CN110167258A - A kind of aluminium plating copper substrate structure and its preparation process - Google Patents

A kind of aluminium plating copper substrate structure and its preparation process Download PDF

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Publication number
CN110167258A
CN110167258A CN201910437385.0A CN201910437385A CN110167258A CN 110167258 A CN110167258 A CN 110167258A CN 201910437385 A CN201910437385 A CN 201910437385A CN 110167258 A CN110167258 A CN 110167258A
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China
Prior art keywords
copper
layer
aluminium
copper foil
foil layer
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CN201910437385.0A
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Chinese (zh)
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CN110167258B (en
Inventor
万海平
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SHANGHAI WLCP ELECTRICAL & TECHNOLOGY Co Ltd
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SHANGHAI WLCP ELECTRICAL & TECHNOLOGY Co Ltd
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    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K1/00Printed circuits
    • H05K1/02Details
    • H05K1/03Use of materials for the substrate
    • H05K1/05Insulated conductive substrates, e.g. insulated metal substrate
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K3/00Apparatus or processes for manufacturing printed circuits
    • H05K3/0058Laminating printed circuit boards onto other substrates, e.g. metallic substrates
    • H05K3/0061Laminating printed circuit boards onto other substrates, e.g. metallic substrates onto a metallic substrate, e.g. a heat sink
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K2201/00Indexing scheme relating to printed circuits covered by H05K1/00
    • H05K2201/09Shape and layout
    • H05K2201/09009Substrate related
    • H05K2201/09054Raised area or protrusion of metal substrate
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K2201/00Indexing scheme relating to printed circuits covered by H05K1/00
    • H05K2201/09Shape and layout
    • H05K2201/09009Substrate related
    • H05K2201/09063Holes or slots in insulating substrate not used for electrical connections
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K2203/00Indexing scheme relating to apparatus or processes for manufacturing printed circuits covered by H05K3/00
    • H05K2203/07Treatments involving liquids, e.g. plating, rinsing
    • H05K2203/0703Plating
    • H05K2203/072Electroless plating, e.g. finish plating or initial plating

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  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Manufacturing & Machinery (AREA)
  • Insulated Metal Substrates For Printed Circuits (AREA)
  • Laminated Bodies (AREA)
  • Electroplating Methods And Accessories (AREA)
  • Cooling Or The Like Of Semiconductors Or Solid State Devices (AREA)

Abstract

A kind of aluminium plating copper substrate structure and its preparation process, structure include: aluminium plating Copper base material matter, polypropylene layer and copper foil layer structure, and aluminium plating Copper base material matter, polypropylene layer and copper foil layer structure are sequentially connected from bottom to up.Wherein, copper foil layer structure includes: copper foil layer, wire line, ink layer and copper foil layer hollow hole.The present invention plates copper base using aluminium by design and replaces pure Cu substrate as Metal Substrate heat-conducting layer, have high thermal conductivity, meet thermally conductive demand, while aluminium copper facing substrate manufacture is convenient, production cost is low, reduces the consumption of metal resource compared with traditional technology.

Description

A kind of aluminium plating copper substrate structure and its preparation process
Technical field
The present invention relates to electronic technology fields, and in particular to a kind of aluminium plating copper substrate structure and its preparation process.
Background technique
With the increasingly maturation of current LED car lamp technology, LED car lamp application is popularized, and existing heat dissipation technology is not only Based on encapsulating structure and material, and there are also be based on energy transfer process.With regard to the circuit base plate material in encapsulating material close several The new development of Nian Zhongyou, recent tendency have been directed toward straight-through radiating copper base circuit board as car light is to the integrated demand of high brightness, Thermally conductive demand is higher and higher, and straight-through radiating copper base circuit board demand gradually increases, lead directly to radiating copper base circuit board manufacture craft with Fine copper needs thicker copper sheet as heat carrier as Metal Substrate heat-conducting layer, no matter from cost or manufacture craft in future Compete it is increasing under the premise of be difficult to be received by market.
To solve the above-mentioned problems, we are made that a series of improvement.
Summary of the invention
The object of the present invention is to provide a kind of aluminium plating copper substrate structure and its preparation processes, to overcome prior art institute Existing disadvantages mentioned above and deficiency.
A kind of aluminium plating copper substrate structure characterized by comprising aluminium copper facing substrate layer, polypropylene layer and copper foil layer structure, The aluminium copper facing substrate layer, polypropylene layer and copper foil layer structure are sequentially connected from bottom to up;
Wherein, the copper foil layer structure includes: copper foil layer, wire line, ink layer and copper foil layer hollow hole, the conducting wire Route is connect with copper foil layer upper surface, and the ink layer is covered in the upper surface of copper foil layer, and the ink layer and wire line are not The boss of contact, the copper foil layer hollow hole and aluminium copper facing substrate layer is socketed.
Further, the aluminium copper facing substrate layer is equipped with several structure holes and boss, the structure hole from bottom to up one Polypropylene layer and copper foil layer structure are run through in side, and the boss is set on aluminium copper facing substrate layer.
Further, the polypropylene layer is equipped with polypropylene hollow hole, and the polypropylene hollow hole and boss are socketed.
A kind of aluminium plating copper base preparation process, it is characterised in that: the following steps are included:
Step 1: surface of aluminum plate processing production, it is by the way of horizontal line machinery brushing that aluminum flake surface removal surface is dirty Dirty and oxidation by the way of horizontal line physics brushing corundum sandblasting forms aluminum flake surface coarse, using tank liquor hydroxide Sodium cleans the aluminium flake after brushing sandblasting, established thick by brushing and sandblasting to surface by micro corrosive effect It is rough sufficiently to be modified, the aluminum flake surface residual alkaline matter after sodium hydroxide cleaning is neutralized using tank liquor sulfuric acid, water After horizontal line washes abundant clean the surface, by treated, aluminum flake surface is dried, and keeps aluminum flake surface coarse;
Step 2: aluminium flake chemical nickel plating uses the mode of chemical nickel plating to plate a layer thickness in aluminum flake surface as the thin of-um Nickel;
Step 3: aluminium flake electroless copper, it is chemical on the nickel layer that aluminum flake surface has been formed by the way of electroless copper One layer of thin copper is plated, thin copper thickness is-um;
Step 4: aluminium flake plating plus copper facing make aluminum flake surface form the surface of chemical copper by the way of electro-coppering Add the thick copper of plating, forms aluminium copper facing substrate layer;
Step 5: boss production, aluminium copper facing substrate layer surface attach etching resisting ink, are etched by image transfer fiting chemical Mode makes the boss for needing to weld LED location;
Step 6: punching hollow out, on the surface of polypropylene layer and copper foil layer, by phase by the way of punching and laser cutting The position of corresponding boss is punched to form hollow out;
Step 7: aluminium copper facing substrate layer, polypropylene layer and copper foil layer are successively combined by pressing in sequence, are combined Triplicity is set to form entirety by the way of temperature-pressure afterwards, the product after combination is by middle layer polypropylene layer as insulating layer It separates LED lug boss position with surface lines copper foil layer, realizes the structure of straight-through independent heat dissipation and wire line separation;
Step 8: wire line production, copper foil layer surface attach etching resisting ink, pass through image transfer fiting chemical etching side Formula makes wire line;
Step 9: ink printing is hindered, the position of welding will not be needed, the layer of ink that oils is printed, is fixedly welded position, avoids Connect tin or other bad in welding process, protects substrate layer;
Step 10: molding makes mechanism orifice and shape by way of punching or CNC;
Step 11: surface treatment, avoiding the exposure of welding copper face, oxidation influences welding in air, improves welding quality, Complete finished product.
Further, during the brushing in the step 1, brusher rod is one group of one group of 500 mesh and 2000 mesh, pressure For 2KG, harness is 2m/ minutes;
In sandblasting procedures, sand is diamond dust, and the Grains of diamond dust is 200, and linear speed is 3m/ minutes;
During surface clean, use tank liquor sodium hydrate content for 2%, linear speed is 3m/ minutes;
In the N-process of surface, use tank liquor sulfuric acid content for 1%, linear speed is 3m/ minutes;
During clean the surface, linear speed is 3m/ minutes;
In drying course, drying temperature is 90 degrees Celsius, and linear velocity is 3m/ minutes.
Further, in the step 2, chemical nickel plating, as additive, handles the time using the nickel sulfate of 20-50 grams per liter It is 3-5 minutes.
Further, in the step 3, electroless copper is using 10-20 grams/every liter of sulfuric acid, the hydroxide of 10-25 grams per liter The disodium ethylene diamine tetraacetate of sodium, the formaldehyde of 3-5 grams per liter, 0.5-2 grams per liter is processed, and is handled time 10-15 minutes.
Further, in the step 4, surface adds the copper thickness for plating thick copper to be 0.1mm-5 millimeters, current density 1.5- 2.0ASD。
Beneficial effects of the present invention:
The present invention plates copper base using aluminium by design and replaces pure Cu substrate thermally conductive as Metal Substrate compared with traditional technology Layer has high thermal conductivity, meets thermally conductive demand, while aluminium copper facing substrate manufacture is convenient, and production cost is low, reduces metal money The consumption in source.
Detailed description of the invention:
Fig. 1 is the structural schematic diagram that aluminium of the invention plates copper base.
Fig. 2 is the structural schematic diagram that aluminium of the invention plates copper base boss.
Fig. 3 is the structural schematic diagram of polypropylene layer of the invention.
Fig. 4 is the structural schematic diagram of copper foil layer of the invention.
Fig. 5 is the structural schematic diagram after completion step 4 of the invention.
Fig. 6 is the structural schematic diagram after completion step 5 of the invention.
Fig. 7 is structural schematic diagram of the invention.
Appended drawing reference:
Aluminium plates Copper base material matter 100, structure hole 110 and boss 120.
Polypropylene layer 200 and polypropylene hollow hole 210.
Copper foil layer structure 300, copper foil layer 310, wire line 320, ink layer 330 and copper foil layer hollow hole 340.
Specific embodiment
Below in conjunction with specific embodiment, progress explanation is made to the present invention.It should be understood that following embodiment is merely to illustrate this hair It is bright not for limiting the scope of the invention.
Embodiment 1
Fig. 1 is the structural schematic diagram that aluminium of the invention plates copper base.Fig. 2 is the structure that aluminium of the invention plates copper base boss Schematic diagram.Fig. 3 is the structural schematic diagram of polypropylene layer of the invention.Fig. 4 is the structural schematic diagram of copper foil layer of the invention.Fig. 5 For the structural schematic diagram after completion step 4 of the invention.Fig. 6 is the structural schematic diagram after completion step 5 of the invention.Fig. 7 For structural schematic diagram of the invention.
As shown in Figure 1, the main material that aluminium plating Copper base material matter 100 is conducted as LED heat, aluminium plate Copper base material matter 100 Making step be progress surface of aluminum plate processing first, then aluminium sheet chemical nickel plating, then on nickel layer it is one layer thin in chemical plating Copper, the surface for making aluminum flake surface form chemical copper by the way of electro-coppering add the thick copper of plating.It is finally plated as shown in Figure 2 in aluminium The surface of copper-based material 100 attaches etching resisting ink, makes to need to weld LED location by image transfer fiting chemical etching mode Boss 120 is made.Meanwhile as shown in Figure 3 and Figure 4, respectively on polypropylene layer 200 and copper foil layer structure 300 using punching The mode cut and be cut by laser is punched corresponding " position of LED boss " and copper foil to form corresponding polypropylene hollow hole 210 and copper foil layer hollow hole 340.Then, as shown in figure 5, successively plating Copper base material matter 100, polypropylene layer 200, copper foil according to aluminium The sequence of layer structure 300 is combined, and polypropylene hollow hole 210 and copper foil layer hollow hole 340 and boss 120 are socketed.
Triplicity is set to form entirety by the way of temperature-pressure after combination, the product after combination is by intermediate layer polypropylene Layer 200 separates LED lug boss position with surface lines copper foil layer 310 as insulating layer, realizes straight-through independent heat dissipation and wire The isolated structure in road 320.As shown in fig. 6, attaching etching resisting ink on 310 surface of copper foil layer, cooperated by way of image transfer Chemical etching mode makes wire line 320.As shown in fig. 7, the position of welding will do not needed on copper foil layer 310, in printing Ink layer 330, is fixedly welded position, avoids connecting tin or other bad, protective substrate in welding process.Finally successively by structure hole 110 and shape made by way of punching, structure hole while being surface-treated to install connection, avoid welding Oxidation influences welding in air for copper face exposure, improves welding quality.
The present invention plates copper base using aluminium by design and replaces pure Cu substrate as Metal Substrate heat-conducting layer, has high-termal conductivity Can, meet thermally conductive demand, while aluminium copper facing substrate manufacture is convenient, production cost is low, reduces the consumption of metal resource.
A specific embodiment of the invention is illustrated above, but the present invention is not limited thereto, without departing from Spirit of the invention, the present invention can also have various change.

Claims (8)

1. a kind of aluminium plates copper substrate structure characterized by comprising aluminium copper facing substrate layer (100), polypropylene layer (200) and copper Layers of foil structure (300), the aluminium copper facing substrate layer (100), polypropylene layer (200) and copper foil layer structure (300) from bottom to up according to Secondary connection;
Wherein, the copper foil layer structure (300) includes: copper foil layer (310), wire line (320), ink layer (330) and copper foil Layer hollow hole (340), the wire line (320) connect with copper foil layer (310) upper surface, and the ink layer (330) is covered in The upper surface of copper foil layer (310), the ink layer (330) do not contact with wire line (320), the copper foil layer hollow hole (340) it is socketed with the boss of aluminium copper facing substrate layer (100).
2. a kind of aluminium according to claim 1 plates copper substrate structure, which is characterized in that the aluminium copper facing substrate layer (100) It is equipped with several structure holes (110) and boss (120), polypropylene layer is run through in side to the structure hole (110) from bottom to up (200) it is set on aluminium copper facing substrate layer (100) with copper foil layer structure (300), the boss (120).
3. a kind of aluminium according to claim 1 plates copper substrate structure, which is characterized in that set on the polypropylene layer (200) Have polypropylene hollow hole (210), the polypropylene hollow hole (210) and boss (120) are socketed.
4. a kind of aluminium plates copper base preparation process, it is characterised in that: the following steps are included:
Step 1: surface of aluminum plate processing production, by the way of horizontal line machinery brushing by aluminum flake surface removal surface it is dirty and It aoxidizes, forms aluminum flake surface by the way of horizontal line physics brushing corundum sandblasting coarse, using tank liquor sodium hydroxide pair Aluminium flake after brushing sandblasting is cleaned, by micro corrosive effect to surface by brushing and sandblasting it is established it is coarse into Row sufficiently modification neutralizes the aluminum flake surface residual alkaline matter after sodium hydroxide cleaning using tank liquor sulfuric acid, horizontal line After washing abundant clean the surface, by treated, aluminum flake surface is dried, and keeps aluminum flake surface coarse;
Step 2: aluminium flake chemical nickel plating uses the mode of chemical nickel plating to plate a layer thickness in aluminum flake surface as the thin of 1-2um Nickel;
Step 3: aluminium flake electroless copper, by the way of electroless copper on the nickel layer that aluminum flake surface has been formed in chemical plating One layer of thin copper, thin copper thickness are 1-2um;
Step 4: aluminium flake plating plus copper facing, the surface for making aluminum flake surface form chemical copper by the way of electro-coppering adds plating Thick copper is formed aluminium copper facing substrate layer (100);
Step 5: boss (120) production, aluminium copper facing substrate layer (100) surface attach etching resisting ink, match combination by image transfer Learning etching mode makes the boss (120) for needing to weld LED location;
Step 6: punching hollow out, on the surface of polypropylene layer (200) and copper foil layer (310), using the side of punching and laser cutting Formula is punched the position of corresponding boss (120) to form hollow out;
Step 7: pressing, successively in sequence by aluminium copper facing substrate layer (100), polypropylene layer (200) and copper foil layer (310) into Row combination, makes triplicity form entirety, the product after combination is by intermediate layer polypropylene after combination by the way of temperature-pressure Layer (200) separates LED lug boss position with surface lines copper foil layer (310) as insulating layer, realizes to lead directly to and independently radiates and lead The structure of line route (320) separation;
Step 8: wire line (320) production, copper foil layer (310) surface attach etching resisting ink, pass through image transfer fiting chemical Etching mode makes wire line (320);
Step 9: hindering ink printing, will not need the position of welding, and printing oils layer of ink (330), is fixedly welded position, keeps away Connect tin or other bad during no-welding, protects substrate layer;
Step 10: molding makes mechanism orifice and shape by way of punching or CNC;
Step 11: surface treatment, avoiding the exposure of welding copper face, oxidation influences welding in air, improves welding quality, completes Finished product.
5. a kind of aluminium according to claim 4 plates copper base preparation process, which is characterized in that the brushing in the step 1 In the process, brusher rod is one group of 500 mesh and one group, pressure 2KG of 2000 mesh, and linear speed is 2m/ minutes;
In sandblasting procedures, sand is diamond dust, and the Grains of diamond dust is 200, and linear speed is 3m/ minutes;
During surface clean, use tank liquor sodium hydrate content for 2%, linear speed is 3m/ minutes;
In the N-process of surface, use tank liquor sulfuric acid content for 1%, linear speed is 3m/ minutes;
During clean the surface, linear speed is 3m/ minutes;
In drying course, drying temperature is 90 degrees Celsius, and linear speed is 3m/ minutes.
6. a kind of aluminium according to claim 4 plates copper base preparation process, which is characterized in that in the step 2, chemistry Using the nickel sulfate of 20-50 grams per liter as additive, handling the time is 3-5 minutes for nickel plating.
7. a kind of aluminium according to claim 4 plates copper base preparation process, which is characterized in that in the step 3, chemistry Copper facing is using 10-20 grams/every liter of sulfuric acid, the sodium hydroxide of 10-25 grams per liter, the formaldehyde of 3-5 grams per liter, the second of 0.5-2 grams per liter Edetate disodium is processed, and is handled time 10-15 minutes.
8. a kind of aluminium according to claim 4 plates copper base preparation process, which is characterized in that in the step 4, surface Adding the copper thickness for plating thick copper is 0.1mm-5 millimeters, current density 1.5-2.0ASD.
CN201910437385.0A 2019-05-24 2019-05-24 Aluminum copper-plated substrate structure and preparation process thereof Active CN110167258B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114058995A (en) * 2021-11-19 2022-02-18 江苏华旺新材料有限公司 Copper-aluminum composite sheet and composite process thereof

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CN104754862A (en) * 2015-04-10 2015-07-01 松扬电子材料(昆山)有限公司 Aluminum foil copper plating substrate for flexible circuit board and manufacturing method of aluminum foil copper plating substrate
CN105541417A (en) * 2016-02-26 2016-05-04 深圳市环基实业有限公司 Production method for cladding copper on surface of aluminum nitride ceramic
CN107124816A (en) * 2017-04-10 2017-09-01 上海温良昌平电器科技股份有限公司 The straight-through radiating copper base of one kind and its preparation technology
CN108221018A (en) * 2017-12-28 2018-06-29 中宥(平原)科技有限公司 A kind of high-efficiency copper based on secondary heavy zinc covers aluminium technique
CN108738237A (en) * 2018-08-06 2018-11-02 深圳市博敏电子有限公司 A kind of manufacturing method of potting aluminium row structure printed circuit board
CN210519030U (en) * 2019-05-24 2020-05-12 上海温良昌平电器科技股份有限公司 Aluminum copper plating substrate structure

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110101410A1 (en) * 2008-03-25 2011-05-05 Lin Charles W C Semiconductor chip assembly with post/base/post heat spreader
CN104754862A (en) * 2015-04-10 2015-07-01 松扬电子材料(昆山)有限公司 Aluminum foil copper plating substrate for flexible circuit board and manufacturing method of aluminum foil copper plating substrate
CN105541417A (en) * 2016-02-26 2016-05-04 深圳市环基实业有限公司 Production method for cladding copper on surface of aluminum nitride ceramic
CN107124816A (en) * 2017-04-10 2017-09-01 上海温良昌平电器科技股份有限公司 The straight-through radiating copper base of one kind and its preparation technology
CN108221018A (en) * 2017-12-28 2018-06-29 中宥(平原)科技有限公司 A kind of high-efficiency copper based on secondary heavy zinc covers aluminium technique
CN108738237A (en) * 2018-08-06 2018-11-02 深圳市博敏电子有限公司 A kind of manufacturing method of potting aluminium row structure printed circuit board
CN210519030U (en) * 2019-05-24 2020-05-12 上海温良昌平电器科技股份有限公司 Aluminum copper plating substrate structure

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114058995A (en) * 2021-11-19 2022-02-18 江苏华旺新材料有限公司 Copper-aluminum composite sheet and composite process thereof
CN114058995B (en) * 2021-11-19 2022-08-16 江苏华旺新材料有限公司 Copper-aluminum composite sheet and composite process thereof

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