DE2046818A1 - Hair dyeing and setting preparations - contng benzimidazole benzophenone and phenylglyoxylic acid derivs - Google Patents

Hair dyeing and setting preparations - contng benzimidazole benzophenone and phenylglyoxylic acid derivs

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Publication number
DE2046818A1
DE2046818A1 DE19702046818 DE2046818A DE2046818A1 DE 2046818 A1 DE2046818 A1 DE 2046818A1 DE 19702046818 DE19702046818 DE 19702046818 DE 2046818 A DE2046818 A DE 2046818A DE 2046818 A1 DE2046818 A1 DE 2046818A1
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DE
Germany
Prior art keywords
hair
benzophenone
benzimidazole
dyes
contng
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
DE19702046818
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German (de)
Inventor
Auf Nichtnennung Antrag
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Deutschland GmbH
Original Assignee
Wella GmbH
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Filing date
Publication date
Application filed by Wella GmbH filed Critical Wella GmbH
Priority to DE19702046818 priority Critical patent/DE2046818A1/en
Publication of DE2046818A1 publication Critical patent/DE2046818A1/en
Pending legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/35—Ketones, e.g. benzophenone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A61K8/411—Aromatic amines, i.e. where the amino group is directly linked to the aromatic nucleus
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A61K8/418—Amines containing nitro groups
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/494—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom
    • A61K8/4946—Imidazoles or their condensed derivatives, e.g. benzimidazoles
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
    • A61Q5/065—Preparations for temporary colouring the hair, e.g. direct dyes

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Emergency Medicine (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)

Abstract

Preparations for dyeing and setting hair contain as protective agents against U. V., cpds. of the benzimidazole, benzophenone and phenylglyoxylic acid series. Hair dyes may be aromatic nitro dyes, azo dyes or triphenylmethane dyes. Other addns. may be hair tonics, hair cosmetics and perfumes. The protective cpds. are used in 0.01-2% concns.

Description

Färbende Haarfestlegemittel Die Erfindung betrifft färbende Haarfestlegemittel, welche Lichtschutzstoffe zum Schutz des gefärbten Haares gegen die Einwirkung ultravioletter Strahlung enthalten.Coloring hair setting agents The invention relates to coloring hair setting agents, which sunscreens to protect colored hair against the effects of ultraviolet rays Contain radiation.

Es ist aus der Friseurpraxis bekannt, daß man menschliche Haare nach einer Dauerwellung oder Haarwäsche mit Haarfestlegemitteln behandelt. WUrde man auf eine derartige Behandlung verzichten, so ließe sich das Haar nur schwer frisieren, da es in seiner Beschaffenheit zu locker und zu weich wäre.It is known from the hairdressing practice that one after human hair a permanent wave or hair wash treated with hair setting agents. One would do without such a treatment, it would be difficult to style the hair, because it would be too loose and too soft in its texture.

Außerdem wUrden die Frisuren bereits bei stärkeren Bewegungen sowie Einwirkung von Wind und Luftfeuchtigkeit rasch ihren frisch erhaltenen Sitz verlieren.In addition, the hairstyles would already be with stronger movements as well The effect of wind and humidity quickly lose their freshly-preserved fit.

Als Haarfestlegemittel, die diese Nachteile vermeiden, hat man im wesentlichen Präparate mit einem Gehalt an hochpolymeren Substanzen herangezogen, welche imstande sind, sich auf die Haaroberfläche in Form eines zusammenhängenden und möglichst feuchtigkeitsbeständigen Films aufzulagern. Durch derartige filmbildende Polymerisate läßt sich die mechanische Festigkeit des Haares und die Haltbarkeit der Frisur wesentlich verbessern. In Bezug auf die Frisierbarkeit des Haares wird ein erhöhter Avivageeffekt, der sich in einer Verbesserung von Kllnmbarkeit, Griff und Glanz des Haares äußert, erreicht.As hair setting agents that avoid these disadvantages, the essential preparations with a content of high polymer substances are used, which are able to apply to the hair surface in the form of a contiguous and to apply a moisture-resistant film as possible. By such film-forming Polymers can be used to increase the mechanical strength of the hair and its durability improve the hairstyle significantly. In terms of the manageability of the hair an increased finishing effect, which results in an improvement in ease of cleaning, grip and the shine of the hair is achieved.

Es sind auch schon färbende Haarfestlegemittel bekannt, die sowohl polymere Substanzen zur Haarfestigung als auch Farbstoffe zur gleichzeitigen Farbveränderung des Haares enthalten sollen. Derartige Mittel sind u.a. in E. Sagarin, "Cosmetics", Science and Technology (1957), Interscience Publishers, Inc., New York, S. 489 beschrieben.There are also already coloring hair setting agents known that both polymeric substances for setting hair as well as dyes for simultaneous color change of the hair should contain. Such agents are, inter alia, in E. Sagarin, "Cosmetics", Science and Technology (1957), Interscience Publishers, Inc., New York, p. 489.

Diese Art von Präparaten hat in der letzten Zeit zunehmend an Bedeutung gewonnen, da in vielen Fällen außer einer Haarfestigung gleichzeitig eine Farbveränderung bzw. Farbauflischung erwUnscht ist.This type of preparation has recently become increasingly important won, as in many cases a color change in addition to a hair fixation or increased color is desired.

In diesem Falle setzt man zur Haarfärbung ausschließlich direkt auf das Haar aufziehende Farbstoffe ein. Diese Farbstoffe sind Jedoch nicht wie die Oxydationsfarbstoffe befähigt, in das Haar einzudringen, weshalb ihre Farbintensität und Beständigkeit gegen äußere EinflUsse auch wesentlich geringer ist.In this case, the hair coloring is only done directly dyes that attract the hair. However, these dyes are not like that Oxidation dyes enable them to penetrate the hair, which is why their color intensity and resistance to external influences is also significantly lower.

Xußere Einflüsse machen sich in besonderem Maße auch dann bemerkbar, wenn die Haarfärbungen dem Einfluß intensiver Sonnenstrahlung ausgesetzt sind. Dabei tritt als Folgeersoheinung sowohl eine Veränderung des Farbtones als auch eine Verminderung der Farbintensität ein.External influences are particularly noticeable when the hair coloring is exposed to the influence of intense solar radiation. Included As a consequence, both a change in the hue and a decrease occur the color intensity.

Nach der vorliegenden Erfindung lassen sich diese nachteiligen Folgen weitgehend dadurch vermeiden, daß man den färbenden Haarfestlegemitteln Lichtschutzstoffe zusetzt.According to the present invention, these adverse consequences can be avoided Avoid largely by adding light protection substances to the coloring hair setting agents clogs.

FUr den vorliegenden Zweck haben sich dabei insbesondere die Lichtschutzstoffe aus der chemischen Klasse der Benzimidazole und Benzophenone als geeignet erwiesen. Von diesen seien vorzugsweise das 2-Phenyl-benzimidazol-5-sulfonsaure Natrium sowie das 2-Hydroxy-4-methoxy-benzophenon und 2-Hydroxy-4-methoxy-benzophenon-5-sulfonsaures Natrium erwähnt. Auch Lichtschutzstoffe von anderen Klassen, beispielsweise den Derivaten der Phenylglyoxylsäure wie das 3,4-Dimethoxy-phenylglyoxylsaure Natrium, sind in erfindungsgemäßem Sinne vorteilhaft verwendbar.The light protection substances in particular have proven useful for the present purpose from the chemical class of the benzimidazoles and benzophenones as proved suitable. Of these, 2-phenylbenzimidazole-5-sulfonic acid are preferred Sodium and 2-hydroxy-4-methoxy-benzophenone and 2-hydroxy-4-methoxy-benzophenone-5-sulfonic acid Sodium Mentioned. Also light protection substances from other classes, for example the Derivatives of phenylglyoxylic acid such as sodium 3,4-dimethoxyphenylglyoxylic acid, can be used advantageously in the context of the invention.

Die Lichtschutzstoffe sind in den färbenden Haarfestlegemitteln in Konzentrationen zwischen 0,01 - 2 % (Gew) enthalten. Voraussetzung dafür ist, daß sie in wässrig-alkoholischem Medium ausreichend löslich sind.The sunscreens are in the coloring hair setting agents Contain concentrations between 0.01 - 2% (weight). The prerequisite for this is that they are sufficiently soluble in an aqueous-alcoholic medium.

Von den polymeren Substanzen zur Festlegung der Haare können die für diesen Zweck bekannten und beschriebenen Polymerisate natürlicher bzw. synthetischer Herkunft, beispielsweise Vinylpolymerisate wie Polyvinylpyrrolidon, Polyvinylacetat oder Polyacrylverbindungen wie Acrylsäure- bzw. Methacrylsäurepolymerisate, basische Polymerisate von Estern aus diesen beiden Säuren und Aminoalkoholen bzw. deren Salze oder Quateierungsprodukte, Polyacrylnitril sowie entsprechende Copolymerisate aus diesen Verbindungen, z.B. Polyvinylpyrrolidon-vinylacetat, gemäß vorliegender Anmeldung in Betracht kommen.Of the polymeric substances used to fix the hair, the for For this purpose known and described polymers of natural or synthetic Origin, for example vinyl polymers such as polyvinylpyrrolidone, polyvinyl acetate or polyacrylic compounds such as acrylic acid or methacrylic acid polymers, basic Polymers of esters from these two acids and amino alcohols or their salts or quaternization products, polyacrylonitrile and corresponding copolymers these compounds, e.g. polyvinylpyrrolidone vinyl acetate, according to the present application be considered.

Als direkt auf das Haar aufziehende Farbstoffe, die erfindungsgemäß verwendbar sind, sollen beispielsweise die folgenden zur Farbveränderung des Haares bekannten Farbstoffgruppen genannt sein: Aromatische Nitrofarbstoffe - wie z.B. 4-Nitro-1,2-diaminobenzol und 2-Nitro-1,4-diaminobenzol Azofarbstoffe - wie z.B. Azilanbraun R Anthraohinonfarbstoffe - wie z.B. die "Cellitone" der Firma BASF Triphenylmethanfarbstoffe - wie z.B. Methylviolett B, wobei die Farbstoffe dieser Klassen Je nach der Art ihrer Substituenten sauren oder basischen Charakter haben können.As dyes which are absorbed directly onto the hair, according to the invention can be used, for example, the following should be used to change the color of the hair known dye groups: Aromatic nitro dyes - such as e.g. 4-nitro-1,2-diaminobenzene and 2-nitro-1,4-diaminobenzene Azo dyes - such as Azilanbraun R anthraquinone dyes - such as the company's "Cellitone" BASF triphenylmethane dyes - such as methyl violet B, where the dyes these classes, depending on the nature of their substituents, have an acidic or basic character can have.

Die Mittel nach der Anmeldung können selbstverständlich mit bekannten und fUr haarkosmetische Präparate Ublichen Zusätzen wie Netzmitteln, Pflegestoffen, ParfUmölen und anderen versehen werden.The means after registration can of course with known and additives common to hair cosmetic preparations such as wetting agents, care substances, Perfume oils and others.

Die folgenden Beispiele sollen den Anmeldungsgegenstand erläutern ohne ihn darauf zu beschränken.The following examples are intended to explain the subject of the application without limiting it to it.

Beispiel 1 4,0 g Copolymerisat von Vinylpyrrolidon-Vinylacetat 60:40 50,0 g Isopropylalkohol 0,5 g Parfümöl 0,5 g 2-Phenyl-benzimidazol-5-sulfonsaures Natrium 0,2 g 2-Nitro-1,4-diaminobenzol-hydrochlorid ad 100,0 g Wasser Blonde menschliche Haare werden gefestigt und erhalten eine gegen Sonnenlicht stabilisierte rötliche Färbung.Example 1 4.0 g copolymer of vinylpyrrolidone-vinyl acetate 60:40 50.0 g isopropyl alcohol 0.5 g perfume oil 0.5 g 2-phenyl-benzimidazole-5-sulfonic acid Sodium 0.2 g 2-nitro-1,4-diaminobenzene hydrochloride to 100.0 g water Blonde human Hair is strengthened and given a reddish color stabilized against sunlight Coloring.

Beispiel 2 4,0 g Lactat des Polymerisates von Aorylsäure-diäthylamino-äthylester (bzw. 4,0 g Copolymerisat von Vinylpyrrolidon-Vinylacetat 60:40) 50,0 g Isopropylalkohol 0,5 g Parfümöl 0,4 g 2-Phanyl-benzimidazol-5-sulfonsaures Natrium 0,1 g Cellitonechtviolett 6 B (Colour Index Nr. 61105) ad 100,0 g Wasser Graues menschliches Haar wird gefestigt und erhält eine leicht blau-violette Färbung, dle gegen Sonnenlicht stabilisiert ist.Example 2 4.0 g of lactate of the polymer of diethylaminoethyl aorylate (or 4.0 g copolymer of Vinyl pyrrolidone vinyl acetate 60:40) 50.0 g isopropyl alcohol 0.5 g perfume oil 0.4 g 2-phanyl-benzimidazole-5-sulfonic acid Sodium 0.1 g cellitone violet 6 B (Color Index No. 61105) to 100.0 g water Gray human hair is strengthened and given a light blue-violet color, dle is stabilized against sunlight.

Beispiel 3 4,0 g Copolymerisat von Vintspyrrolidon-Vinylacetat 60:40 50,0 g thylalkohol 0,5 il'g Parfümöl 1,0 g 2-Hydroxy-4-methoxy-benzophenon 0,02 g Methylviolett B (Colour Index Nr. 42535) ad 100,0 g Wasser Dies Mittel festigt graues menschliches Haar und färbt es, gegen Sonnenlicht stabilisiert, leicht violett.Example 3 4.0 g copolymer of vintspyrrolidone-vinyl acetate 60:40 50.0 g ethyl alcohol 0.5 μg perfume oil 1.0 g 2-hydroxy-4-methoxy-benzophenone 0.02 g of methyl violet B (Color Index No. 42535) to 100.0 g of water This agent sets gray human hair and, stabilized against sunlight, colors it light purple.

Beispiel 4 4,0 g Lactat des Polymerisates von Acrylsäure-diäthylamino-äthylester (bzw. 4,0g Copolymerisat von Vinylpyrrolidon-Vinylacetat 60:40) 50,0 g Isopropylalkohol 0,5 g Parfümöl 0,5 g 2-Hydroxy-4-methoxy-benzophenon 0,1 g 4-Nitro-1,2-diaminobenzol ad 100,0 g Wasser Weißes menschliches Naturhaar wird gefestigt und erhält eine weizenblonde Färbung, die gegen Sonnenlicht stabilisiert ist.Example 4 4.0 g of lactate of the polymer of diethylamino-ethyl acrylate (or 4.0 g copolymer of vinylpyrrolidone-vinyl acetate 60:40) 50.0 g isopropyl alcohol 0.5 g perfume oil 0.5 g 2-hydroxy-4-methoxy-benzophenone 0.1 g of 4-nitro-1,2-diaminobenzene ad 100.0 g of water White natural human hair is strengthened and given a wheat-blonde appearance Coloration stabilized against sunlight.

Die Anwendung der färbenden Haarfestlegemittel erfolgt in bekannter und üblicher Weise durch Festlegen (Einlegen) des Haares zur Frisur und anschließende Trocknung.The coloring hair setting agents are used in a known manner and usually by setting (laying in) the hair to the hairstyle and then Drying.

Die in den Mittelnenthaltenen Farbstoffe können in Konzentrationen von etwa 0,01 - 0,9% (Gew) vorliegen.The dyes contained in the agents can be used in concentrations from about 0.01-0.9% (weight) are present.

Claims (5)

PatentansprücheClaims 1. Färbende Haarfestlegemittel, dadurch gekennzeichnet, daß sie Lichtschutzstoffe gegen die ultraviolette Strahlung enthalten.1. Coloring hair setting agents, characterized in that they contain light protection substances contain against the ultraviolet radiation. 2. Mittel nach Anspruch 1, dadurch gekennzeichnet, daß sie als Lichtschutzstoffe Derivate des BenzSmidazols oder Benzophenons enthalten.2. Means according to claim 1, characterized in that they are used as light protection substances Contain derivatives of BenzSmidazole or Benzophenons. 3. Mittel nach Anspruch 1, dadurch gekennzeichnet, daß sie als Lichtschutzstoffe Derivate der Phenyl-glyoxylsäure enthalten.3. Composition according to claim 1, characterized in that they are used as light protection substances Contain derivatives of phenyl glyoxylic acid. 4. Mittel nach Ansprüchen 1 und 2, dadurch gekennzeichnet, daß sie als Lichtschutzstoffe 2-Phenyl-benzimidazol-5-sulfonsaures Natrium, 2-Hydroxy-4-methoxy-benzophenon oder 2-Hydroxy-4-methoxy-benzophenon-5-sulfonsaures Natrium enthalten.4. Means according to claims 1 and 2, characterized in that it as light protection substances 2-phenyl-benzimidazole-5-sulfonic acid sodium, 2-hydroxy-4-methoxy-benzophenone or contain 2-hydroxy-4-methoxy-benzophenone-5-sulfonic acid sodium. 5. Mittel nach Ansprüchen 1 und 3, dadurch gekennzeichnet, daß sie als tichtschutzstoff 5, 4-Dimethoxy-phenylglyoxylsaures Natrium enthalten.5. Composition according to claims 1 and 3, characterized in that it Contains 5, 4-Dimethoxyphenylglyoxylic acid sodium as a protective substance.
DE19702046818 1970-09-23 1970-09-23 Hair dyeing and setting preparations - contng benzimidazole benzophenone and phenylglyoxylic acid derivs Pending DE2046818A1 (en)

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DE19702046818 DE2046818A1 (en) 1970-09-23 1970-09-23 Hair dyeing and setting preparations - contng benzimidazole benzophenone and phenylglyoxylic acid derivs

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DE19702046818 DE2046818A1 (en) 1970-09-23 1970-09-23 Hair dyeing and setting preparations - contng benzimidazole benzophenone and phenylglyoxylic acid derivs

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2627085A1 (en) * 1988-02-11 1989-08-18 Oreal USE OF 2-HYDROXY-4-METHOXYBENZOPHENONE-5-SULFONIC ACID OR ITS SALTS FOR HAIR PROTECTION AGAINST ATMOSPHERIC AGGRESSIONS, ESPECIALLY AGAINST LIGHT, AND HAIR PROTECTION METHOD USING THE SAME
EP0330193A1 (en) * 1988-02-25 1989-08-30 L'oreal Cosmetic composition containing an oxazoline polymer and a 2-hydroxy-4-methoxy-benzophenone-5-sulfonic acid or its salts to keep one's hair do
US5240695A (en) * 1988-02-11 1993-08-31 L'oreal Use of 2-hydroxy-4-methoxybenzophenone-5-sulphonic acid or its salts for protecting the hair against environmental attacking agents, and especially against light and process for protecting the hair using the compound
US5275810A (en) * 1988-02-25 1994-01-04 L'oreal Cosmetic composition for maintaining the hairstyle containing an oxazoline polymer and a 2-hydroxy-4-methoxy-benzophenone-5-sulphonic acid, salified or otherwise
EP0819422A1 (en) * 1996-07-15 1998-01-21 Kao Corporation Composition for dyeing of human hair
WO2000028957A1 (en) * 1998-11-18 2000-05-25 Henkel Kommanditgesellschaft Auf Aktien Novel use of uv filters, method for colouring keratinic fibres agents for realising this method

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2627085A1 (en) * 1988-02-11 1989-08-18 Oreal USE OF 2-HYDROXY-4-METHOXYBENZOPHENONE-5-SULFONIC ACID OR ITS SALTS FOR HAIR PROTECTION AGAINST ATMOSPHERIC AGGRESSIONS, ESPECIALLY AGAINST LIGHT, AND HAIR PROTECTION METHOD USING THE SAME
BE1003099A5 (en) * 1988-02-11 1991-11-26 Oreal USE OF 2-HYDROXY-4-METHOXYBENZOPHENONE-5-SULFONIC ACID OR ITS SALTS FOR THE PROTECTION OF HAIR AGAINST ATMOSPHERIC AGGRESSIONS, AND PARTICULARLY AGAINST LIGHT, AND METHOD FOR PROTECTING HAIR USING THIS COMPOUND.
US5240695A (en) * 1988-02-11 1993-08-31 L'oreal Use of 2-hydroxy-4-methoxybenzophenone-5-sulphonic acid or its salts for protecting the hair against environmental attacking agents, and especially against light and process for protecting the hair using the compound
EP0330193A1 (en) * 1988-02-25 1989-08-30 L'oreal Cosmetic composition containing an oxazoline polymer and a 2-hydroxy-4-methoxy-benzophenone-5-sulfonic acid or its salts to keep one's hair do
US5275810A (en) * 1988-02-25 1994-01-04 L'oreal Cosmetic composition for maintaining the hairstyle containing an oxazoline polymer and a 2-hydroxy-4-methoxy-benzophenone-5-sulphonic acid, salified or otherwise
EP0819422A1 (en) * 1996-07-15 1998-01-21 Kao Corporation Composition for dyeing of human hair
WO2000028957A1 (en) * 1998-11-18 2000-05-25 Henkel Kommanditgesellschaft Auf Aktien Novel use of uv filters, method for colouring keratinic fibres agents for realising this method

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