CN113317997B - Anti-somberness composition, anti-somberness cosmetic and preparation method thereof - Google Patents
Anti-somberness composition, anti-somberness cosmetic and preparation method thereof Download PDFInfo
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- CN113317997B CN113317997B CN202110753634.4A CN202110753634A CN113317997B CN 113317997 B CN113317997 B CN 113317997B CN 202110753634 A CN202110753634 A CN 202110753634A CN 113317997 B CN113317997 B CN 113317997B
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- titanium dioxide
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- somberness
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- 239000002537 cosmetic Substances 0.000 title claims abstract description 91
- 239000000203 mixture Substances 0.000 title claims abstract description 55
- 238000002360 preparation method Methods 0.000 title abstract description 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 95
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 79
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 47
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 40
- 239000004205 dimethyl polysiloxane Substances 0.000 claims abstract description 36
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims abstract description 36
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims abstract description 36
- 239000000843 powder Substances 0.000 claims abstract description 33
- 230000002209 hydrophobic effect Effects 0.000 claims abstract description 28
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 21
- 238000010521 absorption reaction Methods 0.000 claims abstract description 20
- 239000000758 substrate Substances 0.000 claims abstract description 20
- -1 tri-isostearic acid propoxide titanium salt Chemical compound 0.000 claims abstract description 18
- 239000005058 Isophorone diisocyanate Substances 0.000 claims abstract description 7
- 229920001577 copolymer Polymers 0.000 claims abstract description 7
- 239000002904 solvent Substances 0.000 claims description 19
- 229940008099 dimethicone Drugs 0.000 claims description 18
- 239000007788 liquid Substances 0.000 claims description 16
- 238000002156 mixing Methods 0.000 claims description 14
- 239000003086 colorant Substances 0.000 claims description 13
- 239000003974 emollient agent Substances 0.000 claims description 13
- 239000003755 preservative agent Substances 0.000 claims description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- 239000003995 emulsifying agent Substances 0.000 claims description 12
- 239000003906 humectant Substances 0.000 claims description 12
- 239000003607 modifier Substances 0.000 claims description 12
- 239000003381 stabilizer Substances 0.000 claims description 12
- 239000002002 slurry Substances 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- 239000003963 antioxidant agent Substances 0.000 claims description 8
- 239000006071 cream Substances 0.000 claims description 8
- 229920006037 cross link polymer Polymers 0.000 claims description 8
- 230000002335 preservative effect Effects 0.000 claims description 8
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 7
- UYTPUPDQBNUYGX-UHFFFAOYSA-N guanine Chemical compound O=C1NC(N)=NC2=C1N=CN2 UYTPUPDQBNUYGX-UHFFFAOYSA-N 0.000 claims description 7
- 239000004615 ingredient Substances 0.000 claims description 7
- TXFPEBPIARQUIG-UHFFFAOYSA-N 4'-hydroxyacetophenone Chemical compound CC(=O)C1=CC=C(O)C=C1 TXFPEBPIARQUIG-UHFFFAOYSA-N 0.000 claims description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 6
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 6
- ZAKOWWREFLAJOT-CEFNRUSXSA-N D-alpha-tocopherylacetate Chemical compound CC(=O)OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C ZAKOWWREFLAJOT-CEFNRUSXSA-N 0.000 claims description 5
- LPGFSDGXTDNTCB-UHFFFAOYSA-N [3-(16-methylheptadecanoyloxy)-2,2-bis(16-methylheptadecanoyloxymethyl)propyl] 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(COC(=O)CCCCCCCCCCCCCCC(C)C)(COC(=O)CCCCCCCCCCCCCCC(C)C)COC(=O)CCCCCCCCCCCCCCC(C)C LPGFSDGXTDNTCB-UHFFFAOYSA-N 0.000 claims description 5
- ZAKOWWREFLAJOT-UHFFFAOYSA-N d-alpha-Tocopheryl acetate Natural products CC(=O)OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C ZAKOWWREFLAJOT-UHFFFAOYSA-N 0.000 claims description 5
- DTPCFIHYWYONMD-UHFFFAOYSA-N decaethylene glycol Chemical compound OCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO DTPCFIHYWYONMD-UHFFFAOYSA-N 0.000 claims description 5
- 238000004945 emulsification Methods 0.000 claims description 5
- FOYKKGHVWRFIBD-UHFFFAOYSA-N gamma-tocopherol acetate Natural products CC(=O)OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1 FOYKKGHVWRFIBD-UHFFFAOYSA-N 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- YZUUTMGDONTGTN-UHFFFAOYSA-N nonaethylene glycol Chemical compound OCCOCCOCCOCCOCCOCCOCCOCCOCCO YZUUTMGDONTGTN-UHFFFAOYSA-N 0.000 claims description 5
- 229940057874 phenyl trimethicone Drugs 0.000 claims description 5
- LINXHFKHZLOLEI-UHFFFAOYSA-N trimethyl-[phenyl-bis(trimethylsilyloxy)silyl]oxysilane Chemical compound C[Si](C)(C)O[Si](O[Si](C)(C)C)(O[Si](C)(C)C)C1=CC=CC=C1 LINXHFKHZLOLEI-UHFFFAOYSA-N 0.000 claims description 5
- BYQPMKXSZDJZAW-UHFFFAOYSA-N 1-octanoyloxybutyl octanoate Chemical compound CCCCCCCC(=O)OC(CCC)OC(=O)CCCCCCC BYQPMKXSZDJZAW-UHFFFAOYSA-N 0.000 claims description 4
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 claims description 4
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 4
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 claims description 4
- 229960005323 phenoxyethanol Drugs 0.000 claims description 4
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 claims description 4
- 239000000516 sunscreening agent Substances 0.000 claims description 4
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 claims description 3
- NCZPCONIKBICGS-UHFFFAOYSA-N 3-(2-ethylhexoxy)propane-1,2-diol Chemical compound CCCCC(CC)COCC(O)CO NCZPCONIKBICGS-UHFFFAOYSA-N 0.000 claims description 3
- 230000003078 antioxidant effect Effects 0.000 claims description 3
- 229940100524 ethylhexylglycerin Drugs 0.000 claims description 3
- 235000011187 glycerol Nutrition 0.000 claims description 3
- UCNNJGDEJXIUCC-UHFFFAOYSA-L hydroxy(oxo)iron;iron Chemical compound [Fe].O[Fe]=O.O[Fe]=O UCNNJGDEJXIUCC-UHFFFAOYSA-L 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- YOBAEOGBNPPUQV-UHFFFAOYSA-N iron;trihydrate Chemical compound O.O.O.[Fe].[Fe] YOBAEOGBNPPUQV-UHFFFAOYSA-N 0.000 claims description 3
- 238000012986 modification Methods 0.000 claims description 3
- 230000004048 modification Effects 0.000 claims description 3
- WCVRQHFDJLLWFE-UHFFFAOYSA-N pentane-1,2-diol Chemical compound CCCC(O)CO WCVRQHFDJLLWFE-UHFFFAOYSA-N 0.000 claims description 3
- 229940099549 polyglycerin-3 Drugs 0.000 claims description 3
- 239000011780 sodium chloride Substances 0.000 claims description 3
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 claims description 2
- XUJLWPFSUCHPQL-UHFFFAOYSA-N 11-methyldodecan-1-ol Chemical compound CC(C)CCCCCCCCCCO XUJLWPFSUCHPQL-UHFFFAOYSA-N 0.000 claims description 2
- GTJOHISYCKPIMT-UHFFFAOYSA-N 2-methylundecane Chemical compound CCCCCCCCCC(C)C GTJOHISYCKPIMT-UHFFFAOYSA-N 0.000 claims description 2
- XZOYHFBNQHPJRQ-UHFFFAOYSA-N 7-methyloctanoic acid Chemical compound CC(C)CCCCCC(O)=O XZOYHFBNQHPJRQ-UHFFFAOYSA-N 0.000 claims description 2
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 claims description 2
- SGVYKUFIHHTIFL-UHFFFAOYSA-N Isobutylhexyl Natural products CCCCCCCC(C)C SGVYKUFIHHTIFL-UHFFFAOYSA-N 0.000 claims description 2
- 229920002385 Sodium hyaluronate Polymers 0.000 claims description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 2
- MTZQAGJQAFMTAQ-UHFFFAOYSA-N benzoic acid ethyl ester Natural products CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 claims description 2
- HGKOWIQVWAQWDS-UHFFFAOYSA-N bis(16-methylheptadecyl) 2-hydroxybutanedioate Chemical compound CC(C)CCCCCCCCCCCCCCCOC(=O)CC(O)C(=O)OCCCCCCCCCCCCCCCC(C)C HGKOWIQVWAQWDS-UHFFFAOYSA-N 0.000 claims description 2
- 229960001617 ethyl hydroxybenzoate Drugs 0.000 claims description 2
- 235000010228 ethyl p-hydroxybenzoate Nutrition 0.000 claims description 2
- 239000004403 ethyl p-hydroxybenzoate Substances 0.000 claims description 2
- NUVBSKCKDOMJSU-UHFFFAOYSA-N ethylparaben Chemical compound CCOC(=O)C1=CC=C(O)C=C1 NUVBSKCKDOMJSU-UHFFFAOYSA-N 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- VKPSKYDESGTTFR-UHFFFAOYSA-N isododecane Natural products CC(C)(C)CC(C)CC(C)(C)C VKPSKYDESGTTFR-UHFFFAOYSA-N 0.000 claims description 2
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims description 2
- 235000019341 magnesium sulphate Nutrition 0.000 claims description 2
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 claims description 2
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 claims description 2
- 229960002216 methylparaben Drugs 0.000 claims description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 claims description 2
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 229920003217 poly(methylsilsesquioxane) Polymers 0.000 claims description 2
- 229940010747 sodium hyaluronate Drugs 0.000 claims description 2
- 235000010265 sodium sulphite Nutrition 0.000 claims description 2
- YWIVKILSMZOHHF-QJZPQSOGSA-N sodium;(2s,3s,4s,5r,6r)-6-[(2s,3r,4r,5s,6r)-3-acetamido-2-[(2s,3s,4r,5r,6r)-6-[(2r,3r,4r,5s,6r)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2- Chemical compound [Na+].CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 YWIVKILSMZOHHF-QJZPQSOGSA-N 0.000 claims description 2
- LADGBHLMCUINGV-UHFFFAOYSA-N tricaprin Chemical compound CCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCC)COC(=O)CCCCCCCCC LADGBHLMCUINGV-UHFFFAOYSA-N 0.000 claims description 2
- UUJLHYCIMQOUKC-UHFFFAOYSA-N trimethyl-[oxo(trimethylsilylperoxy)silyl]peroxysilane Chemical compound C[Si](C)(C)OO[Si](=O)OO[Si](C)(C)C UUJLHYCIMQOUKC-UHFFFAOYSA-N 0.000 claims description 2
- 229960005150 glycerol Drugs 0.000 claims 1
- 230000008021 deposition Effects 0.000 abstract description 6
- 230000000694 effects Effects 0.000 description 19
- 238000005282 brightening Methods 0.000 description 14
- 210000002374 sebum Anatomy 0.000 description 13
- 230000000052 comparative effect Effects 0.000 description 10
- 238000012360 testing method Methods 0.000 description 10
- 239000010445 mica Substances 0.000 description 8
- 229910052618 mica group Inorganic materials 0.000 description 8
- 230000001815 facial effect Effects 0.000 description 7
- 230000008901 benefit Effects 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000008367 deionised water Substances 0.000 description 4
- 229910021641 deionized water Inorganic materials 0.000 description 4
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 4
- 230000002035 prolonged effect Effects 0.000 description 4
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- QEYATHUQKXAPIM-NRFANRHFSA-N (4s)-4-amino-5-octadecoxy-5-oxopentanoic acid Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)[C@@H](N)CCC(O)=O QEYATHUQKXAPIM-NRFANRHFSA-N 0.000 description 2
- 229940073609 bismuth oxychloride Drugs 0.000 description 2
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- BWOROQSFKKODDR-UHFFFAOYSA-N oxobismuth;hydrochloride Chemical compound Cl.[Bi]=O BWOROQSFKKODDR-UHFFFAOYSA-N 0.000 description 2
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- 239000011148 porous material Substances 0.000 description 2
- 229940072873 stearoyl glutamic acid Drugs 0.000 description 2
- PBFGMXZRJIUGKU-UHFFFAOYSA-N 3-decanoyloxybutyl decanoate Chemical compound CCCCCCCCCC(=O)OCCC(C)OC(=O)CCCCCCCCC PBFGMXZRJIUGKU-UHFFFAOYSA-N 0.000 description 1
- ANZUDYZHSVGBRF-UHFFFAOYSA-N 3-ethylnonane-1,2,3-triol Chemical compound CCCCCCC(O)(CC)C(O)CO ANZUDYZHSVGBRF-UHFFFAOYSA-N 0.000 description 1
- LFESLSYSZQYEIZ-UHFFFAOYSA-N 3-octanoyloxybutyl octanoate Chemical compound CCCCCCCC(=O)OCCC(C)OC(=O)CCCCCCC LFESLSYSZQYEIZ-UHFFFAOYSA-N 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- ATFFFUXLAJBBDE-FQEVSTJZSA-N N-Stearoyl glutamic acid Chemical compound CCCCCCCCCCCCCCCCCC(=O)N[C@H](C(O)=O)CCC(O)=O ATFFFUXLAJBBDE-FQEVSTJZSA-N 0.000 description 1
- 206010040829 Skin discolouration Diseases 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
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- 230000003020 moisturizing effect Effects 0.000 description 1
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- IKNCGYCHMGNBCP-UHFFFAOYSA-N propan-1-olate Chemical compound CCC[O-] IKNCGYCHMGNBCP-UHFFFAOYSA-N 0.000 description 1
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- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/29—Titanium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/25—Silicon; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/26—Aluminium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Abstract
The application belongs to the technical field of cosmetics, and particularly relates to a dark-resistant cosmetic composition, a cosmetic and a preparation method thereof. The present application provides an anti-sombency composition comprising: triple hydrophobic treatment titanium dioxide, alumina substrate pearl powder and oil absorption silica; the triple hydrophobic titanium dioxide is titanium dioxide modified by tri-isostearic acid propoxide titanium salt, di-PEG-15 dimethyl polysiloxane/IPDI copolymer and PEG-2 soyamine. The cosmetic containing the anti-somberness composition can improve skin color for a long time and resist somberness of the base makeup caused by various factors. Therefore, the invention provides the dark-deposition-resistant composition, the cosmetic and the preparation method thereof, which can effectively solve the technical problems that the dark deposition phenomenon is easy to occur after the use time of the existing cosmetic product is too long, so that the face is dark and the color of the face is not good.
Description
Technical Field
The application belongs to the technical field of cosmetics, and particularly relates to an anti-somberness composition, an anti-somberness cosmetic and a preparation method thereof.
Background
Clean and bright skin has been a pursued goal of many asian women. However, many base make-up lotions are prone to dull and dark phenomena after the make-up time of the face is too long, and the face is dark and bad in smell. The development of a base makeup product with lasting brightness and darkness becomes one of the primary demands of consumers.
In the prior art, for example, patent CN 110693738A discloses a gilding lasting leisure foundation solution and a preparation method thereof, and bismuth oxychloride is added into the foundation solution to enhance the luster. The method does not treat the root cause of the dullness of the base makeup, only brightens the base makeup by means of the metal luster of the bismuth oxychloride, cannot overcome the dullness caused by the loss of powder and insufficient covering power after long-time makeup, and belongs to 'temporary solution treatment and permanent solution treatment'.
Patent CN108472206A discloses compositions with improved gloss effect, mainly consisting of a nacre/mica-based lightening powder, a triglyceride, R 5 -O-R 6 And dextrin esters, and can be used for facial care and/or make-up. However, natural mica/mother-of-pearl has insufficient gloss due to the presence of impurities and problems such as unevenness after grinding. Such compositions have limited lightening benefits for facial make-up products, and can provide immediate lightening benefits in skin care products, but may be difficult to achieve over time in make-up products that inherently contain powders.
In conclusion, the existing foundation liquid is easy to become dark and heavy after the face is worn for too long time, so that the face is dark and bad in smell. The development of a cosmetic with lasting gloss and darkness is a technical problem to be solved urgently by the technical personnel in the field. The application finds that the existing base makeup cosmetics are easy to generate somberness: with the prolonging of the makeup time, a large amount of sebum secreted by the face infiltrates the makeup base toner, the surface treatment of the makeup base toner is damaged, the covering performance is reduced, and the makeup face continuously falls off to expose the original skin color of the face; secondly, the existing makeup base cosmetics have poor compatibility, and the makeup base toner is not fully developed, so that the color of the makeup base cosmetic is inconsistent with the color of the makeup base cosmetic after being coated; finally, existing makeup-based cosmetics only rely on titanium dioxide to achieve covering and brightening effects, and once the covering performance is reduced, the problems of somberness/mottle and the like are very easy to occur.
Therefore, there is an urgent need for a make-up product that improves the problems of the above-mentioned prior art make-up and satisfies the demand of cosmetic users who tend to make oil on the facial skin for anti-dullness and brightening the make-up.
Disclosure of Invention
In view of the above, an object of the present invention is to provide an anti-somberness composition, a cosmetic and a method for preparing the same, which can improve skin color for a long time and prevent somberness of makeup due to various factors.
The present application provides in a first aspect an anti-sombency composition comprising:
triple hydrophobic treatment titanium dioxide, alumina substrate pearl powder and oil absorption silica;
the triple hydrophobic titanium dioxide is titanium dioxide modified by tri-isostearic acid propoxide titanium salt, di-PEG-15 dimethyl polysiloxane/IPDI copolymer and PEG-2 soyamine.
The invention provides an anti-somberness composition, wherein the weight ratio of the triple hydrophobic treated titanium dioxide, the alumina substrate pearl powder and the oil absorption silica is (8-30): (0.5-3): (0.5-4.5).
An anti-somberness composition according to the present invention, wherein said oil-absorbing silica is selected from porous silica or/and spherical silica.
An anti-somberness composition according to the present invention, wherein the oil-absorbing silica is porous silica.
The invention provides a dark-deposition resistant composition, wherein the size of the alumina substrate pearl essence is 5-20 mu m.
An anti-somberness composition according to the present invention, wherein the oil-absorbing silica has an oil absorption value of 60 to 250mg/100g.
The application discloses in a second aspect the use of said anti-sombency composition in a concealer cosmetic.
According to the application of the invention, the cosmetic comprises one or more of foundation liquid, foundation cream, BB cream, pre-makeup emulsion, sun cream, concealer and face cream.
A third aspect of the present application provides a dull-finish cosmetic comprising: the anti-somberness composition, and other ingredients acceptable for use in cosmetics.
The dark-resisting cosmetic comprises one or more of an emollient, a skin feel modifier, an emulsifier, a colorant, a humectant, a preservative, an antioxidant, a stabilizer and a solvent.
According to the dark deposition resisting cosmetic, the dark deposition resisting composition accounts for 9-37.5% by weight based on the total weight of the cosmetic.
According to the dark-deposition-resistant cosmetic, the amount of the triple hydrophobic-treated titanium dioxide is 8-30% by weight based on the total weight of the cosmetic.
According to the dark-colored cosmetic, the amount of the triple hydrophobic-treated titanium dioxide is 10-20% by weight based on the total weight of the cosmetic.
According to the dark-resisting cosmetic, the content of the alumina substrate pearl powder is 0.5 to 3 weight percent based on the total weight of the cosmetic.
The somberness-resistant cosmetic is characterized in that the oil-absorbing silica is used in an amount of 0.5-4.5 wt% based on the total weight of the cosmetic.
A method for producing a cosmetic according to a fourth aspect of the present application, comprising:
step 1, mixing the phase B with the phase A to obtain powder slurry; wherein, the phase A comprises an emollient, an emulsifier and a skin feel modifier, and the phase B comprises a colorant and triple hydrophobic treated titanium dioxide;
step 3, mixing the phase D and the powder slurry obtained in the step 1 in a grading manner until emulsification is achieved, and then continuously adding the phase C and the phase E to obtain a cosmetic; wherein, the phase C comprises alumina substrate pearl powder and oil absorption silica, and the phase E comprises a preservative and a solvent.
Compared with the prior art, the method has the following advantages and effects:
1. the anti-dullness composition can enable cosmetics to have the effects of immediately brightening and dullness skin color, moisturizing and penetrating luster after the cosmetics are applied to the face, create a bright, clean and smooth makeup effect, and overcome the defect that the color of commercially available base makeup is quickly darkened after the base makeup is applied;
2. the cosmetic can fully develop color, has uniform color after being primarily made up and being made up for a long time, can keep bright skin color for a long time, and still cannot generate the phenomena of somberness, gray color, poor complexion and the like after being made up for more than 8 hours.
Drawings
In order to more clearly illustrate the embodiments of the present application or the technical solutions in the prior art, the drawings used in the description of the embodiments or the prior art will be briefly described below.
Fig. 1 is a graph showing somberness (%) at different times of examples 1 to 11 and comparative examples 1 to 5 provided in the test example of the present application.
Detailed Description
The application provides a dark-deposition-resistant composition, a cosmetic and a preparation method thereof, which are used for solving the technical defects that the dark deposition phenomenon is easy to occur after the use time of the existing cosmetic product in the prior art is too long, so that the face is dark and the color of the face is not good.
The technical solutions in the embodiments of the present application will be described clearly and completely below, and it should be understood that the described embodiments are only a part of the embodiments of the present application, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present application.
The present application provides in a first aspect an anti-sombency composition comprising:
triple hydrophobic treatment titanium dioxide, alumina substrate pearl powder and oil absorption silica,
the triple hydrophobic titanium dioxide is titanium dioxide modified by tri-isostearic acid propoxide titanium salt, di-PEG-15 dimethyl polysiloxane/IPDI copolymer and PEG-2 soyamine.
Compared with the common single surface treatment titanium dioxide (such as stearoyl glutamic acid treatment titanium dioxide and polydimethylsiloxane treatment titanium dioxide) on the market, the triple hydrophobic treatment titanium dioxide has excellent dispersibility, skin-sticking property and persistence, and the triple hydrophobic treatment titanium dioxide (titanium dioxide modified by triisostearic acid propoxide, bis-PEG-15 dimethylpolysiloxane/IPDI copolymer and PEG-2 soyamine and firmly coated on the surface of the titanium dioxide by using a chemical treatment agent and hydroxyl adsorbed on the surface of the titanium dioxide through bonding/grafting reaction) with excellent dispersibility, skin-sticking property and persistence is applied to cosmetics, so that the corrosion of sebum and sweat can be well resisted, and meanwhile, the triple hydrophobic treatment titanium dioxide has good dispersibility and color development effects.
The invention provides an anti-somberness composition, wherein the weight ratio of the triple hydrophobic treated titanium dioxide, the alumina substrate pearl powder and the oil absorption silica is (8-30): (0.5-3): (0.5-4.5).
An anti-somberness composition according to the present invention, wherein said oil-absorbing silica is selected from porous silica or/and spherical silica.
An anti-somberness composition according to the present invention, wherein the oil-absorbing silica is porous silica.
The somberness-resisting composition according to the present invention, wherein the oil absorption value of the oil-absorbing silica is 60 to 250mg/100g.
In particular, the surface of the porous silica has more pores, and the oil can be continuously adsorbed by the action of the capillary force and the larger specific surface area of the porous silica, and the adsorbed oil is kept among the pores. The porous silica is one of the components for resisting somberness and deposition, can continuously absorb sebum secreted by the face, reduces the influence of the sebum on the makeup surface, and avoids the phenomena of makeup removal/mottle and the like caused by the continuous accumulation of the facial sebum along with the increase of the makeup time.
The invention provides a dark-deposition resistant composition, wherein the size of the alumina substrate pearl essence is 5-20 mu m.
In the daily chemical industry, the brightening powder is usually mica. Mica is processed from natural minerals, and due to the influence of factors such as raw materials, processes and the like, the surface of the mica is easy to be uneven, the reflection capability of the mica on light is limited, and the brightening effect is not outstanding enough; the aluminum oxide is chemically synthesized, the surface of the aluminum oxide is smooth and flat, and light can be better reflected, so that the brightening effect of the aluminum oxide brightening powder is stronger than that of the mica brightening powder. The alumina base material pearl powder and the oil absorption silica can enable the triple hydrophobic treatment titanium dioxide to have better light ray reflection capability, and have the advantages of more sufficient color development, capability of resisting sebum invasion, more fit with human skin and avoiding makeup removal; can achieve better skin brightening effect.
The application discloses in a second aspect the use of said anti-sombency composition in a concealer cosmetic.
According to the application of the invention, the cosmetic comprises one or more of base liquid, foundation cream, BB cream, makeup front emulsion, sun cream, concealer and face repair cream, loose powder, pressed powder, high gloss paste and high gloss pressed powder, but is preferably the base liquid.
A third aspect of the present application provides a somberness-resisting cosmetic comprising: the anti-somberness composition, and other ingredients acceptable for use in cosmetics.
Specifically, the other ingredients acceptable in the cosmetics used in the present application may be emollients, skin-feel modifiers, emulsifiers, colorants, humectants, preservatives, antioxidants, stabilizers and solvents, fragrances, storage agents, film formers, sunscreens, etc., all of which are conventional agents used in cosmetics at present, and the amounts of the emollients, skin-feel modifiers, emulsifiers, colorants, humectants, preservatives, antioxidants, stabilizers and solvents are all conventional amounts used in cosmetics.
Preferably, the cosmetically acceptable additional ingredients are selected from one or more of emollients, skin feel modifiers, emulsifiers, colorants, humectants, preservatives, antioxidants, stabilizers and solvents.
According to the invention, the dark-deposition resisting cosmetic comprises 9-37.5 wt% of the dark-deposition resisting composition based on the total weight of the cosmetic.
According to the dark-deposition-resistant cosmetic, the amount of the triple hydrophobic-treated titanium dioxide is 8-30% by weight based on the total weight of the cosmetic.
According to the dark-deposition-resistant cosmetic, the amount of the triple hydrophobic-treated titanium dioxide is 10-20% by weight based on the total weight of the cosmetic.
The invention relates to a dark-settling resistant cosmetic, which takes the total weight of the cosmetic as a reference, and the content of the alumina substrate pearl essence is 0.5-3% by weight.
According to the dark-deposition-resistant cosmetic, the oil absorption silica is used in an amount of 0.5-4.5% by weight based on the total weight of the cosmetic.
In another embodiment, the emollient is selected from the group consisting of cyclopentadimethylsiloxane, phenyl trimethicone, tocopheryl acetate, pentaerythritol tetraisostearate, butanediol dicaprylate/dicaprate, isododecane, diisostearyl malate, octyl methicone, C 12-15 One or more of alcohol benzoate, caprylic/capric triglyceride and isotridecanol isononanoate. But are not limited thereto, emollients commonly used in the art may be used, and cyclopentadimethylsiloxane, phenyl trimethicone, tocopheryl acetate, pentaerythritol tetraisostearate and butylene glycol dicaprylate/dicaprate are preferred herein.
In another embodiment, the skin feel modifier is selected from one or more of dimethicone/polyglyceryl-3 crosspolymer, dimethicone crosspolymer, polymethylsilsesquioxane, trimethylsiloxysilicate, and acrylic/dimethicone copolymer. But not limited thereto, skin feel modifiers commonly used in the art may be used, and the polydimethylsiloxane/polyglycerol-3 cross-linked polymer is preferred in the present application.
In another embodiment, the emulsifier is selected from one or more of PEG-10 dimethicone, PEG-9 dimethiconoethyl dimethicone, cetyl PEG/PPG-10/1 dimethicone, sorbitan olivate, and PEG/PPG-18/18 dimethicone. But not limited thereto, emulsifiers commonly used in the art may be used, and PEG-10 polydimethylsiloxane and PEG-9 dimethiconoethyl polydimethylsiloxane are preferred in the present application.
In another embodiment, the colorant is selected from the group consisting of CI77492 iron yellow, CI77491 iron red, CI77499 iron black, a mixture of titanium dioxide and stearyl glutamate, and a mixture of titanium dioxide and polydimethylsiloxane. But not limited thereto, colorants commonly used in the art are available, and preferred colorants for this application are CI77492 iron yellow, CI77491 iron red, CI77499 iron black, a mixture of titanium dioxide and stearyl glutamate, and a mixture of titanium dioxide and polydimethylsiloxane.
In another embodiment, the humectant is selected from one or more of glycerin, butylene glycol, 1, 2-pentanediol, sodium hyaluronate, and propylene glycol. Humectants commonly used in the art may be used, with glycerol, butylene glycol, and 1, 2-pentanediol being preferred herein.
In another embodiment, the preservative is selected from one or more of phenoxyethanol, ethylhexyl glycerol, methylparaben, and ethylparaben. But not limited thereto, preservatives commonly used in the art may be used, and phenoxyethanol and ethylhexylglycerin are preferred in the present application.
In another embodiment, the antioxidant is selected from p-hydroxyacetophenone or/and sodium sulfite. Antioxidants commonly used in the art are all available, and p-hydroxyacetophenone is preferred in the present application.
In another embodiment, the stabilizer is selected from one or more of sodium chloride, EDTA-2Na, and magnesium sulfate. But not limited thereto, a stabilizer commonly used in the art may be used, and sodium chloride is preferred in the present application.
In another embodiment, the solvent is selected from water or/and ethanol. Wherein ethanol is used to dissolve the preservative. But not limited thereto, any solvent commonly used in the art may be used, and water and ethanol are preferable in this application, and the water is deionized water, purified water, or distilled water, etc.
A method for producing a cosmetic according to the fourth aspect of the present application, comprising:
step 1, mixing the phase B with the phase A to obtain powder slurry; wherein the phase A comprises an emollient, an emulsifier and a skin feel modifier, and the phase B comprises a colorant and triple hydrophobic treated titanium dioxide;
step 3, mixing the phase D and the powder slurry obtained in the first step for several times until emulsification is achieved, and then continuously adding the phase C and the phase E to obtain a cosmetic; wherein the phase C comprises alumina substrate pearl powder and oil absorption silica, and the phase E comprises a preservative and a solvent.
Specifically, the mixing in step 1 is three-roll grinding, the homogenization parameter is 6000rpm, and 10 minutes.
Specifically, in step 1, phase A is divided into two parts and mixed with phase B, part of the emollient of phase A is mixed with phase B to prepare a first mixture, and then the rest of the phase A ingredients are mixed with the first mixture to prepare the powder slurry. Wherein, the A phase comprises a first sub A phase and a second sub A phase; the first sub phase A is pentaerythritol tetraisostearate and butanediol dicaprylate/dicaprate; the second sub-phase A is cyclopentadimethylsiloxane, phenyl trimethicone, tocopheryl acetate, PEG-10 polydimethylsiloxane, PEG-9 dimethicoethyl polydimethylsiloxane, and dimethicone/polyglycerin-3 crosspolymer.
Specifically, the phase B and the first sub-phase A are preliminarily premixed and ground three times by a three-roll grinder to prepare a uniform first mixture. Weighing the second sub A phase, mixing with the first mixture, homogenizing for 10 minutes at 6000rpm, and preparing powder slurry.
Specifically, in the step 2, the components of the phase D are heated and stirred at 65-85 ℃ until the components are completely dissolved, and the temperature is reduced to normal temperature, so that the phase D after dissolution and mixing is obtained.
Specifically, in step 3, the phase D after dissolution and mixing is added to the slurry three times in a homogenizer until complete emulsification, so as to obtain a second mixture, wherein the homogenizer has a parameter of 6000rpm for 5 minutes.
Specifically, in step 3, phase C, phase E and the second mixture homogenizer are dispersed and mixed at a low speed, the homogenizer low speed dispersion parameter is 3000rpm,1 minute.
Wherein, the raw materials or reagents used in the following examples are all commercially available or self-made.
Solvents in the present application include water or/and ethanol.
The triple hydrophobic treated titanium dioxide of the following examples was purchased from shin fragrance pigment technology (china) limited and the agency was new-day trade development (hong kong) limited under the trade name UNIPURE WHITE LC888.
The alumina substrate pearlescers of the following examples were obtained from Merck group under the trade name
Glam Silver, an agent is Wanlu chemical Co., ltd, guangzhou.
The porous silicas of the following examples were purchased from Chemland co., ltd, an agency of aoyuan trade Ltd, guangzhou under the trade designation CL Silica 300 or CL-Silica 900.
The following examples of conventional silica were purchased from advanced Korea chemical under the trade name SUNSIL-130L, guangzhou HuaTuo cosmetics science and technology, inc.
The phenoxyethanol, ethylhexylglycerin complexing agents of the following examples were purchased from Shumei GmbH, germany under the trade name of
PE 9010。
The stearoylglutamic acid modified titanium dioxide of the following examples was purchased from Kobo Products, inc. (Shanghai Korea-European resistance agency) under the trade name TiO2-IR300-ASG.
The polydimethylsiloxane modified titania of the following examples was purchased from Kobo Products, inc. (Shanghai Korea-European resistance agency) under the trade name BTD-DS4.
The dimethicone, dimethicone/polyglycerine-3 crosspolymer of the following examples was purchased from Shin-Etsu Silicones Credit Silicone (agency of san Kaes, guangzhou) under the trade name KSG-710.
The components are not limited to the specific commodities, and the same products produced by other companies can be used, and can be prepared and used according to the specifications of the commodities.
Examples
The embodiment of the application provides a preparation method of various foundation solutions, which specifically comprises the following steps:
foundation solutions of examples 1 to 11 and comparative examples 1 to 5 were prepared according to the formulation of table 1, comprising the following steps:
1) Preliminarily premixing the phase B and the first sub phase A, and grinding for three times by using a three-roll grinder to prepare a uniform first mixture. And weighing a second sub A phase, mixing the second sub A phase with the first mixture, homogenizing for 10 minutes at 6000rpm, and preparing powder slurry.
2) Weighing each component of the D phase, heating and stirring at 85 ℃ until each component is completely dissolved, and cooling to normal temperature for later use to obtain a dissolved and mixed D phase; the homogenizer was turned on (6000rpm, 5 minutes), and the D phase after dissolution and mixing was added to the above slurry in three portions until emulsification was completed to obtain a second mixture.
3) And dispersing and mixing the phase C, the phase E and the second mixture by using a homogenizer at a low speed to prepare a liquid foundation, wherein the low speed dispersion parameter of the homogenizer is 3000rpm, and the time is 1 minute.
Wherein,
the phase A comprises an emollient, an emulsifier and a skin feel modifier; wherein, the A phase comprises a first sub A phase and a second sub A phase; the first sub phase A is pentaerythritol tetraisostearate and butanediol dicaprylate/dicaprate; the second sub-phase A is cyclopentadimethylsiloxane, phenyl trimethicone, tocopheryl acetate, PEG-10 polydimethylsiloxane, PEG-9 dimethicoethyl polydimethylsiloxane, and dimethicone/polyglycerin-3 crosspolymer.
The phase B comprises a colorant or/and triple hydrophobic treated titanium dioxide.
The phase C comprises one or more of filling powder, alumina substrate pearl powder and oil absorption silica.
The phase D comprises a first solvent, a humectant and a stabilizer; the first solvent is deionized water.
Phase E comprises a preservative and a second solvent; the second solvent is ethanol.
TABLE 1
In Table 1, "/" is no addition; the amount of deionized water used is "To 100" which means that less than 100% by weight of deionized water is added; the unit of the amount of other raw materials is weight percent.
Test example 1
The test examples of the present application provide the test of the brightness change at different times for examples 1 to 11 and comparative examples 1 to 5, including:
the liquid foundations of examples 1 to 11 and comparative examples 1 to 5 were drawn on a blade to form a film having the same thickness, placed in an oven at 36.5 ℃ for 15 minutes, 1 hour, 4 hours, 8 hours, and 24 hours, photographed and coated, placed in the oven for 15 minutes, 1 hour, 4 hours, and 8 hours, and cardboard was left for 15 minutes, 1 hour, 4 hours, and 8 hours, and measured with a Lab color difference meter for the corresponding L (brightness), a, b, and Δ E values, and the degree of somberness (%) was calculated to determine the change in brightness.
L t : value of L (luminance) at a certain time, L 0 : initial L (brightness) value.
TABLE 2
As can be seen from table 2, the larger the value of the somberness (%) is, the higher the lightness of the liquid foundation is, the better the somberness-resisting effect is. The sombency of comparative examples 1 to 5 decreased greatly with time, indicating that the sombency of the liquid foundation to which the triple hydrophobized titanium dioxide was not added was fast. However, the speed of decrease in the somberness was significantly slower in examples 1 to 11 than in comparative examples 1 to 5, and particularly after 4 hours, it was confirmed that the examples to which the somberness preventing composition was added were more effective in prolonging the skin lightening time of the liquid foundation and significantly delaying the somberness of the liquid foundation than the comparative examples to which the same or two components were added.
Test example 2
The test examples of the present application provide tests on the population according to the above examples 1 to 11 and comparative examples 1 to 5, and specifically include:
30 adult women (18-40 years old, with unlimited skin types) are selected, tested after normal skin care by applying the foundation lotions of example 1-example 11 and comparative example 1-comparative example 5 (the application amount is kept consistent, and is about 0.5 g/time) on the left and right cheeks, and then the foundation lotions are worn for 12 hours to carry out testing.
Δ L value: the L (lightness) value change of the face of the cosmetic test person was measured by using a Lab color difference meter 15 minutes and 8 hours after the application, respectively. Δ L is the difference between the L value measured on the face after 15 minutes of makeup and 8 hours with makeup. The greater the Δ L difference, the more pronounced was the evidence of darkening of the foundation.
Duration of brightness: after 12 hours with makeup, the time at which each makeup test person thinks that makeup begins to appear dark is recorded, and the average value is calculated. The higher the value, the longer the effectiveness of the liquid foundation against sombency.
And (3) brightening effect scoring: the tester scored the lightening of the foundation liquid after first makeup, which was 10 points full. The higher the score, the better the brightening effect.
And (3) scoring the dark effect: after a certain time of dressing, the effect of resisting somberness of the foundation liquid is scored, and the result is fully scored by 10 points. The higher the score, the better the protection against somberness.
And (3) scoring the likeness: and after 12 hours with makeup, carrying out preference score on the comprehensive effect of the foundation liquid, and fully scoring by 10. The higher the score, the higher the preference that represents the consumer.
TABLE 3
As can be seen from the results of tables 2 and 3, the foundation solutions of examples 1 to 11 according to the technical solution of the present invention have a significant somberness-preventing effect and are more excellent in user preference than the foundation solutions of comparative examples 1 to 5 of the prior art; and the somberness-resistant effect and the user preference of the preferred technical solution embodiments 1 to 8 of the present invention are more excellent than those of the technical solution embodiments 9 to 11 out of the preferred range of the present invention; further, examples 1 to 6 of the most preferable embodiment of the present invention are better in the somberness-preventing effect and the user preference than examples 7 to 8 of the preferable range.
In summary, the existing base makeup cosmetics are very facial in behaviors such as adding mica to improve the brightness of powder or adding a film-forming agent to avoid removing makeup. The dark-deposition-resistant cosmetic composition starts from multiple dimensions, the triple hydrophobic treatment titanium dioxide, the alumina substrate pearl essence and the oil absorption silica play roles together, and the triple hydrophobic treatment titanium dioxide has the advantages of full color development, capability of resisting sebum invasion, fit with human skin and avoiding makeup removal and the like; the oil absorption silica can regulate facial sebum for a long time, and the makeup is prevented from being damaged by redundant sebum; the aluminum oxide can better reflect light, and the titanium dioxide subjected to triple hydrophobic treatment is used in the formula, so that a better skin brightening effect can be achieved. The anti-somberness composition can directly hit the reasons of the somberness phenomenon of the makeup from multiple dimensions, and plays a role together, so that the skin brightening time of the makeup liquid is obviously prolonged, and the somberness phenomenon is avoided. Therefore, the dark-deposition-resistant cosmetic composition can effectively solve the problems that a large amount of sebum secreted by the face infiltrates the titanium dioxide toner as the makeup wearing time is prolonged, the surface treatment of the toner is damaged, the covering performance of the toner is reduced, or the makeup continuously falls off to expose the original skin color of the user, so that dark deposition/mottle occurs and the like.
The triple hydrophobic-treated titanium dioxide, the alumina substrate pearl essence and the oil-absorption silica have a synergistic effect as the anti-sombency components, the oil-absorption silica can continuously absorb sebum secreted by the face, the influence of the sebum on the makeup face is reduced, and the phenomena of makeup removal/mottle and the like caused by the fact that the makeup time is prolonged and the facial sebum is continuously accumulated are avoided; the anti-dullness cosmetic composition can directly attack the reasons of the dullness phenomenon of the foundation from multiple dimensions, and can play a role together, so that the skin brightening time of the anti-dullness cosmetic composition is obviously prolonged, and the dullness phenomenon is avoided.
The foregoing is only a preferred embodiment of the present application and it should be noted that those skilled in the art can make several improvements and modifications without departing from the principle of the present application, and these improvements and modifications should also be considered as the protection scope of the present application.
Claims (19)
1. An anti-somberness composition comprising:
the three-dimensional hydrophobic treatment titanium dioxide, the alumina substrate pearl powder and the oil absorption silica;
the triple hydrophobic titanium dioxide is titanium dioxide modified by tri-isostearic acid propoxide titanium salt, di-PEG-15 dimethyl polysiloxane/IPDI copolymer and PEG-2 soyamine;
the oil-absorbing silica is porous silica;
the grain size of the alumina substrate pearl powder is 5-20 mu m;
the weight ratio of the triple hydrophobic treated titanium dioxide, the alumina substrate pearl essence and the oil-absorbing silica is 20;
the modification treatment of the tri-isostearic acid propoxide titanium salt, the bis-PEG-15 dimethylpolysiloxane/IPDI copolymer and the PEG-2 soyamine specifically comprises the following steps: tri-isostearic acid propoxide titanium salt, di-PEG-15 dimethyl polysiloxane/IPDI copolymer and PEG-2 soyamine are bonded or grafted with the surface hydroxyl of titanium dioxide;
the oil absorption value of the oil absorption silica is 60-250 mg/100g.
2. Use of the anti-somberness composition of claim 1 in concealer cosmetics.
3. Use according to claim 2, wherein the cosmetic product comprises one or more of a liquid foundation, a foundation cream, a BB cream, a pre-make up, a sun cream, a concealer and a face toilet.
4. An anti-sombency cosmetic comprising: the anti-somberness composition of claim 1, together with other ingredients acceptable for use in cosmetics.
5. The cosmetic according to claim 4, wherein the other cosmetically acceptable ingredients are selected from one or more of emollients, skin feel modifiers, emulsifiers, colorants, humectants, preservatives, antioxidants, stabilizers and solvents.
6. The cosmetic product of claim 5 wherein said anti-sombency composition is present at 27.5% by weight based on the total weight of said cosmetic product.
7. The cosmetic according to claim 6, wherein the triply hydrophobically treated titanium dioxide is 20% by weight based on the total weight of the cosmetic.
8. The cosmetic according to claim 6, wherein the alumina substrate pearl essence is 3% by weight based on the total weight of the cosmetic.
9. The cosmetic according to claim 6, wherein the oil-absorbing silica is 4.5% by weight based on the total weight of the cosmetic.
10. Cosmetic product according to any one of claims 5 to 9, characterized in that said emollient is chosen from cyclopentadimethicone, phenyl trimethicone, tocopheryl acetate, pentaerythritol tetrakisIsostearate, butanediol dicaprylate/dicaprate, isododecane, diisostearyl malate, octyl methicone, C 12-15 One or more of alcohol benzoate, caprylic/capric triglyceride and isotridecanol isononanoate.
11. The cosmetic according to any one of claims 5 to 9, wherein the skin feel modifier is selected from one or more of dimethicone/polyglycerin-3 crosspolymer, dimethicone crosspolymer, polymethylsilsesquioxane, trimethylsiloxysilicate, and acrylic/dimethicone copolymer.
12. Cosmetic product according to any one of claims 5 to 9, characterized in that said emulsifier is selected from one or more of PEG-10 dimethicone, PEG-9 dimethiconoethyl dimethicone, cetyl PEG/PPG-10/1 dimethicone, sorbitan olivate and PEG/PPG-18/18 dimethicone.
13. The cosmetic according to any one of claims 5 to 9, wherein the coloring agent is one or more selected from the group consisting of CI77492 iron yellow, CI77491 iron red and CI77499 iron black.
14. The cosmetic according to any one of claims 5 to 9, wherein the humectant is one or more selected from glycerin, butylene glycol, 1, 2-pentanediol, sodium hyaluronate, and propylene glycol.
15. The cosmetic according to any one of claims 5 to 9, wherein the preservative is one or more selected from phenoxyethanol, ethylhexyl glycerin, methylparaben and ethylparaben.
16. Cosmetic product according to any one of claims 5 to 9, characterized in that the antioxidant is chosen from p-hydroxyacetophenone and/or sodium sulfite.
17. The cosmetic according to any one of claims 5 to 9, wherein the stabilizer is one or more selected from the group consisting of sodium chloride, EDTA-2Na and magnesium sulfate.
18. The cosmetic according to any one of claims 5 to 9, wherein the solvent is selected from water and/or ethanol.
19. The method for preparing an anti-somberness cosmetic according to claim 4, comprising:
step 1, mixing the phase B with the phase A to obtain powder slurry; wherein, the phase A comprises an emollient, an emulsifier and a skin feel modifier, and the phase B comprises a colorant and triple hydrophobic treated titanium dioxide;
step 2, heating the phase D until all components are dissolved; wherein the phase D comprises a solvent, a humectant and a stabilizer;
step 3, mixing the phase D and the powder slurry obtained in the step 1 in a grading manner until emulsification is achieved, and then continuously adding the phase C and the phase E for mixing to obtain a cosmetic; wherein the phase C comprises alumina substrate pearl powder and oil absorption silica, and the phase E comprises a preservative and a solvent.
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH09221411A (en) * | 1996-02-13 | 1997-08-26 | Kose Corp | Titanium dioxide and composition containing the same |
| CN1793243A (en) * | 2004-12-23 | 2006-06-28 | 德古萨股份公司 | Structure modified titanium dioxides |
| WO2017142057A1 (en) * | 2016-02-18 | 2017-08-24 | ロート製薬株式会社 | Topical dermatological composition |
| CN111683904A (en) * | 2018-05-23 | 2020-09-18 | 株式会社高丝 | Novel titanium oxide powder and cosmetic containing the same |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101212905B1 (en) * | 2005-11-11 | 2012-12-14 | (주)아모레퍼시픽 | Cosmetic composition for make up containing the interference color pigment and preparing method of the same |
| TWI411448B (en) * | 2007-12-27 | 2013-10-11 | Avon Prod Inc | Optical blurring pigment composition suitable for use in cosmetics |
| US9789032B2 (en) * | 2009-12-30 | 2017-10-17 | Avon Products, Inc. | Color cosmetic with high coverage and naturalness |
| FR2971151B1 (en) * | 2011-02-04 | 2013-07-12 | Oreal | COSMETIC COMPOSITION CONTAINING FILTERING PARTICLES OF COMPOSITE MATERIAL, NON-SPHERICAL NON-FILTRATION PARTICLES AND AT LEAST ONE POLAR OIL |
| CN104379216B (en) * | 2012-06-21 | 2019-01-01 | 莱雅公司 | The cosmetic composition with lasting effects is covered with pore |
| CN103800215A (en) * | 2014-03-07 | 2014-05-21 | 澳宝化妆品（惠州）有限公司 | Skin sun-screening composition |
| CN107823040A (en) * | 2017-10-31 | 2018-03-23 | 苏州安特化妆品股份有限公司 | It is long-acting to hold adornment muffin and preparation method thereof |
| KR102575779B1 (en) * | 2018-10-29 | 2023-09-11 | (주)아모레퍼시픽 | Make-up cosmetic composition comprising linear emulsifier and surface-coated pigment as an effective ingredient |
| CN109125188B (en) * | 2018-10-30 | 2021-05-25 | 广州艾蓓生物科技有限公司 | Lipstick with lip plumping effect and preparation method thereof |
| WO2021118781A1 (en) * | 2019-12-11 | 2021-06-17 | Avon Products, Inc. | Compositions with increased color shade stability based on pigmentary tio2, organic pigments and metal oxide particles |
-
2021
- 2021-07-02 CN CN202110753634.4A patent/CN113317997B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH09221411A (en) * | 1996-02-13 | 1997-08-26 | Kose Corp | Titanium dioxide and composition containing the same |
| CN1793243A (en) * | 2004-12-23 | 2006-06-28 | 德古萨股份公司 | Structure modified titanium dioxides |
| WO2017142057A1 (en) * | 2016-02-18 | 2017-08-24 | ロート製薬株式会社 | Topical dermatological composition |
| CN111683904A (en) * | 2018-05-23 | 2020-09-18 | 株式会社高丝 | Novel titanium oxide powder and cosmetic containing the same |
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