CN110055289B - 一种l-草铵膦的制备方法 - Google Patents
一种l-草铵膦的制备方法 Download PDFInfo
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- CN110055289B CN110055289B CN201810162629.4A CN201810162629A CN110055289B CN 110055289 B CN110055289 B CN 110055289B CN 201810162629 A CN201810162629 A CN 201810162629A CN 110055289 B CN110055289 B CN 110055289B
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- Prior art keywords
- glufosinate
- reaction
- dehydrogenase
- ammonium
- concentration
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- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims abstract description 20
- BOPGDPNILDQYTO-NNYOXOHSSA-N nicotinamide-adenine dinucleotide Chemical compound C1=CCC(C(=O)N)=CN1[C@H]1[C@H](O)[C@H](O)[C@@H](COP(O)(=O)OP(O)(=O)OC[C@@H]2[C@H]([C@@H](O)[C@@H](O2)N2C3=NC=NC(N)=C3N=C2)O)O1 BOPGDPNILDQYTO-NNYOXOHSSA-N 0.000 claims abstract description 18
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- IAJOBQBIJHVGMQ-BYPYZUCNSA-N glufosinate-P Chemical class CP(O)(=O)CC[C@H](N)C(O)=O IAJOBQBIJHVGMQ-BYPYZUCNSA-N 0.000 claims description 25
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Classifications
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CN111321193B (zh) * | 2020-03-18 | 2020-11-10 | 浙江工业大学 | 一种生物多酶偶联法氧化还原不对称制备l-草铵膦的方法 |
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