CN101355923B - Cosmetic composition for make up containing the interference color pigment and preparing method of the same - Google Patents

Cosmetic composition for make up containing the interference color pigment and preparing method of the same Download PDF

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Publication number
CN101355923B
CN101355923B CN2006800509388A CN200680050938A CN101355923B CN 101355923 B CN101355923 B CN 101355923B CN 2006800509388 A CN2006800509388 A CN 2006800509388A CN 200680050938 A CN200680050938 A CN 200680050938A CN 101355923 B CN101355923 B CN 101355923B
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cosmetic composition
coated
weight
gloss
interference pigment
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CN101355923A (en
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沈珉敬
权纯祥
朴明三
高昇龙
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Amorepacific Corp
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Amorepacific Corp
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/26—Aluminium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/11—Encapsulated compositions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/25—Silicon; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/27—Zinc; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/28—Zirconium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/29—Titanium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
    • A61K8/585—Organosilicon compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/69—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing fluorine
    • A61K8/70—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing fluorine containing perfluoro groups, e.g. perfluoroethers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/895—Polysiloxanes containing silicon bound to unsaturated aliphatic groups, e.g. vinyl dimethicone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A61Q1/10—Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/12—Face or body powders for grooming, adorning or absorbing
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/41—Particular ingredients further characterized by their size
    • A61K2800/412—Microsized, i.e. having sizes between 0.1 and 100 microns
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/42—Colour properties
    • A61K2800/43—Pigments; Dyes
    • A61K2800/436—Interference pigments, e.g. Iridescent, Pearlescent

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Cosmetics (AREA)

Abstract

The present invention is related to a make-up cosmetic composition containing an interference color pigment in which a planar aluminum oxide is coated with a metallic oxide, or otherwise silicone compound is secondarily coated on the surface of the aluminum oxide in addition to the firstly coated metallic oxide, and a method of preparing the same. The make-up cosmetic composition has a little gloss while showing interference color, having effect of compensating the skin trouble such as pimple scars, speckle, freckle, somberness and so on, or the skin blemish such as skin pores, wrinkle and so on, the effect of offering the skin with cubic effect and natural make-up, providing excellent feeling in use, and having excellent gloss duration.

Description

Comprise cosmetic composition of interference pigment and preparation method thereof
Technical field
The present invention relates to a kind of cosmetic composition that comprises interference pigment (interference color pigment) and preparation method thereof; More specifically; Relate to a kind of tabular alumina (planaraluminum oxide) that comprises wherein by the cosmetic composition of metal oxide coated interference pigment, and preparation method thereof.
Background technology
Traditionally, the colour of skin perhaps hides the method for skin blemishes by way of compensation, and already used only is to utilize titanium dioxide (TiO 2) non-natural covering method, perhaps, seamless (unrelieved) cutaneous manifestations has become main flow, its principle of utilizing light absorption is with the organic/inorganic coloring material performance colour of skin.
But; In order to meet recent natural beauty and healthy trend; The colour of skin and skin blemishes and the pigment of theory that transparency and the stereoeffect of nature are provided have used the pearl pigment (wherein using the natural or synthetic mica of titanium dioxide and iron oxide-coated) that utilizes interference of light principle by way of compensation.
Moreover; Because as the sheet form base material of pearl pigment for example in the natural mica, the color of itself because impurity etc. thickens, and its prepared product color also thickens; So prepared product; Particularly for example produce the very difficult control colors such as cosmetic composition of a lot of colors,, rather than use natural sheet form base material so that used synthesizing flaky substrate recently through synthetic structure.
The most widely used a kind of be the pearlescent pigment that in pearl pigment, utilizes synthetic mica.Because pearlescent pigment usually shows inherent yellow, and mica base self shows a lot of gloss, so be difficult to appear enough color sensitivities when using.
The pearl pigment of even now has interference colours and shows third dimension and the transparency with exquisite color; But it in use also has shortcoming; For example owing to high glaze produces brilliance; Smear the characteristic aspect degradation, be prone to peeling etc., so that there is restriction in it aspect the main coloring pigment of the cosmetic composition that is used as skin.
And because as above these shortcomings, it is usually with mixed with little amount, thereby causes fully showing the problem of interference color effect, and in fact it can not satisfy the demands of consumers.
Summary of the invention
Technical problem
In order to solve the aforementioned problems in the prior; The inventor after deliberation a kind of cosmetic composition, it has a small amount of gloss, shows interference colours simultaneously; Thereby has for example pimple cicatrix, brown patch, freckle, dim pool etc. or the skin blemishes effect of corse sweat pore, wrinkle etc. for example of compensation skin problem; With make skin have the effect of third dimension and dressing nature, and fabulous use feeling is provided, and has fabulous gloss duration.The result is that the inventor has been found that the cosmetic composition through using the interference pigment preparation to have above-mentioned effect; Wherein, Use metal oxide coated tabular alumina; Rather than traditional lamellar natural mica or synthetic mica, perhaps on coating of metal oxides, further be coated with silicon-containing compound.
Therefore, the purpose of this invention is to provide a kind of cosmetic composition, it comprises interference pigment; Wherein, at first use metal oxide coated tabular alumina, perhaps also can on coating of metal oxides, be coated with by further reuse silicon-containing compound; Thereby has a small amount of gloss; Show interference colours simultaneously, have for example pimple cicatrix, brown patch, freckle, dimness etc. or the skin blemishes effect of corse sweat pore, wrinkle etc. for example of compensation skin problem, make skin have third dimension and the natural effect of dressing; And excellent use feeling is provided, and has fabulous gloss duration.
Technical scheme
In order to realize top purpose, a kind of cosmetic composition is provided, it comprises interference pigment, wherein the tabular alumina surfaces coated is furnished with metallic oxide.
In this cosmetic composition, interference pigment is provided so that except the metallic oxide of coating formerly, the surperficial reuse silicon-containing compound coating of tabular alumina.
In this cosmetic composition, comprise the interference pigment of 0.5-80 weight % scope.
In this cosmetic composition, metallic oxide is to be selected from least a in titanium dioxide, ferrum oxide, zinc oxide, zirconium oxide and the stannum oxide.
In this cosmetic composition, said silicon-containing compound is to be selected from silicon dioxide, silicone oil, methylhydrogenpolysi,oxane, alkyl silane, acryloyl group silane, perfluoro silane, perfluoroalkyl silane and to comprise at least a in the polysiloxanes cross linked polymer of dimethicone/vinyl dimethicone crosspolymers.
In this cosmetic composition, tabular alumina has the mean diameter of 5-15 micron, the maximum line diameter/thickness of 5-40,1-4m 2The specific surface area of/g and with the gloss number of gloss meter at the 10-25 of 60 ° of measurements.
In this cosmetic composition, for the gross weight of aluminium oxide, metal oxide coated amount is 10-60 weight %, more preferably is 30-50 weight %.
In this cosmetic composition, based on the gross weight of the interference pigment that at first is coated with metallic oxide, the coating weight then of silicon-containing compound is 0.1-20 weight %, is more preferably 1-10 weight %.
In this cosmetic composition, interference colours are not limited to have the color of particular range of wavelengths, but the color that shows at the whole wave-length coverage 400nm-700nm of Show Color.
In this cosmetic composition, compositions has a small amount of gloss, shows interference colours simultaneously with in order to compensation skin problem or skin blemishes, the modelling effect of skin and the dressing of nature is provided, and improves use feeling and gloss duration.
In this cosmetic composition, the formulation of cosmetic composition be selected from cosmetic sun screen, foundation emulsion, face powder at the bottom of, any in dual-purpose muffin, muffin, loose powder, lip pomade, lip gloss, lip line, mascara, eyebrow pencil, eye shadow and the nial polish.
According to a further aspect in the invention, the method for preparing of the cosmetic composition that comprises interference pigment is provided, it comprises: (1) prepares interference pigment, wherein uses the surface of metal oxide coated tabular alumina; (2) grind the also component of hybridization cosmetic compositions, like oil-soluble oil component, binding agent, pigment, sunscreen, antiseptic and spice; And (3) will be added in the mixture that grinds through step (2) through the interference pigment of step (1) preparation.
In the method for preparing of cosmetic composition, provide in the step (1) interference pigment so that except the metallic oxide of at first coating the surface of reuse silicon-containing compound coating tabular alumina.
In the method for preparing of cosmetic composition, cosmetic composition is the powder or the powder of compacting.
Useful technique effect
Cosmetic composition of the present invention comprises interference pigment; Wherein, use metal oxide coated tabular alumina, perhaps except the metallic oxide of at first coating, also can on alumina surface, be coated with by further reuse silicon-containing compound; Thereby has a small amount of gloss; Show interference colours simultaneously, have for example pimple cicatrix, brown patch, freckle, dimness etc. or the skin blemishes effect of corse sweat pore, wrinkle etc. for example of compensation skin problem, bring skin to have third dimension and the natural effect of dressing; And excellent use feeling is provided, and has fabulous gloss duration.
The specific embodiment
Cosmetic composition of the present invention preferably includes the interference pigment of 0.5-80 weight %.This amount is less than 0.5 weight % if this is, its effect can not fully manifest, and if should measure above 80 weight %, can cause the problem in the formulation.
In cosmetic composition, tabular alumina preferably has the mean diameter of 5-15 micron.
Particle diameter is less than 5 microns if this is; Aluminium oxide is because the diffuse-reflectance of light presents white; And do not manifest pearl, and if it surpasses 15 microns, when cosmetic composition makes up; Smear characteristic and demoted so that aspect use feeling, feel coarse and bad, and color is owing to metallic oxide for example is coated on the inhomogeneous and fuzzy of titanium dioxide on the alumina particle.Therefore, preferred mean diameter is limited to above-mentioned scope.
Preferably, tabular alumina has the maximum line diameter/thickness of 5-40,1-4m 2The specific surface area of/g and with the gloss number 10-25 of gloss meter 60 ° of measurements.
Maximum line diameter/thickness is less than 5 if this is; Aluminium oxide diameter and thickness than aspect diminish so that it shows the tone with fuzzy color rather than clearly demarcated color; And if maximum line diameter/thickness surpasses 40; It has gloss so that when being used for the end when making up, it shows factitious gloss.Therefore, preferred maximum line diameter/thickness is limited to top scope.
Moreover, if the specific surface area of tabular alumina is less than 1m 2/ g can cause producing the problem that factitious gloss and aluminium oxide are prone to peeling, if specific surface area surpasses 4m 2/ g, aluminium oxide shows interference colours improperly owing to many diffuse-reflectance.Therefore, the specific surface area of preferred top scope.
And, if with gloss meter at the gloss number of 60 ° of measurements less than 10, it is too dim that aluminium oxide seems, if surpass 25, it is inappropriate to entire face that gloss shows margaritaceous not natural gloss so that apply aluminium oxide.Therefore, preferred gloss number is limited to top scope.
Wherein the surfaces coated of the tabular alumina interference pigment that is furnished with metallic oxide can show because of argenteous multiple color according to the coating weight of metallic oxide.
At first the metallic oxide of coating is to be selected from least a in titanium dioxide, ferrum oxide, zinc oxide, zirconium oxide and the stannum oxide, and for the gross weight of aluminium oxide, the coating weight of metallic oxide is 10-60 weight %, more preferably is 30-50 weight %.
Less than 10 weight %, perhaps surpass 60 weight % if this is, interference colours can not show, and show fuzzy white.Given this, more preferably metallic oxide is applied the scope into 30-50 weight %.
Following first coating process of preparing; Water, aluminium oxide and acid and thermal agitation are provided; With constant speed to wherein adding titanium chloride solution or titanyl sulfide solution to form titanium deoxid film; And then to wherein adding alkali, wash then with neutralization, and wash in order, dry, heating and coating.At this, coating process is not special to be limited.
Moreover; With metal oxide coated tabular alumina then under the situation with silicon-containing compound coating, the silicon-containing compound of coating is to be selected from least a in silicon dioxide, silicone oil, methylhydrogenpolysi,oxane, alkyl silane, acryloyl group silane, perfluoro silane, perfluoroalkyl silane and the polysiloxanes cross linked polymer once more at first.For the gross weight of the interference pigment that at first is coated with metallic oxide, the coating weight of silicon-containing compound is 0.1-20 weight %, more preferably 1-10 weight %.Powder if being, this, only can be coated with on extraordinary component ground, and if above 20 weight %, because undue coating, can be assembled less than 0.1 weight %.Therefore, the coating weight that is more preferably silicon-containing compound is 1-10 weight %.
Can from dampening, seasoning, CVD method, sol/gel method etc., select the method for coating once more according to cosmetic composition and the purpose that is intended to realize in the cosmetic composition, it does not have special qualification.
When confirming to be coated with once more according to cosmetic composition, it provides the gloss of the interference pigment that further reduction at first is coated with metallic oxide and improves skin attachment and can be too not sticking, and the effect of fixing lastingly is provided.
The formulation of cosmetic composition be selected from cosmetic sun screen, foundation emulsion, face powder at the bottom of, any in dual-purpose muffin, muffin, loose powder, lip pomade, lip gloss, lip line, mascara, eyebrow pencil, eye shadow and the nial polish.The compositions of each formulation can comprise the multiple preparation of formulation and the desired substrate of preparation and the additive of formulation of being suitable for, and those skilled in the art can easily select its type and amount.
Cosmetic composition of the present invention has favorable compatibility to the component of traditional cosmetics compositions; And provide and have the chromatic effect that goes out that a small amount of gloss shows interference colours simultaneously; Thereby has for example pimple cicatrix, brown patch, freckle, dimness etc. or the skin blemishes vision compensation effect of corse sweat pore, wrinkle etc. for example of compensation skin problem; On skin, present various interference colours simultaneously because good skin attachment keeps the dressing nature; Make skin have third dimension, excellent use feeling is provided, and makes skin have fabulous gloss duration.
Simultaneously; Preparation according to the cosmetic composition that comprises interference pigment of the present invention in; At first, the preparation interference pigment so that the surface of tabular alumina at first with metal oxide coated or except at first being coated with reuse silicon-containing compound metal oxide coated.Although before the milled mixtures with can interference pigment be added in the mixture of the component (oil-soluble oil component, binding agent, pigment, sunscreen, antiseptic, spice etc.) except that pigment afterwards; But more strengthen interference colours and gloss control if desired, can after milled mixtures, pigment be added wherein.
Embodiment
This and after, will describe the present invention in detail through embodiment and EXPERIMENTAL EXAMPLE, but the present invention is not limited to this.
[preparation embodiment 1-3 and comparative preparation embodiment 1-2: the preparation of cosmetic composition]
In preparation embodiment 1-3 and comparative preparation embodiment 1-2, cosmetic composition is with component shown in the following table 1 and amount preparation.
At this; In table 1; Preparation embodiment 1-3 relates to component and the amount that comprises the cosmetic composition of interference pigment of the present invention; Comparative preparation embodiment 1 relates to the component and the amount of the cosmetic composition that only comprises traditional general pigment, and comparative preparation embodiment 2 relates to the component and the amount of the cosmetic composition that comprises traditional pearl pigment.
Table 1
Component Comparative preparation embodiment 1 Comparative preparation embodiment 2 Preparation embodiment 1 Preparation embodiment 2 Preparation embodiment 3
1. Talcum To 100 To 100 To 100 To 100 To 100
2. nylon powder 5.0 5.0 5.0 5.0 5.0
3. silicon dioxide 5.0 5.0 5.0 5.0 5.0
4. starch 3.0 3.0 3.0 3.0 3.0
5. titanium dioxide 5.0 5.0 5.0 5.0 5.0
6. red iron oxide 0.4 0.4 0.4 0.4 0.4
7. yellow iron oxide 1.0 1.0 1.0 1.0 1.0
8. black iron oxide 0.2 0.2 0.2 0.2 0.2
9. natural mica+titanium dioxide - 5.0 - - -
10. interference pigment (aluminium oxide+titanium dioxide-coated) - - 5.0 - -
11. interference pigment (aluminium oxide+titanium dioxide-coated+silica-coated) - 5.0 -
12. interference pigment (aluminium oxide+titanium dioxide-coated+silica-coated) (after grinding, introducing) - - - - 5.0
13. Squalene 2.0 2.0 2.0 2.0 2.0
14.Medowfoam seed oil 2.0 2.0 2.0 2.0 2.0
15. antiseptic In right amount In right amount In right amount In right amount In right amount
16. spice 0.3 0.3 0.3 0.3 0.3
The method for preparing of preparation embodiment 1-3 and comparative preparation embodiment 1-2 is following.At first, in preparation embodiment 1, component 1-8 and 10 (wherein; At first coating is the titanium dioxide of about 35 weight % on tabular alumina), in preparation embodiment 2, component 1-8 and 11 is (wherein; At first on tabular alumina, be coated with the titanium dioxide of about 35 weight %, for the gross weight of the interference pigment that at first is coated with titanium dioxide, coating is the silicon dioxide of about 5 weight % more then); In comparative preparation embodiment 1, component 1-8 is in comparative preparation embodiment 2; Measure component 1-8 and 9 (natural mica+titanium dioxide) with its basic weight, grind and with mixer mixing with the acquisition mixture.
Then, 13-16 to 85 ℃ of heat contents ground with fusion, and with mixer mixing to mixture with preparation preparation embodiment 1 and 2 and the cosmetic composition of comparative preparation embodiment 1 and 2.
Moreover, in preparation embodiment 3, measure the basis weight of component 1-8; Grind, then with mixer mixing with the acquisition mixture, 13-16 to 85 ℃ of heat contents is with fusion and be mixed to mixture; Grind; And use mixer mixing, introduce component 12 (wherein at first on aluminium oxide coating be the titanium dioxide of about 35 weight %, then for the gross weight of the interference pigment that at first is coated with titanium dioxide; Coating be the silicon dioxide of about 5 weight % again), and be mixed in the mixture of grinding the cosmetic composition for preparing embodiment 3 with preparation.
At this, the coating process of preparation embodiment 1-3 is following.
In the coating of at first using titanium dioxide; With 8: 2 weight ratio mixing water and aluminium oxide, provide hydrochloric acid in the mixed solution of 10L keeping the pH value of 1-4, heated solution to 65 ℃ also stirred 11 hours with 400rpm; The titanyl sulfide solution (30 weight %) that adds 300ml with constant rate of speed arrives wherein to form titanium deoxid film; Add sodium hydroxide to being 7 wherein, wash, wash and drying, and heat 30 minutes with coating at 600 ℃ with the control pH value.
When the reuse silica-coated, the tabular alumina that at first is coated with titanium dioxide mixes with the Ludox of 2 weight %, the gel of 500 ℃ of dried 20 minutes, thereby with the surface of silica-coated metallic oxide.
[EXPERIMENTAL EXAMPLE 1: the assessment of color]
The cosmetic composition that will in preparation embodiment 1-3 and comparative preparation embodiment 1-2, prepare is applied on the glass plate with 0.5 millimeter thickness, measures color through utilizing spectrometer (CM2002, Minolta company), thereby compares and the assessment color.The result who measures is shown in the following table 2.
Table 2
Type L * a * b * Saturation
Comparative preparation embodiment 1 57.33 6.74 2.65 2.05
Preparation embodiment 1 64.58 11.02 3.13 2.26
Preparation embodiment 3 66.49 12.27 3.42 2.31
L *: brightness
a *: red green degree
b *: the champac degree
Saturation: (a * 2+ b * 2) 1/2, along with its increase, saturation increases.
As shown in table 2, when the color of the cosmetic composition of comparative preparation embodiment 1 and comparative preparation embodiment 1, can know; Compare with comparative preparation embodiment 1; Preparation embodiment 1 increases its red green degree and saturation, and brightness simultaneously increases so that interference colours can show and color in do not have dimness.In the cosmetic composition of preparation embodiment 3; Wherein interference pigment mixed and grinding back introducing in the component that is used for the vague generalization cosmetic compositions; Can know that brightness, red green degree and saturation comparison increase manyly than preparation embodiment 1, so that can show obvious color.
[EXPERIMENTAL EXAMPLE 2: the assessment of glossiness]
The cosmetic composition that will in preparation embodiment 1-3 and comparative preparation embodiment 1-2, prepare through with the color measuring of EXPERIMENTAL EXAMPLE 1 in identical sampling method be applied on the glass plate, through at 60 ° of measurement reflecting bundles and relatively and assess glossiness with gloss meter (BYK Gardner).Measurement result is as shown in table 3 below.
Table 3
Type Gloss unit
Comparative preparation embodiment 1 11
Comparative preparation embodiment 2 37
Preparation embodiment 1 19
Preparation embodiment 2 15
Preparation embodiment 3 17
As shown in table 3; When the glossiness of the cosmetic composition of comparative preparation embodiment 1 and comparative preparation embodiment 2; Can know, compare, comprise that the preparation embodiment 1 of interference pigment has the gloss of minimizing about 1/2 with the comparative preparation embodiment that comprises traditional pearl pigment 2.Moreover when comparing with the comparative preparation embodiment that only comprises traditional general pigment 1, compare gloss significantly increases with comparative preparation embodiment 1, so that the gloss that can not cause obtaining is so much.And, in the cosmetic composition of the preparation embodiment 2 that comprises the interference pigment that except titanium dioxide, also is coated with silicon-containing compound (silicon dioxide), can know that its gloss is compared further reduction with preparation embodiment 1.
[EXPERIMENTAL EXAMPLE 3: compensation skin blemishes effect, modelling effect, dressing nature, use feeling and gloss duration assessment]
About the skin blemishes compensation of the cosmetic composition that in preparation embodiment 1-3 and comparative preparation embodiment 1 and 2, prepares, third dimension, dressing naturally, the effect of use feeling and gloss duration, 30 people of professional group (25-35 year woman) are compared and assess.The result is presented in the following table 4.At this, assess so that the worst assessment corresponding to value 1, best assessment corresponding to the value 9.
Table 4
Figure S2006800509388D00091
As shown in table 4, of the present inventionly comprise that the cosmetic composition of interference pigment is all fabulous in the assessment of all.
In the assessment of skin blemishes compensation effect and modelling effect, to compare with comparative preparation embodiment 1, the cosmetic composition that comprises the preparation embodiment 1-3 of interference pigment is assessed as fabulous, and especially, preparation embodiment 3 is assessed as best.
In the assessment of dressing nature, to compare with 2 with comparative preparation embodiment 1, the cosmetic composition of preparation embodiment 1-3 is assessed as fabulous.Especially, preparation embodiment 2 is assessed as best.Comprise the comparative preparation embodiment 2 of traditional pearl pigment because not being assessed as naturally of Margarita is the poorest.
In the assessment of use feeling, although the cosmetic composition of preparation embodiment 1-3 and comparative preparation embodiment 1-2 all be assessed as more than 7.0 well, those that prepare embodiment 1-3 are assessed as better.Especially, preparation embodiment 2 is assessed as best.
In the assessment of gloss duration, it is better than what prepare embodiment 1 and 2 that the cosmetic composition of preparation embodiment 1-3 is assessed as comparison.Especially, comprise that the preparation embodiment 2 of the interference pigment of further using silicon-containing compound (silicon dioxide) coating and interference pigment wherein are assessed as better than preparing embodiment 1 at the mixed preparation embodiment 3 that introduces with grinding the back of the component that is used for general cosmetic composition.This shows compared with prior art, and the cosmetic composition that comprises interference pigment shows fabulous result in color, regular distribution with according to the improved gloss duration aspect aspect adhering to.
Industrial applicibility
Cosmetic composition of the present invention comprises interference pigment; Wherein, use metal oxide coated tabular alumina, perhaps the burning beyond the region of objective existence except at first coating also can further be coated with silicon-containing compound on alumina surface; Thereby has a small amount of gloss; Show interference colours simultaneously, have for example pimple cicatrix, brown patch, freckle, dimness etc. or the skin blemishes effect of corse sweat pore, wrinkle etc. for example of compensation skin problem, bring to make skin have the effect of third dimension and natural dressing; And excellent use feeling is provided, and has fabulous gloss duration.

Claims (12)

1. cosmetic composition, it comprises interference pigment, and the tabular alumina surfaces coated in the said interference pigment is furnished with titanium dioxide, wherein:
Said cosmetic composition comprises the said interference pigment of 0.5-80 weight % scope;
With respect to the gross weight of said aluminium oxide, the coating weight of said titanium dioxide is 10-60 weight %; With
Said tabular alumina has the mean diameter of 5-15 micron, the maximum line diameter/thickness of 5-40,1-4m 2The specific surface area of/g and with the gloss number of gloss meter at the 10-25 of 60 ° of measurements.
2. cosmetic composition as claimed in claim 1 wherein, provides said interference pigment so that the surface of said tabular alumina is coated with by silicon-containing compound again except the titanium dioxide of at first coating.
3. cosmetic composition as claimed in claim 2, wherein said silicon-containing compound are to be selected from silicon dioxide, methylhydrogenpolysi,oxane, alkyl silane, acryloyl group silane, perfluoro silane and to comprise at least a in the polysiloxanes cross linked polymer of dimethicone/vinyl dimethicone crosspolymers.
4. according to claim 1 or claim 2 cosmetic composition, wherein, for the gross weight of said aluminium oxide, said titanium dioxide-coated amount is 30-50 weight %.
5. cosmetic composition as claimed in claim 2, wherein for the gross weight of the interference pigment that at first is coated with titanium dioxide, the amount that said silicon-containing compound is coated with then is 0.1-20 weight %.
6. cosmetic composition as claimed in claim 5, wherein for the gross weight of the interference pigment that at first is coated with titanium dioxide, the amount that said silicon-containing compound is coated with then is 1-10 weight %.
7. according to claim 1 or claim 2 cosmetic composition, wherein said interference colours are not limited to have the color of particular range of wavelengths, but the color that shows at the whole wave-length coverage 400nm-700nm of Show Color.
8. according to claim 1 or claim 2 cosmetic composition; Wherein said compositions has a small amount of gloss; Show interference colours simultaneously to be used to compensating skin problem or skin blemishes, the third dimension of skin and the dressing of nature are provided, and improve use feeling and gloss duration.
9. according to claim 1 or claim 2 cosmetic composition, the formulation of wherein said cosmetic composition be selected from cosmetic sun screen, foundation emulsion, face powder at the bottom of, any in muffin, loose powder, lip pomade, lip gloss, lip line, mascara, eyebrow pencil, eye shadow and the nial polish.
10. comprise the method for preparing of the cosmetic composition of interference pigment, it comprises:
(1) prepares interference pigment, wherein use the surface of titanium dioxide-coated tabular alumina;
(2) grind the also component of hybridization cosmetic compositions, it comprises oil-soluble oil component, binding agent, pigment, sunscreen, antiseptic and spice; And
(3) will be added to through the said interference pigment of step (1) preparation in the mixture that grinds by step (2), wherein:
Said cosmetic composition comprises the said interference pigment of 0.5-80 weight % scope;
With respect to the gross weight of said aluminium oxide, the coating weight of said titanium dioxide is 10-60 weight %; With
Said tabular alumina has the mean diameter of 5-15 micron, the maximum line diameter/thickness of 5-40,1-4m 2The specific surface area of/g and with the gloss number of gloss meter at the 10-25 of 60 ° of measurements.
11. method as claimed in claim 10 wherein, provides the said interference pigment in the step (1) so that the surface of said tabular alumina is coated with by silicon-containing compound again except the titanium dioxide of at first coating.
12. method as claimed in claim 10, wherein said cosmetic composition are the powder or the powder of compacting.
CN2006800509388A 2005-11-11 2006-11-10 Cosmetic composition for make up containing the interference color pigment and preparing method of the same Expired - Fee Related CN101355923B (en)

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