety of use
In the filter plant and filter material of purification of water quality.
But above filter material has its limitation, in the briny environment with certain corrosivity and chemical condition complexity,
Emulsion paint and air pearl are difficult to keep its stability, and easy disintegration causes secondary pollution, and ceramic bead is sunken to the bottom, response area
It is small, low efficiency, and the particulate matter that still will continue to absorb other partial sizes in water after activated carbon supported nano-titanium dioxide is led
Reaction efficiency is caused to reduce rapidly.In addition, above-mentioned filter material is required to occupy independent fish jar space and is aided with intensive ultraviolet light irradiation,
This with it is traditional incompatible with by Berlin fish culture of bacteriological purification water quality.
Summary of the invention
The purpose of the present invention is to provide a kind of seawater fish jars with purification of water quality ability to make scape stone and preparation method thereof,
To solve the problems mentioned in the above background technology.
To achieve the above object, the invention provides the following technical scheme: a kind of seawater fish jar with purification of water quality ability
Scape stone is made, it includes modified nano-titanium dioxide, distilled water, dehydrated alcohol, the coupling of TC-201 titanate esters which, which makes scape stone,
Agent and one plot of substrate reef.
A kind of production method that the seawater fish jar with purification of water quality ability makes scape stone, including preparing sea described herein
Water fish cylinder makes scape stone, which includes the following steps:
S1, modified nano-titanium dioxide and substrate reef are prepared；
S2, the mixed solution for taking 100ml distilled water and 10ml dehydrated alcohol, are slowly added to TC-201 titanate coupling agent
5ml stirs 10min；
S3,10g modified nano-titanium dioxide is added into mixed solution made from S2, ultrasonic certain time, is obtained after stirring
Obtain dispersed preferable pair of nano-titanium dioxide suspension；
S4, suspension obtained in S3 is attached to substrate reef surface obtained in S1 by way of brushing or spraying,
Naturally dry reef；
S5, repeat step S4 tri- to five times after reef is placed in water tank, be added distilled water to liquid level do not had reef and by
According to 5L/min extraction water simultaneously, it is known that the liquid shows neutral of releasing, limpid and do not observe nanometer under a scanning electron microscope
Titanium dioxide；
S6, reef is taken out, reef is placed in baking oven dry；
S7, the reef after drying is placed on Muffle kiln roasting, the photocatalysis water-purifying sea based on nano-titanium dioxide is made
Water fish cylinder makes scape stone.
Preferably, the preparation method of modified nano-titanium dioxide includes the following steps: in S1
S1011, it weighs more than 1g nano-titanium dioxide in 500ml conical flask, sequentially adds 40ml distilled water, 65ml sewage second
It shakes up, closes the lid after pure and mild 0.1gTC-201 titanate coupling agent；
S1012, conical flask is placed in 46 DEG C of waters bath with thermostatic control after ultrasound 2h, the sewage ethyl alcohol of 25ml is added, be added anhydrous
After ethyl alcohol, conical flask is placed in ultrasound 1h in 50 DEG C of waters bath with thermostatic control again；
S1013, the solution after water bath with thermostatic control ultrasound is dried in certain temperature environment；
S1014, modified nano-titanium dioxide obtained in S1013 is placed in the conical flask of 200ml, it is anhydrous that 25ml is added
Ethyl alcohol shakes up and is placed on the obtained modified nano-titanium dioxide of natural drying in shading environment.
Preferably, the preparation method of substrate reef includes the following steps: in S1
S1021, the coral reef for taking one piece of self-assembling formation, and place it in a water tank equipped with seawater, and make water tank
Interior water did not had the reef；
S1022, be persistently aerated using air pump and irradiate this reef using Metal halogen lamp, and guarantee illumination 20000lx with
On, daily light application time is no less than 16 hours；
S1023, after bearing dense green filiform bath after reef and water tank surface, reef is pulled out, and net cutting, scrubbing
After surface algae and other attachments, reef is immersed in the alcohol that concentration is 70% and impregnates 4h；
S1024, the reef that alcohol in S1023 impregnates is submerged in distilled water and boils 12h, be placed in oven and dried；
S1025, the reef after drying is placed in Muffle kiln roasting, after air natural cooling, obtains the reef of clean dried
Stone.
Preferably, the time stirred in S3 is 20-40min, and the time of ultrasonic treatment is 55-75min.
Preferably, the temperature of baking oven is 100-150 DEG C in S6, and drying time is the roasting of Muffle furnace in 90-150minS7
Temperature is 500-700 DEG C, calcining time 5-8h.
Preferably, the temperature of drying environment is 50-70 DEG C in S1013, drying time 30-90min.
Preferably, the temperature of baking oven is 100-140 DEG C in S1024, drying time 50-70min.
Preferably, the temperature that Muffle furnace roasts in S1025 is 200-400 DEG C, calcining time 5-7h.
Compared with prior art, the beneficial effects of the present invention are: the present invention is by traditional photocatalysis filter material (nanometer titanium dioxide
Titanium) and traditional used in mariculture landscape filter material (making scape stone) (making scape stone while and the good attachment base of nitrobacteria) combination
Together, the water purification ability of catalysis material efficient pollution-free had not only been possessed, but also has not needed separate space and be aided with intensive ultraviolet lamp photograph
(seawater fish tank lighting system is usually full spectrum, and it is big to make scape stone area, does not need additionally to increase ultraviolet light source) is penetrated, simultaneously
Also the demand for meeting Berlin system, the scape stone of making for having loaded nano-titanium dioxide remain to adhere to a certain amount of bacterium, make to pass through
Berlin fish culture and photocatalysis water-purifying material of ecological circulation bacterium water purification have reached compatibility.
Specific embodiment
Below with reference to embodiment, the present invention will be further described.
The following examples are intended to illustrate the invention, but cannot be used to limit the scope of the invention.Item in embodiment
Part can be adjusted according to actual conditions are further, under concept thereof of the invention all to method simple modifications of the invention
Belong to the scope of protection of present invention.
Embodiment 1
A kind of seawater fish jar with purification of water quality ability makes scape stone, and it includes modified nano-silica which, which makes scape stone,
Change titanium, distilled water, dehydrated alcohol, TC-201 titanate coupling agent and one plot of substrate reef.
Institute in a kind of production method that the seawater fish jar with purification of water quality ability makes scape stone, including preparation claim 1
The seawater fish jar stated makes scape stone, which includes the following steps:
S1, modified nano-titanium dioxide and substrate reef are prepared；
The preparation method of modified nano-titanium dioxide includes the following steps:
S1011, it weighs more than 1g nano-titanium dioxide in 500ml conical flask, sequentially adds 40ml distilled water, 65ml sewage second
It shakes up, closes the lid after pure and mild 0.1gTC-201 titanate coupling agent；
S1012, conical flask is placed in 46 DEG C of waters bath with thermostatic control after ultrasound 2h, the sewage ethyl alcohol of 25ml is added, be added anhydrous
After ethyl alcohol, conical flask is placed in ultrasound 1h in 50 DEG C of waters bath with thermostatic control again；
S1013, the solution after water bath with thermostatic control ultrasound is dried into 90min in 50 DEG C of environment；
S1014, modified nano-titanium dioxide obtained in S1013 is placed in the conical flask of 200ml, it is anhydrous that 25ml is added
Ethyl alcohol shakes up and is placed on the obtained modified nano-titanium dioxide of natural drying in shading environment.
The preparation method of substrate reef includes the following steps:
S1021, the coral reef for taking one piece of self-assembling formation, and place it in a water tank equipped with seawater, and make water tank
Interior water did not had the reef；
S1022, be persistently aerated using air pump and irradiate this reef using Metal halogen lamp, and guarantee illumination 20000lx with
On, daily light application time is no less than 16 hours；
S1023, after bearing dense green filiform bath after reef and water tank surface, reef is pulled out, and net cutting, scrubbing
After surface algae and other attachments, reef is immersed in the alcohol that concentration is 70% and impregnates 4h；
S1024, the reef that alcohol in S1023 impregnates is submerged in distilled water and boils 12h, be put into the baking that temperature is 100 DEG C
Dry 70min in case；
S1025, the reef after drying is placed in temperature for 200 DEG C of Muffle kiln roasting 7h, after air natural cooling, obtained
To the reef of clean dried.
S2, the mixed solution for taking 100ml distilled water and 10ml dehydrated alcohol, are slowly added to TC-201 titanate coupling agent
5ml stirs 10min；
S3,10g modified nano-titanium dioxide is added into mixed solution made from S2, after stirring 20min, ultrasonic 75min,
Obtain the nano-titanium dioxide suspension of preferable pair of dispersibility；
S4, suspension obtained in S3 is attached to substrate reef surface obtained in S1 by way of brushing or spraying,
Naturally dry reef；
S5, repeat step S4 tri- to five times after reef is placed in water tank, be added distilled water to liquid level do not had reef and by
According to 5L/min extraction water simultaneously, it is known that the liquid shows neutral of releasing, limpid and do not observe nanometer under a scanning electron microscope
Titanium dioxide；
S6, reef is taken out, reef is placed on dry 150min in the baking oven that temperature is 100；
S7, the reef after drying is placed on to the Muffle kiln roasting 8h that temperature is 500 DEG C, is made and is based on nano-titanium dioxide
Photocatalysis water-purifying seawater fish jar make scape stone.
Embodiment 2
A kind of seawater fish jar with purification of water quality ability makes scape stone, and it includes modified nano-silica which, which makes scape stone,
Change titanium, distilled water, dehydrated alcohol, TC-201 titanate coupling agent and one plot of substrate reef.
Institute in a kind of production method that the seawater fish jar with purification of water quality ability makes scape stone, including preparation claim 1
The seawater fish jar stated makes scape stone, which includes the following steps:
S1, modified nano-titanium dioxide and substrate reef are prepared；
The preparation method of modified nano-titanium dioxide includes the following steps:
S1011, it weighs more than 1g nano-titanium dioxide in 500ml conical flask, sequentially adds 40ml distilled water, 65ml sewage second
It shakes up, closes the lid after pure and mild 0.1gTC-201 titanate coupling agent；
S1012, conical flask is placed in 46 DEG C of waters bath with thermostatic control after ultrasound 2h, the sewage ethyl alcohol of 25ml is added, be added anhydrous
After ethyl alcohol, conical flask is placed in ultrasound 1h in 50 DEG C of waters bath with thermostatic control again；
S1013, the solution after water bath with thermostatic control ultrasound is dried into 60min in 60 DEG C of environment；
S1014, modified nano-titanium dioxide obtained in S1013 is placed in the conical flask of 200ml, it is anhydrous that 25ml is added
Ethyl alcohol shakes up and is placed on the obtained modified nano-titanium dioxide of natural drying in shading environment.
The preparation method of substrate reef includes the following steps:
S1021, the coral reef for taking one piece of self-assembling formation, and place it in a water tank equipped with seawater, and make water tank
Interior water did not had the reef；
S1022, be persistently aerated using air pump and irradiate this reef using Metal halogen lamp, and guarantee illumination 20000lx with
On, daily light application time is no less than 16 hours；
S1023, after bearing dense green filiform bath after reef and water tank surface, reef is pulled out, and net cutting, scrubbing
After surface algae and other attachments, reef is immersed in the alcohol that concentration is 70% and impregnates 4h；
S1024, the reef that alcohol in S1023 impregnates is submerged in distilled water and boils 12h, be put into the baking that temperature is 120 DEG C
Dry 60min in case；
S1025, the reef after drying is placed in temperature for 300 DEG C of Muffle kiln roasting 6h, after air natural cooling, obtained
To the reef of clean dried.
S2, the mixed solution for taking 100ml distilled water and 10ml dehydrated alcohol, are slowly added to TC-201 titanate coupling agent
5ml stirs 10min；
S3,10g modified nano-titanium dioxide is added into mixed solution made from S2, after stirring 30min, ultrasonic 60min,
Obtain the nano-titanium dioxide suspension of preferable pair of dispersibility；
S4, suspension obtained in S3 is attached to substrate reef surface obtained in S1 by way of brushing or spraying,
Naturally dry reef；
S5, repeat step S4 tri- to five times after reef is placed in water tank, be added distilled water to liquid level do not had reef and by
According to 5L/min extraction water simultaneously, it is known that the liquid shows neutral of releasing, limpid and do not observe nanometer under a scanning electron microscope
Titanium dioxide；
S6, reef is taken out, reef is placed on dry 120min in the baking oven that temperature is 120 DEG C；
S7, the reef after drying is placed on to the Muffle kiln roasting 6h that temperature is 600 DEG C, is made and is based on nano-titanium dioxide
Photocatalysis water-purifying seawater fish jar make scape stone.
Embodiment 3
A kind of seawater fish jar with purification of water quality ability makes scape stone, and it includes modified nano-silica which, which makes scape stone,
Change titanium, distilled water, dehydrated alcohol, TC-201 titanate coupling agent and one plot of substrate reef.
Institute in a kind of production method that the seawater fish jar with purification of water quality ability makes scape stone, including preparation claim 1
The seawater fish jar stated makes scape stone, which includes the following steps:
S1, modified nano-titanium dioxide and substrate reef are prepared；
The preparation method of modified nano-titanium dioxide includes the following steps:
S1011, it weighs more than 1g nano-titanium dioxide in 500ml conical flask, sequentially adds 40ml distilled water, 65ml sewage second
It shakes up, closes the lid after pure and mild 0.1gTC-201 titanate coupling agent；
S1012, conical flask is placed in 46 DEG C of waters bath with thermostatic control after ultrasound 2h, the sewage ethyl alcohol of 25ml is added, be added anhydrous
After ethyl alcohol, conical flask is placed in ultrasound 1h in 50 DEG C of waters bath with thermostatic control again；
S1013, the solution after water bath with thermostatic control ultrasound is dried into 30min in 70 DEG C of environment；
S1014, modified nano-titanium dioxide obtained in S1013 is placed in the conical flask of 200ml, it is anhydrous that 25ml is added
Ethyl alcohol shakes up and is placed on the obtained modified nano-titanium dioxide of natural drying in shading environment.
The preparation method of substrate reef includes the following steps:
S1021, the coral reef for taking one piece of self-assembling formation, and place it in a water tank equipped with seawater, and make water tank
Interior water did not had the reef；
S1022, be persistently aerated using air pump and irradiate this reef using Metal halogen lamp, and guarantee illumination 20000lx with
On, daily light application time is no less than 16 hours；
S1023, after bearing dense green filiform bath after reef and water tank surface, reef is pulled out, and net cutting, scrubbing
After surface algae and other attachments, reef is immersed in the alcohol that concentration is 70% and impregnates 4h；
S1024, the reef that alcohol in S1023 impregnates is submerged in distilled water and boils 12h, be put into the baking that temperature is 140 DEG C
Dry 50min in case；
S1025, the reef after drying is placed in temperature for 400 DEG C of Muffle kiln roasting 5h, after air natural cooling, obtained
To the reef of clean dried.
S2, the mixed solution for taking 100ml distilled water and 10ml dehydrated alcohol, are slowly added to TC-201 titanate coupling agent
5ml stirs 10min；
S3,10g modified nano-titanium dioxide is added into mixed solution made from S2, after stirring 40min, ultrasonic 55min,
Obtain the nano-titanium dioxide suspension of preferable pair of dispersibility；
S4, suspension obtained in S3 is attached to substrate reef surface obtained in S1 by way of brushing or spraying,
Naturally dry reef；
S5, repeat step S4 tri- to five times after reef is placed in water tank, be added distilled water to liquid level do not had reef and by
According to 5L/min extraction water simultaneously, it is known that the liquid shows neutral of releasing, limpid and do not observe nanometer under a scanning electron microscope
Titanium dioxide；
S6, reef is taken out, reef is placed on dry 90min in the baking oven that temperature is 150 DEG C；
S7, the reef after drying is placed on to the Muffle kiln roasting 5h that temperature is 700 DEG C, is made and is based on nano-titanium dioxide
Photocatalysis water-purifying seawater fish jar make scape stone.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding
And modification, the scope of the present invention is defined by the appended.
Claims (10)
1. a kind of seawater fish jar with purification of water quality ability makes scape stone, which is characterized in that it includes changing that the seawater fish jar, which makes scape stone,
Property nano-titanium dioxide, distilled water, dehydrated alcohol, TC-201 titanate coupling agent and one plot of substrate reef.
2. a kind of production method that the seawater fish jar with purification of water quality ability makes scape stone, including described in preparation claim 1
Seawater fish jar make scape stone, which is characterized in that the production method includes the following steps:
S1, modified nano-titanium dioxide and substrate reef are prepared；
S2, the mixed solution for taking 100ml distilled water and 10ml dehydrated alcohol are slowly added to TC-201 titanate coupling agent 5ml, stir
Mix 10min；
S3,10g modified nano-titanium dioxide is added into mixed solution made from S2, ultrasonic certain time, is divided after stirring
Dissipate the nano-titanium dioxide suspension of preferable pair of property；
S4, suspension obtained in S3 is attached to substrate reef surface obtained in S1 by way of brushing or spraying, it is natural
Dry reef；
S5, reef is placed in water tank after repeating step S4 tri- to five times, distilled water to liquid level is added and did not had reef and according to 5L/
Min extraction water simultaneously, it is known that the liquid shows neutral of releasing, limpid and do not observe nanometer titanium dioxide under a scanning electron microscope
Titanium；
S6, reef is taken out, reef is placed in baking oven dry；
S7, the reef after drying is placed on Muffle kiln roasting, the photocatalysis water-purifying fish based on nano-titanium dioxide is made
Cylinder makes scape stone.
3. the production method that a kind of seawater fish jar with purification of water quality ability according to claim 2 makes scape stone, special
Sign is that the preparation method of modified nano-titanium dioxide includes the following steps: in S1
S1011, weigh more than 1g nano-titanium dioxide in 500ml conical flask, sequentially add 40ml distilled water, 65ml sewage ethyl alcohol and
It shakes up, closes the lid after 0.1gTC-201 titanate coupling agent；
S1012, conical flask is placed in 46 DEG C of waters bath with thermostatic control after ultrasound 2h, the sewage ethyl alcohol of 25ml is added, dehydrated alcohol is added
Afterwards, conical flask is placed in ultrasound 1h in 50 DEG C of waters bath with thermostatic control again；
S1013, the solution after water bath with thermostatic control ultrasound is dried in certain temperature environment；
S1014, modified nano-titanium dioxide obtained in S1013 is placed in the conical flask of 200ml, the anhydrous second of 25ml is added
Alcohol shakes up and is placed on the obtained modified nano-titanium dioxide of natural drying in shading environment.
4. the production method that a kind of seawater fish jar with purification of water quality ability according to claim 2 makes scape stone, special
Sign is that the preparation method of substrate reef includes the following steps: in S1
S1021, the coral reef for taking one piece of self-assembling formation, and place it in a water tank equipped with seawater, and make in water tank
Water did not had the reef；
S1022, be persistently aerated using air pump and irradiate this reef using Metal halogen lamp, and guarantee illumination in 20000lx or more, often
Day light application time is no less than 16 hours；
S1023, after bearing dense green filiform bath after reef and water tank surface, reef is pulled out, and cutting, scrubbing net surface
After algae and other attachments, reef is immersed in the alcohol that concentration is 70% and impregnates 4h；
S1024, the reef that alcohol in S1023 impregnates is submerged in distilled water and boils 12h, be placed in oven and dried；
S1025, the reef after drying is placed in Muffle kiln roasting, after air natural cooling, obtains the reef of clean dried.
5. a kind of seawater fish jar with purification of water quality ability according to claim 1 makes its production method of scape stone,
It is characterized in that, the time stirred in S3 is 20-40min, and the time of ultrasonic treatment is 55-75min.
6. the production method that a kind of seawater fish jar with purification of water quality ability according to claim 1 makes scape stone, special
Sign is that the temperature of baking oven is 100-150 DEG C in S6, drying time 90-150min.
7. the production method that a kind of seawater fish jar with purification of water quality ability according to claim 1 makes scape stone, special
Sign is that the maturing temperature of Muffle furnace is 500-700 DEG C in S7, calcining time 56-8h.
8. the preparation method of modified nano-titanium dioxide according to claim 3, which is characterized in that dry ring in S1013
The temperature in border is 50-70 DEG C, drying time 30-90min.
9. the preparation method of substrate reef according to claim 4, which is characterized in that the temperature of baking oven is in S1024
100-140 DEG C, drying time 50-70min.
10. the preparation method of substrate reef according to claim 4, which is characterized in that the temperature that Muffle furnace roasts in S1025
Degree is 200-400 DEG C, calcining time 5-7h.
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