CN109381372A - A kind of aqueous, environmental protective color changeable nail enamel - Google Patents
A kind of aqueous, environmental protective color changeable nail enamel Download PDFInfo
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- CN109381372A CN109381372A CN201811165888.9A CN201811165888A CN109381372A CN 109381372 A CN109381372 A CN 109381372A CN 201811165888 A CN201811165888 A CN 201811165888A CN 109381372 A CN109381372 A CN 109381372A
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- aqueous
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- color changeable
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- 230000007613 environmental effect Effects 0.000 title claims abstract description 46
- 230000001681 protective effect Effects 0.000 title claims abstract description 45
- 210000003298 dental enamel Anatomy 0.000 title claims abstract description 44
- 238000002845 discoloration Methods 0.000 claims abstract description 58
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 49
- 230000002441 reversible effect Effects 0.000 claims abstract description 42
- 239000000463 material Substances 0.000 claims abstract description 32
- 239000002562 thickening agent Substances 0.000 claims abstract description 31
- 206010070834 Sensitisation Diseases 0.000 claims abstract description 22
- 230000008313 sensitization Effects 0.000 claims abstract description 22
- 229920002635 polyurethane Polymers 0.000 claims abstract description 21
- 239000004814 polyurethane Substances 0.000 claims abstract description 21
- 239000003086 colorant Substances 0.000 claims abstract description 20
- 125000001931 aliphatic group Chemical group 0.000 claims abstract description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229920006243 acrylic copolymer Polymers 0.000 claims abstract description 15
- 239000003755 preservative agent Substances 0.000 claims abstract description 15
- 230000002335 preservative effect Effects 0.000 claims abstract description 15
- 239000000080 wetting agent Substances 0.000 claims abstract description 15
- 239000002318 adhesion promoter Substances 0.000 claims abstract description 14
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 14
- 239000008367 deionised water Substances 0.000 claims abstract description 12
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 12
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 7
- 239000000049 pigment Substances 0.000 claims abstract description 7
- 239000000853 adhesive Substances 0.000 claims abstract description 5
- 230000001070 adhesive effect Effects 0.000 claims abstract description 5
- 229920003015 aliphatic polyurethane dispersion Polymers 0.000 claims description 16
- -1 compound compound Chemical class 0.000 claims description 12
- 239000002904 solvent Substances 0.000 claims description 12
- 239000006185 dispersion Substances 0.000 claims description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- ANZUDYZHSVGBRF-UHFFFAOYSA-N 3-ethylnonane-1,2,3-triol Chemical compound CCCCCCC(O)(CC)C(O)CO ANZUDYZHSVGBRF-UHFFFAOYSA-N 0.000 claims description 5
- 229920000570 polyether Polymers 0.000 claims description 5
- LXOFYPKXCSULTL-UHFFFAOYSA-N 2,4,7,9-tetramethyldec-5-yne-4,7-diol Chemical compound CC(C)CC(C)(O)C#CC(C)(O)CC(C)C LXOFYPKXCSULTL-UHFFFAOYSA-N 0.000 claims description 4
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 claims description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 4
- 150000008064 anhydrides Chemical class 0.000 claims description 4
- 229940053195 antiepileptics hydantoin derivative Drugs 0.000 claims description 4
- 239000000440 bentonite Substances 0.000 claims description 4
- 229910000278 bentonite Inorganic materials 0.000 claims description 4
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 4
- 239000002775 capsule Substances 0.000 claims description 4
- 229920003086 cellulose ether Polymers 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- 150000001469 hydantoins Chemical class 0.000 claims description 4
- 229960005323 phenoxyethanol Drugs 0.000 claims description 4
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- 239000004973 liquid crystal related substance Substances 0.000 claims description 3
- 239000010445 mica Substances 0.000 claims description 3
- 229910052618 mica group Inorganic materials 0.000 claims description 3
- CUDYYMUUJHLCGZ-UHFFFAOYSA-N 2-(2-methoxypropoxy)propan-1-ol Chemical compound COC(C)COC(C)CO CUDYYMUUJHLCGZ-UHFFFAOYSA-N 0.000 claims description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical class F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims description 2
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 2
- 238000001914 filtration Methods 0.000 claims description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 2
- 239000001023 inorganic pigment Substances 0.000 claims description 2
- 239000012860 organic pigment Substances 0.000 claims description 2
- 239000011049 pearl Substances 0.000 claims description 2
- 229920000515 polycarbonate Polymers 0.000 claims description 2
- 239000004417 polycarbonate Substances 0.000 claims description 2
- 229920000728 polyester Polymers 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims description 2
- 238000012797 qualification Methods 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims 1
- 239000004615 ingredient Substances 0.000 abstract description 9
- 230000009931 harmful effect Effects 0.000 abstract description 3
- 230000036541 health Effects 0.000 abstract description 3
- 230000014759 maintenance of location Effects 0.000 abstract description 2
- 230000035943 smell Effects 0.000 abstract 1
- 210000000282 nail Anatomy 0.000 description 50
- 238000012360 testing method Methods 0.000 description 31
- 239000000843 powder Substances 0.000 description 12
- 210000004905 finger nail Anatomy 0.000 description 8
- 238000001035 drying Methods 0.000 description 7
- 238000011156 evaluation Methods 0.000 description 7
- 238000002474 experimental method Methods 0.000 description 7
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 244000060701 Kaempferia pandurata Species 0.000 description 5
- 235000016390 Uvaria chamae Nutrition 0.000 description 5
- CUVLMZNMSPJDON-UHFFFAOYSA-N 1-(1-butoxypropan-2-yloxy)propan-2-ol Chemical compound CCCCOCC(C)OCC(C)O CUVLMZNMSPJDON-UHFFFAOYSA-N 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 229910000040 hydrogen fluoride Inorganic materials 0.000 description 4
- DAFHKNAQFPVRKR-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylpropanoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)C DAFHKNAQFPVRKR-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 241000220317 Rosa Species 0.000 description 2
- 244000061458 Solanum melongena Species 0.000 description 2
- 241001104043 Syringa Species 0.000 description 2
- 235000004338 Syringa vulgaris Nutrition 0.000 description 2
- NNBFNNNWANBMTI-UHFFFAOYSA-M brilliant green Chemical compound OS([O-])(=O)=O.C1=CC(N(CC)CC)=CC=C1C(C=1C=CC=CC=1)=C1C=CC(=[N+](CC)CC)C=C1 NNBFNNNWANBMTI-UHFFFAOYSA-M 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 1
- 240000000249 Morus alba Species 0.000 description 1
- 235000008708 Morus alba Nutrition 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- YCWSUKQGVSGXJO-NTUHNPAUSA-N nifuroxazide Chemical group C1=CC(O)=CC=C1C(=O)N\N=C\C1=CC=C([N+]([O-])=O)O1 YCWSUKQGVSGXJO-NTUHNPAUSA-N 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 230000008447 perception Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 210000004906 toe nail Anatomy 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/87—Polyurethanes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q3/00—Manicure or pedicure preparations
- A61Q3/02—Nail coatings
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
Abstract
The invention discloses a kind of aqueous, environmental protective color changeable nail enamels, including following component: aqueous aliphatic polyurethane: 40.0-50.0 parts by weight, aqueous aliphatic polyurethane acrylic copolymer: 35.0-45.0 parts by weight, reversible temperature-sensitive discoloration material: 3.0-6.0 parts by weight, reversible sensitization discoloration material: 3.0-6.0 parts by weight, pigment: 0-2.0 parts by weight, wetting agent: 0.1-0.5 parts by weight, thickener: 1.0-2.0 parts by weight, adhesion promoter: 0.5-1.0 parts by weight, defoaming agent: 0.5-1.0 parts by weight, preservative: 0.5-1.0 parts by weight, coalescing agent: 3.0-5.0 parts by weight, other auxiliary agents: 0-2.0 parts by weight, deionized water: surplus.Possibility of reversal toner used in the present invention and other ingredient smells are low, it is harmful to human health, it is environmental-friendly, adhesive force is strong, and the retention time is long on nail, adjustable various colors, and as temperature difference and light intensity difference are changing into different colours, reversible temperature-sensitive discoloration material and reversible sensitization discoloration material stability are good, and fugitive color, does not keep gay colours for a long time.
Description
Technical field
The invention belongs to color make-up class nail polish to produce and process field, and more specifically more particularly to a kind of aqueous, environmental protective becomes
Color nail polish.
Background technique
Nail polish belongs to makeup cosmetic, it not only has the function of beautification and modification finger nail and toenail, passes through
With the collocation of clothes color, the individual character and aesthetic feeling of women can be more shown.Nail polish is many kinds of currently on the market, and quality is irregular not
Together, different according to selected solvent, nail polish can be divided into oiliness nail polish and water-based nail polish two major classes.
Oiliness nail polish contains the ingredients such as nitrocellulose, ethyl acetate, acetone, toluene, these raw materials are all to human body and ring
The harmful property in border, the women more and more to like to be beautiful select aqueous, environmental protective nail polish.
If the patent of Publication No. 101697943A discloses a kind of environment-friendly type nail polish, main component includes: aqueous
Resin, wetting agent, levelling agent, preservative, thickener, pearlescent pigment and mill base etc..It is different in order to which finished product nail polish is presented
Color, can add suitable mill base or pearl powder wherein, and consumer selects the nail polish of suitable color according to the hobby of oneself
To brush.
Nail polish in actual use, the time is slightly long, and the nail polish of solid color can allow consumer products aesthetic tired
Labor loses feeling of freshness.And consumer wants to change another color, it is necessary to coat original nail polish removal and again new
Color will be expend a great deal of time.
For another example Publication No.: the patent of 106924076A discloses a kind of color changeable nail enamel, and main component includes: nitrification
Fiber, film forming agent, ethyl acetate, isopropanol, toluene, possibility of reversal colorant, the primary raw material in formula have human body and environment
Harm, with consumer's environmental protection, the continuous enhancing of health perception, consumer can be more and more prudent to the selection of oiliness nail polish.
Summary of the invention
The purpose of the present invention is to provide a kind of aqueous, environmental protective color changeable nail enamels and preparation method thereof, to solve above-mentioned background
The problem of being proposed in technology.
To achieve the above object, the invention provides the following technical scheme:
The present invention provides a kind of aqueous, environmental protective color changeable nail enamel, including following component:
Aqueous aliphatic polyurethane dispersion: 40.0-50.0 parts by weight
Aqueous aliphatic polyurethane acrylic copolymer: 35.0-45.0 parts by weight
Reversible temperature-sensitive discoloration material: 3.0-6.0 parts by weight
Reversible sensitization discoloration material: 3.0-6.0 parts by weight
Pigment: 0-2.0 parts by weight
Wetting agent: 0.1-0.5 parts by weight
Thickener: 1.0-2.0 parts by weight
Adhesion promoter: 0.5-1.0 parts by weight
Defoaming agent: 0.5-1.0 parts by weight
Preservative: 0.5-1.0 parts by weight
Coalescing agent: 3.0-5.0 parts by weight
Other auxiliary agents: 0-2.0 parts by weight
Deionized water: surplus
It is preferred that are as follows: the aqueous aliphatic polyurethane dispersion is that solid content is 30-40% based on the aqueous of polycarbonate glycol
Aliphatic polyurethane dispersion, or the aqueous aliphatic polyurethane dispersion based on polyester are one or more, have preferable
Richness, flexibility are good, gloss is high, water-tolerant, mix without solvent and reversible temperature-sensitive discoloration material and reversible sensitization discoloration material
Property the characteristics such as good.
It is preferred that are as follows: the aqueous aliphatic polyurethane acrylic copolymer is the water based on polyethers that solid content is 35-42%
Property aliphatic polyurethane acrylic copolymer it is one or more, there is preferable adhesive force, high rigidity, high glaze and preferable resistance to
It is aqueous, without solvent and the characteristics such as reversible temperature-sensitive discoloration material and reversible sensitization discoloration material intermiscibility are good.
It is preferred that are as follows: the reversible temperature-sensitive discoloration material selects fluorane compounds, triarylmethane compound compound and liquid crystal type reversible
Heat discoloration material is one or more.
It is preferred that are as follows: the reversible sensitization discoloration material selects fulgenic anhydride, spirooxazine class compound, diaryl second
One of vinyl compound is a variety of.
It is preferred that are as follows: it is about 0.2- that reversible temperature-sensitive discoloration material and reversible sensitization discoloration material outer layer, which have all wrapped up a layer thickness,
0.5 micron of capsule, capsule average diameter are 2-7 microns.
It is preferred that are as follows: the pigment is inorganic pigment, organic pigment, pearl mica, one or more in colour PET paillette.
It is preferred that are as follows: the wetting agent is TEGO Wet 270, Surfynol 104E, one or more in 345 BYK.
It is preferred that are as follows: the thickener selects polyurethane thickener, polyethers thickener, acrylic thickener, cellulose ether to increase
Thick dose, bentonite, one of silica or a variety of.
It is preferred that are as follows: the adhesion promoter selects DOW CORNING Z-6040 aqueous silane coupling agent, BASF EFW-616 water
One of property adhesion promoter is a variety of.
It is preferred that are as follows: the defoaming agent selects one of TEGO Foamex 825, Corning A34, BYK028 or a variety of.
It is preferred that are as follows: the preservative selects one of Phenoxyethanol, hydantoin derivatives, ethylhexyl glycerol or more
Kind.
It is preferred that are as follows: the coalescing agent selects one of alcohol ester 12, dipropylene glycol methyl ether, dipropylene or more
Kind.
It is preferred that are as follows: one of other selection of auxiliary levelling agents, antifreezing agent, mask agent are a variety of.
A kind of aqueous, environmental protective color changeable nail enamel is prepared by following methods: in the case where 200-300 revs/min stirs at low speed,
It is slowly added to the aqueous aliphatic polyurethane dispersion of 40.0-50.0 parts by weight and the aqueous aliphatic of 35.0-45.0 parts by weight
Polyurethane acroleic acid copolymer opens 700-800 revs/min of middling speed, and 0.5-1.0 weight slowly successively is added in vortex core
After the defoaming agent of part, the thickener of 0.5-1.0 parts by weight, opens 1500-2000 revs/min of high speed dispersion 25-30 minutes and extremely expect
After body fineness reaches requirement, 700-800 revs/min of middling speed is opened, 0.1-0.5 parts by weight slowly successively are added in vortex core
Wetting agent, the adhesion promoter of 0.5-1.0 parts by weight, the preservative of 0.5-1.0 parts by weight, 3.0-5.0 parts by weight at
Film auxiliary agent, other auxiliary agents of 0-2.0 parts by weight, the pigment of 0-2.0 parts by weight, 3.0-6.0 parts by weight reversible temperature-sensitive discoloration material,
The reversible sensitization discoloration material of 3.0-6.0 parts by weight is opened 700-800 revs/min of middling speed and is dispersed 20 minutes, with 0.5-1.0 weight
The thickener of part and the deionized water adjustment viscosity of surplus are measured to qualification, is packed with the strainer filtering of 200 mesh.
Compared with prior art, it the invention has the following advantages: smell is low, is harmful to human health, it is environmental-friendly,
Adhesive force is strong, and the retention time is long on nail, adjustable various colors, and as temperature difference and light intensity difference change
At different colours, reversible temperature-sensitive discoloration material and reversible sensitization discoloration material stability are good, and fugitive color, does not keep bright-coloured color for a long time
It is color.
Specific embodiment
In order to which technical scheme in the embodiment of the invention is clearly and completely described.Obviously, described embodiment
Only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, those skilled in the art
Member can according to need the modification that not creative contribution is made to the present embodiment after reading this specification, but as long as at this
All by the protection of Patent Law in the protection scope of invention.
Below with reference to specific embodiment, the present invention will be further described.
Embodiment 1: a kind of aqueous, environmental protective color changeable nail enamel of the present invention, the formula table of parts by weight are as follows:
| Component | Parts by weight | Purposes |
| Aqueous aliphatic polyurethane dispersion | 47.00 | Film forming agent |
| Aqueous aliphatic polyurethane acrylic copolymer | 35.00 | Film forming agent |
| Black reversible temperature-sensitive color-change powder (fluorane compounds) | 5.00 | Heat discoloration agent |
| The reversible sensitization discoloration powder of purple (fulgenic anhydride) | 3.00 | Sensitization discoloration agent |
| CI77891 stock white | 1.00 | Colorant |
| CI12490 red slurry | 0.15 | Colorant |
| A34 | 0.80 | Defoaming agent |
| Surfynol 104E | 0.50 | Wetting agent |
| Z6040 | 0.50 | Adhesion promoter |
| Polyurethane copolymer | 1.50 | Thickener |
| Yi Shiman TEXANOL | 2.30 | Coalescing agent |
| Phenoxyethanol | 0.50 | Preservative |
| Deionized water | 2.75 | Solvent |
High speed dispersion, which is uniformly mixed, after above each ingredient weighs is made aqueous, environmental protective color changeable nail enamel.
In-service evaluation:
1, a kind of test specimen: aqueous, environmental protective color changeable nail enamel of embodiment 1.
2, content of the test: test specimen is uniformly applied on finger nail, strong respectively at low temperature and poor light, low temperature after surface drying
It is placed 5 seconds under light, high temperature dim light and High temperature, observes its discoloration.Herein, low temperature refers to 0-20 DEG C of (this reality
Testing cryogenic temperature is 5 DEG C), high temperature refers to 25-35 DEG C (this experiment high-temperature temperature is 35 DEG C), and dim light refers to that sunlight is not straight
It connects irradiation or is provided with light and can see the interior of nail colour, strong light refers under outdoor strong sunlight irradiation.
3, test result: embodiment 1 places discoloration in 5 seconds at different conditions:
Low temperature and poor light: light grey
The strong light of low temperature: dark reddish purple color
High temperature dim light: pink
High temperature: aubergine
Wherein also slightly different for the color of the finger tip on nail and finger root, and the state gradually changed from deep to shallow is presented.
Embodiment 2: a kind of aqueous, environmental protective color changeable nail enamel of the present invention, the formula table of parts by weight are as follows:
| Component | Parts by weight | Purposes |
| Aqueous aliphatic polyurethane dispersion | 44.00 | Film forming agent |
| Aqueous aliphatic polyurethane acrylic copolymer | 38.00 | Film forming agent |
| Large red reversible temperature-sensitive color-change powder (triarylmethane compound compound) | 3.00 | Heat discoloration agent |
| The reversible sensitization discoloration powder (spirooxazine class compound) of blue | 5.00 | Sensitization discoloration agent |
| CI77891 stock white | 0.80 | Colorant |
| CI11710 yellow pulp | 0.35 | Colorant |
| TEGO Foamex 825 | 0.80 | Defoaming agent |
| TEGO Wet 270 | 0.50 | Wetting agent |
| Z6040 | 0.50 | Adhesion promoter |
| Silica | 0.90 | Thickener |
| Tao Shi DPM | 3.00 | Coalescing agent |
| Hydantoin derivatives | 0.60 | Preservative |
| Deionized water | 2.55 | Solvent |
High speed dispersion, which is uniformly mixed, after above each ingredient weighs is made aqueous, environmental protective color changeable nail enamel.
In-service evaluation:
1, a kind of test specimen: aqueous, environmental protective color changeable nail enamel of embodiment 2.
2, content of the test: test specimen is uniformly applied on finger nail, strong respectively at low temperature and poor light, low temperature after surface drying
It is placed 5 seconds under light, high temperature dim light and High temperature, observes its discoloration.Herein, low temperature refers to 0-20 DEG C of (this reality
Testing cryogenic temperature is 5 DEG C), high temperature refers to 25-35 DEG C (this experiment high-temperature temperature is 35 DEG C), and dim light refers to that sunlight is not straight
It connects irradiation or is provided with light and can see the interior of nail colour, strong light refers under outdoor strong sunlight irradiation.
3, test result: embodiment 2 places discoloration in 5 seconds at different conditions:
Low temperature and poor light: large red
The strong light of low temperature: aubergine
High temperature dim light: light yellow
High temperature: blue
Wherein also slightly different for the color of the finger tip on nail and finger root, and the state gradually changed from deep to shallow is presented.
Embodiment 3: a kind of aqueous, environmental protective color changeable nail enamel of the present invention, the formula table of parts by weight are as follows:
| Component | Parts by weight | Purposes |
| Aqueous aliphatic polyurethane dispersion | 40.00 | Film forming agent |
| Aqueous aliphatic polyurethane acrylic copolymer | 40.00 | Film forming agent |
| Emerald green reversible temperature-sensitive color-change powder (liquid crystal type compound) | 4.00 | Heat discoloration agent |
| The reversible sensitization discoloration powder of purple (fulgenic anhydride) | 4.00 | Sensitization discoloration agent |
| Colored PET paillette | 4.00 | Colorant |
| BYK028 | 0.80 | Defoaming agent |
| BYK 345 | 0.50 | Wetting agent |
| EFW-616 | 0.50 | Adhesion promoter |
| Oronain bentonite draws in department | 0.90 | Thickener |
| Tao Shi DPNB | 2.80 | Coalescing agent |
| Ethylhexyl glycerol | 0.50 | Preservative |
| Deionized water | 2.00 | Solvent |
High speed dispersion, which is uniformly mixed, after above each ingredient weighs is made aqueous, environmental protective color changeable nail enamel.
In-service evaluation:
1, a kind of test specimen: aqueous, environmental protective color changeable nail enamel of embodiment 3.
2, content of the test: test specimen is uniformly applied on finger nail, strong respectively at low temperature and poor light, low temperature after surface drying
It is placed 5 seconds under light, high temperature dim light and High temperature, observes its discoloration.Herein, low temperature refers to 0-20 DEG C of (this reality
Testing cryogenic temperature is 5 DEG C), high temperature refers to 25-35 DEG C (this experiment high-temperature temperature is 35 DEG C), and dim light refers to that sunlight is not straight
It connects irradiation or is provided with light and can see the interior of nail colour, strong light refers under outdoor strong sunlight irradiation.
3, test result: embodiment 3 places discoloration in 5 seconds at different conditions:
Low temperature and poor light: emerald green
The strong light of low temperature: mulberry
High temperature dim light: naked bright color
High temperature: purple
Wherein also slightly different for the color of the finger tip on nail and finger root, and the state gradually changed from deep to shallow is presented.
Embodiment 4: a kind of aqueous, environmental protective color changeable nail enamel of the present invention, the formula table of parts by weight are as follows:
| Component | Parts by weight | Purposes |
| Aqueous aliphatic polyurethane dispersion | 40.00 | Film forming agent |
| Aqueous aliphatic polyurethane acrylic copolymer | 40.00 | Film forming agent |
| Rose reversible temperature-sensitive color-change powder ((fluorane compounds) | 6.00 | Heat discoloration agent |
| Colored PET paillette | 5.00 | Colorant |
| CI51319 purple | 0.05 | Colorant |
| TEGO Foamex 825 | 0.80 | Defoaming agent |
| BYK 345 | 0.50 | Wetting agent |
| EFW-616 | 0.50 | Adhesion promoter |
| Cellulose ether thickener | 1.80 | Thickener |
| Tao Shi DPNB | 2.80 | Coalescing agent |
| Phenoxyethanol | 0.50 | Preservative |
| Deionized water | 2.05 | Solvent |
High speed dispersion, which is uniformly mixed, after above each ingredient weighs is made aqueous, environmental protective color changeable nail enamel.
In-service evaluation:
1, a kind of test specimen: aqueous, environmental protective color changeable nail enamel of embodiment 4.
2, content of the test: test specimen is uniformly applied on finger nail, after surface drying, respectively at placing 5 under low temperature, high temperature
Second, observe its discoloration.Herein, low temperature refers to 0-20 DEG C (this experiment cryogenic temperature is 5 DEG C), and high temperature refers to 25-
35 DEG C (this experiment high-temperature temperature is 35 DEG C).
3, test result: embodiment 4 places discoloration in 5 seconds at different conditions:
Low temperature: rose
High temperature: lilac
Wherein also slightly different for the color of the finger tip on nail and finger root, and the state gradually changed from deep to shallow is presented.
Embodiment 5: a kind of aqueous, environmental protective color changeable nail enamel of the present invention, the formula table of parts by weight are as follows:
| Component | Parts by weight | Purposes |
| Aqueous aliphatic polyurethane dispersion | 43.00 | Film forming agent |
| Aqueous aliphatic polyurethane acrylic copolymer | 40.00 | Film forming agent |
| Vermilion reversible temperature-sensitive color-change powder ((fluorane compounds) | 6.00 | Heat discoloration agent |
| CI77019 pearl mica powder | 2.00 | Colorant |
| CI74160 blue slurry | 0.10 | Colorant |
| TEGO Foamex 825 | 0.80 | Defoaming agent |
| Surfynol 104E | 0.50 | Wetting agent |
| Z-6040 | 0.50 | Adhesion promoter |
| Cellulose ether thickener | 1.40 | Thickener |
| Acrylic thickener | 1.20 | Thickener |
| Tao Shi DPM | 1.50 | Coalescing agent |
| Tao Shi DPNB | 1.50 | Coalescing agent |
| Hydantoin derivatives | 0.30 | Preservative |
| Deionized water | 1.20 | Solvent |
High speed dispersion, which is uniformly mixed, after above each ingredient weighs is made aqueous, environmental protective color changeable nail enamel.
In-service evaluation:
1, a kind of test specimen: aqueous, environmental protective color changeable nail enamel of embodiment 5.
2, content of the test: test specimen is uniformly applied on finger nail, after surface drying, respectively at placing 5 under low temperature, high temperature
Second, observe its discoloration.Herein, low temperature refers to 0-20 DEG C (this experiment cryogenic temperature is 5 DEG C), and high temperature refers to 25-
35 DEG C (this experiment high-temperature temperature is 35 DEG C).
3, test result: embodiment 5 places discoloration in 5 seconds at different conditions:
Low temperature: vermilion
High temperature: light blue
Wherein also slightly different for the color of the finger tip on nail and finger root, and the state gradually changed from deep to shallow is presented.
Embodiment 6: a kind of aqueous, environmental protective color changeable nail enamel of the present invention, the formula table of parts by weight are as follows:
| Component | Parts by weight | Purposes |
| Aqueous aliphatic polyurethane dispersion | 44.00 | Film forming agent |
| Aqueous aliphatic polyurethane acrylic copolymer | 35.00 | Film forming agent |
| Red reversible photosensitive change powder (diaryl ethylene compounds) | 6.00 | Sensitization discoloration agent |
| Colored PET paillette | 5.00 | Colorant |
| CI51319 purple | 0.06 | Colorant |
| BYK028 | 0.50 | Defoaming agent |
| TEGO Wet 270 | 0.50 | Wetting agent |
| EFW-616 | 0.50 | Adhesion promoter |
| Oronain bentonite draws in department | 0.90 | Thickener |
| Polyethers thickener | 1.40 | Thickener |
| Tao Shi DPNB | 2.30 | Coalescing agent |
| Yi Shiman TEXANOL | 1.40 | Coalescing agent |
| Ethylhexyl glycerol | 0.30 | Preservative |
| Deionized water | 2.14 | Solvent |
High speed dispersion, which is uniformly mixed, after above each ingredient weighs is made aqueous, environmental protective color changeable nail enamel.
In-service evaluation:
1, a kind of test specimen: aqueous, environmental protective color changeable nail enamel of embodiment 6.
2, content of the test: test specimen is uniformly applied on finger nail, after surface drying, respectively at placing 5 under dim light, strong light
Second, observe its discoloration.Herein, dim light refers to that sunlight does not have direct irradiation or is provided with light and can see finger
The interior of first color, strong light refer under outdoor strong sunlight irradiation.
3, test result: embodiment 6 places discoloration in 5 seconds at different conditions:
Dim light: lilac
Qiang Guang: red
Wherein also slightly different for the color of the finger tip on nail and finger root, and the state gradually changed from deep to shallow is presented.
Embodiment 7: a kind of aqueous, environmental protective color changeable nail enamel of the present invention, the formula table of parts by weight are as follows:
| Component | Parts by weight | Purposes |
| Aqueous aliphatic polyurethane dispersion | 42.00 | Film forming agent |
| Aqueous aliphatic polyurethane acrylic copolymer | 38.00 | Film forming agent |
| The reversible photosensitive change powder (fluorane compounds) of yellow | 7.00 | Sensitization discoloration agent |
| CI77891 stock white | 0.70 | Colorant |
| CI12490 red slurry | 0.10 | Colorant |
| BYK028 | 0.50 | Defoaming agent |
| TEGO Wet 270 | 0.50 | Wetting agent |
| Z-6040 | 0.50 | Adhesion promoter |
| Silica | 0.90 | Thickener |
| Polyurethane copolymer | 1.40 | Thickener |
| Tao Shi DPM | 3.50 | Coalescing agent |
| Yi Shiman TEXANOL | 2.50 | Coalescing agent |
| Ethylhexyl glycerol | 0.30 | Preservative |
| Deionized water | 2.10 | Solvent |
High speed dispersion, which is uniformly mixed, after above each ingredient weighs is made aqueous, environmental protective color changeable nail enamel.
In-service evaluation:
1, a kind of test specimen: aqueous, environmental protective color changeable nail enamel of embodiment 6.
2, content of the test: test specimen is uniformly applied on finger nail, after surface drying, respectively at placing 5 under dim light, strong light
Second, observe its discoloration.Herein, dim light refers to that sunlight does not have direct irradiation or is provided with light and can see finger
The interior of first color, strong light refer under outdoor strong sunlight irradiation.
3, test result: embodiment 6 places discoloration in 5 seconds at different conditions:
Dim light: pink
Qiang Guang: yellow
Wherein also slightly different for the color of the finger tip on nail and finger root, and the state gradually changed from deep to shallow is presented.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (17)
1. a kind of aqueous, environmental protective color changeable nail enamel, which is characterized in that contain the following parts by weight:
A, aqueous aliphatic polyurethane dispersion: 40.0-50.0 parts by weight
B, aqueous aliphatic polyurethane acrylic copolymer: 35.0-45.0 parts by weight
C, reversible temperature-sensitive discoloration material: 3.0-6.0 parts by weight
D, reversible sensitization discoloration material: 3.0-6.0 parts by weight
E, pigment: 0-2.0 parts by weight
F, wetting agent: 0.1-0.5 parts by weight
G, thickener: 1.0-2.0 parts by weight
H, adhesion promoter: 0.5-1.0 parts by weight
I, defoaming agent: 0.5-1.0 parts by weight
J, preservative: 0.5-1.0 parts by weight
K, coalescing agent: 3.0-5.0 parts by weight
L, other auxiliary agents: 0-2.0 parts by weight
M, deionized water: surplus.
2. a kind of aqueous, environmental protective color changeable nail enamel according to claim 1, which is characterized in that the component A selection contains admittedly
Amount is the aqueous aliphatic polyurethane dispersion based on polycarbonate glycol of 30-40%, or the aqueous aliphatic poly based on polyester
Urethane dispersion it is one or more.
3. a kind of aqueous, environmental protective color changeable nail enamel according to claim 2, which is characterized in that the aqueous aliphatic poly
Urethane dispersion has good preferable richness, flexibility, high glaze and preferable water resistance, is free of solvent and reversible temperature-sensitive
Discoloration material and reversible sensitization discoloration material intermiscibility are good.
4. a kind of aqueous, environmental protective color changeable nail enamel according to claim 1, which is characterized in that the B component selection contains admittedly
Amount is the one or more of the aqueous aliphatic polyurethane acrylic copolymer based on polyethers of 35-42%.
5. a kind of aqueous, environmental protective color changeable nail enamel according to claim 4, which is characterized in that the aqueous aliphatic poly
Urethane acrylic copolymer has preferable adhesive force, high rigidity, high glaze and preferable water resistance, without solvent and reversible
Heat discoloration material and reversible sensitization discoloration material intermiscibility are good.
6. a kind of aqueous, environmental protective color changeable nail enamel according to claim 1, which is characterized in that the component C reversible temperature-sensitive
Discoloration material selects fluorane compounds, triarylmethane compound compound and liquid crystal type reversible temperature-sensitive discoloration material one or more.
7. a kind of aqueous, environmental protective color changeable nail enamel according to claim 1, which is characterized in that the D component is reversible photosensitive
Discoloration material selects fulgenic anhydride, one of spirooxazine class compound, diaryl ethylene compounds or a variety of.
8. a kind of aqueous, environmental protective color changeable nail enamel according to claim 6 or 7, which is characterized in that the reversible temperature-sensitive becomes
Colorant and reversible sensitization discoloration material outer layer have all wrapped up the capsule that a layer thickness is about 0.2-0.5 microns, and capsule average diameter is
2-7 microns.
9. a kind of aqueous, environmental protective color changeable nail enamel according to claim 1, which is characterized in that the component E pigment is selected
It is inorganic pigment, organic pigment, pearl mica, one or more in colour PET paillette.
10. a kind of aqueous, environmental protective color changeable nail enamel according to claim 1, which is characterized in that the F component wetting agent choosing
With one or more in TEGO Wet 270, Surfynol 104E, 345 BYK.
11. a kind of aqueous, environmental protective color changeable nail enamel according to claim 1, which is characterized in that the G component thickener choosing
With one of polyurethane thickener, polyethers thickener, acrylic thickener, cellulose ether thickener, bentonite, silica or more
Kind.
12. a kind of aqueous, environmental protective color changeable nail enamel according to claim 1, which is characterized in that the H component attachment is made every effort to promote
DOW CORNING Z-6040 aqueous silane coupling agent, one of BASF EFW-616 aqueous adhesive force promotor or more are selected into agent
Kind.
13. a kind of aqueous, environmental protective color changeable nail enamel according to claim 1, which is characterized in that the I component defoaming agent choosing
With one of TEGO Foamex 825, Corning A34, BYK028 or a variety of.
14. a kind of aqueous, environmental protective color changeable nail enamel according to claim 1, which is characterized in that the J component preservative choosing
With one of Phenoxyethanol, hydantoin derivatives, ethylhexyl glycerol or a variety of.
15. a kind of aqueous, environmental protective color changeable nail enamel according to claim 1, which is characterized in that the K component coalescing agent
Select one of alcohol ester 12, dipropylene glycol methyl ether, dipropylene or a variety of.
16. a kind of aqueous, environmental protective color changeable nail enamel according to claim 1, which is characterized in that the other auxiliary agents of L component
Select one of levelling agent, antifreezing agent, mask agent or a variety of.
17. a kind of preparation method of aqueous, environmental protective color changeable nail enamel according to claim 1, which is characterized in that including following
Step: in the case where 200-300 revs/min stirs at low speed, it is slowly added to the aqueous aliphatic polyurethane dispersion of 40.0-50.0 parts by weight
The aqueous aliphatic polyurethane acrylic copolymer of body and 35.0-45.0 parts by weight opens 700-800 revs/min of middling speed, according to
After the secondary defoaming agent that 0.5-1.0 parts by weight are slowly added in vortex core and the thickener of 0.5-1.0 parts by weight, 1500- is opened
After 2000 revs/min reach requirement to Material fineness in high speed dispersion 25-30 minutes, 700-800 revs/min of middling speed is opened, according to
It is secondary that the wetting agent of 0.1-0.5 parts by weight, the adhesion promoter of 0.5-1.0 parts by weight, 0.5-1.0 slowly is added in vortex core
The preservative of parts by weight, the coalescing agent of 3.0-5.0 parts by weight, other auxiliary agents of 0-2.0 parts by weight, 0-2.0 parts by weight face
Expect, the reversible sensitization discoloration material of the reversible temperature-sensitive of 3.0-6.0 parts by weight discoloration material, 3.0-6.0 parts by weight, 700-800 turns of unlatching/
The middling speed of minute is dispersed 20 minutes, is adjusted viscosity to qualification with the thickener of 0.5-1.0 parts by weight and the deionized water of surplus, is used
The strainer filtering of 200 mesh is packed.
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| CN201811165888.9A CN109381372A (en) | 2018-10-08 | 2018-10-08 | A kind of aqueous, environmental protective color changeable nail enamel |
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| CN201811165888.9A CN109381372A (en) | 2018-10-08 | 2018-10-08 | A kind of aqueous, environmental protective color changeable nail enamel |
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| CN109998945A (en) * | 2019-04-17 | 2019-07-12 | 中山市美源化妆品有限公司 | A kind of aqueous, environmental protective nail polish and its manufacturing method |
| CN110151573A (en) * | 2019-07-10 | 2019-08-23 | 中山市美源化妆品有限公司 | A kind of color changeable nail enamel and its manufacturing method |
| GB2581234A (en) * | 2018-11-27 | 2020-08-12 | Theunseen Ltd | Coating compositions |
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| CN109998945A (en) * | 2019-04-17 | 2019-07-12 | 中山市美源化妆品有限公司 | A kind of aqueous, environmental protective nail polish and its manufacturing method |
| CN110151573A (en) * | 2019-07-10 | 2019-08-23 | 中山市美源化妆品有限公司 | A kind of color changeable nail enamel and its manufacturing method |
| KR20210009532A (en) * | 2019-07-17 | 2021-01-27 | 김우석 | Novel base coating gel composition capable of being removed selectively without any nail damages |
| KR102306116B1 (en) | 2019-07-17 | 2021-09-27 | 김우석 | Novel base coating gel composition capable of being removed selectively without any nail damages |
| CN112807246A (en) * | 2019-11-15 | 2021-05-18 | 万华化学集团股份有限公司 | Ultraviolet-curing optically variable nail polish and preparation method thereof |
| CN112807246B (en) * | 2019-11-15 | 2023-01-13 | 万华化学集团股份有限公司 | Ultraviolet-curing optically variable nail polish and preparation method thereof |
| CN112826764A (en) * | 2021-01-11 | 2021-05-25 | 金华市科维思日化有限公司 | Environment-friendly long-acting water-based temperature-variable nail polish and preparation method thereof |
| CN117247731A (en) * | 2023-09-14 | 2023-12-19 | 佛山市三水顺能化工有限公司 | Temperature-sensitive color-changing aqueous color layer coating for electrochemical aluminum and preparation method thereof |
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Application publication date: 20190226 |