CN110028866A - Coating imitating natural marble texture and preparation method thereof - Google Patents
Coating imitating natural marble texture and preparation method thereof Download PDFInfo
- Publication number
- CN110028866A CN110028866A CN201910367730.8A CN201910367730A CN110028866A CN 110028866 A CN110028866 A CN 110028866A CN 201910367730 A CN201910367730 A CN 201910367730A CN 110028866 A CN110028866 A CN 110028866A
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- natural marble
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- 239000004579 marble Substances 0.000 title claims abstract description 49
- 238000002360 preparation method Methods 0.000 title claims abstract description 46
- 238000000576 coating method Methods 0.000 title claims abstract description 38
- 239000011248 coating agent Substances 0.000 title claims abstract description 36
- 239000000843 powder Substances 0.000 claims abstract description 43
- 239000000839 emulsion Substances 0.000 claims abstract description 35
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 32
- 230000001681 protective effect Effects 0.000 claims abstract description 29
- 229920000642 polymer Polymers 0.000 claims abstract description 28
- 239000002994 raw material Substances 0.000 claims abstract description 26
- 239000004200 microcrystalline wax Substances 0.000 claims abstract description 25
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 claims abstract description 23
- 125000000623 heterocyclic group Chemical group 0.000 claims abstract description 23
- 239000001863 hydroxypropyl cellulose Substances 0.000 claims abstract description 23
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 claims abstract description 23
- 239000002002 slurry Substances 0.000 claims abstract description 23
- 239000003112 inhibitor Substances 0.000 claims abstract description 20
- 239000002270 dispersing agent Substances 0.000 claims abstract description 19
- 239000002562 thickening agent Substances 0.000 claims abstract description 18
- 238000009736 wetting Methods 0.000 claims abstract description 18
- 239000000049 pigment Substances 0.000 claims abstract description 17
- 229920002522 Wood fibre Polymers 0.000 claims abstract description 16
- 239000003795 chemical substances by application Substances 0.000 claims description 54
- 238000003756 stirring Methods 0.000 claims description 39
- 239000003973 paint Substances 0.000 claims description 37
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 33
- 239000003292 glue Substances 0.000 claims description 31
- 239000013081 microcrystal Substances 0.000 claims description 29
- 239000002518 antifoaming agent Substances 0.000 claims description 28
- 229920002050 silicone resin Polymers 0.000 claims description 27
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 24
- 238000002156 mixing Methods 0.000 claims description 21
- 239000002585 base Substances 0.000 claims description 20
- 239000006210 lotion Substances 0.000 claims description 20
- -1 polyethylene Polymers 0.000 claims description 20
- 230000000149 penetrating effect Effects 0.000 claims description 16
- 235000012239 silicon dioxide Nutrition 0.000 claims description 16
- 230000003467 diminishing effect Effects 0.000 claims description 15
- 239000010453 quartz Substances 0.000 claims description 12
- 239000004408 titanium dioxide Substances 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 11
- 230000009471 action Effects 0.000 claims description 10
- 229910052681 coesite Inorganic materials 0.000 claims description 10
- 229910052906 cristobalite Inorganic materials 0.000 claims description 10
- 239000000377 silicon dioxide Substances 0.000 claims description 10
- 229910052682 stishovite Inorganic materials 0.000 claims description 10
- 229910052905 tridymite Inorganic materials 0.000 claims description 10
- 239000003513 alkali Substances 0.000 claims description 9
- 230000002209 hydrophobic effect Effects 0.000 claims description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 8
- 239000006185 dispersion Substances 0.000 claims description 8
- 238000006116 polymerization reaction Methods 0.000 claims description 8
- 239000004698 Polyethylene Substances 0.000 claims description 7
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 7
- 229910052593 corundum Inorganic materials 0.000 claims description 7
- 239000003995 emulsifying agent Substances 0.000 claims description 7
- 239000003999 initiator Substances 0.000 claims description 7
- 239000000178 monomer Substances 0.000 claims description 7
- 229920000573 polyethylene Polymers 0.000 claims description 7
- 239000001993 wax Substances 0.000 claims description 7
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 7
- 229920002472 Starch Polymers 0.000 claims description 6
- 229920001296 polysiloxane Polymers 0.000 claims description 6
- 238000012545 processing Methods 0.000 claims description 6
- 235000019698 starch Nutrition 0.000 claims description 6
- 238000003860 storage Methods 0.000 claims description 6
- 235000013339 cereals Nutrition 0.000 claims 1
- 235000013312 flour Nutrition 0.000 claims 1
- 230000007547 defect Effects 0.000 abstract description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052710 silicon Inorganic materials 0.000 abstract description 3
- 239000010703 silicon Substances 0.000 abstract description 3
- 239000000853 adhesive Substances 0.000 abstract description 2
- 230000001070 adhesive effect Effects 0.000 abstract description 2
- 229920005989 resin Polymers 0.000 abstract description 2
- 239000011347 resin Substances 0.000 abstract description 2
- 230000002528 anti-freeze Effects 0.000 abstract 1
- 239000013530 defoamer Substances 0.000 abstract 1
- 235000019808 microcrystalline wax Nutrition 0.000 abstract 1
- 239000002025 wood fiber Substances 0.000 abstract 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 9
- 230000000694 effects Effects 0.000 description 8
- 230000006872 improvement Effects 0.000 description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 238000010276 construction Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000004575 stone Substances 0.000 description 5
- DAFHKNAQFPVRKR-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylpropanoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)C DAFHKNAQFPVRKR-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 229910052719 titanium Inorganic materials 0.000 description 4
- 239000010936 titanium Substances 0.000 description 4
- 241000276489 Merlangius merlangus Species 0.000 description 3
- 229920001800 Shellac Polymers 0.000 description 3
- 230000003796 beauty Effects 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000005034 decoration Methods 0.000 description 3
- 235000013336 milk Nutrition 0.000 description 3
- 239000008267 milk Substances 0.000 description 3
- 210000004080 milk Anatomy 0.000 description 3
- 239000004208 shellac Substances 0.000 description 3
- ZLGIYFNHBLSMPS-ATJNOEHPSA-N shellac Chemical compound OCCCCCC(O)C(O)CCCCCCCC(O)=O.C1C23[C@H](C(O)=O)CCC2[C@](C)(CO)[C@@H]1C(C(O)=O)=C[C@@H]3O ZLGIYFNHBLSMPS-ATJNOEHPSA-N 0.000 description 3
- 229940113147 shellac Drugs 0.000 description 3
- 235000013874 shellac Nutrition 0.000 description 3
- 239000002966 varnish Substances 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000000084 colloidal system Substances 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 238000004134 energy conservation Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000010438 granite Substances 0.000 description 2
- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 description 2
- 229910000271 hectorite Inorganic materials 0.000 description 2
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 2
- 230000008595 infiltration Effects 0.000 description 2
- 238000001764 infiltration Methods 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 238000005461 lubrication Methods 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- IZUPBVBPLAPZRR-UHFFFAOYSA-N pentachlorophenol Chemical compound OC1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl IZUPBVBPLAPZRR-UHFFFAOYSA-N 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 230000002335 preservative effect Effects 0.000 description 2
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 2
- 230000008719 thickening Effects 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- ODIGIKRIUKFKHP-UHFFFAOYSA-N (n-propan-2-yloxycarbonylanilino) acetate Chemical compound CC(C)OC(=O)N(OC(C)=O)C1=CC=CC=C1 ODIGIKRIUKFKHP-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 1
- MBYXEBXZARTUSS-QLWBXOBMSA-N Emetamine Natural products O(C)c1c(OC)cc2c(c(C[C@@H]3[C@H](CC)CN4[C@H](c5c(cc(OC)c(OC)c5)CC4)C3)ncc2)c1 MBYXEBXZARTUSS-QLWBXOBMSA-N 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000006004 Quartz sand Substances 0.000 description 1
- AUVVAXYIELKVAI-UHFFFAOYSA-N SJ000285215 Natural products N1CCC2=CC(OC)=C(OC)C=C2C1CC1CC2C3=CC(OC)=C(OC)C=C3CCN2CC1CC AUVVAXYIELKVAI-UHFFFAOYSA-N 0.000 description 1
- OBNDGIHQAIXEAO-UHFFFAOYSA-N [O].[Si] Chemical compound [O].[Si] OBNDGIHQAIXEAO-UHFFFAOYSA-N 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- PIMYDFDXAUVLON-UHFFFAOYSA-M chloro(triethyl)stannane Chemical compound CC[Sn](Cl)(CC)CC PIMYDFDXAUVLON-UHFFFAOYSA-M 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- AUVVAXYIELKVAI-CKBKHPSWSA-N emetine Chemical compound N1CCC2=CC(OC)=C(OC)C=C2[C@H]1C[C@H]1C[C@H]2C3=CC(OC)=C(OC)C=C3CCN2C[C@@H]1CC AUVVAXYIELKVAI-CKBKHPSWSA-N 0.000 description 1
- 229960002694 emetine Drugs 0.000 description 1
- AUVVAXYIELKVAI-UWBTVBNJSA-N emetine Natural products N1CCC2=CC(OC)=C(OC)C=C2[C@H]1C[C@H]1C[C@H]2C3=CC(OC)=C(OC)C=C3CCN2C[C@H]1CC AUVVAXYIELKVAI-UWBTVBNJSA-N 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 230000014509 gene expression Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 235000012054 meals Nutrition 0.000 description 1
- 150000007974 melamines Chemical class 0.000 description 1
- 239000000693 micelle Substances 0.000 description 1
- 230000000116 mitigating effect Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000001054 red pigment Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000009738 saturating Methods 0.000 description 1
- GOLXNESZZPUPJE-UHFFFAOYSA-N spiromesifen Chemical compound CC1=CC(C)=CC(C)=C1C(C(O1)=O)=C(OC(=O)CC(C)(C)C)C11CCCC1 GOLXNESZZPUPJE-UHFFFAOYSA-N 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000005491 wire drawing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/12—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D151/08—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Plant Pathology (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Paints Or Removers (AREA)
Abstract
The invention relates to the technical field of coatings, and provides a coating for imitating natural marble textures and a preparation method thereof, aiming at solving the defects that the coating for imitating natural marble in the prior art has common textures and can not embody the characteristics of stripes, colorful appearance and clear textures displayed by high-end chain marbles with textures, and the coating for imitating natural marble textures comprises the following raw materials in parts by weight: 200 parts of 190-one water, 7-8 parts of hydroxypropyl cellulose, 3-5 parts of a water-reducing dispersant, 2-5 parts of a wetting penetrant, 3-5 parts of a thick slurry defoamer, 14-17 parts of an antifreeze, 28.5-29.6 parts of a film-forming assistant, 140 parts of a color nano pigment protective adhesive, 240 parts of quartz-grade microcrystalline powder 235-one, 5-7 parts of wood fiber, 5.1-6 parts of microcrystalline wax, 355 parts of a heterocyclic polymer organic silicon resin emulsion 350-one, 2-4 parts of a mildew inhibitor and 5-8 parts of a thickening agent.
Description
Technical field
The present invention relates to technical field of coatings more particularly to a kind of imitating natural marble texture coating and preparation method thereof.
Background technique
Marmorean type is more varied, existing market Major Epidemic: granite, burnt stone, chain latticing line
The colourful texture marble of shape.First two is that people generally use, and chain connects the colourful texture marble of striated and builds at present
Build in the use of object and gone up a high-end step, chain connects striated texture and refers to the texture connected as chain, it with
Clean mark, rough chain connect, colourful beauty and plasticity are very popular, are mainly used for the dress in high-grade place
Decorations, but occur many uncontrollable factor and risk in use.It is mainly reflected in the following:
1, marble (i.e. stone) material is heavier, and large area using building carrier can be made to aggravate, forbid by skyscraper
It uses；
2, resource is limited, non-renewable, seriously polluted, destroys ecology；
3, difficulty of construction is big, easy to fall off, and safety is poor, and cost is high；
4, hygroscopic, building infiltration, emetine are easily caused, the beauty and service life of building decoration object are influenced.
Imitation marble paint is a kind of new material for indoor and outdoor decorating building, its rough, texture chain with striped
Even, effect in different poses and with different expressions, the continuous shape of silk, material is lighter, and the marble material that can solve the prior art cannot be used for again
The defect of skyscraper, but its texture of the imitation marble paint of the prior art is relatively common, the line of common artificial grantie paint
Reason is usually that cannot embody high-end textured chain and connect striped that marble shown, more in spending dotted or graininess to be uniformly distributed
Appearance is colorful and the feature of clean mark.
Chinese Patent Application No. 2013104565726, discloses imitation marble paint, is made of component A and B component, A
Component includes: 4-6 parts of water, 30-40 parts of elastic emulsion, 0.2-0.3 parts of defoaming agent, 0.3-0.5 parts of dispersing agent, coalescing agent 0.4-
0.6 part, 0.2-0.3 parts of preservative, 6-10 parts of titanium dioxide, 35-40 parts of filler, 0.5-1 parts of thickener, pH adjusting agent 0.3-0.5
Part；B component includes: 5-10 parts of mill base；10-20 parts of pregel；50-60 parts of water, 5-10 parts of agent mixture.It, which is claimed, solves
It is existing just to seem the lower defect of parian fidelity, but can specifically accomplish which type of simulated effect has no and illustrate
Also it is explained without specific attached drawing.
Chinese Patent Application No. 2018113752048 discloses a kind of light steel house spray and builds type parian wall covering,
Raw material including following parts by weight: 30~45 parts of conch meal, 20~30 parts of acrylic acid floor paint, 10~15 parts of diatom ooze, glass
5~10 parts of glass fiber, 10~15 parts of gypsum, 3~10 parts of quartz sand, 5~15 parts of adhesive, 1~5 part of pigment, additive 0.5~
2 parts, the coating of the patent is environment friendly and pollution-free, has moisture-proof, fire prevention and water-proof function, is exclusively used in light steel house, it may have Dali
Texture, gloss and the texture of stone, but claimed in its advantages and can be prepared into various marmorean textures, fidelity and Dali
Stone compares favourably, or even the effect for having wonderful workmanship excelling nature, surpassing natural marble, but does not provide the solution for how realizing this effect
Explanation is released, whether really having this effect is also to be worth query, in addition, also not seeing from its raw material can carry out instead
It should obtain parian texture effect.
For another example, Chinese Patent Application No. 2012103445012 disclose a kind of energy saving imitation marble paint preparation method and
Its product comprising following steps: (1) silicate slurry is prepared: each component and its weight percent of the raw material of silicate slurry
Than as follows: water 85-95%, TSPP 0.4-1%, sheet silicate 4-14% are added water in a mixing bowl, starting a mixing bowl into
Row is dispersed with stirring movement, sequentially adds TSPP and sheet silicate, then stirs evenly, and silicate slurry is made；(2) it prepares white
Emulsion paint: each component and its weight percent of the raw material of Virgin's milk shellac varnish are as follows: water 30-40%, hydroxyethyl cellulose 0.5-
1%, dispersing agent 0.3-0.8%, wetting agent 0.2-0.5%, PH regulator 0.1-0.2%, first part of defoaming agent 0.1-0.4%,
Titanium dioxide 1-3%, coarse whiting 4-6%, kaolin 8-12%, TEXANOL 2-4%, ethylene glycol 0.5-1.5%, second part of defoaming agent
0.05-0.15%, first part of pure-acrylic emulsion 25-35%, preservative 0.1-0.3%, silicate slurry 8- made from step (1)
15%；It adds water in a mixing bowl, starting a mixing bowl carries out moderate-speed mixer movement, and hydroxyethyl cellulose, stirring point is then added
It dissipates 8-12 minutes and puts into dispersing agent, wetting agent, PH regulator and first part of defoaming agent again, be then dispersed with stirring to hydroxy ethyl fiber
Element is completely dissolved, and the first mixture is made；Titanium dioxide, coarse whiting and kaolin are added in the first mixture, continue to keep middling speed
Stirring action, until fineness≤50 μm, are made the second mixture；By TEXANOL, ethylene glycol, defoaming agent, pure-acrylic emulsion, anti-corrosion
Agent, silicate slurry are added in the second mixture, then carry out high speed churning action, until stirring evenly, Virgin's milk shellac varnish is made；
(3) mix colours: according to required parian color dot, then which is added step (2) by corresponding A, B, C mill base of preparation
Virgin's milk shellac varnish obtained, it is stand-by to be accordingly tuned into A, B, C colored paint；(4) prepare coating: each component and its weight percent of raw material are such as
Under: A, B, C colored paint 30-40%, thickener 0.4- is made in silicate slurry 20-30% made from step (1), step (3)
0.8%, water 10-20%, second part of pure-acrylic emulsion 10-20%；TEXANOL 1-2%, third part defoaming agent 0.1-0.3%；It will
Silicate slurry is added in paint mixing cylinder, and starting paint mixing cylinder carries out stirring at low speed movement；A, B, C colored paint are crossed with sieve respectively, then
It is added in paint mixing cylinder, continues to keep stirring at low speed movement, keep various colored paints immiscible, be in colorful state；Thickener and water are added
Enter in paint mixing cylinder, continues to keep stirring at low speed movement；Pure-acrylic emulsion, TEXANOL, defoaming agent are mixed in advance, it is mixed that third is made
Object is closed, and the third mixture is slowly added in paint mixing cylinder, is then stirred evenly, energy conservation imitation marble paint is made.This is specially
Benefit is claimed preparation method simple process, is easily achieved, at low cost and high production efficiency, and product energy conservation and environmental protection is easily molded, but saves
It can be being introduced there is no specific of how realizing, Effect value must be queried, and process and remarkable.
Summary of the invention
Therefore, for the above content, the present invention provides a kind of imitating natural marble texture coating and preparation method thereof, solves
The imitating natural marble coating texture of the prior art is common, cannot embody high-end textured chain connect striped that marble is shown and
The defect of colourful and clean mark feature.
In order to achieve the above objectives, the present invention is achieved by the following technical solutions: a kind of imitating natural marble texture painting
Material, is made of each raw material of following parts by weight:
190-200 parts of water
7-8 parts of hydroxypropyl cellulose
3-5 parts of diminishing dispersing agent
2-5 parts of wetting and penetrating agent
Defoaming agent 3-5 parts of thickness slurry
14-17 parts of antifreezing agent
28.5-29.6 parts of coalescing agent
130-140 parts of colored nanopigments protective glue
235-240 parts of quartzy grade micro-crystal powder
5-7 parts of wood fibre
5.1-6 parts of microwax
350-355 parts of heterocycle polymer silicone resin emulsion
2-4 parts of mould inhibitor
5-8 parts of thickener；
The partial size of the colored nanopigments protective glue is 80-100nm, and the partial size of the quartz grade micro-crystal powder is 800-
1000 mesh.
A further improvement is that the imitating natural marble texture coating, is made of each raw material of following parts by weight:
192.3 parts of water
7.8 parts of hydroxypropyl cellulose
3.2 parts of diminishing dispersing agent
3.6 parts of wetting and penetrating agent
4 parts of defoaming agent of thickness slurry
15 parts of antifreezing agent
28.6 parts of coalescing agent
136.5 parts of colored nanopigments protective glue
238.5 parts of quartzy grade micro-crystal powder
6.2 parts of wood fibre
5.6 parts of microwax
350 parts of heterocycle polymer silicone resin emulsion
2.3 parts of mould inhibitor
6.4 parts of thickener.
A further improvement is that: the colored nanopigments protective glue main component includes titanium dioxide, colored pigment and conjunction
At hectorite.
A further improvement is that: the ratio by mass of the titanium dioxide, colored pigment and synthetic soapstone is than calculating=1:
3:2.
A further improvement is that: the quartz grade micro-crystal powder is by SiO2、Al2O3To mix, the content of the SiO2 >
98%.
A further improvement is that: the microwax is oxidic polyethylene wax powder.
A further improvement is that: the heterocycle polymer silicone resin emulsion select Linear volatile silicone in siloxanes with
Acrylic monomers BA, MMA, MAA carry out step-by-step polymerization under the action of emulsifier, initiator and are grafted.
A kind of preparation method of imitating natural marble texture coating includes the preparation of color base paint, the system for wrapping up lotion
The preparation of standby and finished product preparation, the coloured base paint includes following processing step:
(1) first the water of the 60wt% in raw material is added in Scattered Kettle, starts stirring, revolving speed 200r/min is added
Mould inhibitor, the hydroxypropyl cellulose of 50wt%, speed-raising obtain 850r/min dispersion 5-10min, are slow added into color nano face
Expect protective glue, disperses 10-15min；
(2) then 1000r/min is arrived in speed-raising, and thick slurry defoaming agent, diminishing dispersing agent and the wetting and penetrating agent of 50wt% is added,
Quartzy grade micro-crystal powder is added after dispersing 5-8min, stirs 35-40min in 1000r/min after the completion, then revolving speed is reduced into 70r/
Then min is added the heterocycle polymer silicone resin emulsion of 48-50wt%, stands 55min after mixing evenly, spare；
The preparation step of the package lotion are as follows: (1) water remaining in raw material is added in Scattered Kettle, the revolving speed of Scattered Kettle
For 800r/min, hydroxypropyl cellulose is added, remainder thickness starches defoaming agent, antifreezing agent, coalescing agent, wood fibre, stirring
Disperse 10-12min；(2) it is decelerated to 700r/min, remainder hybridized polymer silicone resin emulsion, mould proof is then added
Microwax is added after stirring 5-8min in agent, stirs 25-30min, spare；
The preparation step of the finished product are as follows: the coloured base paint prepared is added in the package lotion prepared,
Thickener is added after carrying out being cut and dispersed into the requirement of required product specification under the mixing speed of 350r/min-400r/min, glues
Degree control filters and packages storage in 90-100ku to get imitating natural marble texture coating is arrived.
A further improvement is that: the described sticky dose alkali swollen thickener for hydrophobic type
By using preceding solution, the beneficial effects of the present invention are: imitating natural marble texture coating of the invention,
It has the advantage that
1, color multiplicity, clean mark can match in excellence or beauty with thick spacious texture marble；
2, versatile, water prescription is environment-protecting and non-poisonous, pollution-free, and GB18582-2008 standard is fully achieved；
3, easy for construction, film thickness is in 150um or so, the significantly load-carrying of the ornament of mitigation monolithic architecture after construction
Amount, never drop-off, recycling property are good；
4, paint film good waterproof performance, self-cleaning is strong, thoroughly solves that infiltration after dry-hang stone water suction, general to subtract whiting etc. abnormal,
It ensure that the permanent aesthetics of monolithic architecture object decoration, stain resistance < 5%；
5, long service life, weatherability was up to 10 years or more, artificial ageing test > 900h；
Reaction principle: one, hydroxypropyl cellulose, wood fibre, colored nanopigments protective glue add in reaction in the design
Entering rear generated colloid has excellent flexibility, draftability, and in construction, color spot micelle can form continuously texture
State.
Two, the wetting and penetrating agent in formula, quartzy grade micro-crystal powder, colored nanopigments protective glue it is compound, make full use of
The porous absorption of quartzy grade micro-crystal powder, high mechanical strength, the principles such as wear resistant corrosion resistant, mildew resistance is good, hardness is high, seep with wetting
Under the action of saturating agent, colored nanopigments colloid is sufficiently adsorbed, so that the weatherability for guaranteeing color pigment was protected up to 10 years or more
Demonstrate,prove bright in luster, colour-fast, artificial ageing test > 1000h.
Three, the special heterocycle polymer silicone resin emulsion selected in this technology is the line style silicon oxygen selected in siloxanes
Alkane carries out step-by-step polymerization with acrylic monomers BA, MMA, MAA under the action of emulsifier, initiator and is grafted.In this formula
Utilize the molecular structure structural bond of the siloxanes of lotionIt is selfed with the propoxyl in hydroxypropyl cellulose
Connection reaction, to improve this product package of cohesion internal force, toughness, stringiness and product to color pigment in the construction process
Property.Using such resin emulsion, there is excellent weather-proof, water-fast self-cleaning, resistance to mechanical impact force, with stone after this product curing and drying
After English grade micro-crystal powder, microwax are used in combination, hardness up to 3H~4H, the toughness for solving granite paint is bad, it is frangible, cannot
Wire drawing, the problems such as not strong wrapped.
Four, heterocycle polymer organic siliconresin, microwax have excellent hydrophobicity, waterproofness in this technology, solve
Texture marble is hygroscopic, the problems such as non-watertight.
Five, colored nanopigments protective glue: being to make size controlling between 80~100nm by mechanical lapping, mainly at
Divide includes: titanium dioxide, red pigment, yellow uitramarine and synthesis (MgSiO3LiSiO3) hectorite protective glue.
Six, quartzy grade micro-crystal powder: the partial size being mainly made of SiO2, Al2O3 etc. is ultra-fine between 800~1000 mesh
Powder is filled, wherein content > 98% of SiO2.Has the characteristics of quartzy grade micro-crystal powder itself, including high mechanical strength, mould proof
The functions such as performance is good, acid-fast alkali-proof and porous absorption.
Seven, microwax: the microwax that this product is selected is oxidic polyethylene wax powder, it and water and lotion mix dissolubility
It is good, it easily emulsifies, inside and outside lubrication good dispersion, the performances such as the damage resistant, feel lubrication of this product can be enhanced.
Specific embodiment
Carry out the embodiment that the present invention will be described in detail below with reference to specific embodiment, how skill is applied to the present invention whereby
Art means solve technical problem, and the realization process for reaching technical effect can fully understand and implement.
Unless otherwise specified, the conventional hand that technological means employed in embodiment is well known to those skilled in the art
Section, used reagent and product are also available commercial.The source of agents useful for same, trade name and it is necessary to list it
Constituent person is indicated on the first occurrence.
A kind of imitating natural marble texture coating is made of each raw material of following parts by weight:
190-200 parts of water
7-8 parts of hydroxypropyl cellulose
3-5 parts of diminishing dispersing agent
2-5 parts of wetting and penetrating agent
Defoaming agent 3-5 parts of thickness slurry
14-17 parts of antifreezing agent
28.5-29.6 parts of coalescing agent
130-140 parts of colored nanopigments protective glue
235-240 parts of quartzy grade micro-crystal powder
5-7 parts of wood fibre
5.1-6 parts of microwax
350-355 parts of heterocycle polymer silicone resin emulsion
2-4 parts of mould inhibitor
5-8 parts of thickener；
The colored nanopigments protective glue main component includes titanium dioxide, colored pigment and synthetic soapstone, the titanium
The ratio by mass of white powder, colored pigment and synthetic soapstone is than calculating=1:3:2, the grain of the colored nanopigments protective glue
Diameter is 80-100nm；The quartz grade micro-crystal powder is by SiO2、Al2O3It is mixed with any ratio, the grain of the quartz grade micro-crystal powder
Diameter is 800-1000 mesh.The microwax is oxidic polyethylene wax powder.The heterocycle polymer silicone resin emulsion selects silicon
Linear volatile silicone in oxygen alkane carries out step-by-step polymerization with acrylic monomers BA, MMA, MAA under the action of emulsifier, initiator and connects
Branch forms.
A kind of preparation method of imitating natural marble texture coating includes the preparation of color base paint, the system for wrapping up lotion
The preparation of standby and finished product preparation, the coloured base paint includes following processing step:
(1) first the water of the 60wt% in raw material is added in Scattered Kettle, starts stirring, revolving speed 200r/min is added
Mould inhibitor, the hydroxypropyl cellulose of 50wt%, speed-raising obtain 850r/min dispersion 5-10min, are slow added into color nano face
Expect protective glue, disperses 10-15min；
(2) then 1000r/min is arrived in speed-raising, and thick slurry defoaming agent, diminishing dispersing agent and the wetting and penetrating agent of 50wt% is added,
Quartzy grade micro-crystal powder is added after dispersing 5-8min, stirs 35-40min in 1000r/min after the completion, then revolving speed is reduced into 70r/
Then min is added the heterocycle polymer silicone resin emulsion of 48-50wt%, stands 55min after mixing evenly, spare；
The preparation step of the package lotion are as follows: (1) water remaining in raw material is added in Scattered Kettle, the revolving speed of Scattered Kettle
For 800r/min, hydroxypropyl cellulose is added, remainder thickness starches defoaming agent, antifreezing agent, coalescing agent, wood fibre, stirring
Disperse 10-12min；(2) it is decelerated to 700r/min, remainder hybridized polymer silicone resin emulsion, mould proof is then added
Microwax is added after stirring 5-8min in agent, stirs 25-30min, spare；
The preparation step of the finished product are as follows: the coloured base paint prepared is added in the package lotion prepared,
Carry out being cut and dispersed into the alkali that hydrophobic type is added after the requirement of required product specification under the mixing speed of 350r/min-400r/min
Swollen thickener, viscosity control filter and package storage in 90-100ku to get imitating natural marble texture coating is arrived.
The diminishing dispersing agent, wetting and penetrating agent, thick slurry defoaming agent, coalescing agent, mould inhibitor are this field routines
Reagent, from directly buying on the market.
Embodiment one
A kind of imitating natural marble texture coating is made of each raw material of following parts by weight:
190 parts of water
7 parts of hydroxypropyl cellulose
3 parts of polycarboxylic acid salt's diminishing dispersing agent
2 parts of wetting and penetrating agent of nonyl phenol polyethylene oxide ether
3 parts of thickness slurry defoaming agent B-98 (manufacturer: middle federation's chemical industry)
14 parts of acylate antifreezing agent
28.5 parts of Lauryl Alcohol ester coalescing agent
130 parts of colored nanopigments protective glue
235 parts of quartzy grade micro-crystal powder
5 parts of wood fibre
5.1 parts of microwax
350 parts of heterocycle polymer silicone resin emulsion
2 parts of triethyltin chloride mould inhibitor
5 parts of hydrophobic type alkali swollen thickener RASE-60 (Tianjin timely snow auxiliary chemicals Co., Ltd)；
The colored nanopigments protective glue main component includes titanium dioxide, colored pigment and synthetic soapstone, the titanium
The ratio by mass of white powder, colored pigment and synthetic soapstone is than calculating=1:3:2, the grain of the colored nanopigments protective glue
Diameter is 80nm；The quartz grade micro-crystal powder is by SiO2、Al2O3It is mixed with the weight ratio of 99:1, the quartz grade micro-crystal powder
Partial size is 800 mesh, and the microwax is oxidic polyethylene wax powder.The heterocycle polymer silicone resin emulsion selects siloxanes
In Linear volatile silicone and acrylic monomers BA, MMA, MAA carry out step-by-step polymerization grafting under the action of emulsifier, initiator and
At.
A kind of preparation method of imitating natural marble texture coating includes the preparation of color base paint, the system for wrapping up lotion
The preparation of standby and finished product preparation, the coloured base paint includes following processing step:
(1) first the water of the 60wt% in raw material is added in Scattered Kettle, starts stirring, revolving speed 200r/min is added
Mould inhibitor, the hydroxypropyl cellulose of 50wt%, speed-raising obtain 850r/min dispersion 5min, are slow added into colored nanopigments guarantor
Glue is protected, 10min is dispersed；
(2) then 1000r/min is arrived in speed-raising, and thick slurry defoaming agent, diminishing dispersing agent and the wetting and penetrating agent of 50wt% is added,
Quartzy grade micro-crystal powder is added after dispersing 5min, stirs 35min in 1000r/min after the completion, then revolving speed is reduced into 70r/min, so
The heterocycle polymer silicone resin emulsion of 48wt% is added afterwards, stands 55min after mixing evenly, it is spare；
The preparation step of the package lotion are as follows: (1) water remaining in raw material is added in Scattered Kettle, the revolving speed of Scattered Kettle
For 800r/min, hydroxypropyl cellulose is added, remainder thickness starches defoaming agent, antifreezing agent, coalescing agent, wood fibre, stirring
Disperse 10min；(2) it is decelerated to 700r/min, remainder hybridized polymer silicone resin emulsion, mould inhibitor is then added,
Microwax is added after stirring 5min, stirs 25min, it is spare；
The preparation step of the finished product are as follows: the coloured base paint prepared is added in the package lotion prepared,
Carry out being cut and dispersed under the mixing speed of 350r/minr/min be added after the requirement of required product specification hydrophobic type alkali soluble it is swollen
Thickener, viscosity control filter and package storage in 90ku to get imitating natural marble texture coating is arrived.
Embodiment two
A kind of imitating natural marble texture coating is made of each raw material of following parts by weight:
192.3 parts of water
7.8 parts of hydroxypropyl cellulose
3.2 parts of polyacrylate diminishing dispersing agent
3.6 parts of Negel wetting and penetrating agent
4 parts of defoaming agent B-99 of thickness slurry
15 parts of fatty acid amide antifreezing agent
28.6 parts of Lauryl Alcohol ester coalescing agent
136.5 parts of colored nanopigments protective glue
238.5 parts of quartzy grade micro-crystal powder
6.2 parts of wood fibre
5.6 parts of microwax
350 parts of heterocycle polymer silicone resin emulsion
2.3 parts of phenol mould inhibitor
6.4 parts of hydrophobic type alkali swollen thickener RASE-60 (Tianjin timely snow auxiliary chemicals Co., Ltd)；
The colored nanopigments protective glue main component includes titanium dioxide, colored pigment and synthetic soapstone, the titanium
The ratio by mass of white powder, colored pigment and synthetic soapstone is than calculating=1:3:2, the grain of the colored nanopigments protective glue
Diameter is 90nm；The quartz grade micro-crystal powder is by SiO2、Al2O3It is mixed with the weight ratio of 99.5:0.5, the quartz grade crystallite
The partial size of powder is 900 mesh, and the microwax is oxidic polyethylene wax powder.The heterocycle polymer silicone resin emulsion selects silicon
Linear volatile silicone in oxygen alkane carries out step-by-step polymerization with acrylic monomers BA, MMA, MAA under the action of emulsifier, initiator and connects
Branch forms.
A kind of preparation method of imitating natural marble texture coating includes the preparation of color base paint, the system for wrapping up lotion
The preparation of standby and finished product preparation, the coloured base paint includes following processing step:
(1) first the water of the 60wt% in raw material is added in Scattered Kettle, starts stirring, revolving speed 200r/min is added
Mould inhibitor, the hydroxypropyl cellulose of 50wt%, speed-raising obtain 850r/min dispersion 5-10min, are slow added into color nano face
Expect protective glue, disperses 12min；
(2) then 1000r/min is arrived in speed-raising, and thick slurry defoaming agent, diminishing dispersing agent and the wetting and penetrating agent of 50wt% is added,
Quartzy grade micro-crystal powder is added after dispersing 6min, stirs 38min in 1000r/min after the completion, then revolving speed is reduced into 70r/min, so
The heterocycle polymer silicone resin emulsion of 49wt% is added afterwards, stands 55min after mixing evenly, it is spare；
The preparation step of the package lotion are as follows: (1) water remaining in raw material is added in Scattered Kettle, the revolving speed of Scattered Kettle
For 800r/min, hydroxypropyl cellulose is added, remainder thickness starches defoaming agent, antifreezing agent, coalescing agent, wood fibre, stirring
Disperse 11min；(2) it is decelerated to 700r/min, remainder hybridized polymer silicone resin emulsion, mould inhibitor is then added,
Microwax is added after stirring 6min, stirs 27min, it is spare；
The preparation step of the finished product are as follows: the coloured base paint prepared is added in the package lotion prepared,
Carry out being cut and dispersed into the swollen thickening of alkali soluble that hydrophobic type is added after the requirement of required product specification under the mixing speed of 380r/min
Agent, viscosity control filter and package storage in 95ku to get imitating natural marble texture coating is arrived.
Embodiment three
A kind of imitating natural marble texture coating is made of each raw material of following parts by weight:
200 parts of water
8 parts of hydroxypropyl cellulose
5 parts of sulfonated melamine resin diminishing dispersing agent
5 parts of polyoxyethylene aliphatic alcohol ether wetting and penetrating agent
5 parts of defoaming agent B-100 of thickness slurry
17 parts of alkylamine antifreezing agent
29.6 parts of Lauryl Alcohol ester coalescing agent
140 parts of colored nanopigments protective glue
240 parts of quartzy grade micro-crystal powder
7 parts of wood fibre
6 parts of microwax
355 parts of heterocycle polymer silicone resin emulsion
4 parts of pentachlorophenol mould inhibitor
8 parts of hydrophobic type alkali swollen thickener RASE-60 (Tianjin timely snow auxiliary chemicals Co., Ltd)；
The colored nanopigments protective glue main component includes titanium dioxide, colored pigment and synthetic soapstone, the titanium
The ratio by mass of white powder, colored pigment and synthetic soapstone is than calculating=1:3:2, the grain of the colored nanopigments protective glue
Diameter is 100nm；The quartz grade micro-crystal powder is by SiO2、Al2O3It is mixed with any ratio, the partial size of the quartz grade micro-crystal powder
For 1000 mesh, the microwax is oxidic polyethylene wax powder.The heterocycle polymer silicone resin emulsion is selected in siloxanes
Linear volatile silicone and acrylic monomers BA, MMA, MAA carry out step-by-step polymerization grafting under the action of emulsifier, initiator and
At.
A kind of preparation method of imitating natural marble texture coating includes the preparation of color base paint, the system for wrapping up lotion
The preparation of standby and finished product preparation, the coloured base paint includes following processing step:
(1) first the water of the 60wt% in raw material is added in Scattered Kettle, starts stirring, revolving speed 200r/min is added
Mould inhibitor, the hydroxypropyl cellulose of 50wt%, speed-raising obtain 850r/min dispersion 10min, are slow added into colored nanopigments
Protective glue disperses 15min；
(2) then 1000r/min is arrived in speed-raising, and thick slurry defoaming agent, diminishing dispersing agent and the wetting and penetrating agent of 50wt% is added,
Quartzy grade micro-crystal powder is added after dispersing 8min, stirs 40min in 1000r/min after the completion, then revolving speed is reduced into 70r/min, so
The heterocycle polymer silicone resin emulsion of 50wt% is added afterwards, stands 55min after mixing evenly, it is spare；
The preparation step of the package lotion are as follows: (1) water remaining in raw material is added in Scattered Kettle, the revolving speed of Scattered Kettle
For 800r/min, hydroxypropyl cellulose is added, remainder thickness starches defoaming agent, antifreezing agent, coalescing agent, wood fibre, stirring
Disperse 12min；(2) it is decelerated to 700r/min, remainder hybridized polymer silicone resin emulsion, mould inhibitor is then added,
Microwax is added after stirring 8min, stirs 30min, it is spare；
The preparation step of the finished product are as follows: the coloured base paint prepared is added in the package lotion prepared,
Carry out being cut and dispersed into the swollen thickening of alkali soluble that hydrophobic type is added after the requirement of required product specification under the mixing speed of 400r/min
Agent, viscosity control filter and package storage in 100ku to get imitating natural marble texture coating is arrived.
The foregoing descriptions are merely the embodiment using this origination techniques content, any those skilled in the art use this wound
Make done modifications and changes, all belong to the scope of the patents of this creation opinion, and is not limited to those disclosed embodiments.
Claims (9)
1. a kind of imitating natural marble texture coating, which is characterized in that be made of each raw material of following parts by weight:
190-200 parts of water
7-8 parts of hydroxypropyl cellulose
3-5 parts of diminishing dispersing agent
2-5 parts of wetting and penetrating agent
Defoaming agent 3-5 parts of thickness slurry
14-17 parts of antifreezing agent
28.5-29.6 parts of coalescing agent
130-140 parts of colored nanopigments protective glue
235-240 parts of quartzy grade micro-crystal powder
5-7 parts of wood fibre
5.1-6 parts of microwax
350-355 parts of heterocycle polymer silicone resin emulsion
2-4 parts of mould inhibitor
5-8 parts of thickener
The partial size of the colored nanopigments protective glue is 80-100nm, and the partial size of the quartz grade micro-crystal powder is 800-1000
Mesh.
2. a kind of anti-natural marble grain coating according to claim 1, which is characterized in that by each of following parts by weight
Raw material composition:
192.3 parts of water
7.8 parts of hydroxypropyl cellulose
3.2 parts of diminishing dispersing agent
3.6 parts of wetting and penetrating agent
4 parts of defoaming agent of thickness slurry
15 parts of antifreezing agent
28.6 parts of coalescing agent
136.5 parts of colored nanopigments protective glue
238.5 parts of quartzy grade micro-crystal powder
6.2 parts of wood fibre
5.6 parts of microwax
350 parts of heterocycle polymer silicone resin emulsion
2.3 parts of mould inhibitor
6.4 parts of thickener.
3. a kind of imitating natural marble texture coating according to claim 1 or 2, it is characterised in that: the color nano
Pigment protective glue main component includes titanium dioxide, colored pigment and synthetic soapstone.
4. a kind of imitating natural marble texture coating according to claim 3, it is characterised in that: the titanium dioxide, coloured
Pigment and the ratio by mass of synthetic soapstone are than calculating=1:3:2.
5. a kind of imitating natural marble texture coating according to claim 1 or 2, it is characterised in that: the quartz grade is micro-
Crystalline flour is by SiO2、Al2O3To mix, content > 98% of the SiO2.
6. a kind of imitating natural marble texture coating according to claim 1 or 2, it is characterised in that: the microwax is
Oxidic polyethylene wax powder.
7. a kind of imitating natural marble texture coating according to claim 1 or 2, it is characterised in that: the heterocycle polymerization
Object silicone resin emulsion selects the Linear volatile silicone in siloxanes with acrylic monomers BA, MMA, MAA in emulsifier, initiator
Under the action of carry out step-by-step polymerization be grafted.
8. a kind of preparation method of imitating natural marble texture coating according to claim 1 or 2, which is characterized in that packet
It includes the preparation of coloured base paint, wrap up the preparation of lotion and the preparation of finished product, the preparation of the coloured base paint includes following
Processing step:
(1) first the water of the 60wt% in raw material is added in Scattered Kettle, starts stirring, 50wt% is added in revolving speed 200r/min
Mould inhibitor, hydroxypropyl cellulose, speed-raising obtain 850r/min dispersion 5-10min, be slow added into colored nanopigments protection
Glue disperses 10-15min；
(2) then 1000r/min is arrived in speed-raising, and thick slurry defoaming agent, diminishing dispersing agent and the wetting and penetrating agent of 50wt%, dispersion is added
Quartzy grade micro-crystal powder is added after 5-8min, stirs 35-40min in 1000r/min after the completion, then revolving speed is reduced into 70r/min, so
The heterocycle polymer silicone resin emulsion of 48-50wt% is added afterwards, stands 55min after mixing evenly, it is spare；
The preparation step of the package lotion are as follows: (1) water remaining in raw material is added in Scattered Kettle, the revolving speed of Scattered Kettle is
Hydroxypropyl cellulose is added in 800r/min, remainder thickness starches defoaming agent, antifreezing agent, coalescing agent, wood fibre, stirring point
Dissipate 10-12min；(2) it is decelerated to 700r/min, remainder hybridized polymer silicone resin emulsion, mould inhibitor is then added,
Microwax is added after stirring 5-8min, stirs 25-30min, it is spare；
The preparation step of the finished product are as follows: the coloured base paint prepared is added in the package lotion prepared, in 350r/
Thickener, viscosity control is added after carrying out being cut and dispersed into the requirement of required product specification under the mixing speed of min-400r/min
In 90-100ku, storage is filtered and packaged to get imitating natural marble texture coating is arrived.
9. a kind of preparation method of imitating natural marble texture coating according to claim 8, it is characterised in that: described glutinous
The thick dose of alkali swollen thickener for hydrophobic type.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910367730.8A CN110028866A (en) | 2019-05-05 | 2019-05-05 | Coating imitating natural marble texture and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN101654578A (en) * | 2008-08-22 | 2010-02-24 | 深圳市展辰达化工有限公司 | Water-base fluorocarbon imitation marble paint, preparation method thereof and method for spraying with imitation marble effect |
| CN102093796A (en) * | 2011-01-31 | 2011-06-15 | 康跃金 | Stone paint coating |
| CN104559497A (en) * | 2013-10-10 | 2015-04-29 | 天长市开林化工有限公司 | High-temperature resistant marble-imitated coating and producing method thereof |
| CN107446449A (en) * | 2017-07-27 | 2017-12-08 | 芜湖市三山龙城新材料有限公司 | Colorful imitation marble paint and preparation method thereof |
| CN109233508A (en) * | 2017-05-23 | 2019-01-18 | 上海三银涂料科技股份有限公司 | Water-water imitation marble paint and its preparation method and application |
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| CN101654578A (en) * | 2008-08-22 | 2010-02-24 | 深圳市展辰达化工有限公司 | Water-base fluorocarbon imitation marble paint, preparation method thereof and method for spraying with imitation marble effect |
| CN102093796A (en) * | 2011-01-31 | 2011-06-15 | 康跃金 | Stone paint coating |
| CN104559497A (en) * | 2013-10-10 | 2015-04-29 | 天长市开林化工有限公司 | High-temperature resistant marble-imitated coating and producing method thereof |
| CN109233508A (en) * | 2017-05-23 | 2019-01-18 | 上海三银涂料科技股份有限公司 | Water-water imitation marble paint and its preparation method and application |
| CN107446449A (en) * | 2017-07-27 | 2017-12-08 | 芜湖市三山龙城新材料有限公司 | Colorful imitation marble paint and preparation method thereof |
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