CN110200835A - A kind of water-based nail polish and preparation method thereof that light becomes - Google Patents

A kind of water-based nail polish and preparation method thereof that light becomes Download PDF

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Publication number
CN110200835A
CN110200835A CN201910326612.2A CN201910326612A CN110200835A CN 110200835 A CN110200835 A CN 110200835A CN 201910326612 A CN201910326612 A CN 201910326612A CN 110200835 A CN110200835 A CN 110200835A
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China
Prior art keywords
weight
parts
water
nail polish
light becomes
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Pending
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CN201910326612.2A
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Chinese (zh)
Inventor
金继月
戴永求
叶志勇
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Jinhua City Keweisi Chemical Co Ltd
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Jinhua City Keweisi Chemical Co Ltd
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Priority to CN201910326612.2A priority Critical patent/CN110200835A/en
Publication of CN110200835A publication Critical patent/CN110200835A/en
Pending legal-status Critical Current

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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/4973Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with oxygen as the only hetero atom
    • A61K8/498Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with oxygen as the only hetero atom having 6-membered rings or their condensed derivatives, e.g. coumarin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q3/00Manicure or pedicure preparations
    • A61Q3/02Nail coatings

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Cosmetics (AREA)

Abstract

The invention proposes the water-based nail polish that a kind of light becomes, component including following parts by weight: film-forming resin: 60-80 parts by weight, coalescing agent: 3-5 parts by weight, thicken suspending agent: 2-5 parts by weight, preservative: 1-3 parts by weight, light become powder: 5-10 parts by weight, other auxiliary agents: 0.5-1.0 parts by weight, pigment: 0-5 parts by weight, essence: 0-3 parts by weight and water: 2-18 parts by weight.The water-based nail polish that light of the present invention becomes becomes powder using the aphthopyrans class light of safety and environmental protection, changes color different out and bright under irradiation by sunlight;It is environmentally protective using water as primary solvent, low emission VOCs;Smell is low, and the fragrance of available similar perfume after essence is added;It is smooth ventilative, it is small to human nails and skin irritatin;Warm water impregnates a few minutes, that is, detachable first-class feature.

Description

A kind of water-based nail polish and preparation method thereof that light becomes
Technical field
The invention belongs to cosmetic technical fields, and in particular to a kind of water-based nail polish and preparation method thereof that light becomes.
Background technique
Nail polish belongs to the color make-up class product in cosmetics, is widely used in finger nail or toenail beautifying and decorating, color It enriches gorgeous, has both beautiful and protective effect, be the irreplaceable a kind of cosmetics of Ms of liking to be beautiful.Existing nail polish is general only There is fixed color, it is more dull, it is not able to satisfy women to the multifarious demand of nail polish.
There are also some light of some patent reports to become nail polish products.As CN201110040843.0, CN201110358487.7, CN201310746497.7, CN201410582427.7, CN201710179691.X are public respectively The light for having opened reapective features becomes nail polish, but belongs to conventional organic solvents type nail polish, and smell is pungent, corrosivity is strong, right Nail and human injury are larger, and environmental pollution is serious and used light becomes powder and is equally harmful to human health. CN201710573687.1 discloses a kind of aqueous photochromic coating, nail polish and ornament materials.But need photocuring Lamp unloads first difficulty, easily causes disconnected first.Water-based nail polish is basic raw material with water, and natural environmental-protective resin is added, and mill base etc. is made, With low smell, low irritant, low VOCs, quality be thin, easy brushing, frangible first-class advantage.But have no that patent report light becomes Water-based nail polish.
Summary of the invention
The purpose of the present invention is being to solve defect of the existing technology, provide a kind of water-based nail polish that light becomes and Preparation method.
The technical scheme of the present invention is realized as follows:
A kind of technical solution 1: water-based nail polish that light becomes, which is characterized in that the component including following parts by weight: film forming Resin: 60-80 parts by weight, coalescing agent: 3-5 parts by weight thicken suspending agent: 2-5 parts by weight, preservative: 1-3 parts by weight, light Become powder: 5-10 parts by weight, other auxiliary agents: 0.5-1.0 parts by weight, pigment: 0-5 parts by weight, essence: 0-3 parts by weight and water: 2- 18 parts by weight.
Technical solution 2: on the basis of technical solution 1, following improvement is further done, the film-forming resin is phenylpropyl alcohol cream One of liquid, polyaminoester emulsion and polyvinyl alcohol are a variety of.
Technical solution 3: on the basis of technical solution 1, further doing following improvement, the coalescing agent alcohol ester 12, One of dipropylene glycol methyl ether and dipropylene are a variety of.
Technical solution 4: on the basis of technical solution 1, following improvement is further done, the thickening suspending agent is that department draws It is one or more in oronain hectorite, silica and polyacrylic acid.
Technical solution 5: on the basis of technical solution 1, further doing following improvement, the preservative be Phenoxyethanol, It is one or more in pungent glycol and Sensiva SC50.
Technical solution 6: on the basis of technical solution 1, following improvement is further done, the light becomes powder to contain naphtho- Pyrans organic matter (7- tert-butyl-n-(the fluoro- 4- methylsulfonyl aminophenyl of 3-)-dihydrobenzopyrans -3- formamide) it is photochromic Material.Naphthopyran compounds had occurred in light quality colourshifting process three-dimensional structure variation, in the solution when, absorb Usually in UV absorption area, color is not presented in wavelength, and heterolytic fission, the conformation of molecule occur for C-O key in molecule after by ultraviolet excitation It changes a lot with electronic configuration, shows colorful color after absorbing red shift.Molecule after its scission of link is commonly referred to as " open loop body " or " discoloration member ", under longer wavelength light action, open loop body occurs cyclization reaction and replys as starting chemical combination Object.
Technical solution 7: on the basis of technical solution 1, following improvement is further done, other described auxiliary agents are aqueous disappear It is one or more in infusion, aqueous dispersion, aqueous wetting agent and aqueous anti-settling agent.
Technical solution 8: on the basis of technical solution 1, following improvement is further done, the pigment is inorganic pigment, has It is one or more in machine pigment, pearl mica and colour PET paillette.
Technical solution 9: on the basis of technical solution 1, following improvement is further done, the essence is that asepsis environment-protecting is fragrant Essence.
Technical solution 10: a kind of preparation method for the water-based nail polish that light becomes is prepared: in accordance with the following methods in revolving speed 600 Under rev/min, the film-forming resin of 60-80 parts by weight, 3-5 parts by weight coalescing agent, 1-3 parts by weight preservative, 0.5- is added Revolving speed is adjusted to 1000 revs/min after dispersion 30 minutes by other auxiliary agents of 1.0 parts by weight, and 2-5 parts by weight are added and thicken suspending agent, 5-10 parts by weight light becomes powder, the pigment of 0-5 parts by weight, 0-3 parts by weight essence and 2-18 parts by weight water, continues dispersion 2 hours, It is filtered and packaged after mixing evenly with 150 mesh filter screens.
Beneficial effects of the present invention are as follows: the aphthopyrans class light of safety and environmental protection is used in the water-based nail polish that the light becomes Become powder, it is made to change color different out and bright under irradiation by sunlight;It is environmentally protective using water as primary solvent, Low emission VOCs;Smell is low, and the fragrance of available similar perfume after essence is added;It is smooth ventilative, to human nails and skin It stimulates small;Warm water impregnates a few minutes, that is, detachable first-class feature.
Specific embodiment
The following is a clear and complete description of the technical scheme in the embodiments of the invention, it is clear that described implementation Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is general Logical technical staff every other embodiment obtained without making creative work, belongs to protection of the present invention Range.
Embodiment 1: a kind of water-based nail polish that light becomes of the present invention, the ingredient of parts by weight:
Component Parts by weight Function
Styrene-acrylic emulsion 75 Film-forming resin
Alcohol ester 12 5 Coalescing agent
Oronain hectorite draws in department 1 Thicken suspending agent
Silica 1 Thicken suspending agent
Phenoxyethanol 3 Preservative
Light becomes powder 10 Light becomes powder
Aqueous defoamer 0.2 Other auxiliary agents
Aqueous dispersion 0.3 Other auxiliary agents
Aqueous anti-settling agent 0.5 Other auxiliary agents
Water 4 Solvent
High speed dispersion is uniformly mixed the water-based nail polish that light change is made after above each ingredient weighs.
Under 600 revs/min of revolving speed, addition styrene-acrylic emulsion, alcohol ester 12, Phenoxyethanol, aqueous defoamer, aqueous point Revolving speed is adjusted to 1000 revs/min after dispersion 30 minutes by powder and aqueous anti-settling agent, addition department drawing oronain hectorite, silica, Light becomes powder and water, continues dispersion 2 hours, is filtered and packaged after mixing evenly with 150 mesh filter screens.
Embodiment 2: a kind of water-based nail polish that light becomes of the present invention, the ingredient of parts by weight:
Under 600 revs/min of revolving speed, addition styrene-acrylic emulsion, polyaminoester emulsion, alcohol ester 12, dipropylene glycol methyl ether, two Revolving speed is adjusted to 1000 after dispersion 30 minutes by propandiol butyl ether, Phenoxyethanol, pungent glycol, aqueous defoamer and aqueous dispersion Rev/min, oronain hectorite, silica draw in addition department, and light becomes powder, and red No. 6 and water continue dispersion 2 hours, after mixing evenly It is filtered and packaged with 150 mesh filter screens.
Embodiment 3: a kind of water-based nail polish that light becomes of the present invention, the ingredient of parts by weight:
Under 600 revs/min of revolving speed, polyaminoester emulsion, dipropylene glycol methyl ether, dipropylene, aqueous dispersion is added Revolving speed is adjusted to 1000 revs/min after dispersion 30 minutes, is added by agent, aqueous defoamer, Phenoxyethanol and Sensiva SC50 Polyacrylic acid, light become powder, iron oxide yellow, peach flavor and water, continue dispersion 2 hours, after mixing evenly with 150 mesh filter screens It filters and packages.
Embodiment 4: a kind of water-based nail polish that light becomes of the present invention, the ingredient of parts by weight:
Component Parts by weight Function
Polyaminoester emulsion 65 Film-forming resin
Polyvinyl alcohol 5 Film-forming resin
Alcohol ester 12 3 Coalescing agent
Dipropylene glycol methyl ether 1 Coalescing agent
Silica 5 Thicken suspending agent
Pungent glycol 2 Preservative
Sensiva SC50 1 Preservative
Light becomes powder 5 Light becomes powder
Aqueous defoamer 0.5 Other auxiliary agents
Aqueous dispersion 0.5 Other auxiliary agents
It is No. 6 red 2 Pigment
Pearl mica 2 Pigment
Flavoring rose essence 1 Essence
Water 7 Solvent
Under 600 revs/min of revolving speed, polyaminoester emulsion is added, polyvinyl alcohol, alcohol ester 12, dipropylene glycol methyl ether is pungent Revolving speed is adjusted to 1000 revs/min after dispersion 30 minutes by glycol, Sensiva SC50, aqueous defoamer and aqueous dispersion, Silica is added, light becomes powder, No. 6 red, pearl mica, and flavoring rose essence and water continue dispersion 2 hours, after mixing evenly with 150 Mesh filter screen filters and packages.
Embodiment 5: a kind of light change nail polish of the present invention, the ingredient of parts by weight:
Component Parts by weight Function
Styrene-acrylic emulsion 30 Film-forming resin
Polyaminoester emulsion 40 Film-forming resin
Polyvinyl alcohol 5 Film-forming resin
Alcohol ester 12 2 Coalescing agent
Dipropylene glycol methyl ether 2 Coalescing agent
Dipropylene 1 Coalescing agent
Silica 1 Thicken suspending agent
Polyacrylic acid 3 Thicken suspending agent
Phenoxyethanol 1 Preservative
Pungent glycol 1 Preservative
Sensiva SC50 0.5 Preservative
Light becomes powder 5 Light becomes powder
Aqueous defoamer 0.2 Other auxiliary agents
Aqueous dispersion 0.2 Other auxiliary agents
Aqueous anti-settling agent 0.6 Other auxiliary agents
Colored PET paillette 1 Pigment
Flavoring rose essence 3 Essence
Water 3.5 Solvent
Under 600 revs/min of revolving speed, styrene-acrylic emulsion, polyaminoester emulsion, polyvinyl alcohol, alcohol ester 12, dipropyl two is added Alcohol methyl ether, dipropylene, pungent glycol, Phenoxyethanol, aqueous defoamer, aqueous dispersion and aqueous anti-settling agent, dispersion 30 Revolving speed is adjusted to 1000 revs/min after minute, is added silica, polyacrylic acid, light becomes powder, colored PET paillette, flavoring rose essence and Water continues dispersion 2 hours, is filtered and packaged after mixing evenly with 150 mesh filter screens.
Test case 1
Light prepared by 1-5 of the embodiment of the present invention becomes water-based nail polish Performance Evaluation by QB/T 2287-2011 nail polish In II type technical requirements detect drying time;Photochromic properties are set according to the Artificial nail that uniform painting brushes light change nail polish Under illumination, observes its discoloration and detected;Smell and irritation are according to brushing nail polish on volunteer's nail and skin It is tested.It the results are shown in Table 1.
Table 1
Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5
Drying time <8min <8min <8min <8min <8min
Optically variable effect It meets the requirements It meets the requirements It meets the requirements It meets the requirements It meets the requirements
Smell It is not pungent It is not pungent It is not pungent It is not pungent It is not pungent
Irritation Irritation is low Irritation is low Irritation is low Irritation is low Irritation is low
Test result meets relevant criterion, finds from test result: using safety and environmental protection in the water-based nail polish of change Aphthopyrans class light becomes powder, it is made to change color different out and bright under irradiation by sunlight;Using water as main molten Agent, environmentally protective, low emission VOCs;Smell is low, and the fragrance of available similar perfume after essence is added;It is smooth ventilative, to people Body nail and skin irritatin are small;Warm water impregnates a few minutes, that is, detachable first-class feature.
The foregoing description of the disclosed embodiments enables those skilled in the art to implement or use the present invention. Various modifications to these embodiments will be readily apparent to those skilled in the art, defined herein General Principle can realize in other embodiments without departing from the spirit or scope of the present invention.Therefore, originally Invention is not intended to be limited to the embodiments shown herein, and is to fit to special with principles disclosed herein and novelty The consistent widest scope of point.

Claims (10)

1. the water-based nail polish that a kind of light becomes, which is characterized in that the component including following parts by weight: film-forming resin: 60-80 weight Part, coalescing agent: 3-5 parts by weight thicken suspending agent: 2-5 parts by weight, preservative: 1-3 parts by weight, light become powder: 5-10 weight Part, other auxiliary agents: 0.5-1.0 parts by weight, pigment: 0-5 parts by weight, essence: 0-3 parts by weight and water: 2-18 parts by weight.
2. the water-based nail polish that a kind of light becomes according to claim 1, which is characterized in that the film-forming resin is phenylpropyl alcohol cream One of liquid, polyaminoester emulsion and polyvinyl alcohol are a variety of.
3. the water-based nail polish that a kind of light becomes according to claim 1, which is characterized in that the coalescing agent alcohol ester 12, One of dipropylene glycol methyl ether and dipropylene are a variety of.
4. the water-based nail polish that a kind of light becomes according to claim 1, which is characterized in that the thickening suspending agent is that chlorine draws in department It is one or more in ammonium hectorite, silica and polyacrylic acid.
5. the water-based nail polish that a kind of light becomes according to claim 1, which is characterized in that the preservative be Phenoxyethanol, It is one or more in pungent glycol and Sensiva SC50.
6. the water-based nail polish that a kind of light becomes according to claim 1, which is characterized in that the light becomes powder to contain naphtho- pyrrole It mutters the photochromic material of organic matter (7- tert-butyl-n-(the fluoro- 4- methylsulfonyl aminophenyl of 3-)-dihydrobenzopyrans -3- formamide) Material.
7. the water-based nail polish that a kind of light becomes according to claim 1, which is characterized in that other described auxiliary agents are aqueous defoaming It is one or more in agent, aqueous dispersion, aqueous wetting agent and aqueous anti-settling agent.
8. the water-based nail polish that a kind of light becomes according to claim 1, which is characterized in that the pigment is inorganic pigment, has It is one or more in machine pigment, pearl mica and colour PET paillette.
9. the water-based nail polish that a kind of light becomes according to claim 1, which is characterized in that the essence is that asepsis environment-protecting is fragrant Essence.
10. a kind of preparation method for the water-based nail polish that light becomes, feature described in -9 any claims exist according to claim 1 In preparing in accordance with the following methods: under 600 revs/min of revolving speed, be added the film-forming resin of 60-80 parts by weight, 3-5 parts by weight at Revolving speed is adjusted to 1000 revs/min after dispersion 30 minutes by film auxiliary agent, 1-3 parts by weight preservative, other auxiliary agents of 0.5-1.0 parts by weight Clock is added 2-5 parts by weight and thickens suspending agent, and 5-10 parts by weight light becomes powder, the pigment of 0-5 parts by weight, 0-3 parts by weight essence and 2- 18 parts by weight water continue dispersion 2 hours, are filtered and packaged after mixing evenly with 150 mesh filter screens.
CN201910326612.2A 2019-04-23 2019-04-23 A kind of water-based nail polish and preparation method thereof that light becomes Pending CN110200835A (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110527382A (en) * 2019-09-09 2019-12-03 天津孚信阳光科技有限公司 A kind of photochromic fragrance slow-release water paint and preparation method thereof
CN110746395A (en) * 2019-11-04 2020-02-04 上海甘田光学材料有限公司 Mercapto-containing naphthopyran photochromic compound and preparation method and application thereof
CN112089634A (en) * 2020-10-29 2020-12-18 广东雅丽诗科技有限公司 Color-changing nail polish
CN112791012A (en) * 2021-01-11 2021-05-14 金华市科维思日化有限公司 High-light-transmission safe water-based nail polish and preparation method thereof
CN112807246A (en) * 2019-11-15 2021-05-18 万华化学集团股份有限公司 Ultraviolet-curing optically variable nail polish and preparation method thereof
CN112826753A (en) * 2021-01-11 2021-05-25 金华市科维思日化有限公司 Environment-friendly high-stability water-based frosted nail polish and preparation method thereof
CN112826764A (en) * 2021-01-11 2021-05-25 金华市科维思日化有限公司 Environment-friendly long-acting water-based temperature-variable nail polish and preparation method thereof

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110527382A (en) * 2019-09-09 2019-12-03 天津孚信阳光科技有限公司 A kind of photochromic fragrance slow-release water paint and preparation method thereof
CN110746395A (en) * 2019-11-04 2020-02-04 上海甘田光学材料有限公司 Mercapto-containing naphthopyran photochromic compound and preparation method and application thereof
CN112807246A (en) * 2019-11-15 2021-05-18 万华化学集团股份有限公司 Ultraviolet-curing optically variable nail polish and preparation method thereof
CN112807246B (en) * 2019-11-15 2023-01-13 万华化学集团股份有限公司 Ultraviolet-curing optically variable nail polish and preparation method thereof
CN112089634A (en) * 2020-10-29 2020-12-18 广东雅丽诗科技有限公司 Color-changing nail polish
CN112791012A (en) * 2021-01-11 2021-05-14 金华市科维思日化有限公司 High-light-transmission safe water-based nail polish and preparation method thereof
CN112826753A (en) * 2021-01-11 2021-05-25 金华市科维思日化有限公司 Environment-friendly high-stability water-based frosted nail polish and preparation method thereof
CN112826764A (en) * 2021-01-11 2021-05-25 金华市科维思日化有限公司 Environment-friendly long-acting water-based temperature-variable nail polish and preparation method thereof

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