CN104559497A - High-temperature resistant marble-imitated coating and producing method thereof - Google Patents
High-temperature resistant marble-imitated coating and producing method thereof Download PDFInfo
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- CN104559497A CN104559497A CN201310471161.4A CN201310471161A CN104559497A CN 104559497 A CN104559497 A CN 104559497A CN 201310471161 A CN201310471161 A CN 201310471161A CN 104559497 A CN104559497 A CN 104559497A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
High-temperature resistant marble-imitated coating and a producing method thereof are disclosed. The coating comprises following components by weight: 0.1-2 parts of cellulose, 0.1-3 parts of a pH conditioner, 200-450 parts of an emulsion, inorganic salt base materials comprising 10-20 parts of silicate and 5-10 parts of phosphate, 5-32 parts of a film coalescing aid, 500-900 parts of quartz sand, 0.1-8 parts of a thickening agent, 0.1-5 parts of a defoaming agent and 50-100 parts of water. The coating can allow a wall to have beauty and texture which are same as that of marble. By addition of the inorganic salt base materials into the coating, the inorganic salt base materials are nonflammable and generate endothermic reactions when encountering high temperature or fire to form an inorganic glaze shape body to insulate air, thus achieving functions of fire prevention and high-temperature resistance.
Description
Technical field
The present invention relates to technical field of coatings, particularly relate to a kind of high temperature resistant imitation marble paint and production method thereof.
Background technology
Natural marble is a kind of finishing material of top grade, but due to store content limited, can not regenerate, so natural marble is very high as the cost of building and ornament materials.Therefore, there is imitation marble paint, adopt natural mineral, containing ion silicone, body of wall is seam absolutely not, has the texture of natural marble, gloss and texture, naturalness can be carried out than U.S. with natural marble, is applicable to market, supermarket, office exhibition room, corridor, elevator.
As from the foregoing, being of wide application of imitation marble paint, and imitation marble paint has waterproof, resistant, the characteristic of weather change, house can be made to keep Nian Jiuru is new, metope can not turn to be yellow because of the passage in years.But existing imitation marble paint is high temperature resistant, and the performance of even fire-resistant aspect is not also fine.When running into short time high temperature, metope variable color, crack or distortion can be caused; If high-temperature time is slightly long, then wall skin can be caused to come off, even on fire.
Summary of the invention
In order to solve the technical problem existed in background technology, the present invention proposes a kind of high temperature resistant imitation marble paint and production method thereof, to make metope not only attractive in appearance as marble and texture, fire-proof high-temperature resistant function can also be had.
The high temperature resistant imitation marble paint of one that the present invention proposes, comprises following composition according to parts by weight:
Mierocrystalline cellulose: 0.1-2 part; PH conditioning agent: 0.1-3 part; Emulsion: 200-450 part; Inorganic salt base-material, it comprises silicate 10-20 part; Phosphoric acid salt 5-10 part; Film coalescence aid: 5-32 part; Quartz sand: 500-900 part; Thickening material: 0.1-8 part; Defoamer: 0.1-5 part; Water: 50-100 part;
Wherein, described Mierocrystalline cellulose comprises: the one or more combination in soluble cotton, butyric acid rhodia, rhodia, propionic acid rhodia, Vltra tears, Natvosol, Walocel MT 20.000PV; Described PH conditioning agent is ammoniacal liquor and trolamine; Described emulsion is stupid third resin emulsion or organosilicon acrylic resin emulsion; Described film coalescence aid comprises: the one or more combination in propylene glycol monomethyl ether, propandiol butyl ether, alcohol ester 12, butyl or stupid methyl alcohol; Described silicate is quartz or SiO 2 powder, 150-300 order; Described phosphoric acid salt comprises sodium phosphate, calcium phosphate or potassiumphosphate, 100-250 order.
Preferably, described high temperature resistant imitation marble paint comprises following composition according to parts by weight:
Mierocrystalline cellulose: 0.5-1.7 part; PH conditioning agent: 0.3-2.9 part; Emulsion: 250-450 part; Inorganic salt base-material, it comprises silicate 12-18 part; Phosphoric acid salt 6-9 part; Film coalescence aid: 8-30 part; Quartz sand: 560-880 part; Thickening material: 0.2-7 part; Defoamer: 0.4-4 part; Water: 60-90 part.
Preferably, described high temperature resistant imitation marble paint comprises following composition according to parts by weight:
Mierocrystalline cellulose: 1-1.5 part; PH conditioning agent: 0.9-2.4 part; Emulsion: 260-430 part; Inorganic salt base-material, it comprises silicate 14-16 part; Phosphoric acid salt 7-8 part; Film coalescence aid: 10-30 part; Quartz sand: 600-850 part; Thickening material: 0.2-6 part; Defoamer: 0.6-3.6 part; Water: 60-90 part.
Based on above-mentioned high temperature resistant imitation marble paint, the present invention proposes a kind of production method of high temperature resistant imitation marble paint, comprise the following steps:
In agitator, add warm water, add by the good Mierocrystalline cellulose of above-mentioned share proportioning and PH conditioning agent under 100-200 rev/min of stir speed (S.S.), improve stir speed (S.S.) to 800-1000 rev/min, stir;
Add by the good defoamer of above-mentioned share proportioning, film coalescence aid, under 45 degree, uniform stirring under 800-1000 rev/min of rotating speed;
Under 800-1000 rev/min of stir speed (S.S.), add emulsion, stir at least 10 minutes;
Add quartz sand, improve stir speed (S.S.) to 1300-1500 rev/min, below 45 degree, stir;
Add by the good inorganic salt base-material of above-mentioned share proportioning, under 500-600 rev/min of stir speed (S.S.), stir at least 10 minutes;
Add thickening material adjusting viscosity, uniform stirring at least 5 minutes.
In the present invention, described high temperature resistant imitation marble paint makes metope not only attractive in appearance as marble and texture, by increasing inorganic salt base-material in imitation marble paint, due to the combustion of inorganic salt base-material difficulty itself, and chance high temperature or fire produce endothermic reaction, form inorganic glaze shape body, isolated air, realizes fire-proof high-temperature resistant function.
Embodiment
The embodiment of the present invention 1 provides a kind of high temperature resistant imitation marble paint, comprises following composition according to parts by weight:
Mierocrystalline cellulose: 0.1-2 part;
PH conditioning agent: 0.1-3 part;
Emulsion: 200-450 part;
Inorganic salt base-material, comprises silicate 10-20 part; Phosphoric acid salt 5-10 part;
Film coalescence aid: 5-32 part;
Quartz sand: 500-900 part;
Thickening material: 0.1-8 part;
Defoamer: 0.1-5 part;
Water: 50-100 part.
The embodiment of the present invention 2 provides a kind of high temperature resistant imitation marble paint, comprises following composition according to parts by weight:
Mierocrystalline cellulose: 0.5-1.7 part;
PH conditioning agent: 0.3-2.9 part;
Emulsion: 250-450 part;
Inorganic salt base-material, it comprises silicate 12-18 part; Phosphoric acid salt 6-9 part;
Film coalescence aid: 8-30 part;
Quartz sand: 560-880 part;
Thickening material: 0.2-7 part;
Defoamer: 0.4-4 part;
Water: 60-90 part.
The embodiment of the present invention 3 provides a kind of high temperature resistant imitation marble paint, comprises following composition according to parts by weight:
Mierocrystalline cellulose: 1-1.5 part;
PH conditioning agent: 0.9-2.4 part;
Emulsion: 260-430 part;
Inorganic salt base-material, it comprises silicate 14-16 part; Phosphoric acid salt 7-8 part;
Film coalescence aid: 10-30 part;
Quartz sand: 600-850 part;
Thickening material: 0.2-6 part;
Defoamer: 0.6-3.6 part;
Water: 60-90 part.
In above-described embodiment 1 to 3, by increasing inorganic salt base-material in imitation marble paint, due to the combustion of inorganic salt base-material difficulty itself, and chance high temperature or fire produce endothermic reaction, and form inorganic glaze shape body, and isolated air, realizes fire-proof high-temperature resistant function; Particularly, inorganic salt base-material comprises silicate and phosphoric acid salt, and wherein, described silicate is quartz or SiO 2 powder, is ground to 150-300 order.Described phosphoric acid salt comprises sodium phosphate, calcium phosphate or potassiumphosphate, is ground to 100-250 order.Mierocrystalline cellulose can have good consistency with filmogen, and can improve drying property and the adhesivity of film.Such as, the one or more combination in soluble cotton, butyric acid rhodia, rhodia, propionic acid rhodia, Vltra tears, Natvosol, Walocel MT 20.000PV.PH conditioning agent is for regulating the auxiliary agent of pH value, and PH adjusting coating conditioning agent such as uses ammoniacal liquor and trolamine.Emulsion can use stupid third resin emulsion, organosilicon acrylic resin emulsion.Film coalescence aid can be the one or more combination in propylene glycol monomethyl ether, propandiol butyl ether, alcohol ester 12, butyl or stupid methyl alcohol.
Based on imitation marble paint high temperature resistant in embodiment 1 to 3, the embodiment of the present invention 4 provides a kind of production method of high temperature resistant imitation marble paint, comprises the following steps:
Step 101, in agitator, add warm water (less than 45 degree), add by the good Mierocrystalline cellulose of above-described embodiment share proportioning and PH conditioning agent under 100-200 rev/min of stir speed (S.S.), improve stir speed (S.S.) to 800-1000 rev/min, stir, this process also will ensure that temperature controls below 45 degree.
Step 102, adds by the good defoamer of above-described embodiment share proportioning, film coalescence aid, under 45 degree, and uniform stirring under 800-1000 rev/min of rotating speed; Wherein, defoamer is applicable to the foam eliminating the systems such as styrene-acrylic latex, ethylene propylene rubber latex, pure third latex, vinyl acetate between to for plastic latex.
Step 103, under 800-1000 rev/min of stir speed (S.S.), adds emulsion, stirs at least 10 minutes.
Step 104, adds quartz sand, improves stir speed (S.S.) to 1300-1500 rev/min, below 45 degree, stirs.Wherein, quartz sand is 100-200 order quartz sand.
Step 105, adds by the good inorganic salt base-material of above-described embodiment share proportioning, under 500-600 rev/min of stir speed (S.S.), stirs at least 10 minutes.Wherein, silicate can be quartz or SiO 2 powder, needs to be ground to 150-300 order; Phosphoric acid salt comprises sodium phosphate, calcium phosphate or potassiumphosphate, needs to be ground to 100-250 order.
Step 106, adds thickening material adjusting viscosity, uniform stirring at least 5 minutes, obtains described high temperature resistant imitation marble paint.
Embodiments provide the above; be only the present invention's preferably embodiment; but protection scope of the present invention is not limited thereto; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; be equal to according to technical scheme of the present invention and inventive concept thereof and replace or change, all should be encompassed within protection scope of the present invention.
Claims (4)
1. a high temperature resistant imitation marble paint, is characterized in that, comprises following composition according to parts by weight:
Mierocrystalline cellulose: 0.1-2 part; PH conditioning agent: 0.1-3 part; Emulsion: 200-450 part; Inorganic salt base-material, it comprises silicate 10-20 part; Phosphoric acid salt 5-10 part; Film coalescence aid: 5-32 part; Quartz sand: 500-900 part; Thickening material: 0.1-8 part; Defoamer: 0.1-5 part; Water: 50-100 part;
Wherein, described Mierocrystalline cellulose comprises: the one or more combination in soluble cotton, butyric acid rhodia, rhodia, propionic acid rhodia, Vltra tears, Natvosol, Walocel MT 20.000PV; Described PH conditioning agent is ammoniacal liquor and trolamine; Described emulsion is stupid third resin emulsion or organosilicon acrylic resin emulsion; Described film coalescence aid comprises: the one or more combination in propylene glycol monomethyl ether, propandiol butyl ether, alcohol ester 12, butyl or stupid methyl alcohol; Described silicate is quartz or SiO 2 powder, 150-300 order; Described phosphoric acid salt comprises sodium phosphate, calcium phosphate or potassiumphosphate, 100-250 order.
2. high temperature resistant imitation marble paint according to claim 1, is characterized in that, comprises following composition according to parts by weight:
Mierocrystalline cellulose: 0.5-1.7 part; PH conditioning agent: 0.3-2.9 part; Emulsion: 250-450 part; Inorganic salt base-material, it comprises silicate 12-18 part; Phosphoric acid salt 6-9 part; Film coalescence aid: 8-30 part; Quartz sand: 560-880 part; Thickening material: 0.2-7 part; Defoamer: 0.4-4 part; Water: 60-90 part.
3. high temperature resistant imitation marble paint according to claim 2, is characterized in that, comprises following composition according to parts by weight:
Mierocrystalline cellulose: 1-1.5 part; PH conditioning agent: 0.9-2.4 part; Emulsion: 260-430 part; Inorganic salt base-material, it comprises silicate 14-16 part; Phosphoric acid salt 7-8 part; Film coalescence aid: 10-30 part; Quartz sand: 600-850 part; Thickening material: 0.2-6 part; Defoamer: 0.6-3.6 part; Water: 60-90 part.
4. a production method for the high temperature resistant imitation marble paint according to any one of claim 1-3, is characterized in that, comprise the following steps:
In agitator, add warm water, add by the good Mierocrystalline cellulose of above-mentioned share proportioning and PH conditioning agent under 100-200 rev/min of stir speed (S.S.), improve stir speed (S.S.) to 800-1000 rev/min, stir;
Add by the good defoamer of above-mentioned share proportioning, film coalescence aid, under 45 degree, uniform stirring under 800-1000 rev/min of rotating speed;
Under 800-1000 rev/min of stir speed (S.S.), add emulsion, stir at least 10 minutes;
Add quartz sand, improve stir speed (S.S.) to 1300-1500 rev/min, below 45 degree, stir;
Add by the good inorganic salt base-material of above-mentioned share proportioning, under 500-600 rev/min of stir speed (S.S.), stir at least 10 minutes;
Add thickening material adjusting viscosity, uniform stirring at least 5 minutes.
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CN201310471161.4A CN104559497A (en) | 2013-10-10 | 2013-10-10 | High-temperature resistant marble-imitated coating and producing method thereof |
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CN201310471161.4A CN104559497A (en) | 2013-10-10 | 2013-10-10 | High-temperature resistant marble-imitated coating and producing method thereof |
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CN201310471161.4A Pending CN104559497A (en) | 2013-10-10 | 2013-10-10 | High-temperature resistant marble-imitated coating and producing method thereof |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110028866A (en) * | 2019-05-05 | 2019-07-19 | 福建惠兴涂料科技发展有限公司 | Coating imitating natural marble texture and preparation method thereof |
CN114539839A (en) * | 2022-01-21 | 2022-05-27 | 宁国市茂发装饰材料有限公司 | Antibacterial ultrathin fireproof water-based paint and preparation method thereof |
-
2013
- 2013-10-10 CN CN201310471161.4A patent/CN104559497A/en active Pending
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110028866A (en) * | 2019-05-05 | 2019-07-19 | 福建惠兴涂料科技发展有限公司 | Coating imitating natural marble texture and preparation method thereof |
CN114539839A (en) * | 2022-01-21 | 2022-05-27 | 宁国市茂发装饰材料有限公司 | Antibacterial ultrathin fireproof water-based paint and preparation method thereof |
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Application publication date: 20150429 |
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