CN109856037B - 一种金属双极板长期稳定性的测定方法 - Google Patents
一种金属双极板长期稳定性的测定方法 Download PDFInfo
- Publication number
- CN109856037B CN109856037B CN201910016183.9A CN201910016183A CN109856037B CN 109856037 B CN109856037 B CN 109856037B CN 201910016183 A CN201910016183 A CN 201910016183A CN 109856037 B CN109856037 B CN 109856037B
- Authority
- CN
- China
- Prior art keywords
- bipolar plate
- test
- corrosion
- metal bipolar
- electrode
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 115
- 239000002184 metal Substances 0.000 title claims abstract description 115
- 238000000034 method Methods 0.000 title claims abstract description 48
- 230000007774 longterm Effects 0.000 title claims abstract description 39
- 230000007797 corrosion Effects 0.000 claims abstract description 146
- 238000005260 corrosion Methods 0.000 claims abstract description 146
- 238000012360 testing method Methods 0.000 claims abstract description 145
- 238000004088 simulation Methods 0.000 claims abstract description 61
- 230000001133 acceleration Effects 0.000 claims abstract description 39
- 239000008151 electrolyte solution Substances 0.000 claims abstract description 26
- 238000013461 design Methods 0.000 claims abstract description 20
- 238000011156 evaluation Methods 0.000 claims abstract description 15
- -1 iron ion Chemical class 0.000 claims description 32
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 30
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 21
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 19
- 229910052742 iron Inorganic materials 0.000 claims description 19
- 239000001301 oxygen Substances 0.000 claims description 19
- 229910052760 oxygen Inorganic materials 0.000 claims description 19
- 239000001257 hydrogen Substances 0.000 claims description 18
- 229910052739 hydrogen Inorganic materials 0.000 claims description 18
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 16
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 15
- 239000000243 solution Substances 0.000 claims description 14
- 238000002484 cyclic voltammetry Methods 0.000 claims description 11
- 229910052697 platinum Inorganic materials 0.000 claims description 8
- 238000004140 cleaning Methods 0.000 claims description 7
- ZOMNIUBKTOKEHS-UHFFFAOYSA-L dimercury dichloride Chemical class Cl[Hg][Hg]Cl ZOMNIUBKTOKEHS-UHFFFAOYSA-L 0.000 claims description 7
- 239000003792 electrolyte Substances 0.000 claims description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 6
- 239000007772 electrode material Substances 0.000 claims description 6
- 239000003292 glue Substances 0.000 claims description 6
- 230000007547 defect Effects 0.000 claims description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 3
- 241000893313 Helochara delta Species 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 230000001351 cycling effect Effects 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- 238000010998 test method Methods 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 2
- 239000003822 epoxy resin Substances 0.000 claims description 2
- 229920000647 polyepoxide Polymers 0.000 claims description 2
- 238000004806 packaging method and process Methods 0.000 claims 1
- 238000013097 stability assessment Methods 0.000 claims 1
- 239000000446 fuel Substances 0.000 description 9
- 239000012085 test solution Substances 0.000 description 8
- 239000000463 material Substances 0.000 description 7
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 6
- 239000011737 fluorine Substances 0.000 description 5
- 229910052731 fluorine Inorganic materials 0.000 description 5
- 239000012528 membrane Substances 0.000 description 5
- 239000000758 substrate Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 239000012466 permeate Substances 0.000 description 3
- 238000007789 sealing Methods 0.000 description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 238000004364 calculation method Methods 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000005868 electrolysis reaction Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229910000510 noble metal Inorganic materials 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000011978 dissolution method Methods 0.000 description 1
- 238000006056 electrooxidation reaction Methods 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- UQSQSQZYBQSBJZ-UHFFFAOYSA-N fluorosulfonic acid Chemical compound OS(F)(=O)=O UQSQSQZYBQSBJZ-UHFFFAOYSA-N 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- TUJKJAMUKRIRHC-UHFFFAOYSA-N hydroxyl Chemical compound [OH] TUJKJAMUKRIRHC-UHFFFAOYSA-N 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
Images
Landscapes
- Testing Resistance To Weather, Investigating Materials By Mechanical Methods (AREA)
Abstract
Description
Claims (23)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201910016183.9A CN109856037B (zh) | 2019-01-08 | 2019-01-08 | 一种金属双极板长期稳定性的测定方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201910016183.9A CN109856037B (zh) | 2019-01-08 | 2019-01-08 | 一种金属双极板长期稳定性的测定方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN109856037A CN109856037A (zh) | 2019-06-07 |
CN109856037B true CN109856037B (zh) | 2021-09-10 |
Family
ID=66894140
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201910016183.9A Active CN109856037B (zh) | 2019-01-08 | 2019-01-08 | 一种金属双极板长期稳定性的测定方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN109856037B (zh) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111198154A (zh) * | 2020-01-08 | 2020-05-26 | 同济大学 | 一种燃料电池金属双极板连续腐蚀可视化测试装置 |
CN111257212B (zh) * | 2020-01-21 | 2021-03-26 | 同济大学 | 燃料电池金属双极板耐久性的恒电位加速测试与评价方法 |
CN111537817A (zh) * | 2020-05-09 | 2020-08-14 | 南京麦澜德医疗科技有限公司 | 一种电极老化寿命自动化测试工装及测试方法 |
CN112285013A (zh) * | 2020-09-28 | 2021-01-29 | 武汉船用电力推进装置研究所(中国船舶重工集团公司第七一二研究所) | 一种金属双极板涂层质量现场快速抽检方法 |
CN113740250B (zh) * | 2021-09-03 | 2023-07-25 | 北京格睿能源科技有限公司 | 一种金属双极板涂层结合力衰减程度的测量方法及装置 |
CN114414460A (zh) * | 2021-12-10 | 2022-04-29 | 安泰环境工程技术有限公司 | 金属双极板防腐性能检测系统及加速检测方法 |
CN114486714B (zh) * | 2022-01-19 | 2023-11-10 | 杭州新坐标科技股份有限公司 | 一种燃料电池金属双极板的梯形电位加速测试方法 |
CN114976135B (zh) * | 2022-05-11 | 2024-03-08 | 上海大学 | 一种汽车用氢燃料电池金属双极板及镀层耐蚀性测试系统及方法 |
Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5297951B2 (ja) * | 2009-09-04 | 2013-09-25 | 株式会社日立製作所 | 防食データ解析システム |
CN103913393A (zh) * | 2014-04-17 | 2014-07-09 | 南通大学 | 一种海洋工程用钢应力腐蚀开裂时间的快速推算方法 |
CN104215545A (zh) * | 2014-04-23 | 2014-12-17 | 超威电源有限公司 | 一种铅酸蓄电池板栅耐腐蚀性能测试方法 |
CN105223125A (zh) * | 2015-10-13 | 2016-01-06 | 哈尔滨工业大学 | 基于应力和结合强度演变机制的涂层寿命预测方法 |
CN107195909A (zh) * | 2017-05-31 | 2017-09-22 | 苏州邦华真空镀膜科技有限公司 | 一种燃料电池双极板及其表面钛金薄膜的制备方法 |
CN107192665A (zh) * | 2017-06-05 | 2017-09-22 | 中国石油大学(华东) | 多电极耦合的非均匀结构局部腐蚀的测试系统及方法 |
CN107478565A (zh) * | 2017-07-13 | 2017-12-15 | 河海大学 | 一种测量卤离子对金属钝化膜影响的循环极化方法 |
CN107478528A (zh) * | 2017-07-19 | 2017-12-15 | 暨南大学 | 一种可用于腐蚀磨损的测试方法 |
CN107884334A (zh) * | 2017-11-21 | 2018-04-06 | 北京市燃气集团有限责任公司 | 一种电偶腐蚀测试系统及其测试方法 |
CN108362636A (zh) * | 2017-12-29 | 2018-08-03 | 上海神力科技有限公司 | 一种燃料电池用双极板耐腐蚀性能测试方法 |
CN110684946A (zh) * | 2019-11-07 | 2020-01-14 | 中国科学院宁波材料技术与工程研究所 | 一种金属双极板高导电耐蚀防护涂层及其制备方法与应用 |
CN110823792A (zh) * | 2019-11-05 | 2020-02-21 | 南京钢铁股份有限公司 | 一种低合金耐蚀钢大气腐蚀的寿命评估方法 |
-
2019
- 2019-01-08 CN CN201910016183.9A patent/CN109856037B/zh active Active
Patent Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5297951B2 (ja) * | 2009-09-04 | 2013-09-25 | 株式会社日立製作所 | 防食データ解析システム |
CN103913393A (zh) * | 2014-04-17 | 2014-07-09 | 南通大学 | 一种海洋工程用钢应力腐蚀开裂时间的快速推算方法 |
CN104215545A (zh) * | 2014-04-23 | 2014-12-17 | 超威电源有限公司 | 一种铅酸蓄电池板栅耐腐蚀性能测试方法 |
CN105223125A (zh) * | 2015-10-13 | 2016-01-06 | 哈尔滨工业大学 | 基于应力和结合强度演变机制的涂层寿命预测方法 |
CN107195909A (zh) * | 2017-05-31 | 2017-09-22 | 苏州邦华真空镀膜科技有限公司 | 一种燃料电池双极板及其表面钛金薄膜的制备方法 |
CN107192665A (zh) * | 2017-06-05 | 2017-09-22 | 中国石油大学(华东) | 多电极耦合的非均匀结构局部腐蚀的测试系统及方法 |
CN107478565A (zh) * | 2017-07-13 | 2017-12-15 | 河海大学 | 一种测量卤离子对金属钝化膜影响的循环极化方法 |
CN107478528A (zh) * | 2017-07-19 | 2017-12-15 | 暨南大学 | 一种可用于腐蚀磨损的测试方法 |
CN107884334A (zh) * | 2017-11-21 | 2018-04-06 | 北京市燃气集团有限责任公司 | 一种电偶腐蚀测试系统及其测试方法 |
CN108362636A (zh) * | 2017-12-29 | 2018-08-03 | 上海神力科技有限公司 | 一种燃料电池用双极板耐腐蚀性能测试方法 |
CN110823792A (zh) * | 2019-11-05 | 2020-02-21 | 南京钢铁股份有限公司 | 一种低合金耐蚀钢大气腐蚀的寿命评估方法 |
CN110684946A (zh) * | 2019-11-07 | 2020-01-14 | 中国科学院宁波材料技术与工程研究所 | 一种金属双极板高导电耐蚀防护涂层及其制备方法与应用 |
Non-Patent Citations (2)
Title |
---|
Bipolar plates for PEM fuel cells - From materials to processing;Xiao-Zi Yuan 等;《Journal of New Materials for Electrochemical Systems》;20051231;全文 * |
质子交换膜燃料电池金属双极板材料腐蚀性能研究;王东等;《复旦大学(自然科学版)》;20040831;第43卷(第4期);全文 * |
Also Published As
Publication number | Publication date |
---|---|
CN109856037A (zh) | 2019-06-07 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN109856037B (zh) | 一种金属双极板长期稳定性的测定方法 | |
Langemann et al. | Validation and characterization of suitable materials for bipolar plates in PEM water electrolysis | |
Yang et al. | Influence of fluoride ions on corrosion performance of 316L stainless steel as bipolar plate material in simulated PEMFC anode environments | |
CN112798513A (zh) | 一种质子交换膜燃料电池金属双极板耐久性加速测试方法 | |
CN114137044B (zh) | 一种海水环境下有机涂层防护性能的现场监测电化学方法 | |
CN108362636B (zh) | 一种燃料电池用双极板耐腐蚀性能测试方法 | |
Cecchetti et al. | Local potential measurement through reference electrodes in vanadium redox flow batteries: Evaluation of overpotentials and electrolytes imbalance | |
Leng et al. | A comparative study of corrosion resistance evaluation of bipolar plate materials for proton exchange membrane fuel cell | |
CN109033614B (zh) | 基于电极反应预测阀冷系统均压电极垢层厚度的方法 | |
CN109596511A (zh) | 燃料电池双极板耐蚀性测试方法 | |
Becker et al. | Assessing potential profiles in water electrolysers to minimise titanium use | |
Reimer et al. | Time Dependence of the Open Circuit Potential of Platinum Disk Electrodes in Half Cell Experiments | |
Seri et al. | Differentiating polarization curve technique for determining the exchange current density of hydrogen electrode reaction | |
Meng et al. | Electrochemical evaluation technologies of organic coatings | |
Creel et al. | Protocol for screening water oxidation or reduction electrocatalyst activity in a three-electrode cell for alkaline exchange membrane electrolysis | |
Okonkwo et al. | Potentiodynamic polarization test as a versatile tool for bipolar plates materials at start-up and shut-down environments: a review | |
CN107039668B (zh) | 一种质子交换膜燃料电池气体扩散层耐久性加速测试方法 | |
Arjmand et al. | Solution resistivity, ohmic drop and oxygen reduction rate at high temperature pressurized water | |
El-Sherbini et al. | Electrochemical behaviour of lead electrode in Na2SO4 solutions | |
Wang et al. | Tungsten diffusion modified AISI 304 stainless steel for PEMFC bipolar plate | |
CN114018797A (zh) | 一种燃料电池金属双极板涂层的耐蚀性测试方法 | |
Chen et al. | A synchronous investigation of the degradation of metallic bipolar plates in real and simulated environments of polymer electrolyte membrane fuel cells | |
Li et al. | Effects of catalyst layer and gas diffusion layer thickness on the performance of activated carbon air-cathode for microbial fuel cells | |
JP4280168B2 (ja) | 燃料電池セパレーター用金属材料の耐食性評価方法 | |
CN112285013A (zh) | 一种金属双极板涂层质量现场快速抽检方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A method for determining the long-term stability of metal bipolar plates Effective date of registration: 20230405 Granted publication date: 20210910 Pledgee: Hangzhou Bank Co.,Ltd. Jiaxing Pinghu Branch Pledgor: ZHEJIANG FENGYUAN HYDROGEN ENERGY TECHNOLOGY Co.,Ltd. Registration number: Y2023330000690 |
|
PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
PC01 | Cancellation of the registration of the contract for pledge of patent right |
Granted publication date: 20210910 Pledgee: Hangzhou Bank Co.,Ltd. Jiaxing Pinghu Branch Pledgor: ZHEJIANG FENGYUAN HYDROGEN ENERGY TECHNOLOGY Co.,Ltd. Registration number: Y2023330000690 |