CN110200849A - A kind of light change nail polish of safety and environmental protection - Google Patents
A kind of light change nail polish of safety and environmental protection Download PDFInfo
- Publication number
- CN110200849A CN110200849A CN201910326729.0A CN201910326729A CN110200849A CN 110200849 A CN110200849 A CN 110200849A CN 201910326729 A CN201910326729 A CN 201910326729A CN 110200849 A CN110200849 A CN 110200849A
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- Prior art keywords
- light
- safety
- nail polish
- environmental protection
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/4973—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with oxygen as the only hetero atom
- A61K8/498—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with oxygen as the only hetero atom having 6-membered rings or their condensed derivatives, e.g. coumarin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/731—Cellulose; Quaternized cellulose derivatives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8147—Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/85—Polyesters
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q3/00—Manicure or pedicure preparations
- A61Q3/02—Nail coatings
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Emergency Medicine (AREA)
- Cosmetics (AREA)
Abstract
The invention proposes a kind of light of safety and environmental protection to become nail polish, including following component: butyl acetate, ethyl acetate, nitrocellulose, acrylic resin, saturated polyester resin, denatured ethyl alcohol, plasticizer, thickening suspending agent, light change powder, pigment and essence.Light of the present invention becomes in nail polish and becomes powder using the aphthopyrans class light of safety and environmental protection, changes color different out and bright under irradiation by sunlight；Using asepsis environment-protecting essence, there is the fragrance of similar perfume；Using to human body and the lesser ethyl acetate of skin irritatin, butyl acetate, denatured ethyl alcohol has abandoned the toluene big to human injury, acetone as solvent；The features such as other materials is selected without benzene, and no toluene, no DBP, formaldehydeless material is smaller to human nails and skin damage, can achieve the purpose that discoloration according to illumination, and bright, adhesive force is strong, and storage stability is high.
Description
Technical field
The invention belongs to cosmetic technical fields, and in particular to a kind of light change nail polish of safety and environmental protection.
Background technique
Nail polish belongs to the color make-up class product in cosmetics, is widely used in finger nail or toenail beautifying and decorating, color
It enriches gorgeous, has both beautiful and protective effect, be the irreplaceable a kind of cosmetics of Ms of liking to be beautiful.Existing nail polish is general only
There is fixed color, it is more dull, it is not able to satisfy women to the multifarious demand of nail polish.There are also some patent reports
Some light become nail polish products.
CN201310746497.7 discloses a kind of Novel photochromic nail polish, has and changes under irradiation by sunlight
For different colors, and uniform hue, the high feature of firmness.But it uses the camphor of dangerous environmental protection as plasticising
Agent.CN201410582427.7 discloses a kind of long-acting color changeable nail enamel, has a bright color, changeable colour, good economy performance,
The features such as easily dry.But use the acetone disabled in cosmetic industry as solvent, human health is injured big.
CN201110391738.1, CN201710179691.X individually disclose a kind of color changeable nail enamel composition and a kind of discoloration
Nail polish all has and meets phototropic, generates the effect of different decoration patterns.But the toluene for using everybody to fear is as solvent,
It is not suitable for marketing.In addition, market glazing become light used in nail polish become powder or color-change powder to human health not
Benefit, and will cause environmental pollution.
Summary of the invention
The purpose of the present invention is being to solve defect of the existing technology, the light for providing a kind of safety and environmental protection becomes nail
Oil.
The technical scheme of the present invention is realized as follows:
Technical solution 1: a kind of light change nail polish of safety and environmental protection, including following component: butyl acetate, ethyl acetate, nitre
Chemical fibre dimension, acrylic resin, saturated polyester resin, denatured ethyl alcohol, plasticizer thicken suspending agent, and light becomes powder, pigment and essence.
Technical solution 2: on the basis of technical solution 1, following improvement is further done, the component including following parts by weight:
Butyl acetate: 25-35 parts by weight, ethyl acetate: 20-30 parts by weight, nitrocellulose: 10-15 parts by weight, acrylic resin: 8-
12 parts by weight, saturated polyester resin: 5-8 parts by weight, denatured ethyl alcohol: 4-6 parts by weight, plasticizer: 2-5 parts by weight, thickening suspend
Agent: 1-4 parts by weight, light change powder: 5-10 parts, pigment: 0-5 parts by weight and essence: 0-3 parts by weight.
Technical solution 3: on the basis of technical solution 1, following improvement is further done, the saturated polyester resin is inclined
The two or more copolymers of benzenetricarboxylic anhydride, neopentyl glycol and pentaerythrite and adipic acid.
Technical solution 4: on the basis of technical solution 1, following improvement is further done, the plasticizer is safety and environmental protection
Tributyl 2-acetylcitrate.
Technical solution 5: on the basis of technical solution 1, following improvement is further done, the thickening suspending agent is that department draws
One of oronain hectorite and silica are a variety of.
Technical solution 6: on the basis of technical solution 1, following improvement is further done, the light becomes powder to contain naphtho-
Pyrans organic matter (7- tert-butyl-n-(the fluoro- 4- methylsulfonyl aminophenyl of 3-)-dihydrobenzopyrans -3- formamide) it is photochromic
Material.Naphthopyran compounds had occurred in light quality colourshifting process three-dimensional structure variation, in the solution when, absorb
Usually in UV absorption area, color is not presented in wavelength, and heterolytic fission, the conformation of molecule occur for C-O key in molecule after by ultraviolet excitation
It changes a lot with electronic configuration, shows colorful color after absorbing red shift.Molecule after its scission of link is commonly referred to as
" open loop body " or " discoloration member ", under longer wavelength light action, open loop body occurs cyclization reaction and replys as starting chemical combination
Object.
Technical solution 7: on the basis of technical solution 1, following improvement is further done, the pigment is inorganic pigment, has
It is one or more in machine pigment, pearl mica and colour PET paillette.
Technical solution 8: on the basis of technical solution 1, following improvement is further done, the essence is that asepsis environment-protecting is fragrant
Essence.
Technical solution 9: a kind of light of safety and environmental protection becomes the preparation method of nail polish, prepares in accordance with the following methods: by acetic acid
Butyl ester, ethyl acetate, nitrocellulose, acrylic resin, saturated polyester resin, denatured ethyl alcohol, plasticizer thicken suspending agent, light
Become powder, pigment and essence mix in proportion, and high speed dispersion is uniform, and the light that safety and environmental protection is made becomes nail polish.
Technical solution 10: on the basis of technical solution 9, following improvement is further done, the revolving speed of the high speed dispersion is
1000-1500r/min。
Compared with prior art, beneficial effects of the present invention are as follows:
By adopting the above technical scheme, a kind of light of safety and environmental protection of the invention becomes in nail polish the naphthalene for using safety and environmental protection
And pyran light becomes powder, it is made to change color different out and bright under irradiation by sunlight；Light, which becomes in nail polish, to be used
Asepsis environment-protecting essence makes it have the fragrance of similar perfume；Use is to human body and the lesser second of skin irritatin in light change nail polish
Acetoacetic ester, butyl acetate, denatured ethyl alcohol have abandoned the toluene big to human injury, acetone as solvent；Light becomes in nail polish
Other materials is selected without benzene, no toluene, no DBP, formaldehydeless material.The light, which becomes nail polish, to be had to human nails and Pi
Skin injury is smaller, can achieve the purpose that discoloration according to illumination, and it is bright, adhesive force is strong, the spies such as storage stability height
Point.
Specific embodiment
The following is a clear and complete description of the technical scheme in the embodiments of the invention, it is clear that described implementation
Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is general
Logical technical staff every other embodiment obtained without making creative work, belongs to protection of the present invention
Range.
Embodiment 1: a kind of light change nail polish of safety and environmental protection of the present invention, the ingredient of parts by weight:
| Component | Parts by weight | Function |
| Butyl acetate | 35 | Solvent |
| Ethyl acetate | 30 | Solvent |
| Nitrocellulose | 10 | Film forming agent |
| Acrylic resin | 8 | Film forming agent |
| Saturated polyester resin | 5 | Film forming agent |
| Denatured ethyl alcohol | 4 | Solvent |
| Tributyl 2-acetylcitrate | 2 | Plasticizer |
| Silica | 1 | Thicken suspending agent |
| Light becomes powder | 5 | Light becomes powder |
Above each ingredient, which is uniformly mixed after weighing with 1000r/min dispersion, to be made the non-colored light change of safety and environmental protection and refers to
Nail polish.
Embodiment 2: a kind of light change nail polish of safety and environmental protection of the present invention, the ingredient of parts by weight:
Above each ingredient is uniformly mixed the pineapple taste white that safety and environmental protection is made with 1500r/min dispersion after weighing
Light becomes nail polish.
Embodiment 3: a kind of light change nail polish of safety and environmental protection of the present invention, the ingredient of parts by weight:
| Component | Parts by weight | Function |
| Butyl acetate | 25 | Solvent |
| Ethyl acetate | 20 | Solvent |
| Nitrocellulose | 13 | Film forming agent |
| Acrylic resin | 15 | Film forming agent |
| Saturated polyester resin | 8 | Film forming agent |
| Denatured ethyl alcohol | 4 | Solvent |
| Tributyl 2-acetylcitrate | 3 | Plasticizer |
| Oronain hectorite draws in department | 1 | Thicken suspending agent |
| Silica | 1 | Thicken suspending agent |
| Light becomes powder | 5 | Light becomes powder |
| Colored PET paillette | 2 | Pigment |
| Peach flavor | 3 | Essence |
Above each ingredient is uniformly mixed the honey peach taste colour that safety and environmental protection is made with 1200r/min dispersion after weighing
Paillette light becomes nail polish.
Embodiment 4: a kind of light change nail polish of safety and environmental protection of the present invention, the ingredient of parts by weight:
| Component | Parts by weight | Function |
| Butyl acetate | 27 | Solvent |
| Ethyl acetate | 21 | Solvent |
| Nitrocellulose | 18 | Film forming agent |
| Acrylic resin | 10 | Film forming agent |
| Saturated polyester resin | 6 | Film forming agent |
| Denatured ethyl alcohol | 5 | Solvent |
| Tributyl 2-acetylcitrate | 2 | Plasticizer |
| Oronain hectorite draws in department | 2 | Thicken suspending agent |
| Silica | 1 | Thicken suspending agent |
| Light becomes powder | 6 | Light becomes powder |
| Pearl mica | 2 | Pigment |
Above each ingredient is uniformly mixed the pearl mica light that safety and environmental protection is made with 1300r/min dispersion after weighing
Become nail polish.
Embodiment 5: a kind of light change nail polish of safety and environmental protection of the present invention, the ingredient of parts by weight:
Above each ingredient is uniformly mixed the grapefruit taste red that safety and environmental protection is made with 1100r/min dispersion after weighing
Light becomes nail polish.
Embodiment 6: a kind of light change nail polish of safety and environmental protection of the present invention, the ingredient of parts by weight:
| Component | Parts by weight | Function |
| Butyl acetate | 28 | Solvent |
| Ethyl acetate | 24 | Solvent |
| Nitrocellulose | 12 | Film forming agent |
| Acrylic resin | 10 | Film forming agent |
| Saturated polyester resin | 6 | Film forming agent |
| Denatured ethyl alcohol | 4 | Solvent |
| Tributyl 2-acetylcitrate | 3 | Plasticizer |
| Silica | 4 | Thicken suspending agent |
| Light becomes powder | 5 | Light becomes powder |
| Iron oxide black | 4 | Pigment |
Above each ingredient, which is uniformly mixed after weighing with 1400r/min dispersion, to be made the black light change of safety and environmental protection and refers to
Nail polish.
Embodiment 7: a kind of light change nail polish of safety and environmental protection of the present invention, the ingredient of parts by weight:
Above each ingredient is uniformly mixed the rose taste red that safety and environmental protection is made with 1250r/min dispersion after weighing
Pearl mica colour PET paillette light becomes nail polish.
Test case 1
The light of 1-7 of the embodiment of the present invention safety and environmental protection prepared is become into the Performance Evaluation of nail polish by QB/T 2287-2011
The technical requirements of I type detect drying time, firmness in nail polish；Heat-resisting according to T/ZZB 0623-2018, cold-resistant detection method
Testing product storage stability；Photochromic properties are placed under illumination according to the Artificial nail that uniform painting brushes light change nail polish, are seen
Its discoloration is examined to be detected；Smell and irritation are tested according to brushing nail polish on volunteer's nail and skin.Knot
Fruit is shown in Table 1.
Table 1
Test result meets relevant criterion.Found from test result: a kind of light become nail polish have to human nails and
Skin damage is smaller, can achieve the purpose that discoloration according to illumination, and it is bright, adhesive force is strong, the spies such as storage stability height
Point.
The foregoing description of the disclosed embodiments enables those skilled in the art to implement or use the present invention.
Various modifications to these embodiments will be readily apparent to those skilled in the art, defined herein
General Principle can realize in other embodiments without departing from the spirit or scope of the present invention.Therefore, originally
Invention is not intended to be limited to the embodiments shown herein, and is to fit to special with principles disclosed herein and novelty
The consistent widest scope of point.
Claims (10)
1. a kind of light of safety and environmental protection becomes nail polish, which is characterized in that including following component: butyl acetate, ethyl acetate, nitrification
Fiber, acrylic resin, saturated polyester resin, denatured ethyl alcohol, plasticizer thicken suspending agent, and light becomes powder, pigment and essence.
2. a kind of light of safety and environmental protection becomes nail polish according to claim 1, which is characterized in that the group including following parts by weight
Point: butyl acetate: 25-35 parts by weight, ethyl acetate: 20-30 parts by weight, nitrocellulose: 10-15 parts by weight, acrylic resin:
8-12 parts by weight, saturated polyester resin: 5-8 parts by weight, denatured ethyl alcohol: 4-6 parts by weight, plasticizer: 2-5 parts by weight, thickening are outstanding
Floating agent: 1-4 parts by weight, light change powder: 5-10 parts, pigment: 0-5 parts by weight and essence: 0-3 parts by weight.
3. a kind of light of safety and environmental protection becomes nail polish according to claim 1, which is characterized in that the saturated polyester resin is
The two or more copolymers of trimellitic anhydride, neopentyl glycol and pentaerythrite and adipic acid.
4. a kind of light of safety and environmental protection becomes nail polish according to claim 1, which is characterized in that the plasticizer is acetyl lemon
Lemon acid tributyl.
5. a kind of light of safety and environmental protection becomes nail polish according to claim 1, which is characterized in that the thickening suspending agent is department
Draw one of oronain hectorite and silica or a variety of.
6. a kind of light of safety and environmental protection becomes nail polish according to claim 1, which is characterized in that the light becomes powder to contain naphthalene
And the light-induced variable of pyrans organic matter (7- tert-butyl-n-(the fluoro- 4- methylsulfonyl aminophenyl of 3-)-dihydrobenzopyrans -3- formamide)
Color material.
7. a kind of light of safety and environmental protection becomes nail polish according to claim 1, which is characterized in that the pigment is inorganic face
It is one or more in material, organic pigment, pearl mica and colour PET paillette.
8. a kind of light of safety and environmental protection becomes nail polish according to claim 1, which is characterized in that the essence is asepsis environment-protecting
Essence.
9. a kind of preparation method of the light change nail polish of safety and environmental protection described in -8 any claims according to claim 1, special
Sign is, prepares in accordance with the following methods: by butyl acetate, ethyl acetate, and nitrocellulose, acrylic resin, saturated polyester resin,
Denatured ethyl alcohol, plasticizer thicken suspending agent, and light becomes powder, and pigment and essence mix in proportion, and high speed dispersion is uniform, and safety is made
The light of environmental protection becomes nail polish.
10. a kind of light of safety and environmental protection becomes the preparation method of nail polish according to claim 9, which is characterized in that the height
The revolving speed of speed dispersion is 1000-1500r/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910326729.0A CN110200849A (en) | 2019-04-23 | 2019-04-23 | A kind of light change nail polish of safety and environmental protection |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910326729.0A CN110200849A (en) | 2019-04-23 | 2019-04-23 | A kind of light change nail polish of safety and environmental protection |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110200849A true CN110200849A (en) | 2019-09-06 |
Family
ID=67786142
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910326729.0A Pending CN110200849A (en) | 2019-04-23 | 2019-04-23 | A kind of light change nail polish of safety and environmental protection |
Country Status (1)
| Country | Link |
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| CN (1) | CN110200849A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112618398A (en) * | 2021-01-11 | 2021-04-09 | 金华市科维思日化有限公司 | Silky smooth abrasive sand nail polish and preparation method thereof |
| CN112641644A (en) * | 2021-01-11 | 2021-04-13 | 金华市科维思日化有限公司 | Transfer nail polish capable of being applied with applique after transfer and preparation method thereof |
| CN112807246A (en) * | 2019-11-15 | 2021-05-18 | 万华化学集团股份有限公司 | Ultraviolet-curing optically variable nail polish and preparation method thereof |
| WO2024184271A1 (en) * | 2023-03-03 | 2024-09-12 | Jbrd Sa | Nail lacquer |
-
2019
- 2019-04-23 CN CN201910326729.0A patent/CN110200849A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112807246A (en) * | 2019-11-15 | 2021-05-18 | 万华化学集团股份有限公司 | Ultraviolet-curing optically variable nail polish and preparation method thereof |
| CN112807246B (en) * | 2019-11-15 | 2023-01-13 | 万华化学集团股份有限公司 | Ultraviolet-curing optically variable nail polish and preparation method thereof |
| CN112618398A (en) * | 2021-01-11 | 2021-04-09 | 金华市科维思日化有限公司 | Silky smooth abrasive sand nail polish and preparation method thereof |
| CN112641644A (en) * | 2021-01-11 | 2021-04-13 | 金华市科维思日化有限公司 | Transfer nail polish capable of being applied with applique after transfer and preparation method thereof |
| WO2024184271A1 (en) * | 2023-03-03 | 2024-09-12 | Jbrd Sa | Nail lacquer |
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Application publication date: 20190906 |