CN112791012A - High-light-transmission safe water-based nail polish and preparation method thereof - Google Patents

High-light-transmission safe water-based nail polish and preparation method thereof Download PDF

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Publication number
CN112791012A
CN112791012A CN202110027775.8A CN202110027775A CN112791012A CN 112791012 A CN112791012 A CN 112791012A CN 202110027775 A CN202110027775 A CN 202110027775A CN 112791012 A CN112791012 A CN 112791012A
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water
nail polish
light
stirring
transmission
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汪胜根
金继月
戴永求
叶志勇
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Jinhua Kvs Daily Chemical Co ltd
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Jinhua Kvs Daily Chemical Co ltd
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/87Polyurethanes
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q3/00Manicure or pedicure preparations
    • A61Q3/02Nail coatings
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/26Optical properties
    • A61K2800/262Transparent; Translucent

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Cosmetics (AREA)

Abstract

The invention discloses a high-light-transmission safe water-based nail polish which comprises film-forming resin, a film-forming additive, a thickening suspending agent, a preservative, an additive, pigment, essence and the balance of deionized water. The pigment is a water-based polyurethane high-molecular dye; the prepared high-light-transmission safe water-based nail polish does not dye nails, is not enriched in human bodies, can completely neglect the damage of pigments to human bodies, has high safety factor and high light transmission, and can have a crystal clear feeling after film forming.

Description

High-light-transmission safe water-based nail polish and preparation method thereof
The technical field is as follows:
the invention relates to the technical field of nail polish, in particular to high-light-transmission safe water-based nail polish and a preparation method thereof.
Background art:
the nail polish belongs to a large class of products in color cosmetic series, is widely used for beautifying and decorating fingernails or toenails, has rich and gorgeous color and both beautiful appearance and protective effect, and is a class of cosmetics which can not be replaced by women who love beauty. Its development has been in the past for thousands of years. With the improvement of quality of life, people have strong pursuit of beauty, originally only luxury goods of the money, are popularized to common people now, and become popular goods for mass consumption.
At present, nail polish on the market is mainly divided into traditional solvent type nail polish and water-based nail polish. The traditional solvent type nail polish is prepared by stirring and mixing additives such as a volatile organic solvent, a film forming agent, a plasticizer, a thickening suspending agent, a pigment, an essence and the like. The traditional solvent type nail polish has the advantages of high gloss, strong adhesive force, strong water resistance, high re-adhesion resistance and the like, but the traditional solvent type nail polish has pungent smell and strong corrosivity and has great harm to nails and human bodies.
The water-based nail polish is prepared by stirring and mixing additives such as water, a water-based film-forming agent, a pigment, an essence and the like. Has the characteristics of low odor, low irritation, high gloss, strong adhesive force and environmental protection. However, the pigments used in the water-based nail polish in the market, especially the organic pigments, can permeate into the cell walls of the skin of a human body due to small molecular size, so that the phenomena of nail staining and skin staining are caused, and the pigments are relatively harmful to the human body due to long-time enrichment and are unsafe. Meanwhile, the light transmittance of the water-based nail polish on the market is poor, and the glittering and translucent feeling can not be achieved.
The invention content is as follows:
the invention aims to solve the technical problem of providing the high-light-transmission safe water-based nail polish which cannot dye nails, cannot be enriched in human bodies, can completely neglect the damage of pigments to human bodies, has high safety coefficient and high light transmission, and can have a glittering and translucent feeling after film forming.
In order to solve the problems, the invention adopts the following technical scheme: the high-light-transmission safe water-based nail polish comprises the following components in parts by weight:
Figure BDA0002890963470000021
the balance of deionized water
The pigment is a water-based polyurethane high-molecular dye.
The further technical scheme is that the film-forming resin is one or a mixture of more than two of styrene-acrylic emulsion, acrylate emulsion, polyurethane emulsion and polyvinyl alcohol.
The film-forming assistant is one or the mixture of more than two of dipropylene glycol methyl ether (DPM), diethylene glycol butyl ether (BDG), ethylene glycol butyl ether (BCS), dipropylene glycol butyl ether (DPnB) and decaglycol ester.
The further technical proposal is that the thickening suspending agent is one or the mixture of more than two of selectrium chloride hectorite, silica and carbomer.
The further technical scheme is that the preservative is phenoxyethanol.
The further technical scheme is that the auxiliary agent is one or a mixture of more than two of a water-based dispersing agent, a water-based wetting agent, a water-based anti-settling agent and a water-based defoaming agent.
A preparation method of a high-light-transmission safe water-based nail polish comprises the following steps:
1) the film-forming resin, the film-forming additive, the thickening suspending agent, the preservative, the additive, the pigment, the essence and the deionized water are dispersed and stirred at a high speed and mixed to obtain the paint.
The water-based polyurethane high-molecular dye is a colored high-molecular polymer formed by introducing organic dye molecules into the main chain or the side chain of high-molecular water-based polyurethane resin through chemical modification. The dye has the advantages of high stability, compatibility, easy film forming property, solvent wiping resistance, heat resistance and migration resistance of the waterborne polyurethane resin, and strong absorptivity and colorability of the organic dye to light.
The waterborne polyurethane macromolecular dye can be completely dissolved in a waterborne nail polish system, but is not dispersed in the waterborne nail polish system in a micro-particle shape, so sunlight can penetrate the waterborne nail polish prepared from the waterborne polyurethane macromolecular dye, the refraction and scattering phenomena are almost few, meanwhile, the molecular size of the waterborne polyurethane macromolecular dye is large, the molecular size of the waterborne polyurethane macromolecular dye is difficult to penetrate the cell wall of the skin of a human body, the prepared waterborne nail polish has high light transmittance, the film can have a glittering and translucent feeling after being formed, the nail is not dyed, the enrichment in the human body is avoided, the harm to the human body caused by the pigment can be completely ignored, and the safety coefficient is high.
The essence is water-soluble nontoxic environment-friendly essence.
A preparation method of a high-light-transmission safe water-based nail polish comprises the following steps:
1) adding the film-forming resin, the film-forming additive and deionized water into a reaction kettle, and starting stirring at the stirring speed of 1500 revolutions per minute;
2) adding the auxiliary agent, the preservative and the thickening suspending agent in turn while stirring. When the addition is finished, the stirring speed is increased to 2000 rpm, and the mixing and stirring are continued for 15 minutes;
3) after the material bodies are uniformly stirred, defoaming the material bodies by using a homogenizer;
4) after defoaming, filtering the material body, and discharging to obtain the high-light-transmission safe water-based nail polish base material;
5) adding the pigment into the high-light-transmission safe water-based nail polish base material prepared from the step 4), and carrying out high-speed dispersion stirring for 20 minutes at a stirring speed of 3000 revolutions per minute. Grinding the uniformly mixed and stirred material body by a basket type sand mill for 3 times to obtain the high-light-transmission safe water-based nail polish color paste;
6) according to actual requirements, adding the high-light-transmission safe water-based nail polish base material prepared from the step 4), the high-light-transmission safe water-based nail polish color paste prepared from the step 5) and essence, mixing colors, adding fragrance, mixing and stirring. Stirring at 3000 r/min for 10 min to obtain the high-light-transmission safe water-based nail polish.
The invention has the beneficial effects that:
according to the invention, by optimizing the formula and the preparation method of the water-based nail polish, the water-based polyurethane polymer dye is used, and can be completely dissolved in a water-based nail polish system, and has the characteristics of large molecular size and difficulty in penetrating through cell walls of human skin, so that the prepared water-based nail polish has the characteristics of no nail dyeing, no enrichment in human bodies, capability of completely neglecting the harm of pigments to human bodies, high safety coefficient and high light transmittance, and the water-based nail polish can have a glittering and translucent feeling after film forming.
The specific implementation mode is as follows:
the following detailed description of the preferred embodiments of the present invention is provided to enable those skilled in the art to more readily understand the advantages and features of the present invention and to clearly and unequivocally define the scope of the present invention.
Example one
The high-light-transmission safe water-based nail polish comprises the following components in parts by weight:
Figure BDA0002890963470000041
the balance of deionized water
The pigment is a water-based polyurethane high-molecular dye.
The film-forming resin is a mixture of styrene-acrylic emulsion and acrylate emulsion, and the weight ratio of the styrene-acrylic emulsion to the acrylate emulsion is 1: 2.
The film-forming assistant is a mixture of dipropylene glycol butyl ether (DPnB) and dodecanol ester, and the weight ratio of the dipropylene glycol butyl ether (DPnB) to the dodecanol ester is 1: 1.
The thickening suspending agent is silica.
The preservative is phenoxyethanol.
The auxiliary agent is a mixture of a water-based dispersing agent, a water-based wetting agent, a water-based anti-settling agent and a water-based defoaming agent, and the weight ratio of the auxiliary agent to the water-based wetting agent to the water-based anti-settling agent is 1:1:1: 1.
The preparation method of the high-light-transmittance safe water-based nail polish comprises the following steps:
1) adding styrene-acrylic emulsion, acrylic ester emulsion, dipropylene glycol butyl ether (DPnB), lauryl ester and deionized water into a reaction kettle, and starting stirring at 1500 rpm;
2) adding water dispersant, water wetting agent, water anti-settling agent, water defoaming agent, phenoxyethanol and silica in turn while stirring. When the addition is finished, the stirring speed is increased to 2000 rpm, and the mixing and stirring are continued for 15 minutes;
3) after the material bodies are uniformly stirred, defoaming the material bodies by using a homogenizer;
4) after defoaming, filtering the material body, and discharging to obtain the high-light-transmission safe water-based nail polish base material;
5) adding the water-based polyurethane polymer dye into the high-light-transmission safe water-based nail polish base material prepared in the step 4), and dispersing and stirring at a high speed for 20 minutes at a stirring speed of 3000 r/min. Grinding the uniformly mixed and stirred material body by a basket type sand mill for 3 times to obtain the high-light-transmission safe water-based nail polish color paste;
6) according to actual requirements, adding the high-light-transmission safe water-based nail polish base material prepared from the step 4), the high-light-transmission safe water-based nail polish color paste prepared from the step 5) and essence, mixing colors, adding fragrance, mixing and stirring. Stirring at 3000 r/min for 10 min to obtain the high-light-transmission safe water-based nail polish.
Example two
The high-light-transmission safe water-based nail polish comprises the following components in parts by weight:
Figure BDA0002890963470000051
Figure BDA0002890963470000061
the balance of deionized water
The pigment is a water-based polyurethane high-molecular dye.
The film-forming resin is a mixture of acrylate emulsion and polyvinyl alcohol, and the weight ratio of the acrylate emulsion to the polyvinyl alcohol is 2: 1.
The film-forming assistant is a mixture of diethylene glycol butyl ether (BDG), dipropylene glycol butyl ether (DPnB) and glycol decahydrate, and the weight ratio of the film-forming assistant is 1:1: 2.
the thickening suspending agent is selectrium chloride hectorite.
The preservative is phenoxyethanol.
The auxiliary agent is a mixture of a water-based dispersing agent, a water-based wetting agent, a water-based anti-settling agent and a water-based defoaming agent, and the weight ratio of the auxiliary agent to the water-based wetting agent to the water-based anti-settling agent is 1:1:2: 1.
The preparation method of the high-light-transmittance safe water-based nail polish comprises the following steps:
1) adding acrylate emulsion, polyvinyl alcohol, diethylene glycol butyl ether (BDG), dipropylene glycol butyl ether (DPnB), dodecanol ester and deionized water into a reaction kettle, and starting stirring at 1500 rpm;
2) adding water-based dispersing agent, water-based wetting agent, water-based anti-settling agent, water-based defoaming agent, phenoxyethanol and sjoram hectorite in sequence while stirring. When the addition is finished, the stirring speed is increased to 2000 rpm, and the mixing and stirring are continued for 15 minutes;
3) after the material bodies are uniformly stirred, defoaming the material bodies by using a homogenizer;
4) after defoaming, filtering the material body, and discharging to obtain the high-light-transmission safe water-based nail polish base material;
5) adding the water-based polyurethane polymer dye into the high-light-transmission safe water-based nail polish base material prepared in the step 4), and dispersing and stirring at a high speed for 20 minutes at a stirring speed of 3000 r/min. Grinding the uniformly mixed and stirred material body by a basket type sand mill for 3 times to obtain the high-light-transmission safe water-based nail polish color paste;
6) according to actual requirements, adding the high-light-transmission safe water-based nail polish base material prepared from the step 4), the high-light-transmission safe water-based nail polish color paste prepared from the step 5) and essence, mixing colors, adding fragrance, mixing and stirring. Stirring at 3000 r/min for 10 min to obtain the high-light-transmission safe water-based nail polish.
EXAMPLE III
The high-light-transmission safe water-based nail polish comprises the following components in parts by weight:
Figure BDA0002890963470000071
the balance of deionized water
The pigment is a water-based polyurethane high-molecular dye.
The film-forming resin is a mixture of acrylate emulsion, polyurethane emulsion and polyvinyl alcohol, and the weight ratio of the acrylate emulsion to the polyurethane emulsion to the polyvinyl alcohol is 1:2: 1.
The film-forming assistant is a mixture of dipropylene glycol butyl ether (DPnB) and dodecanol ester, and the weight ratio of the dipropylene glycol butyl ether (DPnB) to the dodecanol ester is 1: 1.
The thickening suspending agent is a mixture of selectrium chloride hectorite and carbomer, and the weight ratio of the selectrium chloride hectorite to the carbomer is 1: 1.
The preservative is phenoxyethanol.
The auxiliary agent is a mixture of a water-based dispersing agent, a water-based wetting agent, a water-based anti-settling agent and a water-based defoaming agent, and the weight ratio of the auxiliary agent to the water-based wetting agent to the water-based anti-settling agent is 2:1:1: 1.
The preparation method of the high-light-transmittance safe water-based nail polish comprises the following steps:
1) adding acrylate emulsion, polyurethane emulsion, polyvinyl alcohol, dipropylene glycol butyl ether (DPnB), lauryl ester and deionized water into a reaction kettle, and starting stirring at 1500 revolutions per minute;
2) adding water-based dispersing agent, water-based wetting agent, water-based anti-settling agent, water-based defoaming agent, phenoxyethanol, selelammonium hectorite and carbomer in sequence while stirring. When the addition is finished, the stirring speed is increased to 2000 rpm, and the mixing and stirring are continued for 15 minutes;
3) after the material bodies are uniformly stirred, defoaming the material bodies by using a homogenizer;
4) after defoaming, filtering the material body, and discharging to obtain the high-light-transmission safe water-based nail polish base material;
5) adding the water-based polyurethane polymer dye into the high-light-transmission safe water-based nail polish base material prepared in the step 4), and dispersing and stirring at a high speed for 20 minutes at a stirring speed of 3000 r/min. Grinding the uniformly mixed and stirred material body by a basket type sand mill for 3 times to obtain the high-light-transmission safe water-based nail polish color paste;
6) according to actual requirements, adding the high-light-transmission safe water-based nail polish base material prepared from the step 4), the high-light-transmission safe water-based nail polish color paste prepared from the step 5) and essence, mixing colors, adding fragrance, mixing and stirring. Stirring at 3000 r/min for 10 min to obtain the high-light-transmission safe water-based nail polish.
Test one
The aqueous nail varnishes prepared in examples 1 to 3 according to the invention and the commercial products were evaluated for their properties. The drying time is detected according to the technical requirements of type II in QB/T2287-. The light transmittance is observed after the high-light-transmittance safe water-based nail polish is dried to form a film. Nail staining, odor and irritation were tested according to the application of nail polish to the nails and skin of volunteers, and the results are shown in Table 1.
TABLE 1
Figure BDA0002890963470000081
Figure BDA0002890963470000091
From the test results, it was found that: the water-based nail polish is prepared by using the safe water-based polyurethane polymer dye and matching with other additives, all performance indexes conform to the specification of QB/T2287 plus 2011, the water-based polyurethane polymer dye has the characteristics of being completely dissolved in a water-based nail polish system, having large molecular size and being difficult to permeate through the skin cell walls of human bodies, the prepared water-based nail polish has the characteristics which are not possessed by the water-based nail polish on the market, does not dye nails, is not enriched in the human bodies, can completely ignore the damage of pigments to the human bodies, has high safety coefficient and high light transmittance, can have a glittering and translucent feeling after film forming, and cannot embody the advantages of the product on the market.
The above description is only for the specific embodiment of the present invention, but the protection scope of the present invention is not limited thereto, and any changes or substitutions that are not thought of through the inventive work should be covered by the protection scope of the present invention.

Claims (7)

1. A high-light-transmission safe water-based nail polish is characterized in that: the composition comprises the following components in parts by weight:
Figure FDA0002890963460000011
the balance of deionized water
The pigment is a water-based polyurethane high-molecular dye.
2. The high light transmission safety aqueous nail polish of claim 1, wherein: the film-forming resin is one or the mixture of more than two of styrene-acrylic emulsion, acrylate emulsion, polyurethane emulsion and polyvinyl alcohol.
3. The high light transmission safety aqueous nail polish of claim 1, wherein: the film-forming assistant is one or the mixture of more than two of dipropylene glycol methyl ether (DPM), diethylene glycol butyl ether (BDG), ethylene glycol butyl ether (BCS), dipropylene glycol butyl ether (DPnB) and decaglycol ester.
4. The high light transmission safety aqueous nail polish of claim 1, wherein: the thickening suspending agent is one or the mixture of more than two of selectrium chloride hectorite, silica and carbomer.
5. The high light transmission safety aqueous nail polish of claim 1, wherein: the preservative is phenoxyethanol.
6. The high light transmission safety aqueous nail polish of claim 1, wherein: the auxiliary agent is one or the mixture of more than two of a water-based dispersing agent, a water-based wetting agent, a water-based anti-settling agent and a water-based defoaming agent.
7. The preparation method of the high-light-transmission safety water-based nail polish as claimed in claim 1, wherein the preparation method comprises the following steps: the method comprises the following steps:
1) adding the film-forming resin, the film-forming additive and deionized water into a reaction kettle, and starting stirring at the stirring speed of 1500 revolutions per minute;
2) adding the auxiliary agent, the preservative and the thickening suspending agent in turn while stirring. When the addition is finished, the stirring speed is increased to 2000 rpm, and the mixing and stirring are continued for 15 minutes;
3) after the material bodies are uniformly stirred, defoaming the material bodies by using a homogenizer;
4) after defoaming, filtering the material body, and discharging to obtain the high-light-transmission safe water-based nail polish base material;
5) adding the pigment into the high-light-transmission safe water-based nail polish base material prepared from the step 4), and carrying out high-speed dispersion stirring for 20 minutes at a stirring speed of 3000 revolutions per minute. Grinding the uniformly mixed and stirred material body by a basket type sand mill for 3 times to obtain the high-light-transmission safe water-based nail polish color paste;
6) according to actual requirements, adding the high-light-transmission safe water-based nail polish base material prepared from the step 4), the high-light-transmission safe water-based nail polish color paste prepared from the step 5) and essence, mixing colors, adding fragrance, mixing and stirring. Stirring at 3000 r/min for 10 min to obtain the high-light-transmission safe water-based nail polish.
CN202110027775.8A 2021-01-11 2021-01-11 High-light-transmission safe water-based nail polish and preparation method thereof Pending CN112791012A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113384489A (en) * 2021-06-16 2021-09-14 宇虹颜料股份有限公司 Processing method of water-based nail polish preparation

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108272656A (en) * 2018-01-12 2018-07-13 名仕科技股份有限公司 A kind of water-soluble nail polish and preparation method thereof
CN110200835A (en) * 2019-04-23 2019-09-06 金华市科维思日化有限公司 A kind of water-based nail polish and preparation method thereof that light becomes

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108272656A (en) * 2018-01-12 2018-07-13 名仕科技股份有限公司 A kind of water-soluble nail polish and preparation method thereof
CN110200835A (en) * 2019-04-23 2019-09-06 金华市科维思日化有限公司 A kind of water-based nail polish and preparation method thereof that light becomes

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113384489A (en) * 2021-06-16 2021-09-14 宇虹颜料股份有限公司 Processing method of water-based nail polish preparation

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