CN110282831A - Helotism bioreactor couples artificial wet field facilities for treating sewage and its processing method - Google Patents
Helotism bioreactor couples artificial wet field facilities for treating sewage and its processing method Download PDFInfo
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- CN110282831A CN110282831A CN201910627922.8A CN201910627922A CN110282831A CN 110282831 A CN110282831 A CN 110282831A CN 201910627922 A CN201910627922 A CN 201910627922A CN 110282831 A CN110282831 A CN 110282831A
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- 238000003672 processing method Methods 0.000 title claims abstract description 9
- 239000010865 sewage Substances 0.000 title claims abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 69
- 238000012545 processing Methods 0.000 claims abstract description 49
- 238000005192 partition Methods 0.000 claims abstract description 34
- 238000000034 method Methods 0.000 claims abstract description 32
- 238000009360 aquaculture Methods 0.000 claims abstract description 24
- 230000008569 process Effects 0.000 claims abstract description 24
- 244000144974 aquaculture Species 0.000 claims abstract description 23
- 238000005273 aeration Methods 0.000 claims abstract description 19
- 238000006385 ozonation reaction Methods 0.000 claims abstract description 16
- 238000006243 chemical reaction Methods 0.000 claims abstract description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 17
- 241000196324 Embryophyta Species 0.000 claims description 11
- 238000001914 filtration Methods 0.000 claims description 10
- 239000012528 membrane Substances 0.000 claims description 9
- 241000894006 Bacteria Species 0.000 claims description 8
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 7
- 239000004576 sand Substances 0.000 claims description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- 241000195493 Cryptophyta Species 0.000 claims description 6
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 6
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- 238000012986 modification Methods 0.000 claims description 6
- 230000004048 modification Effects 0.000 claims description 6
- 235000015097 nutrients Nutrition 0.000 claims description 6
- 238000000108 ultra-filtration Methods 0.000 claims description 6
- 235000015099 wheat brans Nutrition 0.000 claims description 6
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 5
- 230000001580 bacterial effect Effects 0.000 claims description 5
- 239000013602 bacteriophage vector Substances 0.000 claims description 5
- 238000004659 sterilization and disinfection Methods 0.000 claims description 5
- 241000186000 Bifidobacterium Species 0.000 claims description 4
- 241000108664 Nitrobacteria Species 0.000 claims description 4
- 238000005286 illumination Methods 0.000 claims description 4
- 244000205574 Acorus calamus Species 0.000 claims description 3
- 235000011996 Calamus deerratus Nutrition 0.000 claims description 3
- 235000005273 Canna coccinea Nutrition 0.000 claims description 3
- 240000008555 Canna flaccida Species 0.000 claims description 3
- 241000195649 Chlorella <Chlorellales> Species 0.000 claims description 3
- 241000565118 Cordylophora caspia Species 0.000 claims description 3
- 239000001888 Peptone Substances 0.000 claims description 3
- 108010080698 Peptones Proteins 0.000 claims description 3
- 235000014676 Phragmites communis Nutrition 0.000 claims description 3
- 229920000388 Polyphosphate Polymers 0.000 claims description 3
- 229920000037 Polyproline Polymers 0.000 claims description 3
- 241001509286 Thiobacillus denitrificans Species 0.000 claims description 3
- 241000746966 Zizania Species 0.000 claims description 3
- 235000002636 Zizania aquatica Nutrition 0.000 claims description 3
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 3
- NHSCRWJPZDNMBU-UHFFFAOYSA-L dipotassium carbonic acid carbonate Chemical compound [K+].[K+].OC([O-])=O.OC([O-])=O NHSCRWJPZDNMBU-UHFFFAOYSA-L 0.000 claims description 3
- 229940053838 glucose 1000 mg Drugs 0.000 claims description 3
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims description 3
- 235000019341 magnesium sulphate Nutrition 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 235000019319 peptone Nutrition 0.000 claims description 3
- 239000001205 polyphosphate Substances 0.000 claims description 3
- 235000011176 polyphosphates Nutrition 0.000 claims description 3
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 3
- 239000004800 polyvinyl chloride Substances 0.000 claims description 3
- 239000001103 potassium chloride Substances 0.000 claims description 3
- 235000011164 potassium chloride Nutrition 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 238000012216 screening Methods 0.000 claims description 3
- 244000062720 Pennisetum compressum Species 0.000 claims description 2
- 239000004793 Polystyrene Substances 0.000 claims description 2
- 229920002223 polystyrene Polymers 0.000 claims description 2
- 239000006228 supernatant Substances 0.000 claims description 2
- 239000004094 surface-active agent Substances 0.000 claims description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims 3
- QCVGEOXPDFCNHA-UHFFFAOYSA-N 5,5-dimethyl-2,4-dioxo-1,3-oxazolidine-3-carboxamide Chemical compound CC1(C)OC(=O)N(C(N)=O)C1=O QCVGEOXPDFCNHA-UHFFFAOYSA-N 0.000 claims 1
- 102000002322 Egg Proteins Human genes 0.000 claims 1
- 108010000912 Egg Proteins Proteins 0.000 claims 1
- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 claims 1
- 235000014103 egg white Nutrition 0.000 claims 1
- 210000000969 egg white Anatomy 0.000 claims 1
- 239000002351 wastewater Substances 0.000 abstract description 8
- 230000008878 coupling Effects 0.000 abstract description 5
- 238000010168 coupling process Methods 0.000 abstract description 5
- 238000005859 coupling reaction Methods 0.000 abstract description 5
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 7
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 229910052698 phosphorus Inorganic materials 0.000 description 7
- 239000011574 phosphorus Substances 0.000 description 7
- 241001465754 Metazoa Species 0.000 description 5
- 241000251468 Actinopterygii Species 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000008280 blood Substances 0.000 description 3
- 210000004369 blood Anatomy 0.000 description 3
- 238000001514 detection method Methods 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 description 2
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 2
- 238000009395 breeding Methods 0.000 description 2
- 230000001488 breeding effect Effects 0.000 description 2
- 229920002301 cellulose acetate Polymers 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 210000003608 fece Anatomy 0.000 description 2
- 239000005416 organic matter Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 235000017557 sodium bicarbonate Nutrition 0.000 description 2
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 244000025254 Cannabis sativa Species 0.000 description 1
- 241000238557 Decapoda Species 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 241001434359 Muhlenbergia phleoides Species 0.000 description 1
- 241000605118 Thiobacillus Species 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 230000035568 catharsis Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- DNJIEGIFACGWOD-UHFFFAOYSA-N ethanethiol Chemical compound CCS DNJIEGIFACGWOD-UHFFFAOYSA-N 0.000 description 1
- 230000029142 excretion Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 230000037406 food intake Effects 0.000 description 1
- 239000013505 freshwater Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000002207 metabolite Substances 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000000258 photobiological effect Effects 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 229920006389 polyphenyl polymer Polymers 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- -1 rtificial Species 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/001—Processes for the treatment of water whereby the filtration technique is of importance
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/283—Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
- C02F1/444—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by ultrafiltration or microfiltration
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/78—Treatment of water, waste water, or sewage by oxidation with ozone
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/005—Processes using a programmable logic controller [PLC]
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/04—Disinfection
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/32—Biological treatment of water, waste water, or sewage characterised by the animals or plants used, e.g. algae
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/34—Biological treatment of water, waste water, or sewage characterised by the microorganisms used
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
- Biological Treatment Of Waste Water (AREA)
- Farming Of Fish And Shellfish (AREA)
Abstract
The present invention relates to a kind of helotism bioreactor coupling artificial wet field facilities for treating sewage and its processing methods.The device includes inlet tank, bioreactor and artificial swamp;Inlet tank connects bioreactor by water inlet pipe, and intake pump is provided on water inlet pipe, is provided with inner cylinder in the middle part of bioreactor, bioreactor connects artificial swamp by outlet pipe;It is provided in artificial swamp into water partition, the artificial swamp is divided into wetland variation unit, ozonization unit and film process unit by partition.It the described method comprises the following steps: waste water to be processed is successively passed through into bioreactor and artificial swamp, light source and Aeration fan, qualified discharge or reuse after bioreactor and wetland variation unit, ozonization unit, film process cell processing are opened in reaction process.The present invention is using bioreactor coupling artificial wetland treatment aquaculture tail water and uses PLC overall-in-one control schema, solves the processing problem of such waste water.
Description
Technical field
The invention belongs to technical field of waste water processing, and in particular to a kind of helotism bioreactor coupling Manual moist
Ground sewage-treatment plant and its processing method.
Background technique
Aquaculture be most important component part in China's freshwater aquiculture, by water resource, land area lack etc. first
The multiple factors such as its factor and cultivation infrastructure are poor, environmental pollution is heavy, productivity decline influence, especially with intensive water
The fast development of aquaculture model is produced, water quality deterioration and discharge of wastewater directly constrain the sustainable development of aquaculture industry.It cultivated
The discharge of bait, the decomposition of residual bait, the generation of excreta and chemicals and the use of antibiotic etc. in journey, make to seek in water body
It supports substance, organic debris etc. to severely exceed, causes the Cultivated water ecosystem unbalance, disease is bred, and water body environment evil is exacerbated
Change degree.It directly utilizes or circulating and recovering breeding water body is very harmful to fish, it is necessary to just can be used as cultivation after processing and use
Water.Major pollutants in aquaculture tail water have ammonia nitrogen, nitrite, organic matter, phosphorus etc., and ammonia nitrogen is the excretion of aquatic animal
The final product that the itrogenous organic substances such as object and residual bait, excrement and animals and plants corpse decompose, be easy to cause water body to deteriorate, to cultivation
Animal generates toxicity.Nitrite has very strong toxicity to fish, its presence can lead to fish, the blood red egg of ferrous iron in shrimp blood
It is white to be oxidized to high-speed rail ferrohemoglobin, and the latter cannot deliver oxygen, to inhibit the oxygen carrying capability of blood, cause tissue
Anoxic, the decline of aquatic animal ingestion ability, in addition it is dead.Organic matter is mainly by residual bait, the metabolite of planktonic organism and cultivation
The excreta of animal, which decomposes, to be generated, and high organic content often results in water body deterioration, causes fish growth slow or even general pond or dead
It dies.
A large amount of research has been carried out to aquaculture tail water processing technique and has been answered currently, having more researcher both at home and abroad
With some farms can be filtered tail water and handle using biological ball or filter etc., but this mode can only filter out
The purpose of depollution is not achieved in large granular impurity in tail water;A small number of farms will use the equipment such as Protein Skimmer
To carry out purified treatment to tail water, however, these tail water are usually successively after several cleaning equipments with regard to direct emission at present
It goes out, can still there is more poisonous and harmful substance in treated tail water, biggish pollution still can be caused to environment.
Summary of the invention
In view of this, the present invention aquaculture tail water in the prior art processing be not thorough, poor processing effect aiming at the problem that,
A kind of device suitable for the processing of aquaculture tail water and corresponding processing method are provided.
In order to achieve the above object, the technical solution adopted by the present invention is that:
A kind of helotism bioreactor coupling artificial wet field facilities for treating sewage, it is characterised in that: including water inlet
Case, bioreactor and artificial swamp;The inlet tank connects bioreactor, the water inlet pipe by water inlet pipe
On be provided with intake pump, be provided with inner cylinder in the middle part of the bioreactor, bow font partition be provided in the inner cylinder,
The bow font diaphragm internal is provided with multiple aeration heads, and the bow font diaphragm internal is additionally provided with multiple light sources, institute
It is filled with helotism body in the inner cylinder stated, is provided with overflow weir, the photo-biological above the bioreactor
Reactor connects artificial swamp by outlet pipe;It is provided in the artificial swamp into water partition, the artificial swamp is logical
It crosses partition and is divided into wetland variation unit, ozonization unit and film process unit.
Optionally, there are gaps between the multiple lateral partitions and longitudinal baffle of the bow font partition, and described is multiple
Light source is set to the gap location of multiple lateral partitions and longitudinal baffle, and the light source is incandescent lamp or fluorescent lamp, intensity of illumination
Between 3000-10000lx, pH meter, temperature monitor are additionally provided in the bioreactor.
Optionally, the wetland variation unit sequentially consists of coarse filtration layer, hypothallus, fine sand layer and plant
Layer, the coarse filtration layer are mixed using gravel with haydite, and mixed volume ratio is gravel: haydite 3:1, the hypothallus are adopted
With stalk and active carbon, mixed volume ratio is stalk: active carbon 2-3:1, the layer of plants be selected from canna, calamus,
One of Chinese pennisetum, wild rice stem, reed are a variety of.
Optionally, the processing unit is additionally provided with PLC control system, and the PLC control system is for controlling system
The start and stop of the Inlet and outlet water, light source control, aeration control, ozone generating-device and film process unit of system, multiple aerations
Head connects Aeration fan by aerated conduit.
Optionally, it is provided with ozone generating-device in the ozonization unit, is arranged in the film process unit
There is ultrafiltration membrane, the ultrafiltration membrane material is one of polyvinyl chloride, polystyrene or cellulose acetate, membrane aperture 0.1-
0.3 μm, film wire percent opening is 80%-95%.
The invention also discloses a kind of method using above-mentioned apparatus processing aquaculture tail water, aquacultures to be processed
Tail water is pumped into bioreactor through intake pump, is controlled the temperature in bioreactor by pH meter, temperature monitor and is existed
18-25 DEG C, pH adds the helotism body through taming into bioreactor in 6-7, opens inside bioreactor
Multiple light sources, while opening Aeration fan and handling aquaculture tail water, processing time are 8-14 hours, on treated
Clear liquid enters in artificial swamp through overflow to be continued with, and the bottom of wetland variation unit is entered by the bottom of water inlet partition, successively
It is handled by coarse filtration layer, hypothallus, fine sand layer and layer of plants, the processing time is 1-5 hours, and water outlet enters ozonization unit
Carry out disinfection processing, then enters qualified discharge or reuse after film process cell processing.
Optionally, the preparation process of the helotism body is as follows: separation screening thiobacillus denitrificans, gather nitrobacteria
Phosphorus bacterium and Bifidobacterium compound strain carry out enrichment culture, above-mentioned compound strain are mixed with carrier, the load
Body is wheat bran and modified diatomite, and wherein the mass ratio of hybrid bacterial strain and carrier is 1:3-10, wheat bran and modification in carrier
The mass ratio of diatomite is 1:4-9, load Bacteriophage vectors is obtained after nutrient solution mixed processing is added, then by above-mentioned load thallus
Carrier and chlorella are added in bioreactor for 5:1 according to mass ratio to get helotism body is arrived.
Optionally, the modification infusorial earth is through the modified diatom of surfactant cetyl trimethylammonium bromide
Soil.
Optionally, the group of the nutrient solution becomes glucose 1000mg/L, peptone 225mg/L, potassium chloride 268mg/
L, magnesium sulfate 58mg/L, bicarbonate dipotassium 100mg/L, copper sulphate 20mg/L, sodium bicarbonate 120mg/L.
Optionally, the processing time of the ozonization unit is 3-30 minutes, and the processing time of film process unit is 10-
40 minutes.
Compared with prior art, it includes following technical effect that the present invention, which can get:
1) present invention couples artificial wetland treatment aquaculture tail water using helotism bioreactor, makes full use of
The catharsis of bacterium algae and artificial swamp in bioreactor, collection biological treatment and physical treatment and one, can
Efficient process aquaculture tail water;Reactor operation operation is easy, using PLC overall-in-one control schema, solves the place of such waste water
Manage problem.
2) it using bow font partition setting in helotism bioreactor, and crosses in longitudinal baffle and lateral partitions
Gap location light source is set so that illumination is more uniform, conducive to the growth of algae, while it is more to bend setting at the center of font partition
A aeration head, so that aeration is more uniformly, conducive to the breeding of thallus, while the setting for bending font partition cooperates more aeration heads to expose
Gas, itself is but also form circulation, conducive to the circulation of water body, so as to effective intensified response inside bioreactor
The treatment effect of device.
3) water quality characteristics of aquaculture tail water are directed to, suitable bacterial strain are filtered out by a large amount of cumbersome work, using nitrogen
The compound strain that Thiobacillus, nitrobacteria, polyP bacteria and Bifidobacterium form, and corresponding load carriers are selected, while basis
The suitable bacterial strain of internal structure corresponding selection of bioreactor and algae add ratio, and treatment effeciency is high, treatment effect
It is good.
4) the artificial wetland unit of the present invention has coupled at conventional manual's wetland variation unit, ozonization unit and film
Unit is managed, compared with conventional artificial wetland treatment process, is directed to the water quality characteristics of aquaculture tail water, is increased corresponding smelly
Oxygen disinfection unit, film process unit carry out disinfection processing to microorganism, the germ etc. in tail water, while reducing stench, so that place
Reason water energy reaches qualified discharge or reuse.
Detailed description of the invention
Fig. 1 is that the structure of helotism bioreactor coupling artificial wet field facilities for treating sewage provided by the invention is shown
It is intended to.In figure, 1 it is inlet tank, 2 is intake pump, 3 is water inlet pipe, 4 is bioreactor, 5 is inner cylinder, 6 is light source, 7 is bow
Font partition, 8 be overflow weir, 9 be outlet pipe, 10 be helotism body, 11 be PLC control system, 12 be artificial swamp, 13 are
Water inlet partition, 14 be wetland variation unit, and 15 be ozonization unit, and 16 be film process unit, and 17 be coarse filtration layer, and 18 be matrix
Layer, 19 be fine sand layer, and 20 be layer of plants.
Specific embodiment
The invention will now be described in further detail with reference to the accompanying drawings.
Embodiment 1
As shown in Figure 1, a kind of helotism bioreactor couples artificial wet field facilities for treating sewage, including inlet tank
(1), bioreactor (4) and artificial swamp (12);The inlet tank (1) connects optical-biological reaction by water inlet pipe (3)
Device (4) is provided with intake pump (2) on the water inlet pipe (3), is provided with inner cylinder in the middle part of the bioreactor (4)
(5), bow font partition (7) is provided in the inner cylinder (5), the bow font partition (7) is internally provided with multiple aerations
Head (13), the bow font partition (7) is internal to be additionally provided with multiple light sources (6), total filled with bacterium algae in the inner cylinder (5)
Raw body (10) is provided with overflow weir (8) above the bioreactor (4), and the bioreactor (4) passes through
Outlet pipe (9) connects artificial swamp (12);It is provided in the artificial swamp (12) into water partition (13), the Manual moist
Ground (12) is divided into wetland variation unit (14) by partition, ozonization unit (15) and film process unit (16).It is described
Bow font partition (7) multiple lateral partitions and longitudinal baffle between there are gap, the multiple light sources (6) are set to multiple
The gap location of lateral partitions and longitudinal baffle, the light source (6) are incandescent lamp or fluorescent lamp, and intensity of illumination is in 3000-
Between 10000lx, the bioreactor is additionally provided with pH meter, temperature monitor in (4).The wetland variation unit
(14) coarse filtration layer (17), hypothallus (18), fine sand layer (19) and layer of plants (20), the coarse filtration layer are sequentially consisted of
(17) it is mixed using gravel with haydite, mixed volume ratio is gravel: haydite 3:1, and the hypothallus (18) uses stalk
With active carbon, mixed volume ratio is stalk: active carbon 2-3:1, and the layer of plants (2) is selected from canna, calamus, wolf tail
One of grass, wild rice stem, reed are a variety of.The processing unit is additionally provided with PLC control system (11), the PLC control
System (11) processed is for the Inlet and outlet water of control system, light source control, aeration control, ozone generating-device and film process unit
Start and stop, multiple aeration heads (13) connect Aeration fan by aerated conduit.It is set in the ozonization unit (15)
It is equipped with ozone generating-device, ultrafiltration membrane is provided in the film process unit, the ultrafiltration membrane material is polyvinyl chloride, polyphenyl
One of ethylene or cellulose acetate, membrane aperture are 0.1-0.3 μm, and film wire percent opening is 80%-95%.
Its treatment process are as follows: aquaculture tail water to be processed is pumped into bioreactor (4) through intake pump (2), is led to
Cross pH meter, temperature monitor control bioreactor (4) in temperature at 18-25 DEG C, pH is in 6-7, to bioreactor
(4) the helotism body (10) through taming is added in, is opened bioreactor (4) internal multiple light sources (6), is opened simultaneously
Aeration fan handles aquaculture tail water, and the processing time is 8 hours, and treated supernatant enters Manual moist through overflow
Ground continues in (12), and the bottom of wetland variation unit (14) is entered by the bottom of water inlet partition (13), successively passes through coarse filtration
Layer (17), hypothallus (18), fine sand layer (19) and layer of plants (20) processing, processing time are 2 hours, and water outlet disappears into ozone
Malicious unit (15) carries out disinfection processing, then enters qualified discharge or reuse after film process unit (16) processing.The bacterium algae
The preparation process of homobium (10) is as follows: separation screening thiobacillus denitrificans, nitrobacteria, polyP bacteria and Bifidobacterium compound strain
Enrichment culture is carried out, above-mentioned compound strain is mixed with carrier, the carrier is wheat bran and modified diatom
Soil, wherein the mass ratio of hybrid bacterial strain and carrier is 1:3-10, and the mass ratio of wheat bran and modification infusorial earth is 1:4-9 in carrier,
Load Bacteriophage vectors are obtained after nutrient solution mixed processing is added, then by above-mentioned load Bacteriophage vectors and chlorella according to mass ratio
It is added in bioreactor (4) for 5:1 to get helotism body (10) are arrived.The modification infusorial earth is through surface-active
The modified diatomite of agent cetyl trimethylammonium bromide.The group of the nutrient solution becomes glucose 1000mg/L, albumen
Peptone 225mg/L, potassium chloride 268mg/L, magnesium sulfate 58mg/L, bicarbonate dipotassium 100mg/L, copper sulphate 20mg/L, sodium bicarbonate
120mg/L.The processing time of the ozonization unit (15) is 5 minutes, and the processing time of film process unit (16) is 15 points
Clock.
Certain aquaculture tail water is handled using above-mentioned processing unit and processing method, through detecting the COD in waste water to be processed
Content is 980mg/L, and SS content is 1235mg/L, ammonia-nitrogen content 82mg/L, total phosphorus content 78mg/L.It will be above-mentioned to be processed
Waste water passes sequentially through above-mentioned bioreactor and artificial wetland treatment, and the content of C0D is 26mg/ in detection water outlet after processing
L, SS content are 17mg/L, ammonia-nitrogen content 8mg/L, total phosphorus content 1.8mg/L, obvious processing effect.
Embodiment 2
Certain aquaculture tail water is handled using the processing unit and processing method of embodiment 1, handles the water of waste water
Matter is same as Example 1, and difference is that the processing time of bioreactor (4) is 10 hours, wetland variation unit (14)
Handling the time is 3 hours, and processing time of ozonization unit (15) is 8 minutes, and the processing time of film process unit (16) is
20 minutes, the content of C0D was 18mg/L in detection water outlet after processing, and SS content is 21mg/L, ammonia-nitrogen content 6mg/L, total phosphorus
Content is 2.1mg/L, obvious processing effect.
Embodiment 3
Certain aquaculture tail water is handled using the processing unit and processing method of embodiment 1, treatment process and place
It is same as Example 1 to manage parameter, water quality treatment is that COD content is 1025mg/L, and SS content is 980mg/L, and ammonia-nitrogen content is
75mg/L, total phosphorus content 62mg/L, the content of C0D is 15mg/L in detection water outlet after processing, and SS content is 13mg/L, ammonia nitrogen
Content is 5mg/L, total phosphorus content 1.2mg/L, obvious processing effect.
Above-described embodiment is the preferable implementation of the present invention, and in addition to this, the present invention can be realized with other way,
Do not depart under the premise of present inventive concept it is any obviously replace it is within the scope of the present invention.
Claims (10)
1. a kind of helotism bioreactor couples artificial wet field facilities for treating sewage, it is characterised in that: including inlet tank
(1), bioreactor (4) and artificial swamp (12);The inlet tank (1) connects optical-biological reaction by water inlet pipe (3)
Device (4) is provided with intake pump (2) on the water inlet pipe (3), is provided with inner cylinder in the middle part of the bioreactor (4)
(5), bow font partition (7) is provided in the inner cylinder (5), the bow font partition (7) is internally provided with multiple aerations
Head (13), the bow font partition (7) is internal to be additionally provided with multiple light sources (6), total filled with bacterium algae in the inner cylinder (5)
Raw body (10) is provided with overflow weir (8) above the bioreactor (4), and the bioreactor (4) passes through
Outlet pipe (9) connects artificial swamp (12);It is provided in the artificial swamp (12) into water partition (13), the Manual moist
Ground (12) is divided into wetland variation unit (14) by partition, ozonization unit (15) and film process unit (16).
2. device as described in claim 1, it is characterised in that: multiple lateral partitions of the bow font partition (7) and vertical
To partition room there are gap, the multiple light sources (6) are set to the gap location of multiple lateral partitions and longitudinal baffle, described
Light source (6) is incandescent lamp or fluorescent lamp, and intensity of illumination is between 3000-10000lx, in the bioreactor (4) also
It is provided with pH meter, temperature monitor.
3. device as described in claim 1, it is characterised in that: the wetland variation unit (14) sequentially consists of slightly
Filtering layer (17), hypothallus (18), fine sand layer (19) and layer of plants (20), the coarse filtration layer (17) are mixed using gravel and haydite
It closes, mixed volume ratio is gravel: haydite 3:1, and the hypothallus (18) uses stalk and active carbon, mixed volume ratio
One of canna, calamus, Chinese pennisetum, wild rice stem, reed are selected from for stalk: active carbon 2-3:1, the layer of plants (2)
Or it is a variety of.
4. device as described in claim 1, it is characterised in that: the processing unit is additionally provided with PLC control system (11),
The PLC control system (11) for the Inlet and outlet water of control system, light source control, aeration control, ozone generating-device and
The start and stop of film process unit, multiple aeration heads (13) connect Aeration fan by aerated conduit.
5. device as described in claim 1, it is characterised in that: be provided with ozone in the ozonization unit (15)
Device, ultrafiltration membrane is provided in the film process unit, and the ultrafiltration membrane material is that polyvinyl chloride, polystyrene or acetic acid are fine
One of element is tieed up, membrane aperture is 0.1-0.3 μm, and film wire percent opening is 80%-95%.
6. a kind of method using any one of claim 1-5 described device processing aquaculture tail water, it is characterised in that: wait locate
The aquaculture tail water of reason is pumped into bioreactor (4) through intake pump (2), controls photoproduction by pH meter, temperature monitor
Temperature in object reactor (4) is at 18-25 DEG C, and pH is in 6-7, to helotism of the addition through taming in bioreactor (4)
Body (10) opens bioreactor (4) internal multiple light sources (6), at the same open Aeration fan to aquaculture tail water into
Row processing, processing time are 8-14 hours, and treated, and supernatant enters in artificial swamp (12) through overflow continues with, by into
The bottom of water partition (13) enters the bottom of wetland variation unit (14), successively passes through coarse filtration layer (17), hypothallus (18), fine sand
Layer (19) and layer of plants (20) processing, processing time are 1-5 hour, and water outlet carries out disinfection place into ozonization unit (15)
Reason then enters qualified discharge or reuse after film process unit (16) processing.
7. method as claimed in claim 6, it is characterised in that: the preparation process of the helotism body (10) is as follows: point
Enrichment culture is carried out from screening thiobacillus denitrificans, nitrobacteria, polyP bacteria and Bifidobacterium compound strain, by above-mentioned compound strain
It is mixed with carrier, the carrier is wheat bran and modified diatomite, the wherein quality of hybrid bacterial strain and carrier
Than for 1:3-10, the mass ratio of wheat bran and modification infusorial earth is 1:4-9 in carrier, loaded after nutrient solution mixed processing is added
Above-mentioned load Bacteriophage vectors and chlorella are then that 5:1 is added in bioreactor (4) according to mass ratio by Bacteriophage vectors,
Obtain helotism body (10).
8. processing method as claimed in claim 7, it is characterised in that: the modification infusorial earth is through surfactant 16
The modified diatomite of alkyl trimethyl ammonium bromide.
9. the method for claim 7, it is characterised in that: the group of the nutrient solution becomes glucose 1000mg/L, egg
White peptone 225mg/L, potassium chloride 268mg/L, magnesium sulfate 58mg/L, bicarbonate dipotassium 100mg/L, copper sulphate 20mg/L, bicarbonate
Sodium 120mg/L.
10. method as claimed in claim 6, it is characterised in that: the processing time of the ozonization unit (15) is 3-30
Minute, the processing time of film process unit (16) is 10-40 minutes.
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