CN110078578A - A kind of dedicated gunpowder recipe of pyrotechnics colored drawing and the dedicated paper of pyrotechnics colored drawing - Google Patents

A kind of dedicated gunpowder recipe of pyrotechnics colored drawing and the dedicated paper of pyrotechnics colored drawing Download PDF

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Publication number
CN110078578A
CN110078578A CN201910370653.1A CN201910370653A CN110078578A CN 110078578 A CN110078578 A CN 110078578A CN 201910370653 A CN201910370653 A CN 201910370653A CN 110078578 A CN110078578 A CN 110078578A
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China
Prior art keywords
pyrotechnics
dedicated
nitrate
colored drawing
paper
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CN201910370653.1A
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CN110078578B (en
Inventor
李增源
钱青
谢兴华
孙艳菊
谢亮
张昕
马成帅
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Anhui University of Science and Technology
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Anhui University of Science and Technology
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    • CCHEMISTRY; METALLURGY
    • C06EXPLOSIVES; MATCHES
    • C06BEXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
    • C06B21/00Apparatus or methods for working-up explosives, e.g. forming, cutting, drying
    • C06B21/0083Treatment of solid structures, e.g. for coating or impregnating with a modifier
    • CCHEMISTRY; METALLURGY
    • C06EXPLOSIVES; MATCHES
    • C06BEXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
    • C06B35/00Compositions containing a metal azide
    • CCHEMISTRY; METALLURGY
    • C06EXPLOSIVES; MATCHES
    • C06BEXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
    • C06B37/00Compositions containing a metal fulminate
    • C06B37/02Compositions containing a metal fulminate with a nitrated organic compound or an inorganic oxygen-halogen salt
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21FPAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F11/00Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Air Bags (AREA)
  • Paper (AREA)

Abstract

The present invention relates to a kind of dedicated gunpowder recipes for pyrotechnics colored drawing, and are exclusively used in pyrotechnics colored drawing paper.The dedicated gunpowder recipe, using nitrate, fuel agent and burning ratemodifier are suitably matched as raw material and to each component, final that the gunpowder for being exclusively used in pyrotechnics colored drawing is made.This is exclusively used in pyrotechnics colored drawing paper, joined some flame-retarded technologies on the basis of plain paper, allows to high temperature resistant, for use in pyrotechnics colored drawing.The dedicated gunpowder, it can burn rapidly after lighting, the temperature of generation can make the nitrate being added resolve into its corresponding metal oxide, and the corresponding oxide of nitrate chosen is nonferrous metal oxides, and the metal oxide for reacting generation will be firmly sticked on dedicated paper;And the temperature generated will not have any unfavorable damage to paper.The present invention solves the single disadvantage of traditional pyrotechnics drawing color, to be conducive to the propagation and development of pyrotechnics drawing.

Description

A kind of dedicated gunpowder recipe of pyrotechnics colored drawing and the dedicated paper of pyrotechnics colored drawing
Technical field
The invention belongs to pyrotechnics colored drawing technical fields, and in particular to a kind of dedicated gunpowder recipe of pyrotechnics colored drawing and pyrotechnics colored drawing Dedicated paper.
Background technique
With China's rapid development of economy, our people gradually increases the pursuit of art.Drawing can be improved people's Mastery, moulds the sentiment of people, can open the outlook of people, allows you really to see that is beauty, what is the thing that people is pursued. But since painting process is uninteresting, few people can get down.Therefore, new painting mode urgent need is rejected.What pyrotechnics was drawn Painting process has splendid ornamental value, can increase a few minutes enjoyment to the uninteresting life of people, but traditional pyrotechnics is drawn because of face Color is dull, can not further promote.And pyrotechnics draws paper used and needs high temperature resistant, common paper can not be competent at.
Summary of the invention
In order to solve the above problems existing in the present technology, the present invention provides a kind of dedicated gunpowder recipe of pyrotechnics colored drawing and cigarette The fiery dedicated paper of colored drawing.The gunpowder colored drawing dedicated gunpowder can produce coloured metal oxide, and react generation after reaction Metal oxide can be firmly sticked on paper, be drawn to obtain brightly painted pyrotechnics.The dedicated paper of pyrotechnics colored drawing is resistant to High temperature will not cause unfavorable damage during drawing a picture.
The invention adopts a technical scheme as a kind of dedicated gunpowder recipe of pyrotechnics colored drawing, raw material components include:
Nitrate, 30-70 mass parts;
Fuel agent: TNT, hexogen, one of octogen or a variety of mixture 20- formed in any proportion 50 mass parts;
Burning ratemodifier: mercury fulminate, lead azide, one of Shi Difen lead plumbate or a variety of, what is formed in any proportion is mixed Close object 1-3 mass parts.
The dedicated gunpowder of gunpowder colored drawing, which is characterized in that the nitrate is ferric nitrate, the decomposable production such as copper nitrate The nitrate of raw colored oxide.
A method of the dedicated gunpowder of pyrotechnics colored drawing is prepared, is included the following steps:
(1) it weighs the nitrate and is crushed, obtain nitrate fine powder;
(2) fuel agent is weighed, is melted by the way of heating water bath;
(3) nitrate fine powder obtained by step (1) is added in the fuel agent melted, is slowly stirred, be uniformly mixed it;
(4) gained is mixed and melts liquid, the pattern that will be painted is made, slowly wait its natural coagulation;
(5) etc. it after its solidification, is trimmed, makes it more close to the pattern of being painted, and keep its thickness uniform, and it is thick Degree is within the scope of 2-3mm;
(6) very thin one layer of adjustment of combustion rate is coated on the mixture surface of the nitrate of resulting specific shape and fuel agent Agent;
(7) it places it on dedicated pyrotechnics colored drawing, lights, residue is cleared up after burning to get pyrotechnics colored drawing works.It is a kind of The method of the preparation dedicated paper of pyrotechnics colored drawing, includes the following steps:
(1) in the pulping process of paper, aluminium powder is added, the partial size of aluminium powder is in 30-100 mesh;
(2) it using modulation, manufactures paper with pulp, processes, obtain the dedicated paper presoma of pyrotechnics drawing;
(3) it is the dedicated paper presoma of 1mol/L aluminum nitrate solution sprinkling pyrotechnics drawing with concentration, makes its humidity 10- 20%;
(4) ammonia flow for being 40-60 degrees Celsius with temperature is dry, drying time 30-50 minute;
(5) step (3) are repeated (4) three to five times to get the dedicated paper of pyrotechnics colored drawing.
The invention has the following beneficial effects:
The dedicated gunpowder of pyrotechnics colored drawing of the present invention, using nitrate, fuel agent and burning ratemodifier are as raw material And each component is suitably matched, it is final that the gunpowder for being exclusively used in pyrotechnics colored drawing is made.It is of the present invention to be exclusively used in pyrotechnics coloured silk Paper is drawn, some flame-retarded technologies is joined on the basis of plain paper, allows to high temperature resistant, for use in pyrotechnics colored drawing. The dedicated gunpowder, can burn rapidly after lighting, and the temperature of generation can make the nitrate being added resolve into its corresponding metal oxidation Object, and the corresponding oxide of nitrate chosen is nonferrous metal oxides, the metal oxide for reacting generation will firmly glue On dedicated paper;And the temperature generated will not have any unfavorable damage to paper.
Specific embodiment
The present invention is described in detail combined with specific embodiments below, represents 1g in following example with 1 parts by weight.
Embodiment 1
The present embodiment provides a kind of dedicated gunpowder production method of red gunpowder drawing, raw material components include:
48 parts by weight of ferric nitrate
Fuel agent: the mixture that TNT and hexogen are formed according to mass ratio 60:40,50 parts by weight
Burning ratemodifier: lead azide, 2 mass parts
Further, the dedicated gunpowder production method of red gunpowder drawing is present embodiments provided, is included the following steps:
It weighs the nitrate and is crushed, obtain nitrate fine powder;
The TNT for weighing required quality makes its thawing with 90 degrees Celsius of water-bath, adds the hexogen of required quality, It is slowly stirred, obtains uniformly mixed melting liquid;
Nitrate fine powder obtained by step (1) is added in the fuel agent melted, is slowly stirred, it is uniformly mixed;By institute It must mix and melt liquid, the pattern that will be painted is made, slowly its equal natural coagulation;
After its solidification, is trimmed, make it more close to the pattern of being painted, and keep its thickness uniform, and its thickness For 2mm;
The Azide of required quality is uniformly coated in the nitrate of resulting specific shape and the mixture surface of fuel agent Lead;
It places it on dedicated pyrotechnics colored drawing, lights, residue is cleared up after burning to get pyrotechnics colored drawing works.
It present embodiments provides red gunpowder to paint the production method of dedicated paper, include the following steps:
In the pulping process of paper, it is added aluminium powder, in 30-100 mesh, the mass ratio of aluminium powder and slurries is for the partial size of aluminium powder 1:100;
It using modulation, manufactures paper with pulp, processes, obtain the dedicated paper presoma of pyrotechnics drawing;
It is the dedicated paper presoma of 1mol/L aluminum nitrate solution sprinkling pyrotechnics drawing with concentration, makes its humidity 10-20%; The ammonia flow for being 48 degrees Celsius with temperature is dry, and drying time 30 minutes;
Step (3) are repeated (4) three to five times to get the dedicated paper of pyrotechnics colored drawing.
Embodiment 2
The present embodiment provides a kind of dedicated gunpowder production method of faint yellow gunpowder drawing, raw material components include:
53 parts by weight of cerous nitrate
Fuel agent: the mixture that TNT and hexogen are formed according to mass ratio 50:50,46 parts by weight
Burning ratemodifier: lead azide, 1 mass parts
Further, the dedicated gunpowder production method of faint yellow gunpowder drawing is present embodiments provided, is included the following steps:
(1) it weighs the nitrate and is crushed, obtain nitrate fine powder;
(2) TNT for weighing required quality makes its thawing with 90 degrees Celsius of water-bath, adds the black rope of required quality Gold is slowly stirred, and obtains uniformly mixed melting liquid;
(3) nitrate fine powder obtained by step (1) is added in the fuel agent melted, is slowly stirred, be uniformly mixed it;
(4) gained is mixed and melts liquid, the pattern that will be painted is made, slowly wait its natural coagulation;
(5) etc. it after its solidification, is trimmed, makes it more close to the pattern of being painted, and keep its thickness uniform, and it is thick Degree is 2mm;
(6) nitrine of required quality is uniformly coated on the mixture surface of the nitrate of resulting specific shape and fuel agent Change lead;
(7) it places it on dedicated pyrotechnics colored drawing, lights, residue is cleared up after burning to get pyrotechnics colored drawing works.This reality It applies example and provides faint yellow gunpowder and paint the production method of dedicated paper, include the following steps:
(1) in the pulping process of paper, aluminium powder is added, the partial size of aluminium powder is in 30-100 mesh, the quality of aluminium powder and slurries Than for 2:100;
(2) it using modulation, manufactures paper with pulp, processes, obtain the dedicated paper presoma of pyrotechnics drawing;
(3) it is the dedicated paper presoma of 1mol/L aluminum nitrate solution sprinkling pyrotechnics drawing with concentration, makes its humidity 10- 20%;
(4) ammonia flow for being 55 degrees Celsius with temperature is dry, and drying time 45 minutes;
(5) step (3) are repeated (4) three to five times to get the dedicated paper of pyrotechnics colored drawing.
Embodiment 3
The present embodiment provides a kind of dedicated gunpowder production method of yellow gunpowder drawing, raw material components include:
52 parts by weight of rubidium nitrate
Fuel agent: the mixture that TNT and octogen are formed according to mass ratio 70:30,47 parts by weight
Burning ratemodifier: mercury fulminate, 1 mass parts
Further, the dedicated gunpowder production method of yellow gunpowder drawing is present embodiments provided, is included the following steps:
(1) it weighs the nitrate and is crushed, obtain nitrate fine powder;
(2) TNT for weighing required quality makes its thawing with 90 degrees Celsius of water-bath, adds the Losec of required quality Support is modern, is slowly stirred, and obtains uniformly mixed melting liquid;
(3) nitrate fine powder obtained by step (1) is added in the fuel agent melted, is slowly stirred, be uniformly mixed it;
(4) gained is mixed and melts liquid, the pattern that will be painted is made, slowly wait its natural coagulation;
(5) etc. it after its solidification, is trimmed, makes it more close to the pattern of being painted, and keep its thickness uniform, and it is thick Degree is 2mm;
(6) thunder of required quality is uniformly coated on the mixture surface of the nitrate of resulting specific shape and fuel agent Mercury;
(7) it places it on dedicated pyrotechnics colored drawing, lights, residue is cleared up after burning to get pyrotechnics colored drawing works.This reality It applies example and provides yellow gunpowder and paint the production method of dedicated paper, include the following steps:
(1) in the pulping process of paper, aluminium powder is added, the partial size of aluminium powder is in 30-100 mesh, the quality of aluminium powder and slurries Than for 2:150;
(2) it using modulation, manufactures paper with pulp, processes, obtain the dedicated paper presoma of pyrotechnics drawing;
(3) it is the dedicated paper presoma of 1mol/L aluminum nitrate solution sprinkling pyrotechnics drawing with concentration, makes its humidity 10- 20%;
(4) ammonia flow for being 52 degrees Celsius with temperature is dry, and drying time 35 minutes;
(5) step (3) are repeated (4) three to five times to get the dedicated paper of pyrotechnics colored drawing.
The present invention is not limited to above-mentioned preferred forms, anyone can show that other are various under the inspiration of the present invention The product of form, however, make any variation in its shape or structure, it is all that there is skill identical or similar to the present application Art scheme, is within the scope of the present invention.

Claims (4)

1. a kind of gunpowder recipe for being exclusively used in pyrotechnics colored drawing, which is characterized in that raw material components include:
Nitrate, 30-70 mass parts;
Fuel agent: TNT, hexogen, one of octogen or a variety of mixture 20-50 matter formed in any proportion Measure part;
Burning ratemodifier: mercury fulminate, lead azide, one of Shi Difen lead plumbate or a variety of, the mixture formed in any proportion 1-3 mass parts.
2. the dedicated gunpowder of pyrotechnics colored drawing according to claim 1, which is characterized in that
The nitrate is ferric nitrate, the decomposable nitrate for generating colored oxide such as copper nitrate.
3. a kind of method for preparing the described in any item dedicated gunpowder of pyrotechnics colored drawing of claim 1-2, which is characterized in that including such as Lower step:
(1) it weighs the nitrate and is crushed, obtain nitrate fine powder;
(2) fuel agent is weighed, is melted by the way of heating water bath;
(3) nitrate fine powder obtained by step (1) is added in the fuel agent melted, is slowly stirred, be uniformly mixed it;
(4) gained is mixed and melts liquid, the pattern that will be painted is made, slowly wait its natural coagulation;
(5) etc. it after its solidification, is trimmed, makes it more close to the pattern of being painted, and keep its thickness uniform, and its thickness exists Within the scope of 2-3mm;
(6) very thin one layer of burning ratemodifier is coated on the mixture surface of the nitrate of resulting specific shape and fuel agent;
(7) it places it on dedicated pyrotechnics colored drawing paper, lights, residue is cleared up after burning to get pyrotechnics colored drawing works.
4. a kind of prepare the dedicated paper of pyrotechnics colored drawing, which is characterized in that include the following steps
(1) in the pulping process of paper, aluminium powder is added, the partial size of aluminium powder is in 30-100 mesh;
(2) it using modulation, manufactures paper with pulp, processes, obtain the dedicated paper presoma of pyrotechnics drawing;
(3) it is the dedicated paper presoma of 1mol/L aluminum nitrate solution sprinkling pyrotechnics drawing with concentration, makes its humidity 10-20%;
(4) ammonia flow for being 40-60 degrees Celsius with temperature is dry;
(5) step (3) are repeated (4) three to five times to get the dedicated paper of pyrotechnics colored drawing.
CN201910370653.1A 2019-05-06 2019-05-06 Gunpowder formula special for firework color painting and paper special for firework color painting Active CN110078578B (en)

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110835283A (en) * 2019-12-10 2020-02-25 江西吉润花炮新材料科技有限公司 Environment-friendly firecracker nitrate medicament and preparation method thereof
CN110950723A (en) * 2019-12-10 2020-04-03 江西吉润花炮新材料科技有限公司 Flame bright type smokeless and sulfur-free firecracker nitrate medicament and preparation method thereof
CN110950725A (en) * 2019-12-10 2020-04-03 江西吉润花炮新材料科技有限公司 Antistatic treatment and preparation method of environment-friendly firecracker nitrate medicament
CN110963864A (en) * 2019-12-10 2020-04-07 江西吉润花炮新材料科技有限公司 Low-sensitivity smokeless and sulfur-free firecracker nitrate medicament and preparation method thereof
CN110981658A (en) * 2019-12-10 2020-04-10 江西吉润花炮新材料科技有限公司 Safe smokeless and sulfur-free firecracker and firecracker nitrate medicament and preparation method thereof
CN110981656A (en) * 2019-12-10 2020-04-10 江西吉润花炮新材料科技有限公司 Moisture absorption resistance treatment of smokeless and sulfur-free firecracker nitrate medicament and preparation method thereof
CN110981657A (en) * 2019-12-10 2020-04-10 江西吉润花炮新材料科技有限公司 Antistatic smokeless sulfur-free firecracker nitrate medicament and preparation method thereof
CN111018640A (en) * 2019-12-10 2020-04-17 江西吉润花炮新材料科技有限公司 Stabilizing treatment and preparation method of high-explosive-sound smokeless sulfur-free firecracker nitrate medicament
CN111039730A (en) * 2019-12-10 2020-04-21 江西吉润花炮新材料科技有限公司 Waterproof formula of smokeless and sulfur-free firecracker nitrate medicament and preparation method thereof

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110835283A (en) * 2019-12-10 2020-02-25 江西吉润花炮新材料科技有限公司 Environment-friendly firecracker nitrate medicament and preparation method thereof
CN110950723A (en) * 2019-12-10 2020-04-03 江西吉润花炮新材料科技有限公司 Flame bright type smokeless and sulfur-free firecracker nitrate medicament and preparation method thereof
CN110950725A (en) * 2019-12-10 2020-04-03 江西吉润花炮新材料科技有限公司 Antistatic treatment and preparation method of environment-friendly firecracker nitrate medicament
CN110963864A (en) * 2019-12-10 2020-04-07 江西吉润花炮新材料科技有限公司 Low-sensitivity smokeless and sulfur-free firecracker nitrate medicament and preparation method thereof
CN110981658A (en) * 2019-12-10 2020-04-10 江西吉润花炮新材料科技有限公司 Safe smokeless and sulfur-free firecracker and firecracker nitrate medicament and preparation method thereof
CN110981656A (en) * 2019-12-10 2020-04-10 江西吉润花炮新材料科技有限公司 Moisture absorption resistance treatment of smokeless and sulfur-free firecracker nitrate medicament and preparation method thereof
CN110981657A (en) * 2019-12-10 2020-04-10 江西吉润花炮新材料科技有限公司 Antistatic smokeless sulfur-free firecracker nitrate medicament and preparation method thereof
CN111018640A (en) * 2019-12-10 2020-04-17 江西吉润花炮新材料科技有限公司 Stabilizing treatment and preparation method of high-explosive-sound smokeless sulfur-free firecracker nitrate medicament
CN111039730A (en) * 2019-12-10 2020-04-21 江西吉润花炮新材料科技有限公司 Waterproof formula of smokeless and sulfur-free firecracker nitrate medicament and preparation method thereof

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