CN1102074C - 生产苯酚及其衍生物的催化剂 - Google Patents

生产苯酚及其衍生物的催化剂 Download PDF

Info

Publication number
CN1102074C
CN1102074C CN95193212A CN95193212A CN1102074C CN 1102074 C CN1102074 C CN 1102074C CN 95193212 A CN95193212 A CN 95193212A CN 95193212 A CN95193212 A CN 95193212A CN 1102074 C CN1102074 C CN 1102074C
Authority
CN
China
Prior art keywords
benzene
phenol
catalyzer
gas
nitrous oxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN95193212A
Other languages
English (en)
Chinese (zh)
Other versions
CN1148819A (zh
Inventor
A·S·卡里通诺夫
G·I·彭诺夫
G·A·谢费列瓦
L·V·皮卢科
T·P·沃斯伦森斯卡亚
V·I·索伯列夫
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Monsanto Co
Original Assignee
Solutia Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from RU9494013071A external-priority patent/RU2074164C1/ru
Application filed by Solutia Inc filed Critical Solutia Inc
Publication of CN1148819A publication Critical patent/CN1148819A/zh
Application granted granted Critical
Publication of CN1102074C publication Critical patent/CN1102074C/zh
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/10—Heat treatment in the presence of water, e.g. steam
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/60—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by oxidation reactions introducing directly hydroxy groups on a =CH-group belonging to a six-membered aromatic ring with the aid of other oxidants than molecular oxygen or their mixtures with molecular oxygen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/36—Steaming
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/40—Special temperature treatment, i.e. other than just for template removal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
    • B01J29/072—Iron group metals or copper
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CN95193212A 1994-04-12 1995-04-12 生产苯酚及其衍生物的催化剂 Expired - Fee Related CN1102074C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
RU9494013071A RU2074164C1 (ru) 1994-04-12 1994-04-12 Способ получения фенола или его производных
RU94013071 1994-04-12

Publications (2)

Publication Number Publication Date
CN1148819A CN1148819A (zh) 1997-04-30
CN1102074C true CN1102074C (zh) 2003-02-26

Family

ID=20154684

Family Applications (1)

Application Number Title Priority Date Filing Date
CN95193212A Expired - Fee Related CN1102074C (zh) 1994-04-12 1995-04-12 生产苯酚及其衍生物的催化剂

Country Status (5)

Country Link
JP (1) JP3507500B2 (ja)
KR (1) KR100231372B1 (ja)
CN (1) CN1102074C (ja)
AU (1) AU694967B2 (ja)
BR (1) BR9507387A (ja)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101747155B (zh) * 2008-12-08 2013-04-24 中国石油天然气股份有限公司 一种n2o为氧化剂苯一步氧化合成苯酚的方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4429176A (en) * 1982-02-08 1984-01-31 Mobil Oil Corporation Active zeolite catalysts of improved stability
EP0406050A2 (fr) * 1989-06-22 1991-01-02 Rhone-Poulenc Chimie Procédé de préparation de phénols
US5110995A (en) * 1991-03-12 1992-05-05 Institute Of Catalysis Preparation of phenol or phenol derivatives

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4117511A1 (de) * 1991-05-29 1992-12-03 Vaw Ver Aluminium Werke Ag Verfahren zur modifizierung eines rein-anorganisch synthetisierten zeoliths vom pentasil-typ

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4429176A (en) * 1982-02-08 1984-01-31 Mobil Oil Corporation Active zeolite catalysts of improved stability
EP0406050A2 (fr) * 1989-06-22 1991-01-02 Rhone-Poulenc Chimie Procédé de préparation de phénols
US5110995A (en) * 1991-03-12 1992-05-05 Institute Of Catalysis Preparation of phenol or phenol derivatives

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
MENDELEEV CONNUM.(1993)NO.1 1993-01-01 V.Zholobenko Preparation of Phenol over Dehydroxylated HZSM-5Zeolites *

Also Published As

Publication number Publication date
CN1148819A (zh) 1997-04-30
BR9507387A (pt) 2002-04-16
AU2376795A (en) 1995-10-30
KR100231372B1 (ko) 1999-11-15
JP3507500B2 (ja) 2004-03-15
AU694967B2 (en) 1998-08-06
MX9604787A (es) 1998-05-31
JPH09511445A (ja) 1997-11-18

Similar Documents

Publication Publication Date Title
US5672777A (en) Catalysts for production of phenol and its derivatives
CN1071729C (zh) 生产苯酚及其衍生物的方法
EP1848681B1 (en) Process for dehydrating glycerol to acrolein
JP2968182B2 (ja) フェノールの精製方法
KR20110016969A (ko) 글리세롤의 탈수에 의한 아크롤레인의 제조 방법
Muggli et al. Catalyst design to change selectivity of photocatalytic oxidation
JPH01313448A (ja) ジヒドロキシベンゼンの製造方法
Han et al. VxOy supported on hydrophobic poly (ionic liquid) s as an efficient catalyst for direct hydroxylation of benzene to phenol
CN100337746C (zh) 甲基丙烯酸生产用催化剂的再活化方法
JPH0542299B2 (ja)
Raja et al. Selective oxidation with copper complexes incorporated in molecular sieves
JP4861190B2 (ja) 芳香族炭化水素類の酸化における活性剤としてのアントラセン及び他の多環式芳香族化合物
CN1102074C (zh) 生产苯酚及其衍生物的催化剂
US6531615B2 (en) Process for the oxidation of cyclohexanone to ε-caprolactone
Ivanov et al. New way of hydroquinone and catechol synthesis using nitrous oxide as oxidant
Venkatachalapathy et al. Fries rearrangement of esters in montmorillonite clays: Steric control on selectivity
Yılmaz et al. Effect of sulphation on the catalytic activity of MIL‐101 and the activation energy of an esterification reaction
CN1239443C (zh) 一种甲烷芳构化催化剂及其制备方法和应用
MXPA96004787A (en) Catalysts for the production of phenol and its deriva
AU2001255862B2 (en) Process for activating catalyst for the hydroxylation of aromatics
CN100372826C (zh) 烷基化苯衍生物的催化酰化
CN1121366C (zh) 苯酚及其衍生物的制备
Jarecka et al. Acid and catalytic properties of new thermostable sulfocationic exchangers supported on aluminosilicates
JP3218044B2 (ja) シクロヘキサノールおよびシクロヘキサノンの製造方法
AU2001255862A1 (en) Process for activating catalyst for the hydroxylation of aromatics

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C53 Correction of patent for invention or patent application
COR Change of bibliographic data

Free format text: CORRECT: APPLICANT; FROM: BORESKOVA INST KATALIZA SIBIR TO: MONSANTO CO.

CP03 Change of name, title or address

Address after: American Missouri

Applicant after: Monsanto, Co.

Address before: Russia Novosibirsk

Applicant before: Boreskov Inst. of Catalysis

C53 Correction of patent for invention or patent application
CB02 Change of applicant information

Applicant after: Sorotia Co.

Applicant before: Monsanto, Co.

COR Change of bibliographic data

Free format text: CORRECT: APPLICANT; FROM: MONSANTO CO. TO: SOLUTIA CORP.

C14 Grant of patent or utility model
GR01 Patent grant
C17 Cessation of patent right
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20030226

Termination date: 20140412